SAFETY DATA SHEET IDENTITY:
InjectPro-SuperFast: Component-A
Date prepared: Date revised:
SDS No. I.SF.1
MAY 2015 MARCH 2019
Section 1 – Product Identification IDENTITY:
InjectPro-SuperFast Component-A
Product Name:
Product Use Description:
Polyurethane Injection Grout
AQUAFIN, INC. 505 BLUE BALL RD. #160 ELKTON, MD 21921
24 hr Emergency Phone: Chem-Tel (800) 255-3924 Information Phone No.
(410) 392-2300
www.aquafin.net info@aquafin.net
Recommended use of the chemical and restriction on use:
Refer to the product technical data sheet. For industrial and professional users.
Section 2 – Hazards Identification GHS Classification: Skin irritation, Category 2 Skin sensitization, Category 1 Eye irritation, Category 2A Acute toxicity, inhalation, Category 4 Sensitization, respiratory, Category 1 Respiratory tract irritation, Category 3 Specific target organ toxicity, repeated exposure, Category 2
= H315. = H317. = H319. = H332. = H334. = H335. = H373.
GHS Label element: Hazard Pictograms GHS07
GHS08
Signal Word:
Danger
Hazard Statements: H315: H317: H319: H332: H334: H335: H360: H373:
Causes skin irritation. May cause an allergic skin reaction. Causes serious eye irritation. Harmful if inhaled. May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause respiratory irritation. May damage fertility or the unborn child. May cause damage to respiratory system through prolonged or repeated exposure.
Precautionary Statements: Prevention: P102: Keep out of reach of children. P260: Do not breathe mist, vapours or spray. P264: Wash skin thoroughly after handling. P270: Do not eat, drink or smoke when using this product. P271: Use only outdoors or in a well-ventilated area. P280: Wear protective gloves/protective clothing/eye protection/face protection. P285: In case of inadequate ventilation wear respiratory protection. Page 1 of 6
InjectPro-Superfast Component-A
Response: P302 + P352: P333 + P313: P362: P304 + P340:
P337 + P313 P308 + P313:
Wash with plenty of soap and water. IF SKIN irritation or rash occurs: Get medical attention. Take off contaminated clothing and wash before reuse. IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. If experiencing respiratory symptoms: call a POISON CENTER or physician. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF eye irritation persists, get medical advice/attention. IF exposed or concerned, get medical advice.
Storage: P403 + P410: P405:
Store in a well-ventilated place. Protect from sunlight. Store locked up.
Disposal: P501:
Dispose of contents/container to an approved waste disposal site.
P342 + P311: P305 + P351 + P338:
IF ON SKIN:
Section 3 – Composition / Information on Hazardous Ingredients Component: Diphenylmethane 4,4’-diisocyanate Polymeric diphenylmethane diisocyanate
CAS No. 101-68-8 9016-87-9
% (Weight) 30 - 60 30 - 60
Note: There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section.
Section 4 – First Aid Measures Inhalation:
Supply fresh air and consult a physician if breathing becomes difficult. Symptoms may be delayed for several hours.
Ingestion:
If person is conscious, wash out mouth with water. Do not induce vomiting unless instructed to do so by a poison center or physician.
Skin Contact:
Immediately flush skin with plenty of water. Do not use solvents or thinners. Remove contaminated clothing and shoes. Seek medical advice if irritation or rash occurs. Wash clothing before reuse.
Eye Contact:
Immediately flush eyes with plenty of water for at least 15 minutes, lifting upper and lower eyelids occasionally. Remove contact lenses, if present. Seek medical attention if irritation persists.
Section 5 – Fire Fighting Measures Extinguishing Media:
Water fog, foam, dry chemical or carbon dioxide.
Fire Fighting Procedures:
Standard. As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Containers can build up pressure if exposed to heat (fire). Cool with water spray. Do not scatter material with high pressure water streams. Page 2 of 6
Hazardous Combustion Products:
Carbon oxides, nitrogen oxides, isocyanates and trace amounts of hydrogen cyanide.
Unusual Fire and Explosion Hazards: Water contamination produces carbon dioxide gas. This may cause pressurization or explosion of containers.
Section 6 – Accidental Release Measures Person-related Safety Precautions:
Provide plenty of fresh air. Avoid eye and skin contact. Avoid inhalation of vapors. Wear personal protective equipment. Remove or eliminate all ignition sources.
Methods for cleaning-up:
Prevent from entering into soil, ditches, sewers, waterways and/or groundwater. Small spills: Absorb with dry chemical absorbent, earth, sand or any other inert material. Allow to stand uncovered for 48 hrs. before closing container. Large spills: Create a dike or trench to contain product. Follow same procedure as for a small spill. Clean spill area with a decontamination solution. Suggested formulation: Sodium carbonate (5-10%), liquid detergent (1-2%), water (88-94%). Alternate formulation: Concentrated ammonia (3-8%), liquid detergent (1-2%), water (90-96%). Ensure adequate ventilation to prevent overexposure of ammonia.
Waste Disposal Method:
Dispose in accordance with local, state and federal regulations.
Ecological Information:
Do not allow product to reach ground water, bodies of water, or storm water or sewage systems.
Section 7 – Handling and Storage Handling:
Avoid contact with eyes, skin and clothing. Wash thoroughly after handling. Follow all SDS/label precautions even after the container is emptied because it may retain product residues. Use only with adequate ventilation. Keep container closed when not in use. Do not reseal if contaminated. Keep away from heat and flame.
Storage:
Keep container tightly closed when not in use. Do not store in direct sunlight.
Storage Temperature:
4oC – 32oC (~40oF - ~90oF).
Section 8 – Exposure Controls / Personal Protection Exposure Limits: COMPONENT Diphenylmethane 4,4’-diisocyanate
CAS NUMBER 101-68-8
OSHA/PEL 0.02 ppm (Ceiling) 0.20 mg/m3 (Ceiling)
ACGIH/TLV 0.005 ppm 0.051 mg/m3
Engineering Controls:
Use adequate ventilation.
Respiratory Protection:
Use local exhaust ventilation. For airborne exposure above exposure limit(s), wear a NIOSH approved air-purifying respirator equipped with organic vapor cartridges. For situations where the atmospheric levels may exceed the level for which an air-purifying respirator is effective, use a positive-pressure air-supplying respirator. Page 3 of 6
Skin Protection:
Wear chemical resistant protective clothing and footwear impervious to the product if there is a potential for skin contact.
Hand Protection:
Glove(s): neoprene.
Eye Protection:
Use safety goggles or face shield.
Other Protective Equipment: A safety shower and eye wash fountain should be readily available. Work/Hygienic Practices:
Wash hands before breaks and after work, and before eating, drinking or smoking.
Section 9 – Physical and Chemical Properties Physical state: Color: Odor: Solubility in water: Boiling point: Flash point: Vapor Pressure: Flammability: Specific Gravity (water = 1) at 25oC: Viscosity, (kinematic) at 25oC: Auto ignition Temperature: Lower explosion Limit: Upper explosion Limit:
Liquid Brown Slightly musty Insoluble, reacts with water No data >93°C (>200°F) (closed cup) <0.0001 mmHg at 25oC (77OF) No data 1.22 – 1.24 g/cm3 200 - 300 cps No data available No data available No data available
Section 10 – Stability and Reactivity Stability:
Stable.
Hazardous Decomposition Products: Carbon oxides, nitrogen oxides, isocyanides and trace amounts of hydrogen cyanide. Hazardous Polymerization:
Can be caused by elevated temperatures.
Incompatibilities:
This product will react with any materials containing active hydrogens such as water, alcohol, amines, bases and acids. The reaction with water is very slow under 50oC (122oF), but is accelerated at higher temperatures.
Section 11 – Toxicological Information Acute toxicity: Diphenylmethane 4,4’-diisocyanate
Dermal: Oral: Inhalation:
LD50 LD50 LC50
Carcinogenity: IARC: Not regulated as a carcinogen. NTP:
Not regulated as a carcinogen.
OSHA: Not regulated as a carcinogen.
Section 12 – Ecological Information Page 4 of 6
>9400 mg/kg (rabbit). >10000 mg/kg (rat). 0.49 mg/L/4 h (rat) (respirable aerosol).
Ecotoxicological Information: MDI: LC50 >500 mg/L/96h (zebra fish). EC50 >500 mg/L/24 h (daphnia magna).
Section 13 – Disposal Considerations Product waste:
Must be disposed of in a manner consistent with federal, state and local regulations.
Empty Container:
when cartridge is empty dispose with trash.
RCRA/EPA Waste Information: If discarded in its purchased form, this material is not a RCRA hazardous waste.
Section 14 – Transport Information USDOT (Domestic Surface):
Not regulated
IMO (Ocean):
IATA/ICAO (Air):
Section 15 – Regulatory Information TSCA (Toxic Substances Control Act): RCRA Status:
All components are on TSCA inventory.
If discarded in its purchased form, this material is not a RCRA hazardous waste.
US Federal Regulatory Information: SARA Title III (Superfund Amendments and Reauthorization Act: 311/312 Hazard Categories:
Acute, Chronic, Reactive.
313 Reportable Components: Component
CAS NUMBER
Diphenylmethane 4,4’-diisocyanate (Category Diisocyanate Compounds)
101-68-8
Polymeric diphenylmethane diisocyanate (Category Diisocyanate Compounds)
9016-87-9
CERCLA (Comprehensive Environmental Response and Liability Act) Component Diphenylmethane 4,4’-diisocyanate
National Response Center:
RQ (lbs) 5000
Any spill or release to the environment above RQ must be reported to the National Response Center (800-424-8802).
Section 16 – Other Information Abbreviations and acronyms: USDOT: IMDG: IATA: CAS: LC50:
United States Department of Transportation. International Maritime Code for Dangerous Goods. International Air Transport Association. Chemical Abstracts Service (Division of the American Chemical Society). Lethal concentration, 50 percent. Page 5 of 6
SAFETY DATA SHEET IDENTITY: LD50: EC50: RQ:
Lethal dose, 50 percent. Median effective concentration. Reportable quantity.
SDS prepared by:
Aquafin product safety department.
DISCLAIMER: We believe the statements, technical information and recommendations contained herein are reliable, but they are given without warranty or guarantee of any kind, expressed or implied, and we assume no responsibility for any loss, damage, or expense, direct or consequential, arising out of their use. Aquafin shall not be responsible for the use of this product in a manner to infringe on any patent or any other intellectual property rights held by others. User is responsible for determining appropriate safety measures and for applying the legislation covering his own activities. We recommend that user makes tests to determine the suitability of a product for its particular purpose prior to use. END OF SDS
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(March 21, 2019)