SDS_AQUAFIN-Waterstop-Gun Grade_031319.pdf
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<h1>SDS_AQUAFIN-Waterstop-Gun Grade_031319.pdf</h1> <p>IDENTITY:</p> <p>SAFETY DATA SHEET</p> <p>WATERSTOP–Gun Grade</p> <p>Date prepared: <br />Date revised:</p> <p>SDS No. 1.1</p> <p>AUGUST 2017 <br />FEBRUARY 2019</p> <p>SDS No. 1.1</p> <p>Section 1 – Product Identification <br />IDENTITY:</p> <p>Product Name: <br />Product Use Description:</p> <p>Waterstop-Gun Grade</p> <p>Sealing Strip</p> <p>AQUAFIN, INC. <br />505 BLUE BALL RD. #160 <br />ELKTON, MD 21921</p> <p>24 hr Emergency Phone: Chem-Tel (800) 255-3924</p> <p>Recommended use of the chemical and restriction on use:</p> <p>Refer to the product technical data sheet. <br />For industrial and professional users.</p> <p>Information Phone No.</p> <p>(410) 392-2300</p> <p>www.aquafin.net info@aquafin.net</p> <p>Section 2 – Hazards Identification <br />GHS Classification: <br />Resp. Sens. 1 H334 <br />Carc. 2 <br />H351 <br />Skin Sens. 1 <br />H317</p> <p>May cause allergy or asthma symptoms or breathing difficulties if inhaled. <br />Suspected of causing cancer. <br />May cause an allergic skin reaction.</p> <p>GHS Label element: <br />Hazard Pictograms <br />GHS07</p> <p>GHS08</p> <p>Signal Word:</p> <p>Danger</p> <p>Hazard Statements: <br />H317: <br />H334: <br />H351</p> <p>May cause an allergic skin reaction. <br />May cause allergy or asthma symptoms or breathing difficulties if inhaled. <br />Suspected of causing cancer.</p> <p>Precautionary Statements: <br />Prevention: <br />P102: <br />Keep out of reach of children. <br />P202: <br />Do not handle until all safety precautions have been read and understood <br />P261: <br />Avoid breathing dust/fume/gas/mist/vapors/spray <br />P272: <br />Contaminated work clothing should not be allowed out of the workplace <br />P280: <br />Wear protective gloves/protective clothing/eye protection/face protection. <br />P285: <br />In case of inadequate ventilation wear respiratory protection. <br />Response: <br />P302 + P352: <br />IF ON SKIN: <br />Wash with plenty of soap and water. <br />P333 + P313: <br />IF SKIN irritation or rash occurs: Get medical attention. <br />P362: <br />Take off contaminated clothing and wash before reuse. <br />P304 + P340: <br />IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable <br />for breathing. <br />P342 + P311: <br />If experiencing respiratory symptoms: call a POISON CENTER or <br />physician. <br />Storage: <br />P405: <br />Store locked up.</p> <p>Page 1 of 5</p> <p>IDENTITY:</p> <p>SAFETY DATA SHEET</p> <p>WATERSTOP–Gun Grade</p> <p>Disposal: <br />P501:</p> <p>SDS No. 1.1</p> <p>Dispose of contents/container in accordance with local/regional/national/international <br />regulations.</p> <p>Section 3 – Composition / Information on Hazardous Ingredients <br />Component: <br />propylene carbonate <br />diphenylmethanediisocyanate, isomeres and homologues</p> <p>CAS No. <br />108-32-7 <br />9016-87-9</p> <p>% (Weight) <br />≤ 2.5% <br />≤ 2.5%</p> <p>Note: There are no additional ingredients present which, within the current knowledge of the supplier and in the <br />concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this <br />section.</p> <p>Section 4 – First Aid Measures <br />Inhalation:</p> <p>Supply fresh air and consult a physician in case of complaints.</p> <p>Skin Contact:</p> <p>Generally the product does not irritate the skin.</p> <p>Eye Contact:</p> <p>Immediately flush eyes with plenty of water for at least 15 minutes, lifting upper and <br />lower eyelids occasionally. Remove contact lenses, if present. Seek medical attention <br />if irritation persists.</p> <p>After swallowing:</p> <p>If symptoms persist consult doctor.</p> <p>Section 5 – Fire Fighting Measures <br />Extinguishing Media:</p> <p>Use water fog, foam, dry chemical or carbon dioxide.</p> <p>Fire Fighting Procedures:</p> <p>Standard. As in any fire, wear self-contained breathing apparatus <br />pressure-demand, MSHA/NIOSH (approved or equivalent) and full <br />protective gear. Containers can build up pressure if exposed to heat <br />(fire). Cool with water spray. Do not scatter material with high <br />pressure water streams.</p> <p>Section 6 – Accidental Release Measures <br />Person-related Safety Precautions:</p> <p>Provide plenty of fresh air. Avoid eye and skin contact. Avoid <br />inhalation of vapors. Wear personal protective equipment.</p> <p>Methods for cleaning-up:</p> <p>Dispose contaminated material as waste according to item 13. Ensure <br />adequate ventilation</p> <p>Waste Disposal Method:</p> <p>Dispose in accordance with local, state and federal regulations.</p> <p>Ecological Information:</p> <p>Do not allow product to reach ground water, bodies of water, or storm <br />water or sewage systems. Inform respective authorities in case of <br />seepage into water course or sewage system.</p> <p>Page 2 of 5</p> <p>IDENTITY:</p> <p>SAFETY DATA SHEET</p> <p>WATERSTOP–Gun Grade</p> <p>SDS No. 1.1</p> <p>Section 7 – Handling and Storage <br />Handling:</p> <p>Ensure good ventilation/exhaustion at the workplace. Prevent <br />formation of dust. <br />Protect from heat. Protect against electrostatic charges.</p> <p>Explosions and fires: <br />Storage:</p> <p>Protect from heat and direct sunlight.</p> <p>Storage Temperature:</p> <p>~40 F - ~90 F (4 C – 32 C).</p> <p>o</p> <p>o</p> <p>o</p> <p>o</p> <p>Section 8 – Exposure Controls / Personal Protection <br />Exposure Limits: <br />COMPONENT <br />propylene carbonate</p> <p>CAS NUMBER <br />108-32-7</p> <p>OSHA/PEL <br />0.05 ppm</p> <p>ACGIH/TLV <br />0.05 ppm</p> <p>Diphenylmethanediisocyanate, <br />isomeres and homologues</p> <p>9016-87-9</p> <p>0.02 ppm (Ceiling)</p> <p>0.005 ppm</p> <p>Engineering Controls:</p> <p>Use adequate ventilation.</p> <p>Respiratory Protection:</p> <p>In case of brief exposure or low pollution use respiratory filter device. In case of <br />intensive or longer exposure use respiratory protective device that is independent <br />of circulating air.</p> <p>Skin Protection:</p> <p>Wear chemical resistant protective clothing and footwear impervious to the <br />product if there is a potential for skin contact.</p> <p>Hand Protection:</p> <p>Gloves: Neoprene or a glove material that is impermeable and resistant to the <br />product/ the substance/ the preparation.</p> <p>Eye Protection:</p> <p>Not required.</p> <p>Work/Hygienic Practices:</p> <p>Keep away from foodstuffs, beverages and feed. Wash hands before breaks and <br />at the end of work</p> <p>Section 9 – Physical and Chemical Properties <br />Physical state: <br />Color: <br />Odor: <br />Solubility in water: <br />Boiling point: <br />Flash point: <br />Vapor Pressure: <br />Flammability: <br />o <br />Viscosity, (kinematic) at 25 C: <br />Auto ignition Temperature: <br />Lower explosion Limit: <br />Upper explosion Limit: <br />Solvent content: <br />Organic solvents: <br />VOC content: <br />Solids content:</p> <p>Pasty <br />Light gray <br />Slightly musty <br />Insoluble <br />No data <br />Not applicable <br />Not applicable <br />No data <br />Not applicable <br />Product is not self-igniting <br />Product does not present an explosion hazard <br />Product does not present an explosion hazard <br />2.0 % <br />2.0 % 0.0 g/l / 0.00 lb/gl <br />100.0 % <br />Page 3 of 5</p> <p>IDENTITY:</p> <p>SAFETY DATA SHEET</p> <p>WATERSTOP–Gun Grade</p> <p>SDS No. 1.1</p> <p>Section 10 – Stability and Reactivity <br />Reactivity:</p> <p>No dangerous reactions known under conditions of normal use.</p> <p>Hazardous Decomposition Products: No dangerous decomposition products known. <br />Chemical Stability:</p> <p>Stable under normal temperatures and pressures.</p> <p>Conditions To Avoid:</p> <p>No further relevant information available.</p> <p>Incompatibilities:</p> <p>No further relevant information available.</p> <p>Section 11 – Toxicological Information <br />Acute toxicity: <br />Hydrocarbons, C10-12, <br />iso-alkanes, < 2% aromatics <br />diphenylmethanediisocyanate, <br />isomeres and homologues</p> <p>Dermal: <br />Oral:</p> <p>LD50 <br />LD50</p> <p>Dermal: <br />LD50 <br />Oral: <br />LD50 <br />Inhalation: LC50/4 h</p> <p>Primary irritant effect: <br />On the skin: <br />No irritant effect. <br />On the eye: <br />No irritating effect. <br />Sensitization: Sensitization possible through inhalation.</p> <p>>3160 mg/kg (rabbit) <br />>15,000 mg/kg (rat). <br />>9,400 mg/kg (rabbit) <br />>10 000 mg/kg (rat) <br />.49 mg/l (rat)</p> <p>Additional toxicological information: <br />The product shows the following dangers according to internally approved calculation methods for <br />preparations: Harmful <br />Carcinogenity: <br />IARC: 9016-87-9 diphenylmethanediisocyanate, isomeres and homologues <br />NTP: None of the ingredients is listed. <br />OSHA: None of the ingredients is listed.</p> <p>Section 12 – Ecological Information <br />Ecotoxicological Information: <br />MDI:</p> <p>EC50/24h <br />EC50/96h <br />EC50/72h</p> <p>>1,000 mg/l (daphnia) <br />>1,000 mg/l (fish) <br />>1,640 mg/l (algae)</p> <p>Remark: <br />Harmful to fish <br />General notes: Water hazard class 1 (Self-assessment): slightly hazardous for water. <br />Do not allow undiluted product or large quantities of it to reach ground water, water course or <br />sewage system. <br />Harmful to aquatic organisms.</p> <p>Section 13 – Disposal Considerations</p> <p>Page 4 of 5</p> <p>IDENTITY:</p> <p>SAFETY DATA SHEET</p> <p>WATERSTOP–Gun Grade</p> <p>SDS No. 1.1</p> <p>Product waste: <br />Must not be disposed of together with household garbage. Do not allow product to <br />reach sewage system. <br />Packaging waste:</p> <p>Disposal must be made according to official regulations.</p> <p>Section 14 – Transport Information <br />USDOT (Domestic Surface): <br />IMO (Ocean): <br />IATA/ICAO (Air):</p> <p>Not regulated when shipped below regulated quantity (RQ). <br />Not regulated <br />Not regulated</p> <p>Section 15 – Regulatory Information <br />TSCA (Toxic Substances Control Act): <br />All components are on TSCA inventory. <br />RCRA Status: <br />If discarded in its purchased form, this material is not a RCRA hazardous waste. <br />US Federal Regulatory Information:</p> <p>SARA Title III (Superfund Amendments and Reauthorization Act: <br />313 Reportable Components: <br />Component</p> <p>CAS NUMBER</p> <p>Diphenylmethanediisocyanate, isomeres and homologues</p> <p>9016-87-9</p> <p>National Response Center:</p> <p>Any spill or release to the environment above RQ must be reported to the <br />National Response Center (800-424-8802).</p> <p>Proposition 65:</p> <p>Chemicals known to cause cancer, or reproductive toxicity for females or <br />males, or developmental toxicity: None of the ingredients is listed.</p> <p>Carcinogenic categories: <br />EPA (Environmental Protection Agency): 9016-87-9 diphenylmethanediisocyanate, isomeres and homologues <br />TLV and NIOSH-Ca: <br />None of the ingredients is listed.</p> <p>Section 16 – Other Information <br />Abbreviations and acronyms: <br />USDOT: <br />IMDG: <br />IATA: <br />CAS: <br />LC50: <br />LD50: <br />EC50: <br />RQ:</p> <p>United States Department of Transportation. <br />International Maritime Code for Dangerous Goods. <br />International Air Transport Association. <br />Chemical Abstracts Service (Division of the American Chemical Society). <br />Lethal concentration, 50 percent. <br />Lethal dose, 50 percent. <br />Median effective concentration. <br />Reportable quantity.</p> <p>SDS prepared by:</p> <p>Aquafin product safety department.</p> <p>DISCLAIMER:</p> <p>We believe the statements, technical information and recommendations contained herein are reliable, but they are given <br />without warranty or guarantee of any kind, expressed or implied, and we assume no responsibility for any loss, damage, or <br />expense, direct or consequential, arising out of their use. Aquafin shall not be responsible for the use of this product in a <br />manner to infringe on any patent or any other intellectual property rights held by others. <br />User is responsible for determining appropriate safety measures and for applying the legislation covering his own activities. <br />We recommend that user makes tests to determine the suitability of a product for its particular purpose prior to use. <br />END OF SDS</p> <p>(February 13, 2019) <br />Page 5 of 5</p>
