SDS_AQUAFIN-PRO-Tekt TOPCOAT_A-Component-Poly.pdf
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<h1>SDS_AQUAFIN-PRO-Tekt TOPCOAT_A-Component-Poly.pdf</h1> <p>SAFETY DATA SHEET</p> <p>IDENTITY: PRO-Tekt Topcoat, Component A</p> <p>SDS No. PRO T.3.1</p> <p>Date prepared: MARCH 2017 <br />Date revised: FEBRUARY 2019</p> <p>SDS No. PRO T.3.1</p> <p>Section 1 – Product Identification <br />IDENTITY: Product Name:</p> <p>PRO-TEKT TOPCOAT, Component A</p> <p>AQUAFIN, INC. <br />505 BLUE BALL RD. #160 <br />ELKTON, MD 21921</p> <p>Emergency Phone No. <br />Information Phone No.</p> <p>info@aquafin.net</p> <p>Recommended use of the chemical and restriction on use:</p> <p>(800) 394-1410 <br />(410) 392-2300</p> <p>www.aquafin.net</p> <p>Refer to the product technical data sheet. <br />For industrial and professional users.</p> <p>Section 2 – Hazards Identification <br />GHS Classification: <br />This material is hazardous under the criteria of the Federal OSHA Hazard Communication Standard 29CFR <br />1910.1200. <br />Skin sensitization - Category 1</p> <p>GHS Label</p> <p>element:</p> <p>Hazard Pictograms <br />GHS07 <br />Signal Word:</p> <p>WARNING!</p> <p>Hazard Statements: <br />H317 <br />May cause an allergic skin reaction. <br />Precautionary Statements: <br />Prevention: <br />P201 <br />Obtain special instructions before use. <br />P202 <br />Do not handle until all safety precautions have been read and understood. <br />P261 <br />Avoid breathing dust/ fume/ gas/ mist/ vapors/ spray. <br />P272 <br />Contaminated work clothing should not be allowed out of the workplace. <br />P280 <br />Wear protective gloves/ protective clothing/ eye protection/ face protection. <br />Response: <br />P302+352 <br />P333+313 <br />P363</p> <p>IF ON SKIN: Wash with plenty of soap and water. <br />If skin irritation or rash occurs: Get medical advice/ attention. <br />Wash contaminated clothing before reuse.</p> <p>Disposal: <br />P501:</p> <p>Dispose of contents/container to an approved waste disposal site.</p> <p>Other hazards:</p> <p>No data available.</p> <p>Section 3 – Composition / Information on Ingredients <br />Chemical nature: mixture. <br />Page 1 of 9</p> <p>SAFETY DATA SHEET</p> <p>IDENTITY: PRO-Tekt Topcoat, Component <br />Hazardous Components <br />Aspartic acid, N,N'-(methylenedi-4, <br />1-cyclohexanediyl)bis-, tetraethyl ester <br />2-Butenedioic acid(E)-diethylester</p> <p>SDS No. PRO T.3.1 <br />CAS No.</p> <p>Weight %</p> <p>136210-30-5</p> <p>>= 60.0 - <= 100.0 %</p> <p>623-91-6</p> <p>>= 1.0 - <= 5.0 %</p> <p>There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations <br />applicable, are classified as hazardous to health or the environment and hence not require reporting in this section.</p> <p>Section 4 – First Aid Measures <br />General Advice:</p> <p>First Aid responders should pay attention to self-protection and use the recommended <br />protective clothing (chemical resistant gloves, splash protection). If potential for <br />exposure exists refer to Section 8 for specific personal protective equipment.</p> <p>After Inhalation:</p> <p>Move person to fresh air. If effects occur, consult a physician.</p> <p>After Skin Contact:</p> <p>Remove material from skin immediately by washing with soap and plenty of water. <br />Remove contaminated clothing and shoes while washing. Seek medical attention if <br />irritation persists. Wash clothing before reuse. Discard items which cannot be <br />decontaminated, including leather articles such as shoes, belts and watchbands.</p> <p>After Eye Contact:</p> <p>Flush eyes thoroughly with water for several minutes. Remove contact lenses after the <br />initial 1-2 minutes and continue flushing for several additional minutes. If effects occur, <br />consult a physician, preferably an ophthalmologist.</p> <p>After Ingestion:</p> <p>If swallowed, seek medical attention. Do not induce vomiting unless directed to do so <br />by medical personnel.</p> <p>Most important symptoms and effects, both acute and delayed: Aside from the information found under <br />Description of first aid measures (above) and Indication of immediate medical attention and special treatment <br />needed (below), any additional important symptoms and effects are described in Section 11: Toxicology <br />Information. <br />Indication of any immediate medical attention and special treatment needed <br />Notes to physician: No specific antidote. Treatment of exposure should be directed at the control of symptoms <br />and the clinical condition of the patient.</p> <p>Section 5 – Fire Fighting Measures <br />Suitable Extinguishing Media: Water fog or fine spray. Dry chemical fire extinguishers. Carbon dioxide fire <br />extinguishers. Foam. Do not use direct water stream. May spread fire. General purpose synthetic foams <br />(including AFFF type) or protein foams are preferred if available. Alcohol resistant foams (ATC type) may <br />function. Water fog, applied gently may be used as a blanket for fire extinguishment. <br />Unsuitable extinguishing media: Do not use direct water stream. May spread fire. <br />Special hazards arising from the substance or mixture: <br />Hazardous combustion products: During a fire, smoke may contain the original material in addition to <br />combustion products of varying composition which may be toxic and/or irritating. Combustion products may <br />include and are not limited to: Nitrogen oxides. Hydrogen cyanide. Carbon monoxide. Carbon dioxide. <br />Page 2 of 9</p> <p>IDENTITY: PRO-Tekt Topcoat, Component A</p> <p>SAFETY DATA SHEET <br />SDS No. PRO T.3.1</p> <p>Unusual Fire and Explosion Hazards: Violent steam generation or eruption may occur upon application of <br />direct water stream to hot liquids. <br />Advice for firefighters <br />Fire Fighting Procedures: Keep people away. Isolate fire and deny unnecessary entry. Do not use direct <br />water stream. May spread fire. Burning liquids may be moved by flushing with water to protect personnel and <br />minimize property damage. Water fog, applied gently may be used as a blanket for fire extinguishment. <br />Contain fire water run-off if possible. Fire water run-off, if not contained, may cause environmental damage. <br />Review the "Accidental Release Measures" and the "Ecological Information" sections of this (M)SDS. <br />Special protective equipment for firefighters: Wear positive-pressure self-contained breathing apparatus <br />(SCBA) and protective fire fighting clothing (includes fire fighting helmet, coat, trousers, boots, and gloves). If <br />protective equipment is not available or not used, fight fire from a protected location or safe distance.</p> <p>Section 6 – Accidental Release Measures <br />Personal precautions, protective equipment and emergency procedures: Isolate area. Keep unnecessary <br />and unprotected personnel from entering the area. Refer to section 7, Handling, for additional precautionary <br />measures. No smoking in area. Use appropriate safety equipment. For additional information, refer to Section <br />8, Exposure Controls and Personal Protection. <br />Environmental precautions: Prevent from entering into soil, ditches, sewers, waterways and/or groundwater. <br />See Section 12, Ecological Information. Spills or discharge to natural waterways is likely to kill aquatic <br />organisms. <br />Methods and materials for containment and cleaning up: Contain spilled material if possible. Collect in <br />suitable and properly labeled containers. See Section 13, Disposal Considerations, for additional information.</p> <p>Section 7 – Handling and Storage <br />Precautions for safe handling: Avoid prolonged or repeated contact with skin. Avoid contact with eyes. Wash <br />thoroughly after handling. See Section 8, EXPOSURE CONTROLS AND PERSONAL PROTECTION. <br />Conditions for safe storage: Store in accordance with good manufacturing practices.</p> <p>Section 8 – Exposure Controls / Personal Protection <br />Control parameters <br />Exposure limits are listed below, if they exist. <br />Exposure limits have not been established for those substances listed in the composition, if any have been <br />disclosed. <br />Exposure controls: <br />Engineering controls: Use local exhaust ventilation, or other engineering controls to maintain airborne levels <br />below exposure limit requirements or guidelines. If there are no applicable exposure limit requirements or <br />guidelines, general ventilation should be sufficient for most operations. Local exhaust ventilation may be <br />necessary for some operations. <br />Individual protection measures: <br />Eye/face protection: Use safety glasses (with side shields). <br />Skin protection: <br />Hand protection: Use gloves chemically resistant to this material.</p> <p>Page 3 of 9</p> <p>SAFETY DATA SHEET</p> <p>IDENTITY: PRO-Tekt Topcoat, Component</p> <p>SDS No. PRO T.3.1</p> <p>Other protection: Use protective clothing chemically resistant to this material. Selection of specific <br />items such as face shield, boots, apron, or full body suit will depend on the task. <br />Respiratory protection: Respiratory protection should be worn when there is a potential to exceed the exposure <br />limit requirements or guidelines. If there are no applicable exposure limit requirements or guidelines, wear <br />respiratory protection when adverse effects, such as respiratory irritation or discomfort have been experienced, or <br />where indicated by your risk assessment process. For most conditions no respiratory protection should be needed; <br />however, if discomfort is experienced, use an approved air-purifying respirator. <br />Section</p> <p>9 – Physical and Chemical Properties</p> <p>Appearance: <br />Physical State <br />Color <br />Odor: <br />Odor Threshhold: <br />pH: <br />Melting point/range: <br />Freezing point: <br />Boiling point (760 mmHg): <br />Flash point:</p> <p>Liquid <br />Clear <br />Amine</p> <p>No test data available. <br />No data available. <br />No data available. <br />No data available. <br />No data available. <br />Closed cup 93.3°C (199.9°F) Estimated. <br />Open cup 93.3°C (199.9°F) Estimated. <br />Evaporation Rate (Butyl Acetate =1): Not available. <br />Flammability (solid, gas): <br />Not applicable. <br />Lower explosion limit: <br />Liquid. <br />Upper explosion limit: <br />Liquid. <br />Vapor Pressure: <br />No data available. <br />Relative Vapor Density (air = 1): <br />No data available. <br />Relative Density (water = 1): <br />No data available. <br />Water Solubility: <br />No data available. <br />Partition coefficient: <br />This product is a mixture. See Section 12 for individual component <br />n-octanol/water <br />data. <br />Auto-ignition temperature <br />No data available. <br />Decomposition temperature <br />No data available. <br />Kinematic Viscosity <br />No information available. <br />Explosive properties <br />No data available. <br />Oxidizing properties <br />No data available. <br />Molecular weight <br />Not reported. <br />NOTE: The physical data presented above are typical values and should not be construed as a specification.</p> <p>Section 10 – Stability and Reactivity <br />Reactivity: No data available. <br />Chemical stability: Stable under recommended storage conditions. See Storage, Section 7. <br />Possibility of hazardous reactions: Polymerization will not occur. <br />Conditions to avoid: None known. <br />Incompatible materials: There are no known materials which are incompatible with this product. <br />Page 4 of 9</p> <p>IDENTITY: PRO-Tekt Topcoat, Component A</p> <p>SAFETY DATA SHEET <br />SDS No. PRO T.3.1</p> <p>Hazardous decomposition products: Does not decompose.</p> <p>Section 11 – Toxicological Information <br />Toxicological information appears in this section when such data is available. <br />Acute toxicity <br />Acute oral toxicity <br />Low toxicity if swallowed. Small amounts swallowed incidentally as a result of normal handling operations are <br />not likely to cause injury; however, swallowing larger amounts may cause injury. <br />Single dose oral LD50 has not been determined. Based on information for component(s): <br />LD50, Rat, > 2,000 mg/kg Estimated. <br />Acute dermal toxicity <br />Prolonged skin contact is unlikely to result in absorption of harmful amounts. <br />The dermal LD50 has not been determined. Based on information for component(s): <br />LD50, Rat, > 2,000 mg/kg Estimated. <br />Acute inhalation toxicity <br />Excessive exposure may cause irritation to upper respiratory tract (nose and throat). <br />As product: The LC50 has not been determined. <br />Skin corrosion/irritation <br />Brief contact may cause slight skin irritation with local redness. <br />Effects may be slow to heal. <br />Serious eye damage/eye irritation <br />May cause slight temporary eye irritation. <br />Corneal injury is unlikely. <br />Sensitization <br />For the minor component(s): <br />Has caused allergic skin reactions when tested in guinea pigs. <br />For respiratory sensitization: <br />No relevant data found. <br />Specific Target Organ Systemic Toxicity (Single Exposure) <br />Evaluation of available data suggests that this material is not an STOT-SE toxicant. <br />Specific Target Organ Systemic Toxicity (Repeated Exposure) <br />For some component(s): <br />In animals, effects have been reported on the following organs: <br />Gastrointestinal tract. <br />Thyroid. <br />Carcinogenicity <br />No relevant data found. <br />Teratogenicity <br />For some component(s): Did not cause birth defects or any other fetal effects in laboratory animals. <br />Reproductive toxicity <br />For some component(s): In animal studies, did not interfere with reproduction. In animal studies, did not <br />interfere with fertility.</p> <p>Page 5 of 9</p> <p>SAFETY DATA SHEET</p> <p>IDENTITY: PRO-Tekt Topcoat, Component</p> <p>SDS No. PRO T.3.1</p> <p>Mutagenicity <br />For some component(s): In vitro genetic toxicity studies were negative in some cases and positive in other <br />cases. <br />Aspiration Hazard <br />Based on available information, aspiration hazard could not be determined. <br />COMPONENTS INFLUENCING TOXICOLOGY: <br />Aspartic acid, N,N'-(methylenedi-4,1-cyclohexanediyl)bis-, tetraethyl ester <br />Acute inhalation toxicity <br />Excessive exposure may cause irritation to upper respiratory tract (nose and throat). <br />The LC50 has not been determined. For similar material(s): LC50, Rat, male and female, 4 Hour, dust/mist, > <br />4.224 mg/l No deaths occurred at this concentration. <br />2-Butenedioic acid(E)-diethylester <br />Acute inhalation toxicity <br />The LC50 has not been determined.</p> <p>Section 12 – Ecological Information <br />Ecotoxicological information appears in this section when such data is available. <br />Toxicity <br />Aspartic acid, N,N'-(methylenedi-4,1-cyclohexanediyl)bis-, tetraethyl ester <br />Acute toxicity to fish <br />Material is slightly toxic to aquatic organisms on an acute basis (LC50/EC50 between 10 and 100 mg/L in <br />the most sensitive species tested). <br />For similar material(s): <br />LC50, Danio rerio (zebra fish), semi-static test, 96 Hour, 66 mg/l, OECD Test Guideline 203 ] <br />Acute toxicity to aquatic invertebrates <br />For similar material(s): <br />EC50, Daphnia magna (Water flea), static test, 48 Hour, 88.6 mg/l, Other guidelines <br />Acute toxicity to algae/aquatic plants <br />For similar material(s): <br />ErC50, Desmodesmus subspicatus (Scenedesmus subspicatus), static test, 72 Hour, Growth rate, 113 <br />mg/l, EU Method C.3 (Algal Inhibition test) <br />Toxicity to bacteria <br />EC50, activated sludge, 3 Hour, Respiration rates., 3,110 mg/l, ISO 8192 <br />Chronic toxicity to aquatic invertebrates <br />For similar material(s): <br />NOEC, Daphnia magna (Water flea), semi-static test, 21 d, number of offspring, 0.013 mg/l <br />2-Butenedioic acid(E)-diethylester <br />Acute toxicity to fish <br />Material is moderately toxic to aquatic organisms on an acute basis (LC50/EC50 between 1 and 10 mg/L in <br />the most sensitive species tested). <br />LC50, Oryzias latipes (Orange-red killifish), semi-static test, 96 Hour, 2.4 mg/l, Method Not Specified.</p> <p>Page 6 of 9</p> <p>IDENTITY: PRO-Tekt Topcoat, Component A</p> <p>SAFETY DATA SHEET <br />SDS No. PRO T.3.1</p> <p>Acute toxicity to aquatic invertebrates <br />EC50, Daphnia magna (Water flea), 24 Hour, 11 mg/l, Method Not Specified. <br />Acute toxicity to algae/aquatic plants <br />EC50, Pseudokirchneriella subcapitata (green algae), 72 Hour, Biomass, 1.1 mg/l, Method Not Specified. <br />Persistence and degradability <br />Aspartic acid, N,N'-(methylenedi-4,1-cyclohexanediyl)bis-, tetraethyl ester <br />Biodegradability: No relevant information found. <br />Material is expected to biodegrade very slowly (in the environment). Fails to pass OECD/EEC tests for <br />ready biodegradability. <br />Biodegradation: 0 % <br />Exposure time: 28 d <br />Method: OECD Test Guideline 302C or Equivalent <br />For similar material(s): 10-day Window: Fail <br />Biodegradation: 13 % <br />Exposure time: 28 d <br />Method: OECD Test Guideline 301F <br />Theoretical Oxygen Demand: 2.31 mg/mg <br />Photodegradation <br />Test Type: Half-life (indirect photolysis) <br />Sensitizer: OH radicals <br />Atmospheric half-life: 0.048 d <br />2-Butenedioic acid(E)-diethylester <br />Biodegradability: Material is readily biodegradable. Passes OECD test(s) for ready biodegradability. <br />10-day Window: Not applicable <br />Biodegradation: 92 - 95 % <br />Exposure time: 28 d <br />Method: OECD Test Guideline 301C or Equivalent <br />Theoretical Oxygen Demand: 1.67 mg/mg <br />Photodegradation <br />Test Type: Half-life (indirect photolysis) <br />Sensitizer: OH radicals <br />Atmospheric half-life: 1.045 - 11.50 d <br />Method: Estimated. <br />Photodegradation <br />Test Type: Half-life (indirect photolysis) <br />Sensitizer: Ozone. <br />Atmospheric half-life: 6.55 - 13.1 d <br />Method: Estimated. <br />Bioaccumulative potential <br />Aspartic acid, N,N'-(methylenedi-4,1-cyclohexanediyl)bis-, tetraethyl ester <br />Bioaccumulation: Bioconcentration potential is moderate (BCF between 100 and 3000 or Log Pow <br />between 3 and 5). <br />Partition coefficient: n-octanol/water(log Pow): 5.16 at 25 °C Estimated. <br />Bioconcentration factor (BCF): 1,900 Fish Estimated. <br />Page 7 of 9</p> <p>SAFETY DATA SHEET</p> <p>IDENTITY: PRO-Tekt Topcoat, Component</p> <p>SDS No. PRO T.3.1</p> <p>2-Butenedioic acid(E)-diethylester <br />Bioaccumulation: Bioconcentration potential is low (BCF < 100 or Log Pow < 3). Potential for mobility in <br />soil is very high (Koc between 0 and 50). Bioconcentration potential is low (BCF < 100 or Log Pow < 3). <br />Partition coefficient: n-octanol/water(log Pow): 2.12 at 25 °C OECD Test Guideline 107 or Equivalent <br />Mobility in soil <br />Aspartic acid, N,N'-(methylenedi-4,1-cyclohexanediyl)bis-, tetraethyl ester <br />Given its very low Henry's constant, volatilization from natural bodies of water or moist soil is not expected <br />to be an important fate process. <br />Expected to be relatively immobile in soil (Koc > 5000). <br />Partition coefficient (Koc): > 5000 <br />2-Butenedioic acid(E)-diethylester <br />Potential for mobility in soil is very high (Koc between 0 and 50). <br />Partition coefficient (Koc): 11 Estimated.</p> <p>Section 13 – Disposal Considerations <br />Disposal methods: NOTICE: Research sample for use by qualified personnel only. Upon completion of tests, <br />dispose of material and container safely and in accord with federal, state/provincial and local laws and <br />regulations. If further information is needed on disposal or use, consult your supplier.</p> <p>Section 14 – Transport Information <br />USDOT (Domestic Surface)</p> <p>Not regulated for transport.</p> <p>Classification for SEA transport (IMO-IMDG):</p> <p>Not regulated for transport.</p> <p>Transport in bulk according to Annex I or II <br />of MARPOL 73/78 and the IBC or IGC Code <br />Classification for AIR transport (IATA/ICAO):</p> <p>Consult IMO regulations before transporting ocean bulk</p> <p>Not regulated for transport.</p> <p>This information is not intended to convey all specific regulatory or operational requirements/information <br />relating to this product. Transportation classifications may vary by container volume and may be influenced by <br />regional or country variations in regulations. Additional transportation system information can be obtained <br />through an authorized sales or customer service representative. It is the responsibility of the transporting <br />organization to follow all applicable laws, regulations and rules relating to the transportation of the material.</p> <p>Section 15 – Regulatory Information <br />Superfund Amendments and Reauthorization Act of 1986 Title III (Emergency Planning and Community <br />Right-to-Know Act of 1986) Sections 311 and 312 <br />Acute Health Hazard <br />Superfund Amendments and Reauthorization Act of 1986 Title III (Emergency Planning and Community <br />Right-to-Know Act of 1986) Section 313 <br />To the best of our knowledge, this product does not contain chemicals at levels which require reporting under <br />this statute.</p> <p>Page 8 of 9</p> <p>IDENTITY: PRO-Tekt Topcoat, Component A</p> <p>SAFETY DATA SHEET <br />SDS No. PRO T.3.1</p> <p>Pennsylvania Worker and Community Right-To-Know Act: <br />To the best of our knowledge, this product does not contain chemicals at levels which require reporting under <br />this statute. <br />California Proposition 65 (Safe Drinking Water and Toxic Enforcement Act of 1986) <br />This product contains no listed substances known to the State of California to cause cancer, birth defects or <br />other reproductive harm, at levels which would require a warning under the statute. <br />United States TSCA Inventory (TSCA) <br />All components of this product are in compliance with the inventory listing requirements of the U.S. Toxic <br />Substances Control Act (TSCA) Chemical Substance Inventory.</p> <p>Section 16 – Other Information <br />Other information <br />For research use only. <br />Revision <br />Identification Number: 102998248 / A001 / Issue Date: 03/17/2017 / Version: 0.0 <br />Most recent revision(s) are noted by the bold, double bars in left-hand margin throughout this document. <br />Abbreviations and acronyms: <br />USDOT:</p> <p>United States Department of Transportation.</p> <p>SDS prepared by:</p> <p>Aquafin product safety department.</p> <p>DISCLAIMER: <br />We believe the statements, technical information and recommendations contained herein are reliable, but they are <br />given without warranty or guarantee of any kind, expressed or implied, and we assume no responsibility for any <br />loss, damage, or expense, direct or consequential, arising out of their use. Aquafin shall not be responsible for the <br />use of this product in a manner to infringe on any patent or any other intellectual property rights held by others. <br />END OFsafety <br />MSDS <br />(April 09, 2015) <br />User is responsible for determining appropriate <br />measures and for applying the legislation <br />covering his own <br />activities. We recommend that user makes tests to determine the suitability of a product for its particular purpose <br />prior to use. <br />END OF SDS</p> <p>Page 9 of 9</p> <p>(February 27, 2019)</p>
