Safety Data Sheet (SDS)
Page 1/8
OSHA HazCom Standard 29 CFR 1910.1200(g) and GHS Rev 03.
Printing date 08/11/2022
Reviewed on 08/11/2022
SECTION 1) CHEMICAL PRODUCT AND SUPPLIER'S IDENTIFICATION
IDENTITY:
Product Name: AQUAFIN-TC300V COMPONENT A Product Use Description:
Polyurethane Coating, For Further Information, Refer to the Product Technical Data Sheet.
AQUAFIN, INC. 505 BLUE BALL RD. #160 ELKTON, MD 21921
24 hr Emergency Phone: Chem-Tel (800) 255-3924 Information Phone No: (410) 392-2300
info@aquafin.net
www.aquafin.net
SECTION 2) HAZARDS IDENTIFICATION Classification Skin Irritation - Category 3 Eye Irritation - Category 2A Respiratory Sensitizer (Solid/Liquid) - Category 1 Skin Sensitizer - Category 1 Carcinogenicity - Category 2 Acute aquatic toxicity - Category 3 Chronic aquatic toxicity - Category 3 Flammable Liquids - Category 4
Pictograms
Signal Word Danger
Hazardous Statements - Health H316 - Causes mild skin irritation H319 - Causes serious eye irritation H334 - May cause allergy or asthma symptoms or breathing difficulties if inhaled H317 - May cause an allergic skin reaction H351 - Suspected of causing cancer.
Hazardous Statements - Physical H227 - Combustible Liquid
Hazardous Statements - Environmental H402 - Harmful to aquatic life H412 - Harmful to aquatic life with long lasting effects
SDS AQUAFIN-TC300V Comp A SDS DATE: 22-AUG-11
Page 1 of 8
Precautionary Statements - General P101 - If medical advice is needed, have product container or label at hand. P102 - Keep out of reach of children. P103 - Read label before use.
Precautionary Statements - Prevention P264 - Wash thoroughly after handling. P280 - Wear protective gloves/protective clothing/eye protection/face protection. P261 - Avoid breathing dust/fume/gas/mist/vapors/spray. P284 - [In case of inadequate ventilation] wear respiratory protection. P272 - Contaminated work clothing should not be allowed out of the workplace. P201 - Obtain special instructions before use. P202 - Do not handle until all safety precautions have been read and understood. P273 - Avoid release to the environment. P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
Precautionary Statements - Response P332 + P313 - If skin irritation occurs: Get medical advice/attention. P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P304 + P337 + P340 - IF INHALED: If eye irritation persists: Remove person to fresh air and keep comfortable for breathing. P313 - Get medical advice/attention. P342 + P311 - If experiencing respiratory symptoms: Call a POISON CENTER/doctor. P302 + P352 - IF ON SKIN: Wash with plenty of water. P333 + P313 - If skin irritation or a rash occurs: Get medical advice/attention. P321 - Specific treatment (see section 4 on this SDS). P362 + P364 - Take off contaminated clothing. And wash it before reuse. P308 + P313 - IF exposed or concerned: Get medical advice/attention. P370 + P378 - In case of fire: Use dry chemical, carbon dioxide, foam to extinguish. For detailed information, see Section-5 (Fire Fighting Measures)
Precautionary Statements - Storage P405 - Store locked up. P403 - Store in a well-ventilated place.
Precautionary Statements - Disposal P501 - Dispose of contents/ container to an approved waste disposal plant.
SECTION 3) COMPOSITION/INFORMATION ON INGREDIENTS CAS
Chemical Name
% By Weight
0053880-05-0
POLYURETHANE PREPOLYMER
52% - 95%
0013463-67-7
TITANIUM DIOXIDE
10% - 18%
0000108-32-7
4-METHYL-1,3-DIOXOLAN-2-ONE
3% - 5%
0004098-71-9
ISOPHORONE DIISOCYANATE
1% - 3%
0001333-86-4
CARBON BLACK
0.9% - 1.6%
Specific chemical identity and/or exact percentage (concentration) of the composition has been withheld to protect confidentiality.
SECTION 4) FIRST-AID MEASURES Inhalation Remove source of exposure or move person to fresh air and keep comfortable for breathing. If experiencing respiratory symptoms: Call a POISON CENTER/doctor. If breathing is difficult, trained personnel should administer emergency oxygen if advised to do so by the POISON CENTER/doctor.
Page 2 of 8
If exposed/feel unwell/concerned: Call a POISON CENTER/doctor. Eliminate all ignition sources if safe to do so.
Skin Contact Take off contaminated clothing, shoes and leather goods (e.g. watchbands, belts). Gently blot or brush away excess product. Wash with plenty of lukewarm, gently flowing water for a duration of 15-20 minutes. If skin irritation or rash occurs: Get medical advice/attention. Wash contaminated clothing before re-use or discard. IF exposed or concerned: Get medical advice/attention.
Eye Contact Avoid direct contact. Wear chemical protective gloves, if necessary. Rinse eyes cautiously with lukewarm, gently flowing water for several minutes, while holding the eyelids open. Remove contact lenses, if present and easy to do. Continue rinsing for 15-20 minutes. Take care not to rinse contaminated water into the unaffected eye or onto the face. If eye irritation persists: Get medical advice/attention.
Ingestion Rinse mouth. Do NOT induce vomiting. Immediately call a POISON CENTER/doctor. If vomiting occurs naturally, lie on your side, in the recovery position. IF exposed or concerned: Get medical advice/attention.
SECTION 5) FIRE-FIGHTING MEASURES Suitable Extinguishing Media Dry chemical, foam, carbon dioxide is recommended. Water spray is recommended to cool or protect exposed materials or structures. Carbon dioxide can displace oxygen. Use caution when applying carbon dioxide in confined spaces. Simultaneous use of foam and water on the same surface is to be avoided as water destroys the foam. Sand or earth may be used for small fires only.
Unsuitable Extinguishing Media If water is used, use very large quantities of cold water. The reaction between water and hot isocyanate may be vigorous.
Specific Hazards in Case of Fire Vapors may accumulate and travel to ignition sources distant from the handling site; flash fire can occur. Excessive pressure or temperature may cause explosive rupture of containers. Water contamination will produce carbon dioxide. Do not reseal contaminated containers as pressure buildup may rupture them.
Fire-fighting Procedures Isolate immediate hazard area and keep unauthorized personnel out. Stop spill/release if it can be done safely. Move undamaged containers from immediate hazard area if it can be done safely. Water spray may be useful in minimizing or dispersing vapors and to protect personnel. Water may be ineffective but can be used to cool containers exposed to heat or flame. Caution should be exercised when using water or foam as frothing may occur, especially if sprayed into containers of hot, burning liquid. Dispose of fire debris and contaminated extinguishing water in accordance with official regulations.
Special Protective Actions Wear NIOSH approved self-contained breathing apparatus in positive pressure mode with full-face piece. Boots, gloves (neoprene), googles, and full protective clothing are also required. Care should always be exercised in dust/mist areas.
SECTION 6) ACCIDENTAL RELEASE MEASURES Emergency Procedure ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area). Do not touch or walk through spilled material. Isolate hazard area and keep unnecessary people away. Remove all possible sources of ignition in the surrounding area. Notify authorities if any exposure to the general public or the environment occurs or is likely to occur. If spilled material is cleaned up using a regulated solvent, the resulting waste mixture may be regulated.
Recommended Equipment Appropriate dust or face mask to eliminate breathing foam dust particulates.
Personal Precautions Avoid breathing vapors. Avoid contact with skin, eyes or clothing. Do not touch damaged containers or spilled materials unless wearing appropriate protective clothing.
Environmental Precautions
Page 3 of 8
Stop spill/release if it can be done safely. Prevent spilled material from entering sewers, storm drains, other unauthorized drainage systems and natural waterways by using sand, earth, or other appropriate barriers.
Methods and Materials for Containment and Cleaning up Cover container, but do not seal, and remove from work area. Prepare a decontamination solution of 2.0% liquid detergent and 3-8% concentrated ammonium hydroxide in water (5-10% sodium carbonate may be substituted for the ammonium hydroxide). Follow the precautions on the supplier's safety data sheets. Treat the spill area with the decontamination solution, using about 10 parts of the solution for each part of the spill, and allow it to react for at least 15 minutes. Carbon dioxide will be evolved, leaving insoluble polyureas. Residues from spill cleanup, even when treated as described may continue to be regulated under provisions of RCRA and require storage and disposal as hazardous waste. Slowly stir the isocyanate waste into the decontamination solution described above. Let stand for 48 hours, allowing the evolved carbon dioxide to vent away, residues may still be subject to RCRA storage and disposal requirements. Dispose off in compliance with all relevant local, state, and federal laws and regulations regarding treatment.
SECTION 7) HANDLING AND STORAGE General Wash hands after use. Do not get in eyes, on skin or on clothing. Do not breathe vapors or mists. Use good personal hygiene practices. Eating, drinking and smoking in work areas is prohibited. Remove contaminated clothing and protective equipment before entering eating areas.
Ventilation Requirements Use only with adequate ventilation to control air contaminants to their exposure limits. The use of local ventilation is recommended to control emissions near the source.
Storage Room Requirements Keep container(s) tightly closed and properly labeled. Store in cool, dry, well-ventilated areas away from heat, direct sunlight, strong oxidizers and any incompatibilities. Store in approved containers and protect against physical damage. Keep containers securely sealed when not in use. Indoor storage should meet OSHA standards and appropriate fire codes. Containers that have been opened must be carefully resealed to prevent leakage. Empty container retain residue and may be dangerous. Use non-sparking ventilation systems, approved explosion-proof equipment and intrinsically safe electrical systems in areas where this product is used and stored. Ground and bond containers and receiving equipment. Avoid static electricity by grounding. Do not cut, drill, grind, weld, or perform similar operations on or near containers. Do not pressurize containers to empty them. Ground all structures, transfer containers and equipment to conform to the national electrical code. Use procedures that prevent static electrical sparks. Static electricity may accumulate and create a fire hazard.
SECTION 8) EXPOSURE CONTROLS/PERSONAL PROTECTION Eye Protection Wear eye protection with side shields or goggles. Wear indirect-vent, impact and splash resistant goggles when working with liquids. If additional protection is needed for entire face, use in combination with a face shield.
Skin Protection Use of gloves approved to relevant standards made from the following materials may provide suitable chemical protection: PVC, neoprene or nitrile rubber gloves. Suitability and durability of a glove is dependent on usage, e.g. frequency and duration of contact, chemical resistance of glove material, glove thickness, dexterity. Always seek advice from glove suppliers. Contaminated gloves should be replaced. Use of an apron and over- boots of chemically impervious materials such as neoprene or nitrile rubber is recommended to avoid skin sensitization. The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Launder soiled clothes or properly disposed of contaminated material, which cannot be decontaminated. Depending on conditions of use, additional protection may be required such as apron, arm covers, or full body suit. Wash contaminated clothing before re-wearing.
Respiratory Protection If airborne concentrations exceed or are expected to exceed the TLV, use MSHA/NIOSH approved positive pressure supplied pressure supplied air respiratory with a full face piece or an air supplied hood. For emergencies, use a positive pressure self-contained breathing apparatus. Air purifying (cartridge type) respirators are not approved for protection against isocyanates.
Appropriate Engineering Controls Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors below their respective threshold limit value.
Page 4 of 8
OSHA TWA (ppm)
OSHA TWA (mg/m3)
OSHA STEL (ppm)
OSHA STEL (mg/m3)
OSHA OSHA NIOSH Tables (Z1, OSHA Skin TWA Z2, Z3) Carcinogen designation (ppm)
3.5
1 0.005
15
ACGIH TWA (ppm)
ACGIH TWA (mg/m3)
1
ACGIH STEL (ppm)
NIOSH STEL (ppm)
NIOSH STEL (mg/m3)
3.5a
ISOPHORONE DIISOCYANATE TITANIUM DIOXIDE
NIOSH TWA (mg/m3)
b
0.045
NIOSH Carcinogen 1
0.02
0.180 1
ACGIH STEL (mg/m3)
3 (I)
0.005
10
(I) - Inhalable fraction
SECTION 9) PHYSICAL AND CHEMICAL PROPERTIES Physical and Chemical Properties Density
8.74 lb/gal
Specific Gravity
1.05
VOC Regulatory
0.00 lb/gal
VOC Part A & B Combined
0.125 lb/gal
Appearance
White Viscous Liquid
Odor Threshold
N.A.
Odor Description
Mild Chemical
pH
Water Solubility
Reacts with Water
Flammability
N/A
Flash Point Symbol
Flash Point
94 °C
Viscosity
Lower Explosion Level
Upper Explosion Level
Vapor Pressure
Vapor Density
Heavier than air
Freezing Point
Melting Point
Low Boiling Point
149 °C
High Boiling Point
Auto Ignition Temp
Decomposition Pt
Evaporation Rate
Slower than ether
Coefficient Water/Oil
SECTION 10) STABILITY AND REACTIVITY Stability
Page 5 of 8
Material is stable at standard temperature and pressure.
Conditions to Avoid Heat, high temperature, open flame, sparks, and moisture. Contact with incompatible materials in a closed system will cause liberation of carbon dioxide and buildup of pressure.
Hazardous Reactions/Polymerization Will not occur under normal conditions but under high temperatures in the presence of alkalis,tertiary amines, and metal compounds will accelerate polymerization. Possible evolution of carbon dioxide gas may rupture closed containers.
Incompatible Materials This product will react with any material containing active hydrogens, such as water, alcohol, ammonia, amines, alkalis and acids, the reaction with water is slow under 50°C, but is accelerated at higher temperature and in the presence of alkalis, tertiary amines, and metal compounds. Some reactions can be violent. Material can react with strong oxidizing agents.
Hazardous Decomposition Products Carbon dioxide, carbon monoxide, nitrogen oxides, trace amounts of hydrogen cyanide and unidentified organic compounds may be formed during combustion.
SECTION 11) TOXICOLOGICAL INFORMATION Skin Corrosion/Irritation Isocyanates react with skin protein and moisture and can cause irritation. Prolonged contact can cause reddening, swelling, rash, scaling, blistering, and, in some cases, skin sensitization. Individuals who have developed a skin sensitization can develop these symptoms as a result of contact with very small amounts of liquid material or as a result of exposure to vapor. Causes mild skin irritation
Acute Toxicity No data available
Serious Eye Damage/Irritation Liquid, aerosols or vapors are severely irritating and can cause pain, tearing, reddening and swelling. Prolonged vapor contact may cause conjunctivitis. Any level of contact should not be left untreated. Causes serious eye irritation
Aspiration Hazard No data available
Germ Cell Mutagenicity No data available
Reproductive Toxicity No data available
Specific Target Organ Toxicity - Repeated Exposure No data available
Specific Target Organ Toxicity - Single Exposure No data available
Carcinogenicity Suspected of causing cancer.
Respiratory/Skin Sensitization May cause allergy or asthma symptoms or breathing difficulties if inhaled May cause an allergic skin reaction
LC50 (rat): 123-160 mg/m3 (13.6-17.6 ppm) (4-hour exposure) (aerosol) (1,2) LD50 (oral, male rat): greater than 2,500 mg/kg (1) LD50 (oral, male mouse): greater than 2,500 mg/kg (1) LD50 (dermal, male rat): approx. 1,000 mg/kg (4-hour exposure); approx. 500 mg/kg (4-day exposure) (1) 0001333-86-4
LC50 (rat): 6750 mg/m3 (4-hour exposure); cited as 27000 mg/m3 (27 mg/L) (1-hour exposure) (3)
Chronic Exposure
Page 6 of 8
CARCINOGENIC EFFECTS: In 1996, the IARC reevaluated Carbon Black as a Group 2B carcinogen. This evaluation is given to carbon black for which there is inadequate human evidence, but sufficient animal evidence. Prolonged inhalation of Carbon black can result in lung disease. Symptoms include coughing, shortness of breath, wheezing and reduced pulmonary function.
Potential Health Effects - Miscellaneous 0001333-86-4
Is an IARC, NTP or OSHA carcinogen. Has shown carcinogenic activity in laboratory animals at high doses. Significance to man is unknown. The following medical conditions may be aggravated by exposure: asthma, respiratory disease. WARNING: This chemical is known to the State of California to cause cancer. 0013463-67-7
Is an IARC, NTP or OSHA carcinogen. In a lifetime inhalation test, lung cancers were found in some rats exposed to 250 mg/m3 respirable titanium dust. Analysis of the titanium dioxide concentrations in the rat’s lungs showed that the lung clearance mechanism was overwhelmed and that the results at the massive 250 mg/m3 level are not relevant to the workplace.‘Results of a DuPont epidemiology study showed that employees who had been exposed to Titanium Dioxide were at no greater risk of developing lung cancer than were employees who had not been exposed to Titanium dioxide. No pulmonary fibrosis was found in any of the employees and no association was observed between Titanium dioxide exposure and chronic respiratory disease or x-ray abnormalities. Based on the results of this study DuPont concludes that titanium dioxide will not cause lung cancer or chronic respiratory disease in humans at concentrations experienced in the workplace.‘
SECTION 12) ECOLOGICAL INFORMATION Toxicity No data available. Harmful to aquatic life Harmful to aquatic life with long lasting effects
Other Adverse Effects No data available.
Bio-accumulative Potential 0001333-86-4
A relevant bioaccumulation potential of carbon black is not expected based on its insolubility in organic solvents and in water. Furthermore, since the aggregate diameter of carbon black varies between 80 nm and 810 nm, bioaccumulation of particulate carbon black is not likely oweing to the large diameter of the solid aggregate particles.
Persistence and Degradability 0001333-86-4
Carbon Black's insolubility in water results in it not being biodegradable in any medium or by biota. It is considered persistent in the natural environment.
SECTION 13) DISPOSAL CONSIDERATIONS Waste Disposal Under RCRA, it is the responsibility of the user of the product, to determine a the time of disposal whether the product meets RCRA criteria for hazardous waste. Waste management should be in full compliance with federal, state, and local laws. Empty containers retain product residue which may exhibit hazards of material, therefore do not pressurize, cut, glaze, weld or use for any other purposes. Return drums to reclamation centers for proper cleaning and reuse.
SECTION 14) TRANSPORT INFORMATION U.S. DOT Information Not regulated.
IMDG Information Not regulated.
Page 7 of 8
IATA Information Not regulated.
SECTION 15) REGULATORY INFORMATION
CAS
Regulation List
52% - 95% DSL,SARA312,TSCA
10% - 18% DSL,SARA312,TSCA,CA_Prop65 - California Proposition 65
4-METHYL-1,3-DIOXOLAN -2-ONE
3% - 5% DSL,SARA312,TSCA 1% - 3% SARA313, DSL,SARA312,VOC,TSCA 0.9% - 1.6% DSL,SARA312,TSCA,CA_Prop65 - California Proposition 65
SECTION 16) OTHER INFORMATION OTHER INFORMATION * There are points of differences between OSHA GHS and UN GHS. In 90% of the categories, they can be used interchangeably, but for the Skin Corrosion/Irritant Category and the Specific Target Organ Toxicity (Single and Repeated Exposure) Categories. In these cases, our system will say UN GHS.
GLOSSARY ACGIH- American Conference of Governmental Industrial Hygienists; ANSI- American National Standards Institute; CA Prop65- California Proposition 65; Canadian TDG- Canadian Transportation of Dangerous Goods; CAS- Chemical Abstract Service; Chemtrec- Chemical Transportation Emergency Center (US); CHIP- Chemical Hazard Information and Packaging; DSL- Domestic Substances List; ECEquivalent Concentration; EH40 (UK)- HSE Guidance Note EH40 Occupational Exposure Limits; EPCRA- Emergency Planning and Community Right-To-Know Act; ESL- Effects screening levels; HMIS- Hazardous Material Information Service; LC- Lethal Concentration; LD- Lethal Dose; NFPA- National Fire Protection Association; OEL- Occupational Exposure Limits; OSHA- Occupational Safety and Health Administration, US Department of Labor; PEL- Permissible Exposure Limit; SARA (Title III)- Superfund Amendments and Reauthorization Act; SARA 313- Superfund Amendments and Reauthorization Act, Section 313; SCBA- Self-Contained Breathing Apparatus; STEL- Short Term Exposure Limit; TCEQ- Texas Commission on Environmental Quality; TLV- Threshold Limit Value; TSCAToxic Substances Control Act Public Law 94-469; TWA- Time Weighted Value; US DOT- US Department of Transportation; WHMISWorkplace Hazardous Materials Information System.
DISCLAIMER To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist. The above information pertains to this product as currently formulated, and is based on the information available at this time. Addition of reducers or other additives to this product may substantially alter the composition and hazards of the product. Since conditions of use are outside our control, we make no warranties, express or implied, and assume no liability in connection with any use of this information.
Page 8 of 8