Safety Data Sheet (SDS)
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OSHA HazCom Standard 29 CFR 1910.1200(g) and GHS Rev 03.
Printing date 08/11/2022
Reviewed on 08/11/2022
SECTION 1) PRODUCT NAME AND COMPANY INFORMATION IDENTITY:
Product Name: Coated Quartz Sand Product Use Description:
AQUAFIN, INC.. 505 BLUE BALL RD. #160 ELKTON, MD 21921
Polyurethane Coated Quartz Aggregate, For Further Information, Refer to the Product Technical Data Sheet
info@aquafin.net
24 hr Emergency Phone: Chem-Tel (800) 255-3924 Information Phone No: (410) 392-2300
www.aquafin.net
SECTION 2) HAZARDS IDENTIFICATION
GHS Classification: Carcinogen, Acute toxicity Oral Category 4 Pictograms: Signal Word: Danger Hazard Statement: May cause damage to lungs through prolonged or repeated exposure by inhalation. Precautionary Statements: Do not handle until all safety precautions have been read and understood. Wear respirator if prolonged exposure to dust will occur. If exposed or concerned: Get medical advice. Dispose of container in accordance with local/regional/national regulations. Inhalation: In addition to causing cancer, prolonged exposure to respirable crystalline silica may cause silicosis, a fibrosis (scarring) of the lungs which is permanent and progressive that may lead to death. Silicosis may aggravate or increase the risk of tuberculosis, scleroderma, nephrotoxicity, bronchitis, emphysema, and asthma. Actions taken to control hazards related to respirable crystalline silica are adequate to control hazards from microorganisms that may be also present in some products. Eye Contact: A mechanical irritant which can cause moderate eye irritation. This product may cause abrasion to the cornea. Avoid wearing contact lenses when working with product.
SECTION 3) COMPOSITION / INFORMATION ON INGREDIENTS CAS 7631-86-9 14808-60-7 9009-54-5 14808-60-7
Chemical Name Amorphous Silica, SiO2 Total Crystalline Silica (Quartz), SiO2 Rubinate DINP T-12 Respirable Crystalline Silica (Quartz < 4 μm), SiO2
% By Weight 76 - 87 13 - 24 .57 .06
SECTION 4) FIRST AID MEASURES
Inhalation: No specific first-aid is necessary since adverse health effects associated with exposure to crystalline silica (quartz) result from chronic exposure. In case of gross inhalation, remove the person to fresh air, give artificial respiration if needed and seek medical attention. Eye Contact: Wash immediately with water. If irritation persists, seek medical attention. Skin Contact: None required. Ingestion: Not applicable.
SECTION 5) FIRE FIGHTING MEASURES
This product is not flammable, combustible or explosive. Hazardous polymerization will not occur.
SECTION 6) ACCIDENTAL RELEASE MEASURES
Spills: Use of dustless methods (water or HEPA-A type Vacuum) to clean up if possible. Avoid breathing dust. See personal protective equipment (PPE) specified in EXPOSURE CONTROL/PERSONAL PROTECTION SECTION 8. Waste Disposal Methods: This product is not a hazardous waste and should be disposed of in accordance with federal, state and local regulations. See SECTION 13.
SDS Coated Quartz Sand SDS DATE: 22-AUG-19
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Coated Quartz Sand Safety Data Sheet
SECTION 7) HANDLING AND STORAGE
Precautions During Handling and Use: Do not breathe dust. Use adequate ventilation and/or dust collection methods. Avoid breakage of bagged material or spills of bulk material. Wash or vacuum clothing which becomes dusty. If concentrations exceed applicable standards, then use proper respiratory protection. Avoid contact with eyes. The wearing of contact lenses is not recommended. See SECTION 8: EXPOSURE CONTROLS / PERSONAL PROTECTION. Storage Requirements: Avoid windblown dust by shielding or covering outdoor stockpiles. Special Sensitivity or Incompatibility: Avoid contact with strong acids and oxidizers. See SECTION 10. STABILITY AND REACTIVITY.
SECTION 8) EXPOSURE CONTROLS / PERSONAL PROTECTION
ACGIH OSHA CalOSHA NIOSH NIOSH TLV PEL PEL IDLH REL (mg/m3) (mg/m3) (mg/m3) (mg/m3) (mg/m3) Respirable crystalline silica: 0.025 10 ÷ (%SiO2 + 2) 0.1 50 0.05 Total crystalline silica: 30 ÷ (%SiO2 + 2) 0.3 Amorphous silica: 10 80 ÷ (%SiO2) 6 3000 6 Respirable amorphous silica: 3 5 3 Respirable nuisance dust: 3 5 5 Total nuisance dust: 10 15 10 Engineering and Administrative Controls: Natural ventilation is usually adequate for protection from inhalation hazards. Use designed ventilation systems and/or wet methods to control product in workplace air, if necessary. Use administrative controls such job rotation to supplement engineering controls. Use personal protection equipment (PPE) as a last resort to control exposure. Respiratory Protection: Not normally required. May be required if material is further reduced in size to produce a higher fraction of respirable crystalline silica dust or dispersed into air (e.g. sandblasting). When concentrations exceed applicable standards, a NIOSH/MSHA approved air purifying respirator with HEPA cartridges or supplied air is recommended. Eye Protection: Wear safety glasses with side shields or goggles to protect eyes from dust and particulate. Wearing of contact lenses is not recommended because dust can get under the lenses and cause abrasion of the cornea. Skin Protection: Not required under normal circumstances Exposure Limits
SECTION 9) PHYSICAL AND CHEMICAL PROPERTIES Appearance: This product is a natural sand or aggregate Odor: None Odor threshold: Not Applicable pH: Not Applicable Melting point/freezing point: 3050 ˚F (1677C) Initial Boiling Point: 4046 ˚F (2230 C) Flash point: Not Applicable Evaporation rate: Not Applicable Flammability: Not Applicable
Upper/lower flammability limits: Not Applicable Vapor pressure: Not Applicable Vapor density: Not Applicable Relative density (H2O = 1): 2.60 - 2.65 Solubility: Insoluble Partition coefficient: Not Applicable Auto-ignition temperature: Not Applicable Decomposition temperature: Not Applicable Viscosity: Not Applicable
SECTION 10) STABILITY AND REACTIVITY
Reactivity: Inert Chemical stability: Stable Possibility of hazardous reactions: Unlikely Conditions to avoid: Crushing this material will increase the respirable fraction and related hazards. Incompatible materials: Contact with strong acids or oxidizing agents such as molten magnesium, fluorine, chlorine trifluoride, manganese trioxide, oxygen difluoride, or hydrofluoric acid may cause fires or generation of corrosive gases. Hazardous decomposition products: None
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SECTION 11) TOXICOLOGICAL INFORMATION
Likely routes of exposure: Inhalation and eye contact. Symptoms related to the physical, chemical and toxicological characteristics: Silicosis: Prolonged exposure to respirable crystalline silica may cause silicosis, a fibrosis (scarring) of the lungs which is permanent and progressive that may lead to death. Silicosis may aggravate or increase the risk of tuberculosis, scleroderma, nephrotoxicity, bronchitis, emphysema, and asthma. Eye irritation: This product can cause moderate eye irritation and may cause abrasion to the cornea. Delayed and immediate effects and also chronic effects from short- and long-term exposure: For single or limited exposures there are no signs or symptoms of exposure to respirable crystalline silica. For routine exposure and for individuals with existing respiratory illness (e.g., bronchitis, emphysema, chronic obstructive pulmonary disease) symptoms include shortness of breath, wheezing, cough, sputum production, weight loss, fever. Numerical Measures of Toxicity: This product is not acutely toxic. The literature search did not reveal numerical measures of toxicity (e.g., LC50) other than the regulatory thresholds presented in Section 8. Carcinogenicity: This product contains respirable crystalline silica which is classified as a Class 1 carcinogen by IARC, a known human carcinogen by NTP and OSHA, and a California Proposition 65 carcinogen.
SECTION 12) ECOLOGICAL INFORMATION
This product is not known to be ecotoxic (i.e. there is no data which suggests that this product is toxic to birds, fish, invertebrates, microorganisms or plants).
SECTION 13) DISPOSAL CONSIDERATIONS
Waste Disposal Methods: This product is not a hazardous waste and may be landfilled. If this product is
contaminated with hazardous materials, then place the waste in a properly labeled, suitable waste container. Contaminated material must be disposed in accordance with federal, state and local regulations using the proper waste classification.
SECTION 14) TRANSPORTATION INFORMATION
US DOT Shipping Name: Not Regulated DOT LABEL: None UN/NA Number: None This product not listed as a hazardous substance by U.S. Department of Transportation.
SECTION 15) REGULATORY INFORMATION
TSCA/CEPA Status: Components of this product are included in the TSCA and CEPA Chemical Inventories. CERCLA: Not applicable. RCRA: Not applicable. SARA Title III: Section 302 Extremely Hazardous: Not applicable. Section 311/312 Hazard Categories: Reportable as a hazardous substance. Check with your Local Emergency Planning Committee for reportable quantities. Section 313 Toxic Chemicals: Not applicable.
SECTION 16) OTHER INFORMATION
DISCLAIMER: The information contained herein is believed to be correct. However, Aquafin Inc. makes no guarantee or warranty of any kind, express or implied with respect to the information contained herein and disclaims any liability in connection with any use of this information and or any harmful effects which may be caused by exposure to its silica sand. Distributors, customers and users of silica sand must comply with all applicable health and safety federal, state, local laws, regulations and orders, and must seek medical, legal, and technical opinions regarding their use and hazards. DATE OF LAST REVISION: 8-19-2022
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