Safety Data Sheet (SDS)
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OSHA HazCom Standard 29 CFR 1910.1200(g) and GHS Rev 03.
Printing date 08/18/2022
Reviewed on 08/18/2022
SECTION 1: PRODUCT AND COMPANY IDENTIFICATION
IDENTITY:
Product Name: EPOXY-Gel COMPONENT A Product Use Description: Epoxy Resin Adhesive, For Further Information, Refer to the Product Technical
Data Sheet
AQUAFIN, INC. 505 BLUE BALL RD. #160 ELKTON, MD 21921
24 hr Emergency Phone: Chem-Tel (800) 255-3924 Information Phone No: (410) 392-2300
info@aquafin.net
www.aquafin.net
SECTION 2: HAZARDS IDENTIFICATION GHS Hazard:
ROUTES OF ENTRY: SIGNAL WORD:
EYE:
YES
SKIN:
INGESTION:
INHALATION:
DANGER!
PHYSICAL HAZARDS: Not Classified HEALTH HAZARDS: (ACUTE AND CHRONIC) Serious Eye Damage/Irritant Cat. 1 EYES: Skin Irritant Cat. 2 SKIN: Skin Sensiitization Cat. 1 Genetic Mutagenicity Cat. 2 INGESTION: Genetic Mutagenicity Cat. 2 INHALATION: CARCINOGEN: IARC Cat. 2B ENVIRONMENTAL HAZARDS: Acute Aquatic Cat.2 Chronic Aquatic Cat.2 HAZARD STATEMENTS:
H315 - Causes skin irritation H317 - May cause an allergic skin reaction H319 - Causes serious eye irritation H318 - Causes serious eye damage H411 - Toxic to aquatic life with long lasting effects H341 - Suspected of causing genetic defects
PRECAUTIONARY STATEMENTS: P261 – Avoid breathing mist/vapors/spray. P262 - Do not get in eyes, on skin, or on clothing P264 - Wash…thoroughly after handling with soap and water. P272 – Contaminated work clothing should not be allowed out of the workplace. P273 - Avoid release to the environment P280 - Wear Protective gloves/protective clothing/eye protection/face protection. P302+P352 – IF ON SKIN: Wash with plenty of soap and water. P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, If present and easy to do. Continue rinsing. P310 - Immediately call a POISON CENTER and DOCTOR. P333+P313 – If skin irritation or rash occurs: Get medical advice/attention. P337+P313 If eye irritation persists: Get medical advice/attention. P362 – Take off contaminated clothing and wash before reuse. P391 – Collect spillage. P402 – Store locked up. P501 – Dispose of contents/container through a waste management company authorized by the local government. MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE: Persons with preexisting skin or respiratory disorders may have their conditions aggravated by over exposure to this material.
SDS EPOXY-Gel Comp A SDS DATE: 22-AUG-18
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EPOXY-Gel, Component A Safety Data Sheet
SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS
HAZARDOUS COMPONENTS
CAS #:
CAL-OSHA PEL TWA (8hours)
ACGIH TLV TWA (8 hours)
Other Limits RECOMMENDED
% BY WEIGHT
Bisphenol-A - epichlorohydrin epoxy resin
25068-38-6
No Data
60-80
2,3-epoxypropyl o-tolyl ether
2210-79-9
8-10
[3-(2,3-epoxypropoxy)propyl]trimethoxysilane
2530-83-8
<1
Titanium Dioxide
13463-67-7
15mg/m3
10 mg/m3
9
Silicones and siloxanes, dimethyl-, reaction products with silica
67762-90-7
6
SECTION 4: FIRST AID MEASURES EYES: SKIN: INGESTION: INHALATION:
Immediately flush eyes with water for a minimum of 15 minutes while holding eyes open. Remove contact lenses if present and easy to do. If redness, burning, blurred vision, or swelling persists, consult a physician. Remove contaminated clothing and product. Immediately wash affected area with soap and water. Do not apply greases or ointments. If skin irritation persists, consult a physician. Rinse mouth immediately. Give small amounts of water, only if person is conscious. Only induce vomiting at the instruction of medical personnel. consult a physician Remove patient to fresh air. Give oxygen or artificial respiration if needed. If patient continues to experience difficulty breathing, consult a physician.
SECTION 5: FIRE-FIGHTING MEASURES SUITABLE EXTINGUISHING MEDIA: SPECIAL FIRE FIGHTING PROCEDURES:
HAZARDOUS DECOMPOSITION PRODUCTS:
FLASH POINT: METHOD USED:
Extinguish with foam, carbon dioxide, dry powder, or water fog. Use standard fire-fighting procedures, and consider the hazards of other involved materials. In case of a fire and / or explosion do not breathe fumes. Self-contained breathing apparatus and full protective clothing must be worn. Move containers from fire area if you can do so without risk. Cool containers with flooding quantities of water until well after fire is out. Prevent runoff from fire control or dilution from entering streams, sewers, or drinking water supply. Hazardous decomposition products may occur when material polymerizes at temperatures above 500 oF (260 oC). Irritating and toxic gases/fumes may be released during a fire. Do not allow run-off from fire-fighting to enter drains or water courses.
>250 oF / 121 oC PMCC
SECTION 6: ACCIDENTAL RELEASE MEASURES PERSONAL PROTECTION:
ACCIDENTAL RELEASE MEASURES: WASTE DISPOSAL:
Keep unnecessary personnel away. Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Wear appropriate personal protective equipment. Do not touch containers or spilled material unless wearing appropriate protective clothing. Avoid inhalation of vapors or mists. Ensure adequate ventilation. Local authorities should be advised if significant spillage cannot be contained. In case of spill, clean up using absorbent material such as earth or sand. Small quantities can be wiped up with cloth, place cloth in leak proof container and dispose of properly. Observe Federal, State and local regulations covering chemical waste spills.
SECTION 7: HANDLING AND STORAGE PERSONAL PROTECTION: HANDLING AND STORAGE:
Use personal protective equipment to ensure product does not contact eyes or skin when handling materials. Store in cool dry place out of direct sun rays. Keep from freezing. Recommend storage temperatures range: between 40o and 95 oF (4o - 35 oC)
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SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION PROTECTIVE MEASURE: EYE PROTECTION: HAND PROTECTION: SKIN AND BODY PROTECTION: RESPIRATORY PROTECTION: WORK HYGIENIC PRACTICES: ENGINEERING CONTROLS:
Wear appropriate personal protective equipment. Wear appropriate safety glasses with side shields, goggles or full face shield. When working on an overhead application a full face shield is recommended. Wear chemical-resistant gloves such as: Nitrile, neoprene, butyl. Wear long sleeve shirts/long pants and other clothing as required to minimize contact. Do not breathe gas/fumes/vapor/ or spray. The use of a respirator is not required during general use of this product provided adequate ventilation. If grinding or cutting cured product the use of an approved respirator is recommended. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. When using indoors, good ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. Ready access to running water is required. Provide eyewash station.
EXPOSURE LIMITS Component Bisphenol-A - epichlorohydrin epoxy resin 25068-38-6 2,3-epoxypropyl o-tolyl ether 2210-79-9 [3-(2,3-epoxypropoxy)propyl]trimethoxysilane 2530-83-8 Titanium Dioxide 13463-67-7 Silicones and siloxanes, dimethyl-, reaction products with silica 67762-90-7
OSHA (PEL) No Data No Data No Data TWA 15 mg/m3
ACGIH (TLV) No Data No Data No Data No Data
NIOSH (Pocket Guide) No Data No Data No Data No Data
TWA 80 mg/m3
6 mg/m3
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES APPEARANCE: ODOR: PHYSICAL STATE: pH AS SUPPLIED: BOILING POINT: MELTING POINT: FREEZING POINT: VAPOR PRESSURE (mmHg: VAPOR DENSITY (AIR = 1): SPECIFIC GRAVITY (H2O = 1): EVAPORATION RATE: SOLUBILITY IN WATER: PERCENT SOLIDS BY WEIGHT: PERCENT VOLATILE: VOLATILE ORGANIC COMPOUNDS (VOC): MOLECULAR WEIGHT: VISCOSITY:
White Mild Paste N/D >250F N/D N/D N/D Heavier than air 1.3 @ 25oC Negligible Negligible 0% Negligible ND ND 2100 poise
SECTION 10: STABILITY AND REACTIVITY STABILITY: CONDITIONS TO AVOID (STABILITY): INCOMPATIBILITY (MATERIAL TO AVOID): HAZARDOUS DECOMPOSITION OR BYPRODUCTS: HAZARDOUS POLYMERIZATION:
Stable Exposure to excessive heat and open flame Strong acids, peroxides and other oxidizing agents. Normal combustion forms carbon dioxide, carbon monoxide, oxides of carbon and other organic compounds, Will not occur
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EPOXY-Gel, Component A
Safety Data Sheet
SECTION 11: TOXICOLOGICAL INFORMATION CAS# Acute Oral Toxicity: Oral-Components
No data available on the product itself
LD50 >5,000 mg/kg Species: Rat
2,3-epoxypropyl o-tolyl ether [3-(2,3-epoxypropoxy)propyl]trimethoxysilane Silicones and siloxanes, dimethyl-, reaction products with silica Acute Dermal Toxicity: Dermal-Components
LD50 5,800 mg/kg Species: Rat
2530-83-8 67762-90-7
LD50 7,000-17,000 mg/kg Soecies:Rat LD50 >5,000 mg/kg Species: Rat
LD50 20,000 mg/kg Species: Rabbit
2,3-epoxypropyl o-tolyl ether [3-(2,3-epoxypropoxy)propyl]trimethoxysilane Silicones and siloxanes, dimethyl-, reaction products with silica Acute Inhalation Toxicity: Inhalation-Components
LD50 >2,000 mg/kg Species: Rabbit
LD50 3.97 ml/kg Species: Rabbit LD50 >2,000 mg/kg Species: Rat
2,3-epoxypropyl o-tolyl ether [3-(2,3-epoxypropoxy)propyl]trimethoxysilane Silicones and siloxanes, dimethyl-, reaction products with silica Skin Corrosion/ Irritation: Corrosion/Irritation Components
LC50(4hr): 1220 ppm Species: Rat
LC50 3.97 ml/kg Species: Rabbit LC0(4hr) 0.139 mg/l Species: Rat
Severe skin irritation.
Bisphenol-A - epichlorohydrin epoxy resin Eye Damage/Irritation: Damage/Irritation Components
Causes slight irritation.
Causes serious eye damage.
2,3-epoxypropyl o-tolyl ether Respiratory Damage/Irritation: Damage/irritation Components Sensitization: Sensitization-Components
Mild eye irritation.
2,3-epoxypropyl o-tolyl ether Germ Cell Mutagenicity
Maternal Toxicity: Carcinogenicity: ACGIH: IARC:
NTP OSHA
No data available on the product itself May cause sensitization by inhalation and skin contact. May cause sensitization by skin contact. The product or a component may be mutagenic, the data is inconclusive. No data available on the product itself
No data TiO2: IARC Group 2B carcinogen ''possibly carcinogen to humans''. This product contains titanium dioxide which IARC has classified as a Group 2B carcinogen (possible carcinogenic to humans). Evidence is based on sufficient animal testing as a result of long-term inhalation at high concentrations of respirable amounts of titanium dioxide. Because this product is in liquid or paste form. It does not pose a dust hazard; therefore, this classification is not relevant. Note: sanding of this product will create a possible dust hazard. No data No data
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SECTION 12: ECOLOGICAL INFORMATION
ECOTOXICITY: Aquatic toxicity: Toxicity to Fish-Components Bisphenol-A - epichlorohydrin epoxy resin [3-(2,3-epoxypropoxy)propyl]trimethoxysilane Silicones and siloxanes, dimethyl-, reaction products with silica Toxicity to algae-Components Toxicity-AquaticInvertabrates Bisphenol-A - epichlorohydrin epoxy resin [3-(2,3-epoxypropoxy)propyl]trimethoxysilane Silicones and siloxanes, dimethyl-, reaction products with silica Toxicity to other organisms: PERSISTENCE & DEGRADABILITY: BIODEGRADABILITY: Biodegradability-Components Bisphenol-A - epichlorohydrin epoxy resin [3-(2,3-epoxypropoxy)propyl]trimethoxysilane BIOACCUMULATIVE POTENTIAL: BioAccumulaive-Components: Bisphenol-A - epichlorohydrin epoxy resin MOBILITY IN SOIL: OTHER ADVERSE EFFECTS: AQUATIC RELEASE:
CAS# No data on product itself 25068-38-6 2530-83-8 67762-90-7
LC50(96hr) 1.5mg/l Species: Salo Gairdneri LC50(96hr) 55mg/l Species:Cyprinus carpio LC50(96hr) 10,000 mg/l Species: Brachydanio rerio
25068-38-6 2530-83-8 67762-90-7
EC50(48hr) 2.7mg/l Species: Dapnia Magna LC50(48hr) 324mg/l Species:Simocephalus vetulus EC50(24hr) >1,000 mg/l Species: Daphnia magna
No data available on product itself 25068-38-6 2530-83-8
Not readily biodegradable 5% 28 days Not readily biodegradable No data available on product itself
Low potential to bioaccumulate BCF = 31 NDA NDA Advise authorities if product has entered or may enter watercourses or sewer drains.
SECTION 13: DISPOSAL CONSIDERATIONS WASTE DISPOSAL METHOD:
Do not allow this material to drain into sewers / waterways, ditches, containment pools or water supplies. Dispose of contents / containers in accordance with local/regional/international regulations.
SECTION 14: TRANSPORT INFORMATION U.S. DEPARTMENT OF TRANSPORTATION PROPER SHIPPING NAME: HAZARD CLASS: Not Regulated for transportation ID NUMBER: PACKING GROUP: WATER TRANSPORTATION PROPER SHIPPING NAME: HAZARD CLASS: ID NUMBER: PACKING GROUP:
Environmentally hazardous substance, liquid n.o.s. (Epoxy Resin Mixture), Marine Pullutant 9 UN3082 III
AIR TRANSPORTATION PROPER SHIPPING NAME: HAZARD CLASS: ID NUMBER: PACKING GROUP:
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SECTION 15: REGULATORY INFORMATION U.S. FEDERAL REGULATIONS TSCA (TOXIC SUBSTANCE CONTROL ACT): CERCLA (COMPREHENSIVE RESPONSE COMPENSATION, AND LIABILITY ACT): OSHA: WHMIS
xxxxxxxxxx 29 CFR 1910.1200 (Hazard Communication required) XXXXXXXXXX
SARA TITLE III (SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT): XXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXX 302/304 Acute Health Hazard: Yes 311/312 HAZARD CATEGORIES: Chronic Health Hazard: Yes Fire Hazard: No Pressure Release Hazard: No Reactivity Hazard: No Xxxxxxxxxx 313 REPORTABLE INGREDIENTS: STATE REGULATIONS: CALIFORNIA PROPOSITION 65 (THE SAFE DRINKING WATER AND TOXICS ENFORCEMENT ACT of 1986)
This product does not contain known levels of any chemicals known to cause cancer or reproductive harm. SECTION 16: OTHER INFORMATION HAZARDOUS MATERIALS IDENTIFICATION SYSTEM HMIS HAZARD RATING 2 HEALTH 1 FLAMMABILITY 1 REACTIVITY C PERSONAL PROTECTION 4 – Severe, 3 – Serious, 2 – Moderate, 1 - Slight C – (Safety glasses, gloves, apron) The information provided herein was believed by Aquafin Inc. to be accurate at the time of preparation or prepared from sources believed to be reliable, but it is the responsibility of the user to investigate and understand other pertinent sources of information, to comply with all laws and procedures applicable to the safe handling and use of product and to determine the suitability of the product for its intended use.
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