Safety Data Sheet (SDS)
Page 1/7
OSHA HazCom Standard 29 CFR 1910.1200(g) and GHS Rev 03.
Printing date 01/31/2024
Reviewed on 01/31/2024 ______________________________________________________________________________________________________________ SECTION 1: PRODUCT AND COMPANY IDENTIFICATION IDENTITY:
Product Name: EPOXY-GEL Fast COMPONENT B Product Use Description:
AQUAFIN, INC. 505 BLUE BALL RD. #160 ELKTON, MD 21921
Epoxy Resin Adhesive, For Further Information, Refer to the Product Technical Data Sheet. 24 hr Emergency Phone: Chem-Tel (800) 255-3924 Information Phone No: (410) 392-2300
info@aquafin.net
www.aquafin.net
SECTION 2: HAZARDS IDENTIFICATION GHS Hazard:
ROUTES OF ENTRY:
SIGNAL WORD:
EYES:
YES
SKIN:
INGESTION:
INHALATION:
DANGER!
PHYSICAL HAZARDS: Not Classified
HEALTH HAZARDS (ACUTE AND CHRONIC) EYES: Serious Eye Damage Cat. 1. SKIN: Skin Irritant Cat. 2 Skin Sensitization Cat. 1. Skin Corrosion Cat. 1B INGESTION: Acute Oral Toxicity Cat. 4 Reproductive Toxicity Cat. 1B. Specific target organ toxicity- single exposure Cat.3 INHALATION: Reproductive Toxicity Cat. 1B. Specific target organ toxicity- single exposure Cat.3 ENVIRONMENTAL HAZARDS: Acute Aquatic Cat.2 Chronic Aquatic Cat.1 Acute Toxicity Cat.4 HAZARD STATEMENTS: H227 - Combustible liquid H302+H312 - Harmful if swallowed or in contact with skin H314 - Causes severe skin burns and eye damage H315 - Causes skin irritation H317 - May cause am allergic skin reaction H318 - Causes serioius eye damage H319 - Causes serious eye irritation H330 - Fatal if inhaled H335 - May cause respiratory irritation H361 - Suspected of damaging fertility or the unborn child. H373 - May cause damage to organs through prolonged or repeated exposure if swallowed. H410 - Very toxic to aquatic life with long lasting effects PRECAUTIONARY STATEMENTS: P201 - Obtain special instructions before use P260 - Do not breathe dust/fume/gas/mist/vapors/spray P261 - Avoid breathing dust/fume/gas/mist/vapors/spray. P262 - Do not get in eyes, on skin, or on clothing P264 - Wash…thoroughly after handling with soap and water
SDS EPOXY-GEL Fast Comp B SDS DATE: 24-JAN-31
Page 1 of 7
P270 - Do not eat, drink or smoke when using this product. P271 - Use only outdoors or in a well: ventilated area P273 - Avoid release to the environment P280 - Wear Protective gloves/protective clothing/eye protection/face protection P281 - Use personal protective equipment as required P301+P312 - IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. P301+P330+P331 - IF SWALLOWED: rinse mouth. DO NOT induce vomiting. P304+P340 - IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P303+P361+P353 - If ON SKIN (or hair): Remove/ take off immediately all contaminated clothing. Rinse skin with water/shower. P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses If present and easy to do. Continue rinsing. P310 - Immediately call a POSION CENTER or doctor/physician. P333+P337+P313 - If skin irritation or rash occurs and/or eye irritation persists: Get medical advice/attention. P363 - Wash contaminated clothing before reuse. P391 - Collect spillage. P403+P233 - Store in a well-ventilated place. Keep container tightly closed. P405 - Store locked up. P501 - Dispose of contents/container to an approved waste disposal plant. MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE: Persons with preexisting skin or respiratory disorders may have their conditions aggravated by over exposure to this material. HAZARDS NOT OTHERWISE CLASSIFIED This product is not for use in an aerosol or spray. This product contains a component that is toxic by inhalation when aerosolized or sprayed. Refer to Section 11 of the SDS for toxicity information. Review the toxicity information against your intended use. If product is not being aerosolized or sprayed, the inhalation toxicity may not be applicable. Very toxic by inhalation.
SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS
HAZARDOUS COMPONENTS
CAS #:
CAL-OSHA PEL TWA (8hours)
ACGIH TLV TWA (8 hours)
Other Limits RECOMMENDED
% BY WEIGHT
Diethylenetriamine
111-40-0
No Data
<15%
Benzyl Alcohol
100-51-6
<3%
4-tert-Butylphenol
98-54-4
<10%
2-sec-Butylphenol
89-72-5
<25%
2,4,6-tris(dimethylaminomethyl)phenol
90-72-2
<11%
Bis(dimethylaminomethyl)phenol
71074-89-0
<2%
4-sec-Butylphenol
99-71-8
4,4’-Methylenebis(cyclohexylamine)
1761-71-3
<16%
1,5-Diamino-2-methylpentane
15520-10-2
SECTION 4: FIRST AID MEASURES EYES: SKIN: INGESTION: INHALATION:
Immediately flush eyes with water for a minimum of 15 minutes while holding eyes open. Remove contact lenses if present and easy to do. If redness, burning, blurred vision, or swelling persists, consult a physician. Remove contaminated clothing and product. Immediately wash affected area with soap and water. Do not apply greases or ointments. If skin irritation persists, consult a physician. Rinse mouth immediately. Give small amounts of water, only if person is conscious. Only induce vomiting at the instruction of medical personnel. consult a physician Remove patient to fresh air. Give oxygen or artificial respiration if needed. If patient continues to experience difficulty breathing, consult a physician.
Page 2 of 7
SECTION 5: FIRE-FIGHTING MEASURES SUITABLE EXTINGUISHING MEDIA: SPECIAL FIRE FIGHTING PROCEDURES:
HAZARDOUS DECOMPOSITION PRODUCTS:
Extinguish with foam, carbon dioxide, dry powder, or water fog. Use standard fire-fighting procedures and consider the hazards of other involved materials. In case of a fire and / or explosion do not breathe fumes. Self-contained breathing apparatus and full protective clothing must be worn. Move containers from fire area if you can do so without risk. Cool containers with flooding quantities of water until well after fire is out. Prevent runoff from fire control or dilution from entering streams, sewers, or drinking water supply. Hazardous decomposition products may occur when material polymerizes at temperatures above 500 oF (260 oC). Irritating and toxic gases/fumes may be released during a fire. Do not allow run-off from fire-fighting to enter drains or water courses.
216 oF / 102 oC Tag Closed Cup (TCC)
FLASH POINT: METHOD USED:
SECTION 6: ACCIDENTAL RELEASE MEASURES PERSONAL PROTECTION:
Keep unnecessary personnel away. Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Wear appropriate personal protective equipment. Do not touch containers or spilled material unless wearing appropriate protective clothing. Avoid inhalation of vapors or mists. Ensure adequate ventilation. Local authorities should be advised if significant spillage cannot be contained. In case of spill, clean up using absorbent material such as earth or sand. Small quantities can be wiped up with cloth, place cloth in leak proof container and dispose of properly. Observe Federal, State and local regulations covering chemical waste spills.
ACCIDENTAL RELEASE MEASURES: WASTE DISPOSAL:
SECTION 7: HANDLING AND STORAGE PERSONAL PROTECTION: HANDLING AND STORAGE:
Use personal protective equipment to ensure product does not contact eyes or skin when handling materials. Store in cool dry place out of direct sunrays. Keep from freezing. Recommend storage temperatures range: between 40o and 95 oF (4o - 35 oC)
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION PROTECTIVE MEASURE: EYE PROTECTION: HAND PROTECTION: SKIN AND BODY PROTECTION: RESPIRATORY PROTECTION:
WORK HYGIENIC PRACTICES:
ENGINEERING CONTROLS:
Wear appropriate personal protective equipment. Wear appropriate safety glasses with side shields, goggles or full face shield. When working on an overhead application a full face shield is recommended. Wear chemical-resistant gloves such as: Nitrile, neoprene, butyl. Wear long sleeve shirts/long pants and other clothing as required to minimize contact. Do not breathe gas/fumes/vapor/ or spray. The use of a respirator is not required during general use of this product provided adequate ventilation. If grinding or cutting cured product the use of an approved respirator is recommended. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. When using indoors, good ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. Ready access to running water is required. Provide eyewash station.
EXPOSURE LIMITS Component Diethylenetriamine 111-40-0 Benzyl Alcohol 100-51-6 4-tert-ButylAlcohol 98-54-4 2-sec-Butylphenol 89-72-5 2,4,6-tris(dimethylaminomethyl)phenol 90-72-2
OSHA (PEL) No Data No Data No Data No Data No Data
ACGIH (TLV) No Data No Data No Data 5ppm No Data
NIOSH (Pocket Guide) 1 ppm (4mg/m3) skin No Data No Data 5ppm (30mg/m3)TWA skin No Data
Page 3 of 7
Bis(dimethylaminomethyl)phenol 71074-89-0 4-sec-Butylphenol 99-71-8 4,4’-Methylenebis(cyclohexylamine) 1761-71-3 1,5-Diamino-2-methylpentane 15520-10-2
No Data No Data No Data No Data
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES APPEARANCE: ODOR: PHYSICAL STATE: pH AS SUPPLIED: BOILING POINT: MELTING POINT: FREEZING POINT: VAPOR PRESSURE (mmHg: VAPOR DENSITY (AIR = 1): SPECIFIC GRAVITY (H2O = 1): EVAPORATION RATE: SOLUBILITY IN WATER: PERCENT SOLIDS BY WEIGHT: PERCENT VOLATILE: VOLATILE ORGANIC COMPOUNDS (VOC): MOLECULAR WEIGHT: VISCOSITY: FLASH POINT:
Black Viscous Mild/ Ammonia Liquid basic 402F (206C) N/D N/D N/D N/D 0.95 N/D Slight N/D N/D N/D 150 cps 190 Co
SECTION 10: STABILITY AND REACTIVITY STABILITY: CONDITIONS TO AVOID (STABILITY): INCOMPATIBILITY (MATERIAL TO AVOID): HAZARDOUS DECOMPOSITION OR BYPRODUCTS: HAZARDOUS POLYMERIZATION:
Stable Exposure to excessive heat and open flame Strong acids, peroxides and other oxidizing agents. Normal combustion forms carbon dioxide, carbon monoxide, oxides of carbon and other organic compounds, Will not occur
SECTION 11: TOXICOLOGICAL INFORMATION Acute Oral Toxicity: Oral-Components 4-tert-Butylphenol: Benzyl alcohol 4-sec-Butylphenol 4,4’-Methylenebis(cyclohexylamine) Acute Dermal Toxicity: Dermal-Components 4,4’-Methylenebis(cyclohexylamine) Acute Inhalation Toxicity: Inhalation components: Diethylenetriamine Benzyl Alcohol 4-tert-Butylphenol Skin Corrosion/ Irritation: Corrosion/Irritation Components 4,4’-Methylenebis(cyclohexylamine) 1,5-Diamino-2-methylpentane
No data available on the product itself LD50 >2000mg/kg (OECD Test Guidelines401) LD50 Oral Rat: 1230mg/kg LD50 Oral Rat: 2450mg/kg LD50 Oral Rat: 380mg/kg No data available on the product itself LD50 Dermal Rabbit: male and female: : >1000 mg/kg No data available on the product itself
LC50(4hr): >0.07-0.3 mg/L Species: Rat LC50 (4hr): >4.178 mg/L Species: Rat OECD Test Guideline 403 LCLO 5.6mg/l Species Rat OCED test guideline 403 Severe Skin Irritation/Corrosion Skin: Rabbit(24hr) : Corrosive RTECS: SA0248500 Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Cough, Shortness of breath, Headache, Nausea
Page 4 of 7
Eye Damage/Irritation: Damage/Irritation Components 4,4’-Methylenebis(cyclohexylamine) 4-tert-Butylphenol Respiratory Damage/Irritation: Damage/irritation Components Sensitization: Sensitization Components 4,4’-Methylenebis(cyclohexylamine)
Severe eye damage/irritation Eyes-Rabbit(24hr): Corrosive Cat. 1 irreversible effects on the eye Severe respiratory damage/irritation. May cause sensitization by inhalation and skin contact.
Buehler test-guinea pig–May cause sensitization by skin contact (OECD Test Guideline 406) Germ Cell Mutagenicity The product or a component may be mutagenic, the data is inconclusive. Maternal Toxicity: No data available on the product itself Carcinogenicity: This product contains no listed carcinogens according to IARC,ACGIH,NTP and/or OSHA in concentrations of 0.1 percent or greater. ACGIH: No data IARC: No data NTP No data OSHA No data SECTION 12: ECOLOGICAL INFORMATION ECOTOXICITY: Aquatic toxicity: Toxicity to Fish-Components Benzyl Alcohol Benzyl Alcohol 4-tert-Butylphenol 4-sec-Butylphenol 4,4’-Methylenebis(cyclohexylamine) Toxicity to algae-Components Benzyl Alcohol 4-tert-Butylphenol 4,4’-Methylenebis(cyclohexylamine) Toxicity-AquaticInvertabrates Benzyl Alcohol 4-tert-Butylphenol 4,4’-Methylenebis(cyclohexylamine) Toxicity to other organisims: PERSISTENCE & DEGRADABILITY: BIODEGRADABILITY: Biodegradability-Components 4-tert-Butylphenol BIOACCUMULATIVE POTENTIAL: BioAccumulaive-Components: 4-tert-Butylphenol 4-sec-Butylphenol MOBILITY IN SOIL: OTHER ADVERSE EFFECTS: AQUATIC RELEASE:
Exposure at low concentrations my kill fish LC50(96hr): 10 mg/l Species Bluegill sunfish (Lepomis macrochirus) LC50(96hr): 460 mg/l Species Flathead minnow (Pimephales promelas) LC50(96hr): 5.14mg/l Species: Fathead Minnow LC50(96hr): 0.74mg/l Species: Atlantic Salmon (Salmo salar) LC50(96hr): 67.8mg/l Species: Golden orfe(Leucisus idus) DIN 38412 IC50(72hr): 700mg/l Species: Algae IC50(72hr): 11.2mg/l Species: Algae (Desmodesmus subspicatus) EC50(72hr): 140-200mg/l Species: Green Algae (Desmodesmus subspicatus) EC50(24h): 55mg/l Species: Daphnia magna(OECD Test Guideline 202) EC50(48hr) 4.8mg/l Species: Daphnia magna (OECD Test Guideline 202) EC50(48hr): 9.24mg/l Species: Daphnia Magna EC50(30min): 156mg/l Bacteria: Pseudomonas putida
60% Biodegradable: aerobic-exposure time 28d (OECD Test Guideline 301F)
BCF 120 (3d): 46ug/L Species: Leuciscus idus melanotus BCF 20.43(8w): 40mg/L Species Cyprinus carpio BCF 28 (96hr) : 560mg/l Species: Atlantic salmon (Salmo salar) NDA NDA Advise authorities if product has entered or may enter watercourses or sewer drains.
Page 5 of 7
SECTION 13: DISPOSAL CONSIDERATIONS WASTE DISPOSAL METHOD:
Do not allow this material to drain into sewers / waterways, ditches, containment pools or water supplies. Dispose of contents / containers in accordance with local/regional/international regulations.
SECTION 14: TRANSPORT INFORMATION U.S. DEPARTMENT OF TRANSPORTATION (DOT) PROPER SHIPPING NAME: HAZARD CLASS (sub class): ID NUMBER: PACKING GROUP: LABEL STATEMENT:
CORROSIVE LIQUID, TOXIC, N.O.S. (CONTAIN AMINES) 8 (6.1) UN2922 II CORROSIVE
WATER TRANSPORTATION (IMDG) PROPER SHIPPING NAME: HAZARD CLASS (sub class): ID NUMBER: PACKING GROUP: LABEL STATEMENT: MARINE POLLUTANT:
CORROSIVE LIQUID, TOXIC, N.O.S. (CONTAIN AMINES) 8 (6.1) UN2922 II CORROSIVE Yes
AIR TRANSPORTATION (IATA / ICAO) PROPER SHIPPING NAME: HAZARD CLASS (sub class): ID NUMBER: PACKING GROUP: LABEL STATEMENT:
SECTION 15: REGULATORY INFORMATION U.S. FEDERAL REGULATIONS TSCA (TOXIC SUBSTANCE CONTROL ACT): CERCLA (COMPREHENSIVE RESPONSE COMPENSATION, AND LIABILITY ACT): OSHA: WHMIS
29 CFR 1910.1200 (Hazard Communication required) Class B 3, Class D A, Class E
SARA TITLE III (SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT): 302/304 311/312 HAZARD CATEGORIES: Acute Health Hazard: Chronic Health Hazard: Fire Hazard: Pressure Release Hazard: Reactivity Hazard: 313 REPORTABLE INGREDIENTS: N/A
Yes Yes No No No
STATE REGULATIONS: CALIFORNIA PROPOSITION 65 (THE SAFE DRINKING WATER AND TOXICS ENFORCEMENT ACT) This product contains chemicals in trace quantities that are on the California Proposition 65 carcinogens list.
Page 6 of 7
SECTION 16: OTHER INFORMATION HAZARDOUS MATERIALS IDENTIFICATION SYSTEM HMIS HAZARD RATING 3 HEALTH 1 FLAMMABILITY 1 REACTIVITY C PERSONAL PROTECTION 4 – Severe, 3 – Serious, 2 – Moderate, 1 - Slight C – (Safety glasses, gloves, apron)
The information provided herein was believed to be accurate at the time of preparation or prepared from sources believed to be reliable, but it is the responsibility of the user to investigate and understand other pertinent sources of information, to comply with all laws and procedures applicable to the safe handling and use of product and to determine the suitability of the product for its intended use.
Page 7 of 7