Safety Data Sheet (SDS)
Page 1/6
OSHA HazCom Standard 29 CFR 1910.1200(g) and GHS Rev 03.
Printing date 08/29/2022
Reviewed on 08/29/2022
SECTION 1: PRODUCT AND COMPANY IDENTIFICATION
IDENTITY:
Product Name: EPOXY Healer-Sealer COMPONENT A Product Use Description: Epoxy-Acrylic Resin Coating, For Further Information, Refer to the Product
Technical Data Sheet
AQUAFIN, INC. 505 BLUE BALL RD. #160 ELKTON, MD 21921
24 hr Emergency Phone: Chem-Tel (800) 255-3924 Information Phone No: (410) 392-2300
info@aquafin.net
www.aquafin.net
SECTION 2: HAZARDS IDENTIFICATION GHS Hazard:
ROUTES OF ENTRY: SIGNAL WORD:
EYE:
SKIN:
YES
INGESTION:
INHALATION:
DANGER!
PHYSICAL HAZARDS: Not Classified HEALTH HAZARDS: (ACUTE AND CHRONIC) Eye Irritant Cat. 2 EYES: Skin Irritant Cat. 2 SKIN: Skin Sensitization Cat. 1 No Data INGESTION: Respiratory Irritant INHALATION: ENVIRONMENTAL HAZARDS: Acute Aquatic Cat.2 Chronic Aquatic Cat.2 HAZARD STATEMENTS:
H315 - Causes skin irritation H317 - May cause an allergic skin reaction H319 - Causes serious eye irritation H411 - Toxic to aquatic life with long lasting effects
PRECAUTIONARY STATEMENTS: P262 - Do not get in eyes, on skin, or on clothing P264 - Wash…thoroughly after handling with soap and water P272 – Contaminated work clothing should not be allowed out of the workplace. P280 - Wear Protective gloves/protective clothing/eye protection/face protection P273 - Avoid release to the environment P302+P352 – IF ON SKIN: Wash with plenty of soap and water. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove Contact lenses, if present and easy to do. Continue rinsing. P333+P313 - If skin irritation or rash occurs: Get medical advice/attention. P337+P313 – If eye irritation persists: Get medical advice/attention. P362 – Take off contaminated clothing and wash before reuse. P501 – Dispose of contents/container to an approved waste disposal plant. MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE: Persons with preexisting skin or respiratory disorders may have their conditions aggravated by over exposure to this material. SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS
HAZARDOUS COMPONENTS 2,3-epoxypropyl o-tolyl ether
SDS EPOXY Healer-Sealer Comp A SDS DATE: 22-AUG-29
CAS #: 2210-79-9
CAL-OSHA PEL TWA (8hours) No data available
ACGIH TLV TWA (8 hours) No data available
Other Limits RECOMMENDED N/E
% BY WEIGHT <20%
Page 1 of 6
EPOXY Healer-Sealer, Component A Safety Data Sheet
Formaldehyde, oligiomeric reaction products with 1-chloro-2,3-epoxypropane and phenol
9003-36-5
Hexamethylene diacrylate Trimethylolpropane triacrylate
No data available
N/E
<60%
13048-33-4
1 mg/m3 (DSEN) OARS-WEEL
<18
15625-89-5
1 mg/m3 (skin) OARS-WEEL
<9
SECTION 4: FIRST AID MEASURES EYES: SKIN: INGESTION: INHALATION:
Immediately flush eyes with water for a minimum of 15 minutes while holding eyes open. Remove contact lenses if present and easy to do. If redness, burning, blurred vision, or swelling persists, consult a physician. Remove contaminated clothing and product. Immediately wash affected area with soap and water. Do not apply greases or ointments. If skin irritation persists, consult a physician. Rinse mouth immediately. Give small amounts of water, only if person is conscious. Only induce vomiting at the instruction of medical personnel. consult a physician Remove patient to fresh air. Give oxygen or artificial respiration if needed. If patient continues to experience difficulty breathing, consult a physician.
SECTION 5: FIRE-FIGHTING MEASURES SUITABLE EXTINGUISHING MEDIA: SPECIAL FIRE FIGHTING PROCEDURES:
HAZARDOUS DECOMPOSITION PRODUCTS:
FLASH POINT: METHOD USED:
Extinguish with foam, carbon dioxide, dry powder, or water fog. Use standard fire-fighting procedures and consider the hazards of other involved materials. In case of a fire and / or explosion do not breathe fumes. Self-contained breathing apparatus and full protective clothing must be worn. Move containers from fire area if you can do so without risk. Cool containers with flooding quantities of water until well after fire is out. Prevent runoff from fire control or dilution from entering streams, sewers, or drinking water supply. Hazardous decomposition products may occur when material polymerizes at temperatures above 500 oF (260 oC). Irritating and toxic gases/fumes may be released during a fire. Do not allow run-off from fire-fighting to enter drains or water courses.
>250 oF / 121 oC PMCC
SECTION 6: ACCIDENTAL RELEASE MEASURES PERSONAL PROTECTION:
ACCIDENTAL RELEASE MEASURES: WASTE DISPOSAL:
Keep unnecessary personnel away. Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Wear appropriate personal protective equipment. Do not touch containers or spilled material unless wearing appropriate protective clothing. Avoid inhalation of vapors or mists. Ensure adequate ventilation. Local authorities should be advised if significant spillage cannot be contained. In case of spill, clean up using absorbent material such as earth or sand. Small quantities can be wiped up with cloth, place cloth in leak proof container and dispose of properly. Observe Federal, State and local regulations covering chemical waste spills.
SECTION 7: HANDLING AND STORAGE PERSONAL PROTECTION: HANDLING AND STORAGE:
Use personal protective equipment to ensure product does not contact eyes or skin when handling materials. Store in cool, dry place out of direct sun rays. Keep from freezing. Recommend storage temperatures range: between 40o and 95 oF (4o - 35 oC)
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION PROTECTIVE MEASURE: EYE PROTECTION: HAND PROTECTION: SKIN AND BODY PROTECTION: RESPIRATORY PROTECTION: WORK HYGIENIC PRACTICES:
Wear appropriate personal protective equipment. Wear appropriate safety glasses with side shields, goggles or full face shield. When working on an overhead application a full face shield is recommended. Wear chemical-resistant gloves such as: Nitrile, neoprene, butyl. Wear long sleeve shirts/long pants and other clothing as required to minimize contact. Do not breathe gas/fumes/vapor/ or spray. The use of a respirator is not required during general use of this product provided adequate ventilation. If grinding or cutting cured product the use of an approved respirator is recommended. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants.
Page 2 of 6
ENGINEERING CONTROLS:
When using indoors, good ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. Ready access to running water is required. Provide eyewash station.
EXPOSURE LIMITS Component 2,3-epoxypropyl o-tolyl ether 2210-79-9 Formaldehyde, oligiomeric reaction products with 1chloro-2,3-epoxypropane and phenol 9003-36-5 Hexamethylene diacrylate 13048-33-4 Trimethylolpropane triacrylate 15625-89-5
OSHA (PEL) No data available No data available
ACGIH (TLV) No data available No data available
NIOSH (Pocket Guide) No data available No data available
No data available No data available
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES APPEARANCE: ODOR: PHYSICAL STATE: pH AS SUPPLIED: BOILING POINT: MELTING POINT: FREEZING POINT: VAPOR PRESSURE (mmHg: VAPOR DENSITY (AIR = 1): SPECIFIC GRAVITY (H2O = 1): EVAPORATION RATE: SOLUBILITY IN WATER: PERCENT SOLIDS BY WEIGHT: PERCENT VOLATILE: VOLATILE ORGANIC COMPOUNDS (VOC): MOLECULAR WEIGHT: VISCOSITY:
Amber Color ND Liquid N/D >100 C N/D N/D N/D N/D 1.1 @ 25oC Negligible Negligible 0% N/D ND ND ND
SECTION 10: STABILITY AND REACTIVITY STABILITY: CONDITIONS TO AVOID (STABILITY): INCOMPATIBILITY (MATERIAL TO AVOID): HAZARDOUS DECOMPOSITION OR BYPRODUCTS: HAZARDOUS POLYMERIZATION:
Stable Exposure to excessive heat and open flame Strong acids, peroxides and other oxidizing agents. Normal combustion forms carbon dioxide, peroxides, strong bases, reactive metals, carbon monoxide, oxides of carbon and other organic compounds, Will not occur
SECTION 11: TOXICOLOGICAL INFORMATION Acute Oral Toxicity: Oral-Components Trimethylolpropane triacrylate Acute Dermal Toxicity: Dermal-Components
No data available on the product itself
Hexamethylene diacrylate
LD50 Rabbit – 3650 mg/kg (OECD Test Guideline 402)
Trimethylolpropane triacrylate Acute Inhalation Toxicity: Inhalation-Components
LD50 5170 mg/l Rabbit
Hexamethylene diacrylate Skin Corrosion/ Irritation: Corrosion/Irritation Components Trimethylolpropane triacrylate
LC0(7hr) 0.41 mg/l Rat – M/F
Hexamethylene diacrylate Sensitization: Sensitization Components Trimethylolpropane triacrylate
LC50(6hr) >0.55mg/l Rat – M/F No data available on the product itself
Irritating to skin Rabbit – Irritating to skin 24hr Irritating to skin May cause sensitization by inhalation and skin contact. May cause sensitization by inhalation and skin contact.
Page 3 of 6
Hexamethylene diacrylate Germ Cell Mutagenicity
May cause sensitization by inhalation and skin contact. The product or a component may be mutagenic, the data is inconclusive.
Maternal Toxicity:
Carcinogenicity: ACGIH: IARC: NTP OSHA
This product contains no listed carcinogens according to IARC,ACGIH,NTP and/or OSHA in concentrations of 0.1 percent or greater. No data No data No data No data
SECTION 12: ECOLOGICAL INFORMATION ECOTOXICITY: Aquatic toxicity: Toxicity to Fish-Components Formaldehyde, oligiomeric reaction products with 1-chloro-2,3-epoxypropane and phenol 9003-36-5
LC50(96hr) 0.5mg/l Species: Oncorhynchus mykiss static test LC50 - Leuciscus idus (Golden orfe) - 4.6 - 10 mg/l - 96 h (DIN 38412)
Toxicity to algae-Components Formaldehyde, oligiomeric reaction products with 1-chloro-2,3-epoxypropane and phenol 9003-36-5 Hexamethylene diacrylate
PERSISTENCE & DEGRADABILITY: BIODEGRADABILITY: Biodegradability-Components
EC50(72hr) 1.8mg/l Species: elenastrum capricornutum
static test EC50 - Desmodesmus subspicatus (Scenedesmus subspicatus) - 1.5 mg/l - 72 h
Not readily biodegradable. 0% degradation after 28 days.
BIOACCUMULATIVE POTENTIAL: BioAccumulaive-Components:
High Formaldehyde, oligiomeric reaction products with 1-chloro-2,3-epoxypropane and phenol: LogP0w : 3.
MOBILITY IN SOIL: OTHER ADVERSE EFFECTS: AQUATIC RELEASE:
NDA NDA Advise authorities if product has entered or may enter watercourses or sewer drains.
SECTION 13: DISPOSAL CONSIDERATIONS WASTE DISPOSAL METHOD:
Do not allow this material to drain into sewers / waterways, ditches, containment pools or water supplies. Dispose of contents / containers in accordance with local/regional/international regulations.
Page 4 of 6
SECTION 14: TRANSPORT INFORMATION U.S. DEPARTMENT OF TRANSPORTATION PROPER SHIPPING NAME: HAZARD CLASS: Not Regulated for Transportation ID NUMBER: PACKING GROUP: LABEL STATEMENT: HAZARD CLASS:
NONE
WATER TRANSPORTATION PROPER SHIPPING NAME: HAZARD CLASS: ID NUMBER: PACKING GROUP: LABEL STATEMENT:
ID NUMBER:
D.O.T SHIPPING LABEL:
NOT REGULATED BY D.O.T
Environmentally hazardous substance, liquid n.o.s. (Epoxy Resin Mixture), Marine Pollutant 9 UN3082 III
AIR TRANSPORTATION PROPER SHIPPING NAME: HAZARD CLASS: ID NUMBER: PACKING GROUP: LABEL STATEMENT:
Environmentally hazardous substance, liquid n.o.s. (Epoxy Resin Mixture) , Marine Pollutant 9 UN3082 III
Page 5 of 6
SECTION 15: REGULATORY INFORMATION U.S. FEDERAL REGULATIONS TSCA (TOXIC SUBSTANCE CONTROL ACT): CERCLA (COMPREHENSIVE RESPONSE COMPENSATION, AND LIABILITY ACT): OSHA: WHMIS
None. Included on Inventory
29 CFR 1910.1200 (Hazard Communication required) Class D-2B: Toxic material causing other toxic effects (Toxic).
SARA TITLE III (SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT): No Ingredients Listed. 302/304 Acute Health Hazard: 311/312 HAZARD CATEGORIES: Chronic Health Hazard: Fire Hazard: Pressure Release Hazard: Reactivity Hazard: No ingredients listed. 313 REPORTABLE INGREDIENTS:
Yes Yes No No No
STATE REGULATIONS: CALIFORNIA PROPOSITION 65 (THE SAFE DRINKING WATER AND TOXICS ENFORCEMENT ACT of 1986)
This product does not contain known levels of any chemicals known to cause cancer or reproductive harm. SECTION 16: OTHER INFORMATION HAZARDOUS MATERIALS IDENTIFICATION SYSTEM HMIS HAZARD RATING 2 HEALTH 1 FLAMMABILITY 2 REACTIVITY C PERSONAL PROTECTION 4 – Severe, 3 – Serious, 2 – Moderate, 1 - Slight C – (Safety glasses, gloves, apron) The information provided herein was believed by Aquafin Inc. to be accurate at the time of preparation or prepared from sources believed to be reliable, but it is the responsibility of the user to investigate and understand other pertinent sources of information, to comply with all laws and procedures applicable to the safe handling and use of product and to determine the suitability of the product for its intended use.
Page 6 of 6