Safety Data Sheet (SDS)
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OSHA HazCom Standard 29 CFR 1910.1200(g) and GHS Rev 03.
Printing date 08/29/2022
Reviewed on 08/29/2022
______________________________________________________________________________________________________________ SECTION 1: PRODUCT AND COMPANY IDENTIFICATION
IDENTITY:
Product Name: EPOXY Healer-Sealer COMPONENT B Product Use Description: Epoxy-Acrylic Resin Coating, For Further Information, Refer to the Product
Technical Data Sheet
AQUAFIN, INC. 505 BLUE BALL RD. #160 ELKTON, MD 21921
24 hr Emergency Phone: Chem-Tel (800) 255-3924 Information Phone No: (410) 392-2300
info@aquafin.net
www.aquafin.net
SECTION 2: HAZARDS IDENTIFICATION GHS Hazard:
ROUTES OF ENTRY: SIGNAL WORD:
EYES:
YES
SKIN:
INGESTION:
INHALATION:
DANGER!
PHYSICAL HAZARDS: Not Classified HEALTH HAZARDS (ACUTE AND CHRONIC) Serious Eye Damage Cat. 1. EYES: Skin Irritant Cat. 2 SKIN: Acute Toxicity Cat. 4 Skin Sensitization Cat. 1. Skin Corrosion Cat. 1B Acute Oral Toxicity Cat. 4 INGESTION: Acute Toxicity Cat. 4. INHALATION: Reproductive Toxicity Cat. 2 OTHER: Specific Target Organ Toxicity – single exposure Cat. 3 ENVIRONMENTAL HAZARDS: Acute Aquatic Cat.2 Chronic Aquatic Cat.1 Acute Toxicity Cat.4 HAZARD STATEMENTS: H227 - Combustible liquid H302+H312+H332 - Harmful if swallowed, inhaled or in contact with skin H314 - Causes severe skin burns and eye damage H315 - Causes skin irritation H317 - May cause am allergic skin reaction H318 - Causes serious eye damage H319 - Causes serious eye irritation H330 - Fatal if inhaled H335 - May cause respiratory irritation H361 - Suspected of damaging fertility or the unborn child H373 - May cause damage to organs through prolonged or repeated exposure if swallowed. H410 - Very toxic to aquatic life with long lasting effects PRECAUTIONARY STATEMENTS: P201 - Obtain special instructions before use P260 - Do not breathe fume/gas/mist/vapors/spray P261 - Avoid breathing fume/gas/mist/vapors/spray. P262 - Do not get in eyes, on skin, or on clothing P264 - Wash…thoroughly after handling with soap and water P271 - Use only outdoors or in a well-ventilated area P273 - Avoid release to the environment P280 - Wear protective gloves/protective clothing/eye protection/face protection
SDS EPOXY Healer-Sealer Comp B SDS DATE: 22-AUG-29
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EPOXY Healer-Sealer, Component B Safety Data Sheet
P281 - Use personal protective equipment as required P301+P330+P331 - IF SWALLOWED: rinse mouth. DO NOT induce vomiting. P304+P340 - IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses If present and easy to do. Continue rinsing. P310 - Immediately call a poison center or doctor/physician P333+P337+P313 - If skin irritation or rash occurs and/or eye irritation persists: Get medical advice/attention. P363 - Wash contaminated clothing before reuse. P403+P233 - Store in a well ventilated place. Keep container tightly closed. P405 - Store locked up. P501 - Dispose of contents/container to an approved waste disposal plant. MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE: Persons with preexisting skin or respiratory disorders may have their conditions aggravated by over exposure to this material. HAZARDS NOT OTHERWISE CLASSIFIED This product is not for use in an aerosol or spray. This product contains a component that is toxic by inhalation when aerosolized or sprayed. Refer to Section 11 of the SDS for toxicity information. Review the toxicity information against your intended use. If product is not being aerosolized or sprayed, the inhalation toxicity may not be applicable. Very toxic by inhalation. SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS
HAZARDOUS COMPONENTS
CAS #:
CAL-OSHA PEL TWA (8hours)
ACGIH TLV TWA (8 hours)
Other Limits RECOMMENDED
% BY WEIGHT
1,3 Benzenedimethanamine
1477-55-0
No Data
0.1 mg/m3
>10%
Diethylenetriamine
111-40-0
Phenol, 4,4’-(1-methylethylidene)bis
80-05-7
SECTION 4: FIRST AID MEASURES EYES: SKIN: INGESTION: INHALATION:
Immediately flush eyes with water for a minimum of 15 minutes while holding eyes open. Remove contact lenses if present and easy to do. Get medical attention immediately. If physician is not available, continue flushing with water for 1 hour. Do NOT use chemical antidote. Remove contaminated clothing and product and wash before reuse with a heavy detergent. Immediately wash affected area with soap and water for 15 minutes. Do not apply greases or ointments. If skin irritation persists, consult a physician. Rinse mouth immediately and drink two large glasses of water. Never give anything by mouth to an unconscious person. Only induce vomiting at the instruction of medical personnel. Consult a physician. Remove patient to fresh air. Give oxygen or artificial respiration if needed. If patient experiences difficulty breathing or a burning sensation in the throat or chest get medical attention immediately.
SECTION 5: FIRE-FIGHTING MEASURES SUITABLE EXTINGUISHING MEDIA: SPECIAL FIRE FIGHTING PROCEDURES:
HAZARDOUS DECOMPOSITION PRODUCTS:
FLASH POINT: METHOD USED:
Extinguish with foam, carbon dioxide, dry powder, or water fog. Water or foam may cause frothing, especially if sprayed directly into containers of hot, burning liquid. Use standard fire-fighting procedures and consider the hazards of other involved materials. In case of a fire and / or explosion do not breathe fumes. Self-contained breathing apparatus and full protective clothing must be worn. Move containers from fire area if you can do so without risk. Cool containers with flooding quantities of water until well after fire is out. Prevent runoff from fire control or dilution from entering streams, sewers, or drinking water supply. Hazardous decomposition products such as carbon monoxide, ammonia gas, toxic nitrogen oxide gases, and amines may occur when material polymerizes at temperatures above 500 oF (260 oC). Irritating and toxic gases/fumes may be released during a fire. Do not allow run-off from fire-fighting to enter drains or water courses.
102 C (216F) TCC
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SECTION 6: ACCIDENTAL RELEASE MEASURES PERSONAL PROTECTION:
ACCIDENTAL RELEASE MEASURES:
WASTE DISPOSAL:
Keep unnecessary personnel away. Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Wear appropriate personal protective equipment, including a selfcontained breathing apparatus and chemical protective clothing. Do not touch containers or spilled material unless wearing appropriate protective clothing. Avoid inhalation of vapors or mists. Ensure adequate ventilation. Local authorities should be advised if significant spillage cannot be contained. Evacuate personnel to safe areas. In case of spill, clean up using absorbent material such as earth or sand. Small quantities can be wiped up with cloth, place cloth in leak proof container and dispose of properly. This material is toxic to fish and other aquatic organisms. Do not allow run-off to enter rivers, streams, lakes, or other bodies of water. Observe Federal, State and local regulations covering chemical waste spills.
SECTION 7: HANDLING AND STORAGE PERSONAL PROTECTION: HANDLING AND STORAGE:
Use personal protective equipment to ensure product does not contact eyes or skin when handling materials. Eye wash facilities and an emergency shower must be readily available when handling this product. Store in cool dry place out of direct sunrays. Keep from freezing. Recommend storage temperatures range: between 40o and 95 oF (4o - 35 oC). Store away from oxidizing materials and acids.
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION PROTECTIVE MEASURE: EYE PROTECTION: HAND PROTECTION: SKIN AND BODY PROTECTION: RESPIRATORY PROTECTION: WORK HYGIENIC PRACTICES: ENGINEERING CONTROLS:
Wear appropriate personal protective equipment. Wear appropriate safety glasses with side shields, goggles or full face shield. When working on an overhead application a full face shield is recommended. Wear chemical-resistant, impervious gloves such as: Nitrile, neoprene, butyl. Wear impervious long sleeve shirts/long pants and other clothing as required to minimize contact. Do not breathe gas/fumes/vapor/ or spray. The use of a respirator is not required during general use of this product provided adequate ventilation. If grinding or cutting cured product the use of an approved respirator is recommended. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. When using indoors, good ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. Ready access to running water is required. Provide eyewash station.
EXPOSURE LIMITS Component
OSHA (PEL)
ACGIH (TLV)
NIOSH (Pocket Guide)
Diethylenetriamine 111-40-0
1 ppm (4mg/m3)
1,3 Benzenedimethanamine 1477-55-0
Phenol, 4,4’-(1-methylethylidene)bis 80-05-7
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SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES APPEARANCE: ODOR: PHYSICAL STATE: pH AS SUPPLIED: BOILING POINT: MELTING POINT: FREEZING POINT: VAPOR PRESSURE (mmHg: VAPOR DENSITY (AIR = 1): SPECIFIC GRAVITY (H2O = 1): EVAPORATION RATE: SOLUBILITY IN WATER: PERCENT SOLIDS BY WEIGHT: PERCENT VOLATILE: VOLATILE ORGANIC COMPOUNDS (VOC): MOLECULAR WEIGHT: VISCOSITY:
Dark purple/black Mild/ Ammonia Liquid Basic 217 F (103 C) N/D N/D 1mm (DETA) Heavier than air 0.97 Negligible Slight No Data N/D N/D N/D 95 Cps
SECTION 10: STABILITY AND REACTIVITY STABILITY: CONDITIONS TO AVOID (STABILITY): INCOMPATIBILITY (MATERIAL TO AVOID): HAZARDOUS DECOMPOSITION OR BYPRODUCTS: HAZARDOUS POLYMERIZATION:
Stable under normal conditions of temperature and pressure. Exposure to excessive heat and open flame Strong acids, reactive metals, peroxides and other oxidizing agents. Normal combustion forms carbon dioxide, carbon monoxide, oxides of nitrogen and other organic compounds, Will not occur
SECTION 11: TOXICOLOGICAL INFORMATION Acute Oral Toxicity:
LD50 (rat) 930 mg/kg
Acute Dermal Toxicity:
LD50 (Rabbit) 1,090 mg/kg
Acute Inhalation Toxicity:
No data available on the product itself
Skin Corrosion/ Irritation:
Severe Skin Irritation/Corrosion
Eye Damage/Irritation:
Severe eye damage/irritation
Respiratory Damage/Irritation:
Severe respiratory damage/irritation.
Germ Cell Mutagenicity
The product or a component may be mutagenic, the data is inconclusive.
Maternal Toxicity:
Carcinogenicity: ACGIH: IARC: NTP OSHA
This product contains no listed carcinogens according to IARC,ACGIH,NTP and/or OSHA in concentrations of 0.1 percent or greater. No data No data No data No data
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SECTION 12: ECOLOGICAL INFORMATION ECOTOXICITY: 96 hr. LC50 Oryzias Latipes 48 hr. EC50 Daphnia magna 72 hr EC50 Selenastrum capricornutum 21 day NOEC Daphnia magna Toxicity to STP Microorganisms 3 hr EC50 PERSISTENCE & DEGRADABILITY: BIODEGRADABILITY: BIOACCUMULATIVE POTENTIAL: MOBILITY IN SOIL: OTHER ADVERSE EFFECTS: AQUATIC RELEASE:
87.6 mg/l (OECD 203) 15.2 mg/l (OECD 202) 20.3 mg/l, NOEC 10.5 mg/l (OECD 201) 4.7 mg/l (OECD 211) >1000 mg/l, activated sludge (OECD 209)
Not readily biodegradable. 49% degradation in a CO2 evolution Ready Biodegradation test in 28 days (OECD 301B) Will not bio-accumulate – (calculated BCF value 3.16 l/kg) Partition coefficient @ 77 oF (25 oC) – 0.18 OECD107 The product is miscible in water and may spread in water systems. None known. Advise authorities if product has entered or may enter watercourses or sewer drains.
SECTION 13: DISPOSAL CONSIDERATIONS WASTE DISPOSAL METHOD:
Do not allow this material to drain into sewers / waterways, ditches, containment pools or water supplies. Dispose of contents / containers in accordance with local/regional/international regulations. Incineration is the recommended disposal method for chemical wastes such as this product and residues of this product. This product, if disposed of, may be considered a corrosive waste (D002) under current RCRA regulations due to the pH of the material.
SECTION 14: TRANSPORT INFORMATION U.S. DEPARTMENT OF TRANSPORTATION (DOT) PROPER SHIPPING NAME: HAZARD CLASS: ID NUMBER: PACKING GROUP: LABEL STATEMENT:
Amines, liquide, corrosive, n.o.s. (m-xylenediamine mixture) 8 UN2735 II Corrosive
WATER TRANSPORTATION (IMDG) PROPER SHIPPING NAME: HAZARD CLASS: ID NUMBER: PACKING GROUP: LABEL STATEMENT:
Amines, liquide, corrosive, n.o.s. (m-xylenediamine mixture), Marine Polluant 8 UN2735 II Corrosive
AIR TRANSPORTATION (IATA / ICAO) PROPER SHIPPING NAME: HAZARD CLASS: ID NUMBER: PACKING GROUP: LABEL STATEMENT:
Amines, liquide, corrosive, n.o.s. (m-xylenediamine mixture), Marine Pollutant 8 UN2735 II Corrosive
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SECTION 15: REGULATORY INFORMATION U.S. FEDERAL REGULATIONS TSCA (TOXIC SUBSTANCE CONTROL ACT): CERCLA (COMPREHENSIVE RESPONSE COMPENSATION, AND LIABILITY ACT):
Included on inventory
SARA TITLE III (SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT): N/A 302: Acute Health Hazard: 311/312 HAZARD CATEGORIES: Chronic Health Hazard: Fire Hazard: Pressure Release Hazard: Reactivity Hazard: Phenol, 4,4’-(1-Methylethylidene)bis 313 PORTABLE INGREDIENTS:
Yes No No No No
STATE REGULATIONS: CALIFORNIA PROPOSITION 65 (THE SAFE DRINKING WATER AND TOXICS ENFORCEMENT ACT) This product contains chemicals in trace quantities that are on the California Proposition 65 carcinogens list. SECTION 16: OTHER INFORMATION HAZARDOUS MATERIALS IDENTIFICATION SYSTEM HMIS HAZARD RATING 3 HEALTH 1 FLAMMABILITY 1 REACTIVITY C PERSONAL PROTECTION 4 – Severe, 3 – Serious, 2 – Moderate, 1 - Slight C – (Safety glasses, gloves, apron)
The information provided herein was believed by Aquafin Inc. to be accurate at the time of preparation or prepared from sources believed to be reliable, but it is the responsibility of the user to investigate and understand other pertinent sources of information, to comply with all laws and procedures applicable to the safe handling and use of product and to determine the suitability of the product for its intended use.
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