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Safety Data Sheet (SDS) OSHA HazCom Standard 29 CFR 1910.1200(g) and GHS Rev 03.
Issue date 11/02/2018
Reviewed on 11/02/2018
* 1 Identification · Product Identifier · Trade Name: EPOXY-MV Component B · Relevant identified uses of the substance or mixture and uses advised against: No further relevant information available. · Product Description: Medium-viscosity epoxy adhesive · Details of the Supplier of the Safety Data Sheet: · Manufacturer/Supplier: Aquafin Inc. 505 Blue Ball Road #160 Elkton, MD 21921 Phone: 410-392-2300 Fax: 410-392-2324 Email: info@aquafin.net Web: www.aquafin.net · Emergency telephone number: Chemtrec at 1-800-424-9300 24 Hours Outside the U.S., call Chemtrec collect at 703-527-3887
2 Hazard(s) Identification · Classification of the substance or mixture: Health hazard Resp. Sens. 1 Repr. 2
H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. H361 Suspected of damaging fertility or the unborn child.
Corrosion Skin Corr. 1B Eye Dam. 1
H314 Causes severe skin burns and eye damage. H318 Causes serious eye damage.
Environment Aquatic Acute 1 H400 Very toxic to aquatic life. Aquatic Chronic 1 H410 Very toxic to aquatic life with long lasting effects.
Acute Tox. 4 Skin Sens. 1
H302 Harmful if swallowed. H317 May cause an allergic skin reaction.
Flam. Liq. 4
H227 Combustible liquid.
· Label elements: · GHS label elements The product is classified and labeled according to the Globally Harmonized System (GHS). (Contd. on page 2)
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Trade Name: EPOXY-MV Component B · Hazard pictograms:
GHS05 GHS07 GHS08 GHS09 · Signal word: Danger · Hazard-determining components of labeling: 4-nonylphenol, branched Tall Oil Fatty Acids, Reaction Product With Tiethylenetetramine triethylenetetramine · Hazard statements: H227 Combustible liquid. H302 Harmful if swallowed. H314 Causes severe skin burns and eye damage. H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. H317 May cause an allergic skin reaction. H361 Suspected of damaging fertility or the unborn child. H400 Very toxic to aquatic life. H410 Very toxic to aquatic life with long lasting effects. · Precautionary statements: P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been read and understood. P210 Keep away from flames and hot surfaces. – No smoking. P260 Do not breathe dusts or mists. P261 Avoid breathing dust/fume/gas/mist/vapors/spray. P264 Wash thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P272 Contaminated work clothing must not be allowed out of the workplace. P273 Avoid release to the environment. P280 Wear protective gloves/protective clothing/eye protection/face protection. P284 [In case of inadequate ventilation] wear respiratory protection. P301+P312 If swallowed: Call a poison center/doctor if you feel unwell. P301+P330+P331 If swallowed: Rinse mouth. Do NOT induce vomiting. P302+P352 If on skin: Wash with plenty of water. P303+P361+P353 If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/ shower. P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P304+P341 If inhaled: If breathing is difficult, remove person to fresh air and keep comfortable for breathing. P305+P351+P338 If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310 Immediately call a poison center/doctor. P308+P313 IF exposed or concerned: Get medical advice/attention. P321 Specific treatment (see supplementary first aid instructions on this Safety Data Sheet). P333+P313 If skin irritation or rash occurs: Get medical advice/attention. P342+P311 If experiencing respiratory symptoms: Call a poison center/doctor. P363 Wash contaminated clothing before reuse. P370+P378 In case of fire: Use for extinction: CO2, powder or water spray. P391 Collect spillage. P403+P235 Store in a well-ventilated place. Keep cool. (Contd. on page 3)
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Trade Name: EPOXY-MV Component B P405 P501
Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations. · Unknown acute toxicity: 90 % of the mixture consists of component(s) of unknown toxicity. · Classification system: · NFPA ratings (scale 0 - 4)
3
1
Health = 3 Fire = 1 Reactivity = 0
0
· HMIS-ratings (scale 0 - 4) HEALTH
*3
FIRE
REACTIVITY 0
Health = *3 Fire = 1 Physical Hazard = 0
· Hazard(s) not otherwise classified (HNOC): None known
3 Composition/Information on Ingredients · Chemical characterization: Mixtures · Description: Mixture of substances listed below with non-hazardous additions. · Dangerous Components: 25-50% 84852-15-3 4-nonylphenol, branched Repr. 2, H361; Skin Corr. 1B, H314; Aquatic Acute 1, H400; Aquatic Chronic 1, H410; Acute Tox. 4, H302 68919-79-9 Tall Oil Fatty Acids, Reaction Product With Tiethylenetetramine 25-50% Resp. Sens. 1B, H334; Acute Tox. 4, H302; Acute Tox. 4, H312; Skin Irrit. 2, H315; Skin Sens. 1B, H317; Eye Irrit. 2B, H320 112-24-3 triethylenetetramine 5-10% Skin Corr. 1B, H314; Acute Tox. 4, H312; Skin Sens. 1, H317; Aquatic Chronic 3, H412 · Additional information: The exact percentages of the ingredients of this mixture are considered to be proprietary and are withheld in accordance with the provisions of paragraph (i) of §1910.1200 of 29 CFR 1910.1200 Trade Secrets.
4 First-Aid Measures · Description of first aid measures · General information: Immediately remove any clothing soiled by the product. Symptoms of poisoning may occur after exposure to dust, fumes or particulates; seek medical attention if feeling unwell. · After inhalation: In case of unconsciousness place patient stably in side position for transportation. Supply fresh air. If required, provide artificial respiration. Consult doctor if symptoms persist. · After skin contact: Immediately wash with water and soap and rinse thoroughly. · After eye contact: Rinse opened eye for several minutes under running water. Then consult a doctor. · After swallowing: Drink copious amounts of water and provide fresh air. Immediately call a doctor. · Information for doctor · Most important symptoms and effects, both acute and delayed: No further relevant information available.
(Contd. on page 4)
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Trade Name: EPOXY-MV Component B · Indication of any immediate medical attention and special treatment needed: No further relevant information available.
5 Fire-Fighting Measures · Extinguishing media · Suitable extinguishing agents: CO₂, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant foam. · For safety reasons unsuitable extinguishing agents: No further relevant information is available. · Special hazards arising from the substance or mixture: Combustible liquid. Vapors can travel to a source of ignition and flash back. Explosive mixtures may occur at temperatures at or above flashpoint. · Advice for firefighters · Special protective equipment for firefighters: As in any fire, wear self-contained breathing apparatus pressure-demand (NIOSH approved or equivalent) and full protective gear to prevent contact with skin and eyes.
6 Accidental Release Measures · Personal precautions, protective equipment and emergency procedures: Wear protective equipment. Keep unprotected persons away. · Environmental precautions: Do not allow product to reach sewage system or any water course. Inform respective authorities in case of seepage into water course or sewage system. Do not allow to enter sewers/surface or ground water. · Methods and material for containment and cleaning up: Ensure adequate ventilation. Use neutralizing agent. Absorb with liquid-binding material (i.e. sand, diatomite, acid binders, universal binders, sawdust). Dispose contaminated material as waste according to section 13. · Reference to other sections: See Section 7 for information on safe handling. See Section 8 for information on personal protection equipment. See Section 13 for disposal information. · Protective Action Criteria for Chemicals · PAC-1: 84852-15-3 4-nonylphenol, branched 3.9 mg/m³ 112-24-3 triethylenetetramine 3 ppm · PAC-2: 84852-15-3 4-nonylphenol, branched 112-24-3 triethylenetetramine
43 mg/m³ 14 ppm
· PAC-3: 84852-15-3 4-nonylphenol, branched 112-24-3 triethylenetetramine
260 mg/m³ 83 ppm
7 Handling and Storage · Handling · Precautions for safe handling: Ensure good ventilation/exhaustion at the workplace. Avoid contact with skin, eyes and clothing Avoid breathing fume/gas/mist/vapors/spray. (Contd. on page 5)
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Trade Name: EPOXY-MV Component B Do not take internally. Use personal protection equipment as outlined in section 8. Prevent formation of aerosols. · Information about protection against explosions and fires: Protect from heat. Keep ignition sources away - Do not smoke. · Conditions for safe storage, including any incompatibilities · Storage · Requirements to be met by storerooms and receptacles: Store in a cool, dry place in tightly closed receptacles. · Information about storage in one common storage facility: Not required. · Further information about storage conditions: Protect from heat and direct sunlight. · Specific end use(s): No further relevant information available.
8 Exposure Controls/Personal Protection · Additional information about design of technical systems: No further data; see section 7. · Control parameters: · Components with occupational exposure limits: The following constituent is the only constituent of the product which has a PEL, TLV or other recommended exposure limit. At this time, the other constituents have no known exposure limits. 112-24-3 triethylenetetramine WEEL Long-term value: 6 mg/m³, 1 ppm Skin · Additional information: The lists that were valid during the creation of this SDS were used as basis. · Exposure controls: · Personal protective equipment · General protective and hygienic measures: Keep away from foodstuffs, beverages and feed. Immediately remove all soiled and contaminated clothing and wash before reuse. Wash hands before breaks and at the end of work. Avoid contact with the eyes and skin. · Breathing equipment: In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure, use respiratory protective device that is independent of circulating air. · Protection of hands: Protective gloves The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the chemical mixture. Select glove material based on penetration times, rates of diffusion and degradation. · Material of gloves: The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material cannot be calculated in advance and has therefore to be checked prior to the application. (Contd. on page 6)
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Issue date 11/02/2018 Trade Name: EPOXY-MV Component B
· Penetration time of glove material: The exact break-through time has to be determined and observed by the manufacturer of the protective gloves. · Eye protection: Tightly sealed goggles
9 Physical and Chemical Properties · Information on basic physical and chemical properties · General Information · Appearance: Liquid Form: Amber Color: · Odour: Distinctive · Odor threshold: Not determined. · pH-value @ 20 °C (68 °F):
12
· Change in condition Melting point/Melting range: Boiling point/Boiling range:
Not determined. 220 °C (428 °F)
· Flash point:
92 °C (197.6 °F)
· Flammability (solid, gaseous):
Not applicable.
· Ignition temperature:
315 °C (599 °F)
· Decomposition temperature:
Not determined.
· Auto igniting:
Product is not self-igniting.
· Danger of explosion:
· Explosion limits: Lower: Upper:
2.1 Vol % 10.5 Vol %
· Vapor pressure @ 20 °C (68 °F):
0.1 hPa (0.1 mm Hg)
· Density @ 20 °C (68 °F): · Relative density: · Vapor density: · Evaporation rate:
0.956 g/cm³ (7.9778 lbs/gal) Not determined. Not determined. Not determined.
· Solubility in / Miscibility with: Water:
Not miscible or difficult to mix.
· Partition coefficient (n-octanol/water): Not determined. · Viscosity: Dynamic: Kinematic:
Not determined. Not determined.
· Solvent content: Organic solvents:
0.0 %
(Contd. on page 7)
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Issue date 11/02/2018 Trade Name: EPOXY-MV Component B · Other information:
No further relevant information available.
10 Stability and Reactivity · Reactivity: No further relevant information available. · Chemical stability: Stable under normal conditions. · Thermal decomposition / conditions to be avoided: Carbon Oxides · Possibility of hazardous reactions: Reacts with oxidizing agents. · Conditions to avoid: Heat and direct sunlight · Incompatible materials: Strong oxidizing agents.
11 Toxicological Information · Information on toxicological effects: · Acute toxicity: · LD/LC50 values that are relevant for classification: 84852-15-3 4-nonylphenol, branched Oral LD50 1,412 mg/kg (Rat) 112-24-3 triethylenetetramine Oral LD50 2,500 mg/kg (Rat) Dermal LD50 805 mg/kg (Rabbit) · Primary irritant effect: · On the skin: Strong caustic effect on skin and mucous membranes. May cause an allergic skin reaction. · On the eye: Strong irritant with the danger of severe eye injury. Corrosive effect. Causes serious eye irritation. · Sensitization: Sensitization possible through inhalation. Sensitization possible through skin contact. · Additional toxicological information: The product shows the following dangers according to internally approved calculation methods for preparations: Harmful Corrosive Irritant Swallowing will lead to a corrosive effect on mouth and throat and to the danger of perforation of esophagus and stomach. · Carcinogenic categories: · IARC (International Agency for Research on Cancer): None of the ingredients are listed. · NTP (National Toxicology Program): None of the ingredients are listed. · OSHA-Ca (Occupational Safety & Health Administration): None of the ingredients are listed. (Contd. on page 8)
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12 Ecological Information · Toxicity: · Aquatic toxicity: Avoid release into the environment. Runoff from fire control or dilution water may cause pollution. 84852-15-3 4-nonylphenol, branched EC50 0.844 mg/l (Daphnia) · Persistence and degradability: No further relevant information available. · Behavior in environmental systems: · Bioaccumulative potential: No further relevant information available. · Mobility in soil: No further relevant information available. · Ecotoxical effects: · Remark: Very toxic for fish · Additional ecological information: · General notes: Do not allow product to reach ground water, water course or sewage system. Must not reach bodies of water or drainage ditch undiluted or unneutralized. Danger to drinking water if even small quantities leak into the ground. Poisonous for fish and plankton in water bodies. Very toxic for aquatic organisms Rinse off of bigger amounts into drains or the aquatic environment may lead to increased pH-values. A high pH-value harms aquatic organisms. In the dilution of the use-level the pH-value is considerably reduced, so that after the use of the product the aqueous waste, emptied into drains, is only low water-dangerous. · Results of PBT and vPvB assessment: · PBT: Not applicable. · vPvB: Not applicable. · Other adverse effects: No further relevant information available.
13 Disposal Considerations · Waste treatment methods · Recommendation: Must not be disposed of together with household garbage. Do not allow product to reach sewage system. · Uncleaned packaging · Recommendation: Disposal must be made according to official regulations.
14 Transport Information · UN-Number: · DOT, ADR/ADN, IMDG, IATA · UN proper shipping name: · DOT · ADR/ADN · IMDG · IATA
UN3266 Corrosive liquid, basic, inorganic, n.o.s. (4-nonylphenol, branched, Triethylenetetramine) UN3266 Corrosive liquid, basic, inorganic, n.o.s. (4-nonylphenol, branched, Triethylenetetramine), ENVIRONMENTALLY HAZARDOUS CORROSIVE LIQUID, BASIC, INORGANIC, N.O.S. (4nonylphenol, branched, TRIETHYLENETETRAMINE), MARINE POLLUTANT CORROSIVE LIQUID, BASIC, INORGANIC, N.O.S. (4nonylphenol, branched, TRIETHYLENETETRAMINE) (Contd. on page 9)
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Issue date 11/02/2018 Trade Name: EPOXY-MV Component B · Transport hazard class(es): · DOT
· Class: · Label:
8 Corrosive substances 8
· ADR/ADN
8 (C5) Corrosive substances 8
· IMDG
· IATA
· Class: · Label: · Packing group: · DOT, ADR/ADN, IMDG, IATA · Environmental hazards:
8 Corrosive substances 8 II Product contains environmentally hazardous substances: 4nonylphenol, branched Symbol (fish and tree) Warning: Corrosive substances 80 F-A,S-B Alkalis B SW2 Clear of living quarters. SG35 Stow "separated from" acids.
· Special marking (ADR/ADN): · Special precautions for user: · Danger code (Kemler): · EMS Number: · Segregation groups: · Stowage Category · Stowage Code · Segregation Code · Transport in bulk according to Annex II of Not applicable. MARPOL73/78 and the IBC Code: · Transport/Additional information: · DOT · Quantity limitations:
On passenger aircraft/rail: 1 L On cargo aircraft only: 30 L
(Contd. on page 10)
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Issue date 11/02/2018 Trade Name: EPOXY-MV Component B · Remarks: · ADR/ADN · Excepted quantities (EQ):
· IMDG · Limited quantities (LQ): · Excepted quantities (EQ): · UN "Model Regulation":
Special marking with the symbol (fish and tree). Code: E2 Maximum net quantity per inner packaging: 30 ml Maximum net quantity per outer packaging: 500 ml 1L Code: E2 Maximum net quantity per inner packaging: 30 ml Maximum net quantity per outer packaging: 500 ml UN 3266 CORROSIVE LIQUID, BASIC, INORGANIC, N.O.S. ( 4 - N O N Y L P H E N O L , B R A N C H E D , TRIETHYLENETETRAMINE), 8, II, ENVIRONMENTALLY HAZARDOUS
15 Regulatory Information · Safety, health and environmental regulations/legislation specific for the substance or mixture: · SARA (Superfund Amendments and Reauthorization): · Section 355 (extremely hazardous substances): None of the ingredients are listed. · Section 313 (Specific toxic chemical listings): 84852-15-3 4-nonylphenol, branched · TSCA (Toxic Substances Control Act): All ingredients are listed or exempt from listing. · California Proposition 65: · Chemicals known to cause cancer: None of the ingredients are listed. · Chemicals known to cause reproductive toxicity for females: None of the ingredients are listed. · Chemicals known to cause reproductive toxicity for males: None of the ingredients are listed. · Chemicals known to cause developmental toxicity: None of the ingredients are listed. · New Jersey Right-to-Know List: 112-24-3 triethylenetetramine · New Jersey Special Hazardous Substance List: 112-24-3 triethylenetetramine
CO
· Pennsylvania Right-to-Know List: 112-24-3 triethylenetetramine · Pennsylvania Special Hazardous Substance List: None of the ingredients are listed. (Contd. on page 11)
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Trade Name: EPOXY-MV Component B · Carcinogenic categories: · EPA (Environmental Protection Agency): None of the ingredients are listed. · TLV (Threshold Limit Value established by ACGIH): None of the ingredients are listed. · NIOSH-Ca (National Institute for Occupational Safety and Health): None of the ingredients are listed. · GHS label elements The product is classified and labeled according to the Globally Harmonized System (GHS). · Hazard pictograms:
GHS05 GHS07 GHS08 GHS09 · Signal word: Danger · Hazard-determining components of labeling: 4-nonylphenol, branched Tall Oil Fatty Acids, Reaction Product With Tiethylenetetramine triethylenetetramine · Hazard statements: H227 Combustible liquid. H302 Harmful if swallowed. H314 Causes severe skin burns and eye damage. H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. H317 May cause an allergic skin reaction. H361 Suspected of damaging fertility or the unborn child. H400 Very toxic to aquatic life. H410 Very toxic to aquatic life with long lasting effects. · Precautionary statements: P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been read and understood. P210 Keep away from flames and hot surfaces. – No smoking. P260 Do not breathe dusts or mists. P261 Avoid breathing dust/fume/gas/mist/vapors/spray. P264 Wash thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P272 Contaminated work clothing must not be allowed out of the workplace. P273 Avoid release to the environment. P280 Wear protective gloves/protective clothing/eye protection/face protection. P284 [In case of inadequate ventilation] wear respiratory protection. P301+P312 If swallowed: Call a poison center/doctor if you feel unwell. P301+P330+P331 If swallowed: Rinse mouth. Do NOT induce vomiting. P302+P352 If on skin: Wash with plenty of water. P303+P361+P353 If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/ shower. P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. (Contd. on page 12)
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Trade Name: EPOXY-MV Component B P304+P341
If inhaled: If breathing is difficult, remove person to fresh air and keep comfortable for breathing. P305+P351+P338 If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310 Immediately call a poison center/doctor. P308+P313 IF exposed or concerned: Get medical advice/attention. P321 Specific treatment (see supplementary first aid instructions on this Safety Data Sheet). P333+P313 If skin irritation or rash occurs: Get medical advice/attention. P342+P311 If experiencing respiratory symptoms: Call a poison center/doctor. P363 Wash contaminated clothing before reuse. P370+P378 In case of fire: Use for extinction: CO2, powder or water spray. P391 Collect spillage. P403+P235 Store in a well-ventilated place. Keep cool. P405 Store locked up. P501 Dispose of contents/container in accordance with local/regional/national/international regulations. · National regulations: None of the ingredients are listed. · Chemical safety assessment: A Chemical Safety Assessment has not been carried out.
16 Other Information The information and recommendations in this safety data sheet are, to the best of our knowledge, accurate as of the date of issue. Nothing herein shall be deemed to create warranty, expressed or implied, and shall not establish a legally valid contractual relationship. It is the responsibility of the user to determine applicability of this information and the suitability of the material or product for any particular purpose. · Date of preparation / last revision: 11/02/2018 / 8 · Abbreviations and acronyms:
ADR: The European Agreement concerning the International Carriage of Dangerous Goods by Road ADN: The European Agreement concerning the International Carriage of Dangerous Goods by Inland Waterways IMDG: International Maritime Code for Dangerous Goods DOT: US Department of Transportation IATA: International Air Transport Association ACGIH: American Conference of Governmental Industrial Hygienists EINECS: European Inventory of Existing Commercial Chemical Substances ELINCS: European List of Notified Chemical Substances CAS: Chemical Abstracts Service (division of the American Chemical Society) NFPA: National Fire Protection Association (USA) HMIS: Hazardous Materials Identification System (USA) LC50: Lethal concentration, 50 percent LD50: Lethal dose, 50 percent PBT: Persistent, Bioaccumulative and Toxic vPvB: very Persistent and very Bioaccumulative NIOSH: National Institute for Occupational Safety and Health OSHA: Occupational Safety & Health Administration TLV: Threshold Limit Value PEL: Permissible Exposure Limit REL: Recommended Exposure Limit Flam. Liq. 4: Flammable liquids – Category 4 Acute Tox. 4: Acute toxicity – Category 4 Skin Corr. 1B: Skin corrosion/irritation – Category 1B Skin Irrit. 2: Skin corrosion/irritation – Category 2 Eye Dam. 1: Serious eye damage/eye irritation – Category 1 Eye Irrit. 2B: Serious eye damage/eye irritation – Category 2B Resp. Sens. 1: Respiratory sensitisation – Category 1 Resp. Sens. 1B: Respiratory sensitisation – Category 1B Skin Sens. 1: Skin sensitisation – Category 1 Skin Sens. 1B: Skin sensitisation – Category 1B Repr. 2: Reproductive toxicity – Category 2 (Contd. on page 13)
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Issue date 11/02/2018 Trade Name: EPOXY-MV Component B Aquatic Acute 1: Hazardous to the aquatic environment - acute aquatic hazard – Category 1 Aquatic Chronic 1: Hazardous to the aquatic environment - long-term aquatic hazard – Category 1 Aquatic Chronic 3: Hazardous to the aquatic environment - long-term aquatic hazard – Category 3
· * Data compared to the previous version altered. SDS created by MSDS Authoring Services www.msdsauthoring.com
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