SDS_EPOXY-N161 B Component - 121422.pdf
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<h1>SDS_EPOXY-N161 B Component - 121422.pdf</h1> <p>EPOXY-N161 (Novolac) COMPONENT B - SAFETY DATASHEET <br />SECTION 1: PRODUCT AND COMPANY IDENTIFICATION <br />PRODUCT NAME: <br />SYNONYMS: <br />PRODUCT CODES:</p> <p>EPOXY-N161 (Novolac)</p> <p>Part: B</p> <p>MANUFACTURER: <br />ADDRESS:</p> <p>Aquafin Inc. <br />505 Blue Ball Rd., #160 <br />Elkton, MD 21921 <br />+1-410-392-2300</p> <p>EMERGENCY PHONE: <br />Chemtrec:</p> <p>PHONE: <br />RECOMENDED USE:</p> <p>(800) 255-3924</p> <p>Epoxy Resin, For further information refer to the Product Data Sheet.</p> <p>SECTION 2: HAZARDS IDENTIFICATION <br />GHS Hazard:</p> <p>ROUTES OF ENTRY: <br />SIGNAL WORD:</p> <p>EYES:</p> <p>YES</p> <p>SKIN:</p> <p>YES</p> <p>INGESTION:</p> <p>YES</p> <p>INHALATION:</p> <p>YES</p> <p>DANGER!</p> <p>HEALTH HAZARDS (ACUTE AND CHRONIC) <br />Serious Eye Damage Cat. 2. <br />EYES: <br />Eye irritation Cat. 2 <br />Acute Dermal Toxicity Cat.4 <br />SKIN: <br />Skin Irritant Cat. 2 <br />Skin Sensitization Cat. 1. <br />Skin Corrosion Cat. 1B <br />Acute Oral Toxicity Cat. 4 <br />INGESTION: <br />INHALATION:</p> <p>Acute Toxicity Cat 4</p> <p>ENVIRONMENTAL HAZARDS: <br />Acute Aquatic Cat.1 <br />Chronic Aquatic Cat.1 <br />Acute Toxicity Cat.4 <br />HAZARD STATEMENTS: <br />H302+H312+H332 - Harmful if swallowed, inhaled or in contact with skin <br />H314 - Causes severe skin burns and eye damage <br />H315 - Causes skin irritation <br />H317 - May cause am allergic skin reaction <br />H318 - Causes serioius eye damage <br />H332 - Harmful if inhaled <br />PRECAUTIONARY STATEMENTS: <br />P201 - Obtain special instructions before use <br />P202 - Do not handle until all safety regulations have been read and understood. <br />P261 - Avoid breathing dust/fume/gas/mist/vapors/spray. <br />P264 - Wash…thoroughly after handling with soap and water <br />P270 - Do not eat, drink or smoke when using this product. <br />P271 - Use only outdoors or in a well-ventilated area <br />P273 - Avoid release to the environment <br />P280 - Wear Protective gloves/protective clothing/eye protection/face protection <br />P301+P312 - IF SWALLOWED Call a POISON CENTER or doctor/physician if you feel unwell. <br />P301+P330+P331 - IF SWALLOWED rinse mouth. DO NOT induce vomiting. <br />P304+P340 - IF INHALED Remove victim to fresh air and keep at rest in a position comfortable for breathing. <br />P303+P361+P353 - If ON SKIN (or hair): Remove/ take off immediately all contaminated clothing. Rinse skin with</p> <p>EPOXY-N161 (Novolac)-b <br />SDS DATE: 22-Dec-14</p> <p>PAGE 1 OF 6</p> <p>EPOXY-N161 (Novolac) COMPONENT B - SAFETY DATASHEET <br />water/shower. <br />P305+P351+P338 - IF IN EYES Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to <br />do. Continue rinsing. <br />P333+P313 - If skin irritation or rash occurs: Get medical advice/attention. <br />P363 - Wash contaminated clothing before reuse. <br />P370+P378 - In case of fire: Use dry sand, dry chemical or alcohol-resistant foam for extinction. <br />P391 - Collect spillage. <br />P403+P235 - Store in a well-ventilated place. Keep cool. <br />P405 - Store locked up. <br />P501 - Dispose of contents/container to an approved waste disposal plant. <br />MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE: <br />Persons with preexisting skin or respiratory disorders may have their conditions aggravated by over exposure to this material. <br />This product is not for use in an aerosol or spray. This product contains a component that is toxic by inhalation when <br />aerosolized or sprayed. Refer to Section 11 of the SDS for toxicity information. Review the toxicity information against your <br />intended use. If product is not being aerosolized or sprayed, inhalation toxicity is not applicable. <br />SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS</p> <p>HAZARDOUS COMPONENTS</p> <p>CAS #:</p> <p>CAL-OSHA <br />PEL TWA <br />(8hours)</p> <p>ACGIH TLV <br />TWA (8 <br />hours)</p> <p>Other Limits <br />RECOMMENDED</p> <p>% BY <br />WEIGHT</p> <p>2,2'-iminodiethylamine</p> <p>111-40-0</p> <p>No Data</p> <p>No Data</p> <p>30-50</p> <p>Benzenediamine, ar, ar-diethyl-ar-methyl-</p> <p>68479-98-1</p> <p>No Data</p> <p>No Data</p> <p>30-50</p> <p>2-sec-BUTYLPHENOL</p> <p>89-72-5</p> <p>No Data</p> <p>No Data</p> <p>30-50</p> <p>SECTION 4: FIRST AID MEASURES <br />EYES: <br />SKIN: <br />INGESTION: <br />INHALATION:</p> <p>Immediately flush eyes with water for a minimum of 15 minutes while holding eyes open. Remove contact lenses if <br />present and easy to do. If redness, burning, blurred vision, or swelling persists, consult a physician. <br />Remove contaminated clothing and product. Immediately wash affected area with soap and water. Do not apply <br />greases or ointments. If skin irritation persists, consult a physician. <br />Rinse mouth immediately. Give small amounts of water, only if person is conscious. Only induce vomiting at the <br />instruction of medical personnel. consult a physician <br />Remove patient to fresh air. Give oxygen or artificial respiration if needed. If patient continues to experience difficulty <br />breathing, consult a physician. Call Poison Center</p> <p>SECTION 5: FIRE-FIGHTING MEASURES <br />SUITABLE EXTINGUISHING MEDIA: <br />SPECIAL FIRE FIGHTING PROCEDURES:</p> <p>HAZARDOUS DECOMPOSITION PRODUCTS:</p> <p>FLASH POINT: <br />METHOD USED:</p> <p>EPOXY-N161 (Novolac)-b <br />SDS DATE: 22-Dec-14</p> <p>Extinguish with foam, carbon dioxide, dry powder, or water fog. <br />Use standard fire-fighting procedures and consider the hazards of other involved <br />materials. In case of a fire and / or explosion do not breathe fumes. Self-contained <br />breathing apparatus and full protective clothing must be worn. Move containers from <br />fire area if you can do so without risk. Cool containers with flooding quantities of <br />water until well after fire is out. Prevent runoff from fire control or dilution from <br />entering streams, sewers, or drinking water supply. <br />Hazardous decomposition products may occur when material polymerizes at <br />temperatures above 500 oF (260 oC). Irritating and toxic gases/fumes may be <br />released during a fire. Do not allow run-off from fire-fighting to enter drains or water <br />courses.</p> <p>205 oF / 96 oC <br />(TCC)</p> <p>PAGE 2 OF 6</p> <p>EPOXY-N161 (Novolac) COMPONENT B - SAFETY DATASHEET <br />SECTION 6: ACCIDENTAL RELEASE MEASURES <br />PERSONAL PROTECTION:</p> <p>ACCIDENTAL RELEASE MEASURES: <br />WASTE DISPOSAL:</p> <p>Keep unnecessary personnel away. Eliminate all ignition sources (no smoking, flares, sparks, <br />or flames in immediate area). Wear appropriate personal protective equipment. Do not touch <br />containers or spilled material unless wearing appropriate protective clothing. Avoid inhalation <br />of vapors or mists. Ensure adequate ventilation. Local authorities should be advised if <br />significant spillage cannot be contained. <br />In case of spill, clean up using absorbent material such as earth or sand. Small quantities can <br />be wiped up with cloth, place cloth in leak proof container and dispose of properly. <br />Observe Federal, State and local regulations covering chemical waste spills.</p> <p>SECTION 7: HANDLING AND STORAGE <br />PERSONAL PROTECTION: <br />HANDLING AND STORAGE:</p> <p>Use personal protective equipment to ensure product does not contact eyes or skin when handling <br />materials. <br />Store in cool dry place out of direct sunrays. Keep from freezing. Recommend storage temperatures <br />range: between 40o and 95 oF (4o - 35 oC)</p> <p>SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION <br />PROTECTIVE MEASURE: <br />EYE PROTECTION: <br />HAND PROTECTION: <br />SKIN AND BODY PROTECTION: <br />RESPIRATORY PROTECTION:</p> <p>WORK HYGIENIC PRACTICES:</p> <p>ENGINEERING CONTROLS:</p> <p>Wear appropriate personal protective equipment. <br />Wear appropriate safety glasses with side shields, goggles or full face shield. When working on an <br />overhead application a full face shield is recommended. <br />Wear chemical-resistant gloves such as: Nitrile, neoprene, butyl. <br />Wear long sleeve shirts/long pants and other clothing as required to minimize contact. <br />Do not breathe gas/fumes/vapor/ or spray. The use of a respirator is not required during general <br />use of this product provided adequate ventilation. If grinding or cutting cured product the use of an <br />approved respirator is recommended. <br />Always observe good personal hygiene measures, such as washing after handling the material and <br />before eating, drinking and/or smoking. Routinely wash work clothing and protective equipment to <br />remove contaminants. <br />When using indoors, good ventilation (typically 10 air changes per hour) should be used. <br />Ventilation rates should be matched to conditions. Ready access to running water is required. <br />Provide eyewash station.</p> <p>EXPOSURE LIMITS <br />Component <br />2,2'-iminodiethylamine 111-40-0 <br />Benzenediamine, ar, ar-diethyl-ar-methyl68479-98-1 <br />2-sec-BUTYLPHENOL – 89-72-5</p> <p>EPOXY-N161 (Novolac)-b <br />SDS DATE: 22-Dec-14</p> <p>OSHA (PEL)</p> <p>ACGIH (TLV)</p> <p>NIOSH (Pocket Guide)</p> <p>No Data</p> <p>No Data</p> <p>No Data</p> <p>No Data</p> <p>No Data</p> <p>No Data</p> <p>No Data</p> <p>TWA 5 ppm</p> <p>TWA 30mg/m3</p> <p>PAGE 3 OF 6</p> <p>EPOXY-N161 (Novolac) COMPONENT B - SAFETY DATASHEET <br />SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES <br />APPEARANCE: <br />ODOR: <br />PHYSICAL STATE: <br />pH AS SUPPLIED: <br />BOILING POINT: <br />MELTING POINT: <br />FREEZING POINT: <br />VAPOR PRESSURE (mm Hg): <br />VAPOR DENSITY (AIR = 1): <br />SPECIFIC GRAVITY (H2O = 1): <br />EVAPORATION RATE: <br />SOLUBILITY IN WATER: <br />PERCENT SOLIDS BY WEIGHT: <br />PERCENT VOLATILE: <br />VOLATILE ORGANIC COMPOUNDS (VOC): <br />MOLECULAR WEIGHT: <br />VISCOSITY:</p> <p>Amber liquid <br />Ammonia <br />Liquid <br />Alkaline <br />ND <br />N/D <br />N/D <br />1 mmHg 20C (DETA) <br />Heavier than air <br />1.0 <br />Negligible <br />Slight <br />No Data <br />Negligible <br />No Data <br />N/D <br />1400 cp.</p> <p>SECTION 10: STABILITY AND REACTIVITY <br />STABILITY: <br />CONDITIONS TO AVOID (STABILITY): <br />INCOMPATIBILITY (MATERIAL TO AVOID): <br />HAZARDOUS DECOMPOSITION OR BYPRODUCTS: <br />HAZARDOUS POLYMERIZATION:</p> <p>Stable <br />Exposure to excessive heat and open flame <br />Strong acids, peroxides and other oxidizing agents. <br />Normal combustion forms carbon dioxide, carbon monoxide, oxides of carbon and other <br />organic compounds, <br />Will not occur</p> <p>SECTION 11: TOXICOLOGICAL INFORMATION <br />CAS# <br />Acute Oral Toxicity: <br />No data available on the product itself <br />2,2'-iminodiethylamine <br />111-40-0 <br />LD50: Oral Rat: 1080 mg/kg <br />Benzenediamine,ar, ar-diethyl-ar68479-98-1 <br />LD50: Oral Rat: 738 mg/kg <br />methyl2-sec-BUTYLPHENOL – <br />89-72-5 <br />LD50: Oral Rat: 200-2000 mg/kg (OECD 401) <br />Acute Dermal Toxicity: <br />No data available on the product itself <br />2,2'-iminodiethylamine <br />111-40-0 <br />LD50 1090 mg/kg Species: Rabbit <br />LD50 Dermal Rabbit M : >2000 mg/kg <br />Benzenediamine,ar, ar-diethyl-ar68479-98-1 <br />methylLD50 Dermal Rabbit : 5560 mg/kg <br />2-sec-BUTYLPHENOL – <br />89-72-5 <br />Acute Inhalation Toxicity: <br />No data available on the product itself <br />Inhalation/toxicity Components <br />2,2'-iminodiethylamine <br />111-40-0 <br />LC50 4 hours – 0.3mg/l Species: Rat <br />Carcinogenicity: <br />This product contains no listed carcinogens according to IARC, ACGIH, NTP and/or OSHA in concentrations of 0.1 percent or <br />greater. <br />No data <br />ACGIH: <br />No data <br />IARC: <br />No data <br />NTP <br />No data <br />OSHA</p> <p>EPOXY-N161 (Novolac)-b <br />SDS DATE: 22-Dec-14</p> <p>PAGE 4 OF 6</p> <p>EPOXY-N161 (Novolac) COMPONENT B - SAFETY DATASHEET <br />SECTION 12: ECOLOGICAL INFORMATION <br />ECOTOXICITY: <br />Aquatic toxicity: <br />Toxicity to Fish-Components <br />2,2'-iminodiethylamine <br />Benzenediamine,ar, ar-diethyl-armethyl2-sec-BUTYLPHENOL – <br />Toxicity to algae-Components <br />2,2'-iminodiethylamine <br />Benzenediamine,ar, ar-diethyl-armethyl2-sec-BUTYLPHENOL – <br />Toxicity-Aquatic Invertebrates <br />2,2'-iminodiethylamine <br />Benzenediamine,ar, ar-diethyl-armethyl2-sec-BUTYLPHENOL – <br />PERSISTENCE & DEGRADABILITY: <br />BIODEGRADABILITY: <br />2,2'-iminodiethylamine <br />Benzenediamine,ar, ar-diethyl-armethyl2-sec-BUTYLPHENOL – <br />BIOACCUMULATIVE POTENTIAL: <br />MOBILITY IN SOIL: <br />OTHER ADVERSE EFFECTS: <br />AQUATIC RELEASE:</p> <p>CAS# <br />Exposure at low concentrations my kill fish <br />111-40-0 <br />68479-98-1</p> <p>NA <br />LC50(96hr): 104 mg/l Species: Fathead Minnow</p> <p>89-72-5</p> <p>LC50(96hr): 0.05 mg/l Species: Fish</p> <p>111-40-0 <br />68479-98-1</p> <p>NA <br />EC50(72hr): 104 mg/l Species: Algae</p> <p>89-72-5</p> <p>EC50(72hr): 10 mg/l Species: Algae</p> <p>111-40-0 <br />68479-98-1</p> <p>NA <br />EC50(48hr): 5.8 mg/l Species: Daphnia</p> <p>89-72-5</p> <p>EC50(48hr): 3.7 mg/l Species: Daphnia</p> <p>111-40-0 <br />68479-98-1</p> <p>NA <br />Not readily biodegradable</p> <p>89-72-5</p> <p>Biodegrades Slowly <br />NA <br />Yes <br />NDA <br />Advise authorities if product has entered or may enter watercourses or <br />sewer drains.</p> <p>SECTION 13: DISPOSAL CONSIDERATIONS <br />WASTE DISPOSAL METHOD:</p> <p>EPOXY-N161 (Novolac)-b <br />SDS DATE: 22-Dec-14</p> <p>Do not allow this material to drain into sewers / waterways, ditches, containment pools or water <br />supplies. Dispose of contents / containers in accordance with local/regional/international <br />regulations.</p> <p>PAGE 5 OF 6</p> <p>EPOXY-N161 (Novolac) COMPONENT B - SAFETY DATASHEET <br />SECTION 14: TRANSPORT INFORMATION <br />U.S. DEPARTMENT OF TRANSPORTATION (DOT) <br />PROPER SHIPPING NAME: <br />HAZARD CLASS: <br />ID NUMBER: <br />PACKING GROUP:</p> <p>Polyamines, Liquid, Corrosive, n.o.s. (Diethylenetriamine) <br />8 <br />UN2735 <br />II</p> <p>WATER TRANSPORTATION (IMDG) <br />PROPER SHIPPING NAME: <br />HAZARD CLASS: <br />ID NUMBER: <br />PACKING GROUP:</p> <p>Polyamines, Liquid, Corrosive, n.o.s. (Diethylenetriamine), Marine Pollutant <br />8 <br />UN2735 <br />II</p> <p>AIR TRANSPORTATION (IATA / ICAO) <br />PROPER SHIPPING NAME: <br />HAZARD CLASS: <br />ID NUMBER: <br />PACKING GROUP:</p> <p>Polyamines, liquid, corrosive, n.o.s. (Diethylenetriamine) <br />8 <br />UN2735 <br />II</p> <p>SECTION 15: REGULATORY INFORMATION <br />U.S. FEDERAL REGULATIONS <br />TSCA (TOXIC SUBSTANCE CONTROL ACT): <br />CERCLA (COMPREHENSIVE RESPONSE <br />COMPENSATION, AND LIABILITY ACT): <br />OSHA: <br />WHMIS</p> <p>Not Listed <br />29 CFR 1910.1200 (Hazard Communication required) <br />Class D: Corrosive, Div.2, Sub. A&B; Class E</p> <p>SARA TITLE III (SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT): <br />No <br />302/304 <br />Acute Health Hazard: <br />311/312 HAZARD CATEGORIES: <br />Chronic Health Hazard: <br />Fire Hazard: <br />Pressure Release Hazard: <br />Reactivity Hazard: <br />None <br />313 REPORTABLE INGREDIENTS:</p> <p>Yes <br />Yes <br />No <br />No <br />No</p> <p>STATE REGULATIONS: <br />CALIFORNIA PROPOSITION 65 (THE SAFE DRINKING WATER AND TOXICS ENFORCEMENT ACT) <br />This product contains chemicals in trace quantities that are on the California Proposition 65 carcinogens list. <br />SECTION 16: OTHER INFORMATION <br />HAZARDOUS MATERIALS IDENTIFICATION SYSTEM <br />HMIS HAZARD RATING <br />3 <br />HEALTH <br />1 <br />FLAMMABILITY <br />1 <br />REACTIVITY <br />C <br />PERSONAL PROTECTION <br />4 – Severe, 3 – Serious, 2 – Moderate, 1 - Slight <br />C – (Safety glasses, gloves, apron) <br />The information provided herein was believed by Aquafin Inc. to be accurate at the time of preparation or prepared from sources <br />believed to be reliable, but it is the responsibility of the user to investigate and understand other pertinent sources of information, to comply <br />with all laws and procedures applicable to the safe handling and use of product and to determine the suitability of the product for its intended <br />use.</p> <p>EPOXY-N161 (Novolac)-b <br />SDS DATE: 22-Dec-14</p> <p>PAGE 6 OF 6</p>
