42.2.29
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Safety Data Sheet (SDS) OSHA HazCom Standard 29 CFR 1910.1200(g) and GHS Rev 03.
Issue date 06/01/2016
Reviewed on 06/01/2016
* 1 Identification · Product Identifier · Trade name: EPOXY-SLV Component A · Relevant identified uses of the substance or mixture and uses advised against: No further relevant information available. · Product Description Low viscosity epoxy resin · Details of the Supplier of the Safety Data Sheet: · Manufacturer/Supplier: Aquafin Inc. 505 Blue Ball Road #160 Elkton, MD 21921 Phone: 410-392-2300 Fax: 410-392-2324 Email: info@aquafin.net Web: www.aquafin.net · Emergency telephone number: Chemtrec at 1-800-424-9300 24 Hours Outside the U.S., call Chemtrec collect at 703-527-3887
2 Hazard(s) Identification · Classification of the substance or mixture:
~ d
GHS09 Environment
Aquatic Chronic 2 H411 Toxic to aquatic life with long lasting effects.
~ d
GHS07
Skin Irrit. 2 Eye Irrit. 2A Skin Sens. 1
H315 Causes skin irritation. H319 Causes serious eye irritation. H317 May cause an allergic skin reaction.
· Label elements: · GHS label elements The product is classified and labeled according to the Globally Harmonized System (GHS). · Hazard pictograms:
d ~ d ~ GHS07 GHS09
· Signal word: Warning · Hazard-determining components of labeling: Epoxy resin · Hazard statements: H315 Causes skin irritation. H319 Causes serious eye irritation. H317 May cause an allergic skin reaction. H411 Toxic to aquatic life with long lasting effects. (Contd. on page 2)
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Trade name: EPOXY-SLV Component A · Precautionary statements: P261 Avoid breathing dust/fume/gas/mist/vapors/spray. P280 Wear protective gloves. P280 Wear eye protection / face protection. P273 Avoid release to the environment. P264 Wash thoroughly after handling. P272 Contaminated work clothing must not be allowed out of the workplace. P305+P351+P338 If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P321 Specific treatment (see supplementary first aid instructions on this Safety Data Sheet). P363 Wash contaminated clothing before reuse. P332+P313 If skin irritation occurs: Get medical advice/attention. P333+P313 If skin irritation or rash occurs: Get medical advice/attention. P337+P313 If eye irritation persists: Get medical advice/attention. P302+P352 IF ON SKIN: Wash with plenty of water. P391 Collect spillage. P362+P364 Take off contaminated clothing and wash it before reuse. P501 Dispose of contents/container in accordance with local/regional/national/international regulations. · Unknown acute toxicity: 25 % of the mixture consists of component(s) of unknown toxicity. · Classification system: · NFPA ratings (scale 0 - 4)
1
Health = 1 Fire = 1 Reactivity = 0
0
· HMIS-ratings (scale 0 - 4) HEALTH
FIRE
REACTIVITY 0
· Hazard(s) not otherwise classified (HNOC): None known
3 Composition/Information on Ingredients · Non-hazardous components: 2461-15-6 [[(2-ethylhexyl)oxy]methyl]oxirane 15-35% · Chemical characterization: Mixtures · Description: Mixture of substances listed below with non-hazardous additions. · Dangerous Components: 70-90% 25068-38-6 Epoxy resin Aquatic Chronic 2, H411; d ~ d Skin Irrit. 2, H315; Eye Irrit. 2, H319; Skin Sens. 1, H317 ~
4 First-Aid Measures · Description of first aid measures: · After inhalation: In case of unconsciousness place patient stably in side position for transportation. Supply fresh air and to be sure call for a doctor. · After skin contact: Immediately wash with water and soap and rinse thoroughly. (Contd. on page 3)
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Trade name: EPOXY-SLV Component A If skin irritation occurs, consult a doctor. · After eye contact: Rinse opened eye for at least 15 minutes under running water. If symptoms persist, consult a doctor. · After swallowing: Rinse out mouth and then drink plenty of water. Never give anything by mouth to an unconscious person. Seek medical treatment. · Information for doctor: · Most important symptoms and effects, both acute and delayed: No further relevant information available. · Indication of any immediate medical attention and special treatment needed: No further relevant information available.
5 Fire-Fighting Measures · Extinguishing media: · Suitable extinguishing agents: CO₂, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant foam. · Special hazards arising from the substance or mixture: No further relevant information available. · Advice for firefighters: · Protective equipment: Because fire may produce thermal decomposition products, wear a self-contained breathing apparatus (SCBA) with a full face piece operated in pressure-demand or positive-pressure mode.
6 Accidental Release Measures · Personal precautions, protective equipment and emergency procedures: Ensure adequate ventilation. Wear protective equipment. Keep unprotected persons away. · Environmental precautions: Inform respective authorities in case of seepage into water course or sewage system. Dilute with plenty of water. Do not allow to enter sewers/surface or ground water. · Methods and material for containment and cleaning up: Absorb with liquid-binding material (i.e. sand, diatomite, acid binders, universal binders, sawdust). Ensure adequate ventilation. Dispose contaminated material as waste according to section 13. · Reference to other sections: See Section 7 for information on safe handling. See Section 8 for information on personal protection equipment. See Section 13 for disposal information.
7 Handling and Storage · Handling · Precautions for safe handling: Ensure good ventilation/exhaustion at the workplace. Avoid contact with skin, eyes and clothing Avoid breathing fume/gas/mist/vapors/spray. Do not take internally. Use personal protection equipment as outlined in section 8. Prevent formation of aerosols. · Information about protection against explosions and fires: No special measures required.
(Contd. on page 4)
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Trade name: EPOXY-SLV Component A · Conditions for safe storage, including any incompatibilities: · Storage · Requirements to be met by storerooms and receptacles: Store in a cool, dry place. Store in a well ventilated place. · Information about storage in one common storage facility: Not required. · Further information about storage conditions: Keep receptacle tightly sealed. · Specific end use(s): No further relevant information available.
8 Exposure Controls/Personal Protection · Additional information about design of technical systems: No further data; see section 7. · Control parameters: · Components with occupational exposure limits: The product does not contain any relevant quantities of materials with critical values that have to be monitored at the workplace. · Additional information: The lists that were valid during the creation of this SDS were used as basis. · Exposure controls: · Personal protective equipment: · General protective and hygienic measures: Keep away from foodstuffs, beverages and feed. Immediately remove all soiled and contaminated clothing and wash before reuse. Wash hands before breaks and at the end of work. Avoid contact with the eyes and skin. · Breathing equipment: In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure, use respiratory protective device that is independent of circulating air. · Protection of hands:
S _
Protective gloves
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. · Penetration time of glove material: The exact break-through time has to be determined and observed by the manufacturer of the protective gloves. · Eye protection:
R _
Tightly sealed goggles
9 Physical and Chemical Properties · Information on basic physical and chemical properties · General Information · Appearance: Liquid Form: Clear Color: · Odor: Mild
(Contd. on page 5)
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Trade name: EPOXY-SLV Component A · Odor threshold:
Not determined.
· pH-value @ 20 °C (68 °F):
7
· Change in condition Melting point/Melting range: Boiling point/Boiling range:
Not determined. Not determined.
· Flash point:
248 °C (478 °F)
· Flammability (solid, gaseous):
Not applicable.
· Ignition temperature: Decomposition temperature:
· Auto igniting:
Product is not self-igniting.
· Danger of explosion:
Product does not present an explosion hazard.
· Explosion limits: Lower: Upper:
· Vapor pressure:
· Density @ 20 °C (68 °F): · Relative density: · Vapor density: · Evaporation rate:
1.1 g/cm³ (9.18 lbs/gal) Not determined. Not determined. Not determined.
· Solubility in / Miscibility with: Water:
Fully miscible.
· Partition coefficient (n-octanol/water): Not determined. · Viscosity: Dynamic: Kinematic:
· Solvent content: Organic solvents: · Other information:
0.0 % No further relevant information available.
10 Stability and Reactivity · Reactivity: No further relevant information available. · Chemical stability: Stable under normal conditions. · Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications. · Possibility of hazardous reactions: No dangerous reactions known. · Conditions to avoid: No further relevant information available. · Incompatible materials: Strong oxidizing agents. Strong acids, strong bases · Hazardous decomposition products: Carbon dioxide, carbon monoxide and nitrogen oxides.
(Contd. on page 6)
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Trade name: EPOXY-SLV Component A
11 Toxicological Information · Information on toxicological effects: · Acute toxicity: · Primary irritant effect: · On the skin: Irritant to skin and mucous membranes. May cause an allergic skin reaction. · On the eye: Irritating effect. Causes serious eye irritation. · Sensitization: Sensitization possible through skin contact. · Additional toxicological information: The product shows the following dangers according to internally approved calculation methods for preparations: Irritant · Carcinogenic categories: · IARC (International Agency for Research on Cancer): Substance is not listed. None of the ingredients are listed. · NTP (National Toxicology Program): None of the ingredients are listed. · OSHA-Ca (Occupational Safety & Health Administration): None of the ingredients are listed.
12 Ecological Information · Toxicity: · Aquatic toxicity: Avoid release into the environment. Runoff from fire control or dilution water may cause pollution. · Persistence and degradability: No further relevant information available. · Behavior in environmental systems: · Bioaccumulative potential: No further relevant information available. · Mobility in soil: No further relevant information available. · Ecotoxical effects: · Remark: Toxic for fish · Additional ecological information: · General notes: Do not allow product to reach ground water, water course or sewage system. Danger to drinking water if even small quantities leak into the ground. Poisonous for fish and plankton in water bodies. Toxic for aquatic organisms · Results of PBT and vPvB assessment: · PBT: Not applicable. · vPvB: Not applicable. · Other adverse effects: No further relevant information available.
(Contd. on page 7)
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13 Disposal Considerations · Waste treatment methods: · Recommendation: Do not allow product to reach sewage system. It is the generators responsibility to determine if the waste meets applicable definitions of hazardous waste. State and local regulations may differ from federal disposal regulations. Dispose of waste material according to local, state and federal environmental regulations. · Uncleaned packagings · Recommendation: Disposal must be made according to official regulations. · Recommended cleansing agent: Water, if necessary with cleansing agents.
14 Transport Information · UN-Number: · DOT, ADR, ADN, IATA · IMDG · UN proper shipping name: · DOT, ADR, ADN, IATA · IMDG
Non-Regulated Material UN3082 Non-Regulated Material ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Epoxy resin), MARINE POLLUTANT
· Transport hazard class(es): · DOT, ADR, ADN, IATA · Class:
Non-Regulated Material
· IMDG
pd c̀ d ́ · Class: · Label: · Packing group: · DOT, ADR, IATA · IMDG · Environmental hazards:
9 Miscellaneous dangerous substances and articles 9 Non-Regulated Material III Product contains environmentally hazardous substances: Epoxy resin Not applicable. F-A,S-F
· Special precautions for user: · EMS Number: · Transport in bulk according to Annex II of Not applicable. MARPOL73/78 and the IBC Code: · Transport/Additional information: · IMDG · Limited quantities (LQ): · Excepted quantities (EQ): · UN "Model Regulation":
5L Code: E1 Maximum net quantity per inner packaging: 30 ml Maximum net quantity per outer packaging: 1000 ml Non-Regulated Material (Contd. on page 8)
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15 Regulatory Information · Safety, health and environmental regulations/legislation specific for the substance or mixture: · SARA (Superfund Amendments and Reauthorization): · Section 355 (extremely hazardous substances): None of the ingredients are listed. · Section 313 (Specific toxic chemical listings): None of the ingredients are listed. · TSCA (Toxic Substances Control Act): All ingredients are listed or exempt from listing. · California Proposition 65: · Chemicals known to cause cancer: None of the ingredients are listed. · Chemicals known to cause reproductive toxicity for females: None of the ingredients are listed. · Chemicals known to cause reproductive toxicity for males: None of the ingredients are listed. · Chemicals known to cause developmental toxicity: None of the ingredients are listed. · Carcinogenic categories: · EPA (Environmental Protection Agency): None of the ingredients are listed. · TLV (Threshold Limit Value established by ACGIH): None of the ingredients are listed. · NIOSH-Ca (National Institute for Occupational Safety and Health): None of the ingredients are listed. · GHS label elements The product is classified and labeled according to the Globally Harmonized System (GHS). · Hazard pictograms:
· Signal word: Warning · Hazard-determining components of labeling: Epoxy resin · Hazard statements: H315 Causes skin irritation. H319 Causes serious eye irritation. H317 May cause an allergic skin reaction. H411 Toxic to aquatic life with long lasting effects. · Precautionary statements: P261 Avoid breathing dust/fume/gas/mist/vapors/spray. (Contd. on page 9)
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Trade name: EPOXY-SLV Component A P280 Wear protective gloves. P280 Wear eye protection / face protection. P273 Avoid release to the environment. P264 Wash thoroughly after handling. P272 Contaminated work clothing must not be allowed out of the workplace. P305+P351+P338 If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P321 Specific treatment (see supplementary first aid instructions on this Safety Data Sheet). P363 Wash contaminated clothing before reuse. P332+P313 If skin irritation occurs: Get medical advice/attention. P333+P313 If skin irritation or rash occurs: Get medical advice/attention. P337+P313 If eye irritation persists: Get medical advice/attention. P302+P352 IF ON SKIN: Wash with plenty of water. P391 Collect spillage. P362+P364 Take off contaminated clothing and wash it before reuse. P501 Dispose of contents/container in accordance with local/regional/national/international regulations. · National regulations: The product is subject to be classified according with the latest version of the regulations on hazardous substances. · Chemical safety assessment: A Chemical Safety Assessment has not been carried out.
16 Other Information The information and recommendations in this safety data sheet are, to the best of our knowledge, accurate as of the date of issue. Nothing herein shall be deemed to create warranty, expressed or implied, and shall not establish a legally valid contractual relationship. It is the responsibility of the user to determine applicability of this information and the suitability of the material or product for any particular purpose. · Date of preparation / last revision: 06/01/2016 / 3 · Abbreviations and acronyms:
ADR: The European Agreement concerning the International Carriage of Dangerous Goods by Road ADN: The European Agreement concerning the International Carriage of Dangerous Goods by Inland Waterways IMDG: International Maritime Code for Dangerous Goods DOT: US Department of Transportation IATA: International Air Transport Association ACGIH: American Conference of Governmental Industrial Hygienists EINECS: European Inventory of Existing Commercial Chemical Substances ELINCS: European List of Notified Chemical Substances CAS: Chemical Abstracts Service (division of the American Chemical Society) NFPA: National Fire Protection Association (USA) HMIS: Hazardous Materials Identification System (USA) PBT: Persistent, Bioaccumulative and Toxic vPvB: very Persistent and very Bioaccumulative NIOSH: National Institute for Occupational Safety OSHA: Occupational Safety & Health TLV: Threshold Limit Value PEL: Permissible Exposure Limit REL: Recommended Exposure Limit Skin Irrit. 2: Skin corrosion/irritation – Category 2 Eye Irrit. 2: Serious eye damage/eye irritation – Category 2 Eye Irrit. 2A: Serious eye damage/eye irritation – Category 2A Skin Sens. 1: Skin sensitisation – Category 1 Aquatic Chronic 2: Hazardous to the aquatic environment - long-term aquatic hazard – Category 2
· * Data compared to the previous version altered. SDS created by MSDS Authoring Services www.msdsauthoring.com
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