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Safety Data Sheet (SDS) OSHA HazCom Standard 29 CFR 1910.1200(g) and GHS Rev 03.
Printing date 01/21/2015
Reviewed on 01/21/2015
* 1 Identification · Product identifier · Trade name: EPOXY XP50 HYBRID Component A · Relevant identified uses of the substance or mixture and uses advised against No further relevant information available. · Product description Epoxy urethane bonding system · Details of the supplier of the safety data sheet · Manufacturer/Supplier: Aquafin Inc. 505 Blue Ball Road #160 Elkton, MD 21921 Phone: 410-392-2300 Fax: 410-392-2324 Email: info@aquafin.net Web: www.aquafin.net · Emergency telephone number: Chemtrec at 1-800-424-9300 24 Hours Outside the U.S., call Chemtrec collect at 703-527-3887
2 Hazard(s) identification · Classification of the substance or mixture GHS08 Health hazard Resp. Sens. 1
H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled.
GHS09 Environment Aquatic Chronic 2 H411 Toxic to aquatic life with long lasting effects. GHS07 Skin Irrit. 2 Eye Irrit. 2A Skin Sens. 1
H315 Causes skin irritation. H319 Causes serious eye irritation. H317 May cause an allergic skin reaction.
· Label elements · GHS label elements The product is classified and labeled according to the Globally Harmonized System (GHS). · Hazard pictograms
GHS08 GHS09 · Signal word Danger · Hazard-determining components of labeling: Epoxy resin (Contd. on page 2)
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Trade name: EPOXY XP50 HYBRID Component A (Contd. of page 1)
Proprietary Isocyanate · Hazard statements Causes skin irritation. Causes serious eye irritation. May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause an allergic skin reaction. Toxic to aquatic life with long lasting effects. · Precautionary statements Wear respiratory protection. Avoid breathing dust/fume/gas/mist/vapors/spray Wear protective gloves. Wear eye protection / face protection. Avoid release to the environment. Wash thoroughly after handling. Contaminated work clothing must not be allowed out of the workplace. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Specific treatment (see on this label). If experiencing respiratory symptoms: Call a poison center/doctor. Wash contaminated clothing before reuse. If inhaled: If breathing is difficult, remove person to fresh air and keep comfortable for breathing. If skin irritation or rash occurs: Get medical advice/attention. If eye irritation persists: Get medical advice/attention. If on skin: Wash with plenty of water. Collect spillage. Take off contaminated clothing and wash it before reuse. Dispose of contents/container in accordance with local/regional/national/international regulations. · Unknown acute toxicity: 90 percent of the mixture consists of ingredient(s) of unknown toxicity. · Classification system: · NFPA ratings (scale 0 - 4)
1
Health = 1 Fire = 1 Reactivity = 0
0
· HMIS-ratings (scale 0 - 4) HEALTH
*1
FIRE
REACTIVITY 0
Health = *1 Fire = 1 Reactivity = 0
· Other hazards None known * 3 Composition/information on ingredients · Chemical characterization: Mixtures · Description: Mixture of substances listed below with nonhazardous additions.
(Contd. on page 3)
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Trade name: EPOXY XP50 HYBRID Component A (Contd. of page 2)
· Dangerous Components: 25068-38-6 Epoxy resin Aquatic Chronic 2, H411; Skin Irrit. 2, H315; Eye Irrit. 2, H319; Skin Sens. 1, H317 Proprietary Isocyanate Resp. Sens. 1, H334; Acute Tox. 4, H302; Acute Tox. 4, H312; Acute Tox. 4, H332; Eye Irrit. 2A, H319; Skin Sens. 1B, H317
60-90%
10-40%
4 First-aid measures · Description of first aid measures · After inhalation: In case of unconsciousness, place patient securely on side position for transportation. Supply fresh air. If required, provide artificial respiration. Consult doctor if symptoms persist. · After skin contact: Immediately wash with water and soap and rinse thoroughly. If skin irritation continues, consult a doctor. · After eye contact: Rinse opened eye for at least 15 minutes under running water. If symptoms persist, consult a doctor. · After swallowing: Do not induce vomiting; immediately call for medical help. · Information for doctor: · Most important symptoms and effects, both acute and delayed No further relevant information available. · Indication of any immediate medical attention and special treatment needed No further relevant information available.
5 Fire-fighting measures · Extinguishing media · Suitable extinguishing agents: CO2, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant foam. · Special hazards arising from the substance or mixture No further relevant information available. · Advice for firefighters · Protective equipment: Because fire may produce thermal decomposition products, wear a self-contained breathing apparatus (SCBA) with a full face piece operated in pressure-demand or positive-pressure mode.
6 Accidental release measures · Personal precautions, protective equipment and emergency procedures Wear protective equipment. Keep unprotected persons away. · Environmental precautions: Inform respective authorities in case of seepage into water course or sewage system. Do not allow to enter sewers/ surface or ground water. · Methods and material for containment and cleaning up: Ensure adequate ventilation. Absorb with liquid-binding material (ie. sand, diatomite, acid binders, universal binders, sawdust). Dispose contaminated material as waste according to section 13. · Reference to other sections See Section 7 for information on safe handling. See Section 8 for information on personal protection equipment. See Section 13 for disposal information. (Contd. on page 4)
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Trade name: EPOXY XP50 HYBRID Component A (Contd. of page 3)
7 Handling and storage · Handling: · Precautions for safe handling Ensure good ventilation/exhaustion at the workplace. Avoid contact with skin, eyes and clothing Avoid breathing fume/gas/mist/vapors/spray. Do not take internally. Use personal protection equipment as outlined in section 8. Prevent formation of aerosols. · Information about protection against explosions and fires: No special measures required. · Conditions for safe storage, including any incompatibilities · Storage: · Requirements to be met by storerooms and receptacles: Store in a cool, dry place. Store in a well ventilated place. · Information about storage in one common storage facility: Not required. · Further information about storage conditions: Keep receptacle tightly sealed. · Specific end use(s) No further relevant information available.
8 Exposure controls/personal protection · Additional information about design of technical systems: No further data; see section 7. · Control parameters · Components with occupational exposure limits: The product does not contain any relevant quantities of materials with critical values that have to be monitored at the workplace. · Additional information: The lists that were valid during the creation were used as basis. · Exposure controls · Personal protective equipment: · General protective and hygienic measures: Keep away from foodstuffs, beverages and feed. Immediately remove all soiled and contaminated clothing. Wash hands before breaks and at the end of work. Avoid contact with the eyes and skin. · Breathing equipment: In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure, use respiratory protective device that is independent of circulating air. · Protection of hands: Protective gloves The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. · Penetration time of glove material The exact break-through time has to be determined and observed by the manufacturer of the protective gloves. · Eye protection: Tightly sealed goggles
(Contd. on page 5)
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Printing date 01/21/2015 Trade name: EPOXY XP50 HYBRID Component A
(Contd. of page 4)
9 Physical and chemical properties · Information on basic physical and chemical properties · General Information · Appearance: Liquid Form: Blue Color: · Odor: Mild · Odor threshold: Not determined. · pH-value:
Not determined.
· Change in condition Melting point/Melting range: Boiling point/Boiling range:
Not determined. Not determined.
· Flash point:
192 °C (378 °F)
· Flammability (solid, gaseous):
Not applicable.
· Ignition temperature: Decomposition temperature:
· Auto igniting:
Product is not selfigniting.
· Danger of explosion:
Product does not present an explosion hazard.
· Explosion limits: Lower: Upper:
· Vapor pressure:
· Density @ 20 °C (68 °F): · Relative density · Vapour density · Evaporation rate
1.14 g/cm³ (9.513 lbs/gal) Not determined. Not determined. Not determined.
· Solubility in / Miscibility with Water:
Not miscible or difficult to mix.
· Partition coefficient (n-octanol/water): Not determined. · Viscosity: Dynamic: Kinematic:
· Solvent content: Organic solvents:
0.0 %
Solids content: · Other information
100.0 % No further relevant information available.
10 Stability and reactivity · Reactivity No further relevant information available. · Chemical stability Stable under normal conditions. · Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications. · Possibility of hazardous reactions No dangerous reactions known.
(Contd. on page 6)
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Trade name: EPOXY XP50 HYBRID Component A (Contd. of page 5)
· Conditions to avoid No further relevant information available. · Incompatible materials: No further relevant information available. · Hazardous decomposition products: No dangerous decomposition products known.
11 Toxicological information · Information on toxicological effects · Acute toxicity: · LD/LC50 values that are relevant for classification: 102900-03-8 Alkyl Phenol Blocked Polyisocyanate Oral LD50 >5.000 mg/kg (rat) · Primary irritant effect: · on the skin: Irritant to skin and mucous membranes. May cause an allergic skin reaction. · on the eye: Irritating effect. Causes serious eye irritation. · Sensitization: Sensitization possible through inhalation. Sensitization possible through skin contact. · Additional toxicological information: The product shows the following dangers according to internally approved calculation methods for preparations: Harmful Irritant · Carcinogenic categories · IARC (International Agency for Research on Cancer) Group 1 - Carcinogenic to humans Group 2A - Probably carcinogenic to humans Group 2B - Possibly carcinogenic to humans Group 3 - Not classifiable as to its carcinogenicity to humans Group 4 - Probably not carcinogenic to humans · NTP (National Toxicology Program) None of the ingredients are listed. · OSHA-Ca (Occupational Safety & Health Administration) None of the ingredients are listed.
12 Ecological information · Toxicity · Aquatic toxicity: Avoid release into the environment. Runoff from fire control or dilution water may cause pollution. · Persistence and degradability No further relevant information available. · Behavior in environmental systems: · Bioaccumulative potential No further relevant information available. · Mobility in soil No further relevant information available. · Ecotoxical effects: · Remark: Toxic for fish
(Contd. on page 7)
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(Contd. of page 6)
· Additional ecological information: · General notes: Also poisonous for fish and plankton in water bodies. Toxic for aquatic organisms Do not allow product to reach ground water, water course or sewage system. Danger to drinking water if even small quantities leak into the ground. · Results of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable. · Other adverse effects No further relevant information available.
13 Disposal considerations · Waste treatment methods · Recommendation: Do not allow product to reach sewage system. It is the generators responsibility to determine if the waste meets applicable definitions of hazardous waste. State and local regulations may differ from federal disposal regulations. Dispose of waste material according to local, state and federal environmental regulations. · Uncleaned packagings: · Recommendation: Disposal must be made according to official regulations.
14 Transport information · UN-Number · DOT · ADR, IMDG, IATA · UN proper shipping name · DOT · ADR · IMDG · IATA
Non-Regulated Material UN3082 Non-Regulated Material UN3082 Environmentally hazardous substances, liquid, n.o.s. (Epoxy resin) ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Epoxy resin), MARINE POLLUTANT ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Epoxy resin)
· Transport hazard class(es) · DOT · Class
Non-Regulated Material
· ADR
· Class · Label
9 (M6) Miscellaneous dangerous substances and articles 9 (Contd. on page 8)
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(Contd. of page 7)
· IMDG, IATA
· Class · Label · Packing group · DOT · ADR, IMDG, IATA · Environmental hazards: · Marine pollutant:
9 Miscellaneous dangerous substances and articles 9 Non-Regulated Material III Product contains environmentally hazardous substances: Epoxy resin Yes Symbol (fish and tree) Symbol (fish and tree) Symbol (fish and tree) Warning: Miscellaneous dangerous substances and articles 90 F-A,S-F
· Special marking (ADR): · Special marking (IATA): · Special precautions for user · Danger code (Kemler): · EMS Number: · Transport in bulk according to Annex II of Not applicable. MARPOL73/78 and the IBC Code · Transport/Additional information: · ADR · Excepted quantities (EQ)
· IMDG · Limited quantities (LQ) · Excepted quantities (EQ) · UN "Model Regulation":
Code: E1 Maximum net quantity per inner packaging: 30 ml Maximum net quantity per outer packaging: 1000 ml 5L Code: E1 Maximum net quantity per inner packaging: 30 ml Maximum net quantity per outer packaging: 1000 ml UN3082, Environmentally hazardous substances, liquid, n.o.s. (Epoxy resin), 9, III
* 15 Regulatory information · Safety, health and environmental regulations/legislation specific for the substance or mixture · Sara · Section 355 (extremely hazardous substances): None of the ingredients are listed. · Section 313 (Specific toxic chemical listings): None of the ingredients are listed. · TSCA (Toxic Substances Control Act): All ingredients are listed. · Proposition 65 · Chemicals known to cause cancer: None of the ingredients are listed. (Contd. on page 9)
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Trade name: EPOXY XP50 HYBRID Component A (Contd. of page 8)
· Chemicals known to cause reproductive toxicity for females: None of the ingredients are listed. · Chemicals known to cause reproductive toxicity for males: None of the ingredients are listed. · Chemicals known to cause developmental toxicity: None of the ingredients are listed. · Carcinogenic categories · EPA (Environmental Protection Agency) None of the ingredients are listed. · TLV (Threshold Limit Value established by ACGIH) None of the ingredients are listed. · NIOSH-Ca (National Institute for Occupational Safety and Health) None of the ingredients are listed. · GHS label elements The product is classified and labeled according to the Globally Harmonized System (GHS). · Hazard pictograms
GHS08 GHS09 · Signal word Danger · Hazard-determining components of labeling: Epoxy resin Proprietary Isocyanate · Hazard statements Causes skin irritation. Causes serious eye irritation. May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause an allergic skin reaction. Toxic to aquatic life with long lasting effects. · Precautionary statements Wear respiratory protection. Avoid breathing dust/fume/gas/mist/vapors/spray Wear protective gloves. Wear eye protection / face protection. Avoid release to the environment. Wash thoroughly after handling. Contaminated work clothing must not be allowed out of the workplace. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Specific treatment (see on this label). If experiencing respiratory symptoms: Call a poison center/doctor. Wash contaminated clothing before reuse. If inhaled: If breathing is difficult, remove person to fresh air and keep comfortable for breathing. If skin irritation or rash occurs: Get medical advice/attention. If eye irritation persists: Get medical advice/attention.
(Contd. on page 10)
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Trade name: EPOXY XP50 HYBRID Component A (Contd. of page 9)
If on skin: Wash with plenty of water. Collect spillage. Take off contaminated clothing and wash it before reuse. Dispose of contents/container in accordance with local/regional/national/international regulations. · National regulations: The product is subject to be labeled according with the prevailing version of the regulations on hazardous substances. · State Right to Know 25068-38-6 Epoxy resin Aquatic Chronic 2, H411; Skin Irrit. 2, H315; Eye Irrit. 2, H319; Skin Sens. 1, H317 Proprietary Isocyanate Resp. Sens. 1, H334; Acute Tox. 4, H302; Acute Tox. 4, H312; Acute Tox. 4, H332; Eye Irrit. 2A, H319; Skin Sens. 1B, H317 All ingredients are listed. · Chemical safety assessment: A Chemical Safety Assessment has not been carried out.
16 Other information The information and recommendations in this safety data sheet are, to the best of our knowledge, accurate as of the date of issue. Nothing herein shall be deemed to create warranty, expressed or implied and shall not establish a legally valid contractual relationship. It is the responsibility of the user to determine applicability of this information and the suitability of the material or product for any particular purpose. · Date of preparation / last revision 01/21/2015 / 3 · Abbreviations and acronyms:
ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of Dangerous Goods by Road) ADN: The European Agreement concerning the International Carriage of Dangerous Goods by Inland Waterways IMDG: International Maritime Code for Dangerous Goods DOT: US Department of Transportation IATA: International Air Transport Association ACGIH: American Conference of Governmental Industrial Hygienists EINECS: European Inventory of Existing Commercial Chemical Substances ELINCS: European List of Notified Chemical Substances CAS: Chemical Abstracts Service (division of the American Chemical Society) NFPA: National Fire Protection Association (USA) HMIS: Hazardous Materials Identification System (USA) LC50: Lethal concentration, 50 percent LD50: Lethal dose, 50 percent Acute Tox. 4: Acute toxicity, Hazard Category 4 Skin Irrit. 2: Skin corrosion/irritation, Hazard Category 2 Eye Irrit. 2: Serious eye damage/eye irritation, Hazard Category 2 Eye Irrit. 2A: Serious eye damage/eye irritation, Hazard Category 2A Resp. Sens. 1: Sensitisation - Respirat., Hazard Category 1 Skin Sens. 1: Sensitisation - Skin, Hazard Category 1 Skin Sens. 1B: Sensitisation - Skin, Hazard Category 1B Aquatic Chronic 2: Hazardous to the aquatic environment - Chronic Hazard, Category 2
· * Data compared to the previous version altered. SDS created by MSDS Authoring Services www.msdsauthoring.com
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