41.2.4
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Safety Data Sheet (SDS) OSHA HazCom Standard 29 CFR 1910.1200(g) and GHS Rev 03.
Issue date 09/03/2015
Reviewed on 09/03/2015
* 1 Identification · Product identifier · Trade name: EPOXY XP50 HYBRID Component B · Relevant identified uses of the substance or mixture and uses advised against: No further relevant information available. · Product description Epoxy urethane bonding system · Details of the supplier of the safety data sheet: · Manufacturer/Supplier: Aquafin Inc. 505 Blue Ball Road #160 Elkton, MD 21921 Phone: 410-392-2300 Fax: 410-392-2324 Email: info@aquafin.net Web: www.aquafin.net · Emergency telephone number: Chemtrec at 1-800-424-9300 24 Hours Outside the U.S., call Chemtrec collect at 703-527-3887 * 2 Hazard(s) identification · Classification of the substance or mixture:
~ d
GHS08 Health hazard
Repr. 2
~ d
H361 Suspected of damaging fertility or the unborn child. GHS05 Corrosion
Skin Corr. 1A Eye Dam. 1
~ d
H314 Causes severe skin burns and eye damage. H318 Causes serious eye damage.
GHS09 Environment
Aquatic Chronic 2 H411 Toxic to aquatic life with long lasting effects.
~ d
GHS07
Acute Tox. 4 Skin Sens. 1
H302 Harmful if swallowed. H317 May cause an allergic skin reaction.
Flam. Liq. 4
H227 Combustible liquid.
· Label elements: · GHS label elements The product is classified and labeled according to the Globally Harmonized System (GHS). (Contd. on page 2)
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Trade name: EPOXY XP50 HYBRID Component B · Hazard pictograms:
d ~ d d ~ d ~ ~ GHS05 GHS07 GHS08 GHS09
· Signal word: Danger · Hazard-determining components of labeling: 4-nonylphenol, branched 2-piperazin-1-ylethylamine triethylenetetramine 2,4,6-tris(dimethylaminomethyl)phenol Poly(propylene glycol) bis(2-aminopropyl ether) · Hazard statements: Combustible liquid. Harmful if swallowed. Causes severe skin burns and eye damage. May cause an allergic skin reaction. Suspected of damaging fertility or the unborn child. Toxic to aquatic life with long lasting effects. · Precautionary statements: Keep away from flames and hot surfaces. – No smoking. Do not breathe dusts or mists. Avoid breathing dust/fume/gas/mist/vapors/spray. Wear protective gloves / eye protection / face protection. Wear protective gloves. Wear eye protection / face protection. Avoid release to the environment. Wash thoroughly after handling. Do not eat, drink or smoke when using this product. Contaminated work clothing must not be allowed out of the workplace. Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor. IF SWALLOWED: Call a POISON CENTER/doctor if you feel unwell. Specific treatment (see supplementary first aid instructions on this Safety Data Sheet). IF INHALED: Remove person to fresh air and keep comfortable for breathing. Wash contaminated clothing before reuse. IF exposed or concerned: Get medical advice/attention. If skin irritation or rash occurs: Get medical advice/attention. If swallowed: Rinse mouth. Do NOT induce vomiting. In case of fire: Use for extinction: CO2, powder or water spray. IF ON SKIN: Wash with plenty of water. Collect spillage. Store locked up. Store in a well-ventilated place. Keep cool. Dispose of contents/container in accordance with local/regional/national/international regulations.
(Contd. on page 3)
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Trade name: EPOXY XP50 HYBRID Component B · Unknown acute toxicity: 25 % of the mixture consists of component(s) of unknown toxicity. · Classification system: · NFPA ratings (scale 0 - 4)
2
Health = 2 Fire = 2 Reactivity = 0
0
· HMIS-ratings (scale 0 - 4) HEALTH
FIRE
REACTIVITY 0
· Hazard(s) not otherwise classified (HNOC): None known * 3 Composition/information on ingredients · Chemical characterization: Mixtures · Description: Mixture of substances listed below with nonhazardous additions. · Dangerous Components: CAS: 84852-15-3 4-nonylphenol, branched Repr. 2, H361; d ~ d Skin Corr. 1B, H314; d ~ Aquatic Acute 1, H400; Aquatic ~ Chronic 1, H410;d Acute Tox. 4, H302 ~ CAS: 9046-10-0 Poly(propylene glycol) bis(2-aminopropyl ether) Skin Corr. 1A, H314; Eye Dam. 1, H318; Aquatic Acute 3, H402; Aquatic ~ d Chronic 3, H412 CAS: 112-24-3 triethylenetetramine Skin Corr. 1B, H314; d ~ d Acute Tox. 4, H312; Skin Sens. 1, H317; Aquatic ~ Chronic 3, H412 CAS: 140-31-8 2-piperazin-1-ylethylamine RTECS: TK 8050000 d Skin Corr. 1B, H314; d ~ Acute Tox. 4, H302; Acute Tox. 4, H312; Skin ~ Sens. 1, H317; Flam. Liq. 4, H227; Aquatic Chronic 3, H412 CAS: 90-72-2 2,4,6-tris(dimethylaminomethyl)phenol Acute Tox. 4, H302; Skin Irrit. 2, H315; Eye Irrit. 2A, H319 ~ d
15-35%
2-12%
4 First-aid measures · Description of first aid measures: · General information: Immediately remove any clothing soiled by the product. Symptoms of poisoning may occur after several hours; therefore medical observation is advised for at least 48 hours after the accident. Remove breathing apparatus only after contaminated clothing have been completely removed. In case of irregular breathing or respiratory arrest provide artificial respiration. · After inhalation: Supply fresh air or oxygen; call for doctor. Supply fresh air. If required, provide artificial respiration. Consult doctor if symptoms persist. In case of unconsciousness place patient stably in side position for transportation. · After skin contact: Immediately wash with water and soap and rinse thoroughly. If skin irritation occurs, consult a doctor. (Contd. on page 4)
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Trade name: EPOXY XP50 HYBRID Component B · After eye contact: Rinse opened eye for several minutes under running water. Then consult a doctor. · After swallowing: Do not induce vomiting; immediately call for medical help. Drink copious amounts of water and provide fresh air. Immediately call a doctor. · Information for doctor: · Most important symptoms and effects, both acute and delayed: No further relevant information available. · Indication of any immediate medical attention and special treatment needed: No further relevant information available.
5 Fire-fighting measures · Extinguishing media: · Suitable extinguishing agents: CO₂, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant foam. · Special hazards arising from the substance or mixture: Combustible liquid. Vapors can travel to a source of ignition and flash back. Explosive mixtures may occur at temperatures at or above flashpoint. · Advice for firefighters: · Protective equipment: Mouth respiratory protective device. Because fire may produce thermal decomposition products, wear a self-contained breathing apparatus (SCBA) with a full face piece operated in pressure-demand or positive-pressure mode.
6 Accidental release measures · Personal precautions, protective equipment and emergency procedures: Wear protective equipment. Keep unprotected persons away. · Environmental precautions: Inform respective authorities in case of seepage into water course or sewage system. Dilute with plenty of water. Do not allow to enter sewers/ surface or ground water. · Methods and material for containment and cleaning up: Ensure adequate ventilation. Use neutralizing agent. Absorb with liquid-binding material (i.e. sand, diatomite, acid binders, universal binders, sawdust). Dispose contaminated material as waste according to section 13. · Reference to other sections: See Section 7 for information on safe handling. See Section 8 for information on personal protection equipment. See Section 13 for disposal information.
7 Handling and storage · Handling · Precautions for safe handling: Ensure good ventilation/exhaustion at the workplace. Avoid contact with skin, eyes and clothing Avoid breathing fume/gas/mist/vapors/spray. Do not take internally. Use personal protection equipment as outlined in section 8. Open and handle receptacle with care. Prevent formation of aerosols. · Information about protection against explosions and fires: Protect from heat. (Contd. on page 5)
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Trade name: EPOXY XP50 HYBRID Component B Keep protective respiratory device available. · Conditions for safe storage, including any incompatibilities: · Storage · Requirements to be met by storerooms and receptacles: Store in a cool, dry place away from sparks and flame. · Information about storage in one common storage facility: Not required. · Further information about storage conditions: No further relevant information available.. Protect from heat and direct sunlight. · Specific end use(s): No further relevant information available. * 8 Exposure controls/personal protection · Additional information about design of technical systems: No further data; see section 7. · Control parameters: · Components with occupational exposure limits: 112-24-3 triethylenetetramine WEEL Long-term value: 6 mg/m³, 1 ppm Skin · Additional information: The lists that were valid during the creation of this SDS were used as basis. · Exposure controls: · Personal protective equipment: · General protective and hygienic measures: Keep away from foodstuffs, beverages and feed. Immediately remove all soiled and contaminated clothing and wash before reuse. Wash hands before breaks and at the end of work. Store protective clothing separately. Avoid contact with the eyes. Avoid contact with the eyes and skin. · Breathing equipment: Not required. · Protection of hands:
S _
Protective gloves
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. · Penetration time of glove material: The exact break-through time has to be determined and observed by the manufacturer of the protective gloves. · Eye protection:
R _
Tightly sealed goggles
Slash proof without any vent holes are recommended. (Contd. on page 6)
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Issue date 09/03/2015 Trade name: EPOXY XP50 HYBRID Component B
9 Physical and chemical properties · Information on basic physical and chemical properties · General Information · Appearance: Liquid Form: Yellow to light amber Color: · Odor: Amine-like · Odor threshold: Not determined. · pH-value:
Acidic
· Change in condition Melting point/Melting range: Boiling point/Boiling range:
Not determined. 220 °C (428 °F)
· Flash point:
92 °C (198 °F)
· Flammability (solid, gaseous):
Not applicable.
· Ignition temperature:
240 °C (464 °F)
· Decomposition temperature:
Not determined.
· Auto igniting:
Product is not self-igniting.
· Danger of explosion:
· Explosion limits: Lower: Upper:
0.7 Vol % 10.5 Vol %
· Vapor pressure @ 20 °C (68 °F):
0.1 hPa
· Density @ 20 °C (68 °F): · Relative density: · Vapor density: · Evaporation rate:
0.95 g/cm³ (7.928 lbs/gal) Not determined. Not determined. Not determined.
· Solubility in / Miscibility with: Water:
Fully miscible.
· Partition coefficient (n-octanol/water): Not determined. · Viscosity: Dynamic: Kinematic:
Not determined. Not determined.
· Solvent content: Organic solvents: · Other information:
0.0 % No further relevant information available.
10 Stability and reactivity · Reactivity: No further relevant information available. · Chemical stability: Stable under normal conditions. · Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications. · Possibility of hazardous reactions: No dangerous reactions known. · Conditions to avoid: No further relevant information available.
(Contd. on page 7)
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Trade name: EPOXY XP50 HYBRID Component B · Incompatible materials: Strong oxidizing agents. Strong acids, strong bases · Hazardous decomposition products: Carbon dioxide, carbon monoxide and nitrogen oxides. * 11 Toxicological information · Information on toxicological effects: · Acute toxicity: · LD/LC50 values that are relevant for classification: 9046-10-0 Poly(propylene glycol) bis(2-aminopropyl ether) Oral LD50 2885.3 mg/kg (rat) Dermal LD50 2980 mg/kg (rabbit) Skin - rabbit - Corrosive, category 1C - where responses occur after exposures between 1 hour and 4 hours and observations up to 14 days. - OECD Test Guideline 404. Inhalative LC50/4 h >0.74 mg/l (rat) (8 hours) 112-24-3 triethylenetetramine Oral LD50 2500 mg/kg (rat) Dermal LD50 805 mg/kg (rabbit) 140-31-8 2-piperazin-1-ylethylamine Oral LD50 2140 mg/kg (rat) Dermal LD50 880 mg/kg (rabbit) Inhalative LC50/4 h 100 mg/l (Trout) · Primary irritant effect: · On the skin: Strong caustic effect on skin and mucous membranes. May cause an allergic skin reaction. · On the eye: Corrosive effect. Causes serious eye irritation. · Sensitization: Sensitization possible through skin contact. · Additional toxicological information: The product shows the following dangers according to internally approved calculation methods for preparations: Harmful Corrosive Irritant Swallowing will lead to a corrosive effect on mouth and throat and to the danger of perforation of esophagus and stomach. · Carcinogenic categories: · IARC (International Agency for Research on Cancer): None of the ingredients are listed. · NTP (National Toxicology Program): None of the ingredients are listed. · OSHA-Ca (Occupational Safety & Health Administration): None of the ingredients are listed. (Contd. on page 8)
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12 Ecological information · Toxicity: · Aquatic toxicity: Avoid release into the environment. Runoff from fire control or dilution water may cause pollution. 140-31-8 2-piperazin-1-ylethylamine EC50 32 mg/l (daphnia) · Persistence and degradability: No further relevant information available. · Behavior in environmental systems: · Bioaccumulative potential: No further relevant information available. · Mobility in soil: No further relevant information available. · Ecotoxical effects: · Remark: Toxic for fish · Additional ecological information: · General notes: Water hazard class 3 (Self-assessment): extremely hazardous for water Do not allow product to reach ground water, water course or sewage system, even in small quantities. Must not reach bodies of water or drainage ditch undiluted or unneutralized. Danger to drinking water if even extremely small quantities leak into the ground. Poisonous for fish and plankton in water bodies. Toxic for aquatic organisms · Results of PBT and vPvB assessment: · PBT: Not applicable. · vPvB: Not applicable. · Other adverse effects: No further relevant information available.
13 Disposal considerations · Waste treatment methods: · Recommendation: Do not allow product to reach sewage system. It is the generators responsibility to determine if the waste meets applicable definitions of hazardous waste. State and local regulations may differ from federal disposal regulations. Dispose of waste material according to local, state and federal environmental regulations. · Uncleaned packagings: · Recommendation: Disposal must be made according to official regulations. · Recommended cleansing agent: Water, if necessary with cleansing agents. * 14 Transport information · UN-Number · DOT · ADR, IMDG, IATA · UN proper shipping name · DOT · ADR · IMDG · IATA
Non-Regulated Material UN2922 Non-Regulated Material UN2922 Corrosive liquids, toxic, n.o.s. (4-nonylphenol, branched, Triethylenetetramine), ENVIRONMENTALLY HAZARDOUS CORROSIVE LIQUID, TOXIC, N.O.S. (4-nonylphenol, branched, TRIETHYLENETETRAMINE), MARINE POLLUTANT CORROSIVE LIQUID, TOXIC, N.O.S.
(Contd. on page 9)
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Issue date 09/03/2015 Trade name: EPOXY XP50 HYBRID Component B Transport hazard class(es) · Class: · Label:
Non-Regulated Material
· ADR
} d́ o c a d · Class: · Label:
8 (C9) Corrosive substances 8
· IMDG
8 Corrosive substances 8
· IATA
} o c a d · Class: · Label: · Packing group: · DOT, ADR, IMDG, IATA · Environmental hazards:
8 Corrosive substances 8 II Product contains environmentally hazardous substances: 4nonylphenol, branched Symbol (fish and tree) Warning: Corrosive substances 80 F-A,S-B Alkalis
· Special marking (ADR): · Special precautions for user: · Danger code (Kemler): · EMS Number: · Segregation groups: · Transport in bulk according to Annex II of Not applicable. MARPOL73/78 and the IBC Code: · Transport/Additional information: · DOT · Quantity limitations: · Remarks:
On passenger aircraft/rail: 1 L On cargo aircraft only: 30 L Special marking with the symbol (fish and tree).
(Contd. on page 10)
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Issue date 09/03/2015 Trade name: EPOXY XP50 HYBRID Component B · ADR · Excepted quantities (EQ):
· IMDG · Limited quantities (LQ): · Excepted quantities (EQ): · UN "Model Regulation":
Code: E2 Maximum net quantity per inner packaging: 30 ml Maximum net quantity per outer packaging: 500 ml 1L Code: E2 Maximum net quantity per inner packaging: 30 ml Maximum net quantity per outer packaging: 500 ml UN1760, Corrosive liquids, n.o.s. (4-nonylphenol, branched, Triethylenetetramine), ENVIRONMENTALLY HAZARDOUS, 8, II
* 15 Regulatory information · Safety, health and environmental regulations/legislation specific for the substance or mixture: · SARA (Superfund Amendments and Reauthorization): · Section 355 (extremely hazardous substances): None of the ingredients are listed. · Section 313 (Specific toxic chemical listings): None of the ingredients are listed. · TSCA (Toxic Substances Control Act): All ingredients are listed. · California Proposition 65: · Chemicals known to cause cancer: None of the ingredients are listed. · Chemicals known to cause reproductive toxicity for females: None of the ingredients are listed. · Chemicals known to cause reproductive toxicity for males: None of the ingredients are listed. · Chemicals known to cause developmental toxicity: None of the ingredients are listed. · Carcinogenic categories: · EPA (Environmental Protection Agency): None of the ingredients are listed. · TLV (Threshold Limit Value established by ACGIH): None of the ingredients are listed. · NIOSH-Ca (National Institute for Occupational Safety and Health): None of the ingredients are listed. · GHS label elements The product is classified and labeled according to the Globally Harmonized System (GHS). (Contd. on page 11)
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· Signal word: Danger · Hazard-determining components of labeling: 4-nonylphenol, branched 2-piperazin-1-ylethylamine triethylenetetramine 2,4,6-tris(dimethylaminomethyl)phenol Poly(propylene glycol) bis(2-aminopropyl ether) · Hazard statements: Combustible liquid. Harmful if swallowed. Causes severe skin burns and eye damage. May cause an allergic skin reaction. Suspected of damaging fertility or the unborn child. Toxic to aquatic life with long lasting effects. · Precautionary statements: Keep away from flames and hot surfaces. – No smoking. Do not breathe dusts or mists. Avoid breathing dust/fume/gas/mist/vapors/spray. Wear protective gloves / eye protection / face protection. Wear protective gloves. Wear eye protection / face protection. Avoid release to the environment. Wash thoroughly after handling. Do not eat, drink or smoke when using this product. Contaminated work clothing must not be allowed out of the workplace. Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor. IF SWALLOWED: Call a POISON CENTER/doctor if you feel unwell. Specific treatment (see supplementary first aid instructions on this Safety Data Sheet). IF INHALED: Remove person to fresh air and keep comfortable for breathing. Wash contaminated clothing before reuse. IF exposed or concerned: Get medical advice/attention. If skin irritation or rash occurs: Get medical advice/attention. If swallowed: Rinse mouth. Do NOT induce vomiting. In case of fire: Use for extinction: CO2, powder or water spray. IF ON SKIN: Wash with plenty of water. Collect spillage. Store locked up. Store in a well-ventilated place. Keep cool. Dispose of contents/container in accordance with local/regional/national/international regulations. (Contd. on page 12)
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Trade name: EPOXY XP50 HYBRID Component B · National regulations: The product is subject to be classified according with the latest version of the regulations on hazardous substances. · State Right to Know: CAS: 84852-15-3 4-nonylphenol, branched Repr. 2, H361; d ~ d Skin Corr. 1B, H314; d ~ Aquatic Acute 1, H400; Aquatic ~ Chronic 1, H410;d Acute Tox. 4, H302 ~ CAS: 9046-10-0 Poly(propylene glycol) bis(2-aminopropyl ether) Skin Corr. 1A, H314; Eye Dam. 1, H318; Aquatic Acute 3, H402; Aquatic ~ d Chronic 3, H412 CAS: 112-24-3 triethylenetetramine Skin Corr. 1B, H314; d ~ d Acute Tox. 4, H312; Skin Sens. 1, H317; Aquatic ~ Chronic 3, H412 CAS: 140-31-8 2-piperazin-1-ylethylamine RTECS: TK 8050000 d Skin Corr. 1B, H314; d ~ Acute Tox. 4, H302; Acute Tox. 4, H312; Skin ~ Sens. 1, H317; Flam. Liq. 4, H227; Aquatic Chronic 3, H412 All ingredients are listed. · Chemical safety assessment: A Chemical Safety Assessment has not been carried out.
16 Other information The information and recommendations in this safety data sheet are, to the best of our knowledge, accurate as of the date of issue. Nothing herein shall be deemed to create warranty, expressed or implied, and shall not establish a legally valid contractual relationship. It is the responsibility of the user to determine applicability of this information and the suitability of the material or product for any particular purpose. · Date of preparation / last revision: 09/03/2015 / 6 · Abbreviations and acronyms:
ADR: The European Agreement concerning the International Carriage of Dangerous Goods by Road ADN: The European Agreement concerning the International Carriage of Dangerous Goods by Inland Waterways IMDG: International Maritime Code for Dangerous Goods DOT: US Department of Transportation IATA: International Air Transport Association ACGIH: American Conference of Governmental Industrial Hygienists EINECS: European Inventory of Existing Commercial Chemical Substances ELINCS: European List of Notified Chemical Substances CAS: Chemical Abstracts Service (division of the American Chemical Society) NFPA: National Fire Protection Association (USA) HMIS: Hazardous Materials Identification System (USA) LC50: Lethal concentration, 50 percent LD50: Lethal dose, 50 percent PBT: Persistent, Bioaccumulative and Toxic vPvB: very Persistent and very Bioaccumulative Flam. Liq. 4: Flammable liquids, Hazard Category 4 Acute Tox. 4: Acute toxicity, Hazard Category 4 Skin Corr. 1A: Skin corrosion/irritation, Hazard Category 1A Skin Corr. 1B: Skin corrosion/irritation, Hazard Category 1B Skin Irrit. 2: Skin corrosion/irritation, Hazard Category 2 Eye Dam. 1: Serious eye damage/eye irritation, Hazard Category 1 Eye Irrit. 2A: Serious eye damage/eye irritation, Hazard Category 2A Skin Sens. 1: Sensitisation - Skin, Hazard Category 1 Repr. 2: Reproductive toxicity, Hazard Category 2 Aquatic Acute 1: Hazardous to the aquatic environment - AcuteHazard, Category 1 Aquatic Acute 3: Hazardous to the aquatic environment - AcuteHazard, Category 3 Aquatic Chronic 1: Hazardous to the aquatic environment - Chronic Hazard, Category 1 Aquatic Chronic 2: Hazardous to the aquatic environment - Chronic Hazard, Category 2 Aquatic Chronic 3: Hazardous to the aquatic environment - Chronic Hazard, Category 3
· * Data compared to the previous version altered. SDS created by MSDS Authoring Services www.msdsauthoring.com
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