SDS_AQUAFIN-InjectPro-PM3811 - HARDENER -Component-B-Powder_012219.pdf
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<h1>SDS_AQUAFIN-InjectPro-PM3811 - HARDENER -Component-B-Powder_012219.pdf</h1> <p>IDENTITY: InjectPro-PM3811-HARDENER (COMPONENT-B) <br />Date prepared: <br />Date revised:</p> <p>SAFETY DATA SHEET <br />SDS No. IM1.1.1.C</p> <p>MARCH 2010</p> <p>JANUARY 2019</p> <p>SDS No. IM.1.1.1.C</p> <p>Section 1 – Product Identification <br />IDENTITY:</p> <p>Product Name:</p> <p>for products:</p> <p>InjectPro PM3811-HARDENER <br />Powder - Component – B (SDS 3 of 3)</p> <p>InjectPro-PM3811-SoilStabilizer; PM3811-Flex; PM3811-Fast; + PM3811-UltraSeal <br />Product Use Description:</p> <p>Injection resin</p> <p>AQUAFIN, INC. <br />505 BLUE BALL RD. #160 <br />ELKTON, MD 21921</p> <p>24 hr Emergency Phone: Chem-Tel (800) 255-3924</p> <p>Recommended use of the chemical and restriction on use:</p> <p>Refer to the product technical data sheet. <br />For industrial and professional users.</p> <p>Information Phone No.</p> <p>info@aquafin.net</p> <p>(410) 392-2300</p> <p>www.aquafin.net</p> <p>Section 2 – Hazards Identification <br />GHS Classification: <br />Acute toxicity, oral, Category 4 <br />Skin irritation, Category 3 <br />Serious eye irritation, Category 2B <br />Acute toxicity, inhalation, Category 4</p> <p>H302: <br />H316: <br />H320: <br />H332:</p> <p>Harmful if swallowed. <br />Causes mild skin irritation. <br />Causes eye irritation. <br />Harmful if inhaled.</p> <p>GHS Label element: <br />Hazard Pictograms <br />GHS07 <br />Signal Word:</p> <p>Warning</p> <p>Hazard Statements: <br />H302: <br />H316: <br />H320: <br />H332:</p> <p>Harmful if swallowed. <br />Causes mild skin irritation. <br />Causes eye irritation. <br />Harmful if inhaled.</p> <p>Precautionary Statements: <br />Prevention: <br />P102: <br />Keep out of reach of children. <br />P264: <br />Wash skin thoroughly after handling. <br />P280: <br />Wear protective gloves/protective clothing/ eye protection/face protection. <br />Response: <br />P302 + P352: <br />P304 + P340:</p> <p>IF ON SKIN: <br />IF INHALED:</p> <p>P305 + P351 + P338:</p> <p>IF IN EYES:</p> <p>Wash with plenty of soap and water. <br />Remove victim to fresh air and keep at rest in a position comfortable <br />for breathing. <br />Rinse cautiously with water for several minutes. Remove contact <br />lenses if present and easy to do. Continue rinsing. <br />Page 1 of 6</p> <p>SAFETY DATA SHEET</p> <p>IDENTITY: InjectPro-PM3811-HARDENER (COMPONENT-B) <br />P308 + P313 <br />P332 + P313: <br />P362: <br />Storage: <br />P403 + P232: <br />Disposal: <br />P501: <br />P502:</p> <p>SDS No. IM1.1.1.C</p> <p>IF exposed or concerned, get medical advice/attention. <br />IF skin irritation occurs, get medical advice/attention. <br />Take off contaminated clothing and wash before reuse. <br />Store in a well-ventilated place. Protect from moisture. <br />Dispose of contents/container to an approved waste disposal site. <br />Refer to manufacturer/supplier for information on recovery/recycling.</p> <p>Section 3 – Composition / Information on Hazardous Ingredients <br />Hazardous Components <br />Sodium Persulfate</p> <p>CAS No. <br />7775-27-1</p> <p>Wt. % EC No. <br />>99 <br />231-892-1</p> <p>EC Class <br />Xn-O; R8-R22-R36/37/38-R42/43</p> <p>Note: There are no additional ingredients present which, within the current knowledge of the supplier and in the <br />concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in <br />this section.</p> <p>Section 4 – First Aid Measures <br />Emergency Overview:</p> <p>White, odorless, crystals. <br />Oxidizer. Decomposes in storage under conditions of moisture (water/water vapor) and/or <br />excessive heat causing release of oxides of sulfur and oxygen that supports combustion. <br />Decomposition could form a high temperature melt. See Section 10 ("Stability and <br />Reactivity").</p> <p>Potential Health Effects: Airborne persulfate dust may be irritating to eyes, nose, lungs, throat and skin upon <br />contact. Exposure to high levels of persulfate dust may cause difficulty in breathing in <br />sensitive persons. <br />Inhalation:</p> <p>Remove to fresh air. If breathing difficulty or discomfort occurs and persists, contact a <br />medical doctor.</p> <p>Ingestion:</p> <p>Rinse mouth with water. Dilute by giving 1 or 2 glasses of water. Do not induce vomiting. <br />Never give anything by mouth to an unconscious person. See a medical doctor <br />immediately.</p> <p>Skin Contact:</p> <p>Wash with plenty of soap and water. Get medical attention if irritation occurs and persists.</p> <p>Eye Contact:</p> <p>Flush with plenty of water. Get medical attention if irritation occurs and persists.</p> <p>Section 5 – Fire Fighting Measures <br />Extinguishing Media:</p> <p>Water. Cool containers with flooding of water until well after fire is out.</p> <p>Unsuitable Extinguishing Media: Do not use carbon dioxide or other gas filled fire extinguishers; they will have <br />little effect on decomposing persulfate. <br />Fire / Explosion Hazards:</p> <p>Product is non-combustible. On decomposition releases oxygen which may <br />intensify fire. Presence of water accelerates decomposition.</p> <p>Fire Fighting Procedures:</p> <p>As in any fire, wear self-contained breathing apparatus pressure-demand, <br />MSHA/NIOSH (approved or equivalent) and full protective gear.</p> <p>Page 2 of 6</p> <p>IDENTITY: InjectPro-PM3811-HARDENER (COMPONENT-B)</p> <p>SAFETY DATA SHEET <br />SDS No. IM1.1.1.C</p> <p>Section 6 – Accidental Release Measures <br />Person-related Safety Precautions:</p> <p>Avoid eye and skin contact. Avoid breathing dust. Wear personal <br />protective equipment.</p> <p>Methods for containment:</p> <p>Vacuum, shovel or pump waste into a drum and label for disposal. Avoid <br />dust formation. Store in closed container.</p> <p>Methods for cleaning-up:</p> <p>Clean up spill area and treat as special waste.</p> <p>Waste Disposal Method:</p> <p>Dispose in accordance with local, state and federal regulations.</p> <p>Section 7 – Handling and Storage <br />Handling:</p> <p>Use adequate ventilation when transferring product from bags or drums. Avoid dust formation. <br />Wear respiratory protection if ventilation is inadequate or not available. Use eye and skin <br />protection. Use clean plastic or stainless steel scoops only.</p> <p>Storage:</p> <p>Store (unopened) in a cool, clean, dry place away from point sources of heat, e.g. radiant heaters <br />or steam pipes. Use first in, first out storage system. Avoid contamination of opened product. In <br />case of fire or decomposition (fuming/smoking) deluge with plenty of water to control <br />decomposition. For storage, refer to NFPA Bulletin 430 on storage of liquid and solid oxidizing <br />materials.</p> <p>Section 8 – Exposure Controls / Personal Protection <br />Product <br />Sodium Persulfate</p> <p>7775-27-1</p> <p>Exposure Limits <br />3 <br />ACGIH TWA: 0.1 mg/m (TWA)</p> <p>Engineering Controls:</p> <p>Provide mechanical local general room ventilation to prevent release of dust into <br />the work environment. Remove contaminated clothing immediately and wash <br />before reuse.</p> <p>Respiratory Protection:</p> <p>Use approved dust respirator when airborne dust is expected.</p> <p>Skin Protection:</p> <p>Suitable work clothes. Rubber or neoprene footwear.</p> <p>Hand Protection:</p> <p>Rubber or neoprene gloves. Thoroughly wash the outside of gloves with soap <br />and water prior to removal. Inspect regularly for leaks.</p> <p>Eye & Face Protection:</p> <p>Use cup type chemical goggles. Full face shield may be used.</p> <p>Hygiene Measures:</p> <p>Keep away from food and drink. Do not eat, drink or smoke when using this <br />product. Wash hands before breaks and after shifts. Keep work clothes separate, <br />remove contaminated clothing – launder after open handling of product.</p> <p>Section 9 – Physical and Chemical Properties <br />Physical state: <br />Odor: <br />Appearance: <br />Autoignition Temperature: <br />Boiling Point: <br />Oxidizing Properties:</p> <p>Powder <br />None <br />White crystals <br />Not applicable. No evidence of combustion up to 800°C. <br />Decomposition will occur upon heating. <br />Decomposes <br />Oxidizer <br />Page 3 of 6</p> <p>SAFETY DATA SHEET</p> <p>IDENTITY: InjectPro-PM3811-HARDENER (COMPONENT-B) <br />Evaporation Rate: <br />Flash Point: <br />Melting Point: <br />Odor Threshold: <br />Oxidizing Properties: <br />Percent Volatile: <br />pH: <br />Solubility in Water: <br />Specific Gravity: <br />VOC: <br />Vapor Density: <br />Vapor Pressure:</p> <p>SDS No. IM1.1.1.C</p> <p>Not applicable (Butyl Acetate = 1) <br />Not flammable <br />Decomposes <br />Not applicable <br />Oxidizer <br />Not applicable <br />typically 5.0 - 7.0 @ 25 °C (1% solution) <br />73 % @ 25 °C (by wt.) <br />3 <br />1.7 - 2.6 g/dm (H2O=1) <br />Not applicable <br />Not applicable (Air = 1) <br />Not applicable</p> <p>Section 10 – Stability and Reactivity <br />Stability:</p> <p>Stable (becomes unstable in presence of heat, moisture and/or <br />contamination).</p> <p>Conditions to Avoid:</p> <p>Heat, (decomposes at 275 C (527 F)) Moisture.</p> <p>Hazardous Polymerization:</p> <p>Will not occur</p> <p>Incompatibilities:</p> <p>Acids, alkalis, halides (fluorides, chlorides, bromides and iodides), <br />combustible materials, most metals and heavy metals, oxidizable <br />materials, other oxidizers, reducing agents, cleaners, and organic or <br />carbon containing compounds. Contact with incompatible materials <br />can result in a material decomposition or other uncontrolled reactions.</p> <p>0</p> <p>o</p> <p>Hazardous Decomposition Products: Oxygen that supports combustion and oxides of sulfur. <br />Comments:</p> <p>Precautionary Statement: Use of persulfates in chemical reactions <br />requires appropriate precautions and design considerations for <br />pressure and thermal relief. Decomposing persulfates will evolve <br />large volumes of gas and/or vapor, can accelerate exponentially with <br />heat generation, and create significant and hazardous pressures if <br />contained and not properly controlled or mitigated. Use with alcohols <br />in the presence of water has been demonstrated to generate <br />conditions that require rigorous adherence to process safety methods <br />and standards to prevent escalation to an uncontrolled reaction.</p> <p>Section 11 – Toxicological Information <br />Acute Effects: <br />Eye Effects: <br />Non-irritating (rabbit) [FMC Ref. ICG/T-79.029] <br />Skin effects: <br />Non-irritating (rabbit) [fmc ref. Icg/t-79.029] <br />Dermal LD50: <br />> 10 g/kg [fmc ref. Icg/t-79.029] <br />Oral LD50: <br />895 mg/kg (rat) [fmc ref. Icg/t-79.029] <br />Inhalation LC50: <br />5.1 mg/l (rat) [fmc ref. I95-2017] <br />Sensitization: <br />May be sensitizing to allergic persons. [fmc ref. Icg/t-79.029] <br />Target organs: <br />Eyes, skin, respiratory passages <br />Acute effects from overexposure: Dust may be harmful and irritating. May be harmful if swallowed. <br />Chronic effects from overexposure: Sensitive persons may develop dermatitis and asthma [Respiration <br />38:144, 1979]. Groups of male and female rats were fed 0, 300 or 3000 ppm <br />sodium persulfate in the diet for 13 weeks, followed by 5000 ppm for 5 weeks. <br />Microscopic examination of tissues revealed some injury to the <br />gastrointestinal tract at the high dose (3000 ppm) only. This effect is not <br />Page 4 of 6</p> <p>IDENTITY: InjectPro-PM3811-HARDENER (COMPONENT-B)</p> <p>Carcinogenicity: <br />NTP: <br />IARC: <br />OSHA: <br />OTHER:</p> <p>SAFETY DATA SHEET <br />SDS No. IM1.1.1.C</p> <p>unexpected for an oxidizer at high concentrations. [Ref. FMC I90-1151, <br />Toxicologist 1:149, 1981]. <br />Not listed <br />Not listed <br />Not listed <br />ACGIH: Not listed</p> <p>Section 12 – Ecological Information <br />Ecotoxicological Information: <br />Bluegill sunfish, 96-hour LC50 <br />Rainbow trout, 96-hour LC50 <br />Daphnia, 48-hour LC50 <br />Grass shrimp, 96-hour LC50</p> <p>= 771 mg/L [FMC Study I92-1250] <br />= 163 mg/L [FMC Study I92-1251] <br />= 133 mg/L [FMC Study I92-1252] <br />= 519 mg/L [FMC Study I92-1253]</p> <p>Chemical Fate Information: Biodegradability does not apply to inorganic substances.</p> <p>Section 13 – Disposal Considerations <br />Disposal:</p> <p>Must be disposed of in a manner consistent with federal, state and local regulations. <br />Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains <br />and sewers.</p> <p>Section 14 – Transport Information <br />USDOT, NON Bulk:</p> <p>UN1505, Sodium Persulfate, Class 5.1 (Oxidizer), PGIII.</p> <p>IATA/ICAO:</p> <p>UN1505, Sodium Persulfate, Class 5.1 (Oxidizer), PGIII.</p> <p>IMDG:</p> <p>UN1505, Sodium Persulfate, Class 5.1 (Oxidizer), PGIII.</p> <p>Other Information:</p> <p>Protect from physical damage. Do not store near acids, moisture or heat.</p> <p>Section 15 – Regulatory Information <br />UNITED STATES <br />Sara Title III (Superfund Amendments and Reauthorization Act) <br />- Section 302 Extremely Hazardous Substances (40 cfr 355, appendix a): Not applicable <br />- Section 311 Hazard Categories (40 CFR 370): Fire Hazard, Immediate (Acute) Health Hazard <br />- Section 312 Threshold Planning Quantity (40 CFR 370): <br />The Threshold Planning Quantity (TPQ) for this product, if treated as a mixture, is 10,000 lbs; however, <br />this product contains the following ingredients with a TPQ of less than 10,000 lbs.: None <br />- Section 313 Reportable Ingredients (40 CFR 372): <br />There are no ingredients in this product, which are subject to Section 313 reporting requirements. <br />CERCLA (Comprehensive Environmental Response Compensation and Liability Act) <br />- CERCLA Designation & Reportable Quantities (RQ) (40 CFR 302.4): <br />Unlisted, RQ = 100 lbs., Ignitability <br />TSCA (Toxic Substance Control Act) <br />- TSCA Inventory Status (40 CFR 710): <br />All components are listed or exempt.</p> <p>Page 5 of 6</p> <p>IDENTITY: InjectPro-PM3811-HARDENER (COMPONENT-B)</p> <p>SAFETY DATA SHEET <br />SDS No. IM1.1.1.C</p> <p>Resource Conservation and Recovery Act (RCRA) <br />- RCRA Identification of Hazardous Waste (40 CFR 261): <br />Waste Number: D001 <br />Hazard and Risk Phrase Descriptions: <br />EC Symbols: <br />Xn (Harmful) <br />O (Oxidizer) <br />EC Risk Phrases:</p> <p>R8 (Contact with combustible material may cause fire) <br />R22 (Harmful if swallowed.) <br />R36/37/38 (Irritating to eyes, respiratory system and skin.) <br />R42/43 (May cause sensitization by inhalation or by skin contact.)</p> <p>Section 16 – Other Information <br />(Hazard Rating:</p> <p>0 = Minimal;</p> <p>HMIS III rating: <br />Health: 1* <br />Flammability: 1</p> <p>1 = Slight;</p> <p>2 = Moderate;</p> <p>3 = Serious;</p> <p>4 = Severe; * = Chronic)</p> <p>Physical hazard: 0</p> <p>Abbreviations and acronyms: <br />USDOT: <br />United States Department of Transportation. <br />IMDG: <br />International Maritime Code for Dangerous Goods. <br />IATA: <br />International Air Transport Association. <br />CAS: <br />Chemical Abstracts Service (Division of the American Chemical Society). <br />LC50: <br />Lethal concentration, 50 percent. <br />LD50: <br />Lethal dose, 50 percent. <br />SDS prepared by:</p> <p>Aquafin product safety department.</p> <p>DISCLAIMER: <br />We believe the statements, technical information and recommendations contained herein are reliable, but they are <br />given without warranty or guarantee of any kind, expressed or implied, and we assume no responsibility for any <br />loss, damage, or expense, direct or consequential, arising out of their use. Aquafin shall not be responsible for the <br />use of this product in a manner to infringe on any patent or any other intellectual property rights held by others. <br />User is responsible for determining appropriate safety measures and for applying the legislation covering his own <br />activities. We recommend that user makes tests to determine the suitability of a product for its particular purpose <br />prior to use. <br />END OF SDS</p> <p>Page 6 of 6</p> <p>(January 22, 2019)</p>
