IDENTITY:
SAFETY DATA SHEET SDS No. E.1.2.1
InjectProECO-ACCELERATOR-CCS
Date prepared: JANUARY 2017 Date revised: MAY 2021
SDS No. E.1.2.1
Section 1 – Product Identification IDENTITY:
Product Name: Chemical Characterization: Product Use Description:
Hexadecyldimethylamine Accelerant for PU injection resin
AQUAFIN, INC. 505 BLUE BALL RD. #160 ELKTON, MD 21921
Emergency Phone No. Information Phone No.
info@aquafin.net
Recommended use of the chemical and restriction on use:
(800) 394-1410 (410) 392-2300
www.aquafin.net
Refer to the product technical data sheet. For industrial and professional users.
Section 2 – Hazards Identification GHS Classification: Skin Corr. 1B Eye Dam. 1 Acute Tox. 4
H314 Causes severe skin burns and eye damage. H318 Causes serious eye damage. H302 Harmful if swallowed.
GHS Label element: Hazard Pictograms GHS05 Signal Word:
GHS07
Danger
Hazard Statements: H302 Harmful if swallowed H314 Causes severe skin burns and eye damage H318 Causes serious eye damage Precautionary Statements: Prevention: P260 Do not breathe dust/fume/gas/mist/vapors/spray P280 Wear protective gloves/protective clothing/eye protection/face protection P282 Wear face shield/eye protection P264 Wash … thoroughly after handling P270 Do not eat, drink or smoke when using this product Response: P302 + P362 + P353 P305 + P351 + P338 P301 + P312 + P330 P330 P304 + P340 P363
IF ON SKIN: P362 Take off contaminated clothing and wash before reuse. Rinse skin with water/shower IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Call a POISON CENTER/doctor if you feel unwell. Rinse mouth. Do NOT induce vomiting IF INHALED: Remove person to fresh air and keep comfortable for breathing. Wash contaminated clothing before reuse.
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Storage: P404 +405: Disposal: P501:
Store in a closed container. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations
Section 3 – Composition / Information on Ingredients Description: Mixture of the substances listed below with nonhazardous additions. Hazardous Components Hexadecyldimethylamine
CAS No. 112-69-6
Weight % 25-50%
There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence not require reporting in this section.
Section 4 – First Aid Measures General Information: Immediately remove any clothing soiled by the product. Symptoms of poisoning may even occur after several hours; therefore, medical observation is suggested for at least 48 hours after the accident. After Inhalation:
In case of unconsciousness place patient stably in side position for transportation.
After Ingestion:
Immediately seek medical attention. Do not induce vomiting without medical advice. If conscious, drink plenty of water.
After Skin Contact:
Immediately wash with water and soap and rinse thoroughly.
After Eye Contact:
Rinse opened eye for several minutes under running water. Then consult a doctor.
Section 5 – Fire Fighting Measures Extinguishing Media:
Carbon Dioxide (CO2), extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant foam
Special Fire Fighting Procedures:
As in any fire, wear full protective gear and NIOSH-approved selfcontained breathing apparatus with full face-piece operated in the pressure demand or other positive pressure mode.
Section 6 – Accidental Release Measures Personal Safety Precautions:
Wear protective equipment. Keep unprotected persons away.
Environmental precautions:
Do not allow to enter sewers/ surface or ground water. Inform respective authorities in case of seepage into water course or sewage system.
Methods for Cleaning up:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). Use neutralizing agent. Dispose contaminated material as waste according to item 13. Ensure adequate ventilation. Page 2 of 6
Section 7 – Handling and Storage Handling: Storage:
Ensure good ventilation/exhaustion at the workplace. Prevent formation of aerosols. Store in an enclosed area in tightly closed containers.
Section 8 – Exposure Controls / Personal Protection Engineering Controls:
Use with adequate general and local exhaust ventilation.
Skin Protection:
Avoid contact with the skin. Immediately remove all soiled and contaminated clothing.
Eye Protection:
Wear tightly sealed goggles. Avoid contact with the eyes. .
Work/Hygienic Practices:
Keep away from foodstuffs, beverages and feed. Wash hands before breaks and at the end of work.
Breathing Equipment:
In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use respiratory protective device that is independent of circulating air.
Gloves:
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Section 9 – Physical and Chemical Properties Physical State: Appearance/Color: Odor: Solubility in water: Boiling Point: Melting Point: Flash Point: Auto ignition: Specific Gravity: pH (in water): VOC Concentration:
Fluid Colorless Amine-like Not miscible or difficult to mix. No data. No data. Product is not self-igniting Not determined. Not determined. No VOCs. 0.0 g/l / 0.00 lb/gl
Section 10 – Stability and Reactivity Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
No further relevant information available.
Hazardous Decomposition Products: No dangerous decomposition products known. Incompatibilities:
Section 11 – Toxicological Information Acute toxicity: 112-69-6 Hexadecyldimethylamine
Oral:
LD50 301 - 2000 mg/kg (rat) Page 3 of 6
Primary irritant effect: On the skin: Strong caustic effect on skin and mucous membranes. On the eye: Strong caustic effect. Sensitization: No sensitizing effects known. Additional toxicological information: The product shows the following dangers according to internally approved calculation methods for preparations: Harmful Corrosive Swallowing will lead to a strong caustic effect on mouth and throat and to the danger of perforation of esophagus and stomach. IARC: Not regulated as a carcinogen. NTP:
Not regulated as a carcinogen.
OSHA: Not regulated as a carcinogen.
Section 12 – Ecological Information Ecological Information:
Toxicity
Aquatic toxicity: 112-69-6
Hexadecyldimethylamine
LC50/96h
0.1-1 mg/l
(zebrafish)
Very toxic for fish Remark: Additional ecological information: General notes: Water hazard class 2 (Self-assessment): hazardous for water. Do not allow product to reach ground water, water course or sewage system. Must not reach bodies of water or drainage ditch undiluted or unneutralized. Danger to drinking water, if even small quantities leak into the ground. Also poisonous for fish and plankton in water bodies. Very toxic for aquatic organisms.
Section 13 – Disposal Considerations Waste Disposal Method:
Recommendation: Must not be disposed of together with household garbage. Do not allow product to reach sewage system.
Container disposal:
Disposal must be made according to official regulations.
Section 14 – Transport Information UN-Number: DOT, IMDG, IATA UN2735 UN Proper Shipping Name: DOT: Amines, liquid, corrosive, n.o.s. (Hexadecyldimethylamine) IMDG: A M I N E S , L I Q U I D , C O R R O S I V E , N . O . S . (Hexadecyldimethylamine), MARINE POLLUTANT IATA: A M I N E S , L I Q U I D , C O R R O S I V E , N . O . S . (Hexadecyldimethylamine) Transport Hazard Class: USDOT (Domestic Surface) IMDG (Ocean) Hazard Class or Division: IATA/ICAO (Air) Hazard Class or Division:
Class 8 Corrosive substances 8 Corrosive substances 8 Corrosive substances
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Label Packaging Group 8 III 8 III 8 III
Environmental hazards Marine pollutant Special precautions for user Danger code (Kemler) EMS Number: Segregation groups Stowage Category Segregation Code
Product contains environmentally hazardous substances: Hexadecyldimethylamine · Yes Symbol (fish and tree) Warning: Corrosive substances 80 F-A,S-B Alkalis A SG35 Stow "separated from" acids.
Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code: Not applicable. Transport/Additional information: DOT: Quantity limitations On passenger aircraft/rail: 1 L On cargo aircraft only: 30 L Remarks Special marking with the symbol (fish and tree). IMDG: Limited quantities (LQ) Excepted quantities (EQ) Code:
UN "Model Regulation":
5L E1 Maximum net quantity per inner packaging: 30 ml Maximum net quantity per outer packaging: 1000 ml UN 2 735 AMINES , LIQUID, CORROSIVE, N.O.S. (HEXADECYLDIMETHYLAMINE),8,III, ENVIRONMENTALLY HAZARDOUS
Section 15 – Regulatory Information SARA 355 (Extremely Hazardous Substances): None of the ingredients is listed. SARA Section 313 Notification: CERCLA: TSCA (Toxic Substances Control Act): 28553-12-0 112-69-6
None of the ingredients is listed. No CERCLA chemicals exist in this product above reportable concentrations. Di-''isononyl'' phthalate Hexadecyldimethylamine
California Proposition 65: Warning – This product contains a chemical known to the State of California to cause cancer: 28553-12-0 di-''isononyl'' phthalate
Section 16 – Other Information Abbreviations and acronyms: USDOT: IMDG: IATA:
United States Department of Transportation. International Maritime Code for Dangerous Goods. International Air Transport Association.
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CAS: HMIS: LC50: LD50: NIOSH: OSHA: TLV: PEL: REL:
Chemical Abstracts Service (Division of the American Chemical Society). Hazardous Materials Identification System (USA) Lethal concentration, 50 percent. Lethal dose, 50 percent. National Institute for Occupational Safety Occupational Safety & Health Threshold Limit Value Permissible Exposure Limit Recommended Exposure Limit
SDS prepared by:
Aquafin product safety department.
DISCLAIMER: We believe the statements, technical information and recommendations contained herein are reliable, but they are given without warranty or guarantee of any kind, expressed or implied, and we assume no responsibility for any loss, damage, or expense, direct or consequential, arising out of their use. Aquafin shall not be responsible for the use of this product in a manner to infringe on any patent or any other intellectual property rights held by others. END OFsafety MSDS (April 09, 2015) User is responsible for determining appropriate measures and for applying the legislation covering his own activities. We recommend that user makes tests to determine the suitability of a product for its particular purpose prior to use. END OF SDS
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(May 10, 2021)