SDS_InjectProECO-CombiGrout_012519.pdf
6 Pages
194 KB
Download
<h1>SDS_InjectProECO-CombiGrout_012519.pdf</h1> <p>IDENTITY:</p> <p>SAFETY DATA SHEET</p> <p>InjectProECO-CombiGrout</p> <p>Date prepared: <br />Date revised:</p> <p>SDS No. E.1.1</p> <p>JANUARY 2017 <br />JANUARY 2019</p> <p>SDS No. E.1.1</p> <p>Section 1 – Product Identification <br />IDENTITY:</p> <p>Product Name: <br />Chemical Characterization: <br />Product Use Description:</p> <p>InjectProECO-CombiGrout</p> <p>Diphenylmethanediisocyanate <br />PU injection resin - waterproofing</p> <p>AQUAFIN, INC. <br />505 BLUE BALL RD. #160 <br />ELKTON, MD 21921</p> <p>Emergency Phone No. <br />Information Phone No.</p> <p>info@aquafin.net</p> <p>Recommended use of the chemical and restriction on use:</p> <p>www.aquafin.net</p> <p>Refer to the product technical data sheet. <br />For industrial and professional users.</p> <p>Section 2 – Hazards Identification <br />GHS Classification: <br />Resp. Sens. 1 H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. <br />Carc. 2 <br />H351 Suspected of causing cancer. <br />STOT RE 2 <br />H373 May cause damage to organs through prolonged or repeated exposure. <br />Acute Tox. 4 <br />Skin Irrit. 2 <br />Eye Irrit. 2A <br />Skin Sens. 1 <br />STOT SE 3</p> <p>H332 Harmful if inhaled. <br />H315 Causes skin irritation. <br />H319 Causes serious eye irritation. <br />H317 May cause an allergic skin reaction. <br />H335 May cause respiratory irritation.</p> <p>GHS Label element: <br />Hazard Pictograms <br />GHS07 <br />Signal Word:</p> <p>GHS08</p> <p>Danger</p> <p>Hazard Statements: <br />H332 Harmful if inhaled. <br />H315 Causes skin irritation. <br />H320 Causes serious eye irritation. <br />H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. <br />H317 May cause an allergic skin reaction. <br />H351 Suspected of causing cancer. <br />H335 May cause respiratory irritation. <br />H373 May cause damage to organs through prolonged or repeated exposure. <br />Precautionary Statements: <br />P201 Obtain special instructions before use. <br />P202 Do not handle until all safety precautions have been read and understood. <br />P260 Do not breathe dust/fume/gas/mist/vapors/spray. <br />P285 In case of inadequate ventilation, wear respiratory protection. <br />P261 Avoid breathing dust/fume/gas/mist/vapors/spray <br />P280 Wear protective gloves/protective clothing/eye protection/face protection. <br />P264</p> <p>Wash thoroughly after handling. <br />Page 1 of 6</p> <p>(800) 394-1410 <br />(410) 392-2300</p> <p>IDENTITY:</p> <p>P271 <br />P272</p> <p>SAFETY DATA SHEET</p> <p>InjectProECO-CombiGrout</p> <p>SDS No. E.1.1</p> <p>Use only outdoors or in a well-ventilated area. <br />Contaminated work clothing must not be allowed out of the workplace.</p> <p>Prevention: <br />P305+351+338</p> <p>If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if <br />present and easy to do. Continue rinsing. <br />If experiencing respiratory symptoms: Call a POISON CENTER/doctor. <br />IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a <br />POISON CENTER/doctor if you feel unwell. <br />Wash contaminated clothing before reuse.</p> <p>P342+311 <br />P304+340+312 <br />P363 <br />Response: <br />P308+313 <br />P333+313 <br />P337+313 <br />P314 <br />P303+352+362 <br />Storage: <br />P403 + P232: <br />Disposal: <br />P501:</p> <p>IF exposed or concerned: Get medical advice/attention. <br />If skin irritation or rash occurs: Get medical advice/attention. <br />If eye irritation persists: Get medical advice/attention. <br />Get medical advice/attention if you feel unwell. <br />IF ON SKIN: Wash with plenty of water. Take off contaminated clothing and wash it before <br />reuse <br />Store in a well-ventilated place. Protect from moisture. <br />Dispose of contents/container in accordance with local/regional/national/international <br />regulations.</p> <p>Section 3 – Composition / Information on Ingredients <br />Mixture of the substances listed below with nonhazardous additions. <br />Hazardous Components <br />Diphenylmethanediisocyanate, isomeres and homologues</p> <p>CAS No. <br />9016-87-9</p> <p>Weight % <br />25 - 50</p> <p>4,4'-methylenediphenyl diisocyanate</p> <p>101-68-8</p> <p>10 - 25</p> <p>Isocyanic acid, polymethylenepolyphenylene ester, polymer with .alpha.hydro- .omega.-hydroxypolyoxy(methyl-1,2-ethanediyl)</p> <p>53862-89-8</p> <p>10 - 25</p> <p>There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations <br />applicable, are classified as hazardous to health or the environment and hence not require reporting in this section.</p> <p>Section 4 – First Aid Measures <br />General information: Symptoms of poisoning may even occur after several hours; therefore medical <br />observation for at least 48 hours after the accident is suggested. <br />After Inhalation:</p> <p>Supply fresh air and be sure to call for a doctor. In case of unconsciousness, place <br />patient stably on side position for transportation.</p> <p>After Ingestion:</p> <p>Immediately seek medical attention. Do not induce vomiting without medical advice.</p> <p>After Skin Contact:</p> <p>Immediately wash with water and soap and rinse thoroughly. Seek medical attention if <br />symptoms persist.</p> <p>After Eye Contact:</p> <p>Rinse opened eye for several minutes under running water. If symptoms persist, consult a <br />Page 2 of 6</p> <p>IDENTITY:</p> <p>SAFETY DATA SHEET</p> <p>InjectProECO-CombiGrout</p> <p>SDS No. E.1.1</p> <p>doctor.</p> <p>Section 5 – Fire Fighting Measures <br />Extinguishing Media:</p> <p>Carbon dioxide (CO2), extinguishing powder or water spray. Fight <br />larger fires with water spray or alcohol resistant foam.</p> <p>Special Fire Fighting Procedures:</p> <p>As in any fire, wear full protective gear and NIOSH-approved selfcontained breathing apparatus with full face-piece operated in the <br />pressure demand or other positive pressure mode.</p> <p>Section 6 – Accidental Release Measures <br />Person-related Safety Precautions: <br />Environmental precautions:</p> <p>Not required. <br />Prevent material from reaching sewage and drainage systems or <br />bodies of water.</p> <p>Methods for Cleaning up:</p> <p>Absorb with liquid-binding material (sand, diatomite, acid binders, <br />universal binders, sawdust). Dispose contaminated material as waste <br />according to item 13. Ensure adequate ventilation.</p> <p>Section 7 – Handling and Storage <br />Handling: <br />Storage:</p> <p>Ensure good ventilation/exhaustion at the workplace. Prevent formation of aerosols. <br />Store in tightly closed containers.</p> <p>Section 8 – Exposure Controls / Personal Protection <br />Engineering Controls:</p> <p>Use with adequate general and local exhaust ventilation.</p> <p>Respiratory Protection:</p> <p>In case of brief exposure or low pollution use respiratory filter device. In case of <br />intensive or longer exposure use respiratory protective device that is independent <br />of circulating air.</p> <p>Skin Protection:</p> <p>The glove material has to be impermeable and resistant to the product/ the <br />substance/ the preparation</p> <p>Eye Protection:</p> <p>Wear tightly sealed goggles.</p> <p>Work/Hygienic Practices:</p> <p>Keep away from foodstuffs, beverages and feed. Immediately remove all soiled <br />and contaminated clothing. Wash hands before breaks and at the end of work. <br />Avoid contact with the eyes and skin.</p> <p>Exposure Limits:</p> <p>COMPONENT <br />4,4'-methylenediphenyl diisocyanate</p> <p>CAS NUMBER <br />101-68-8</p> <p>Section 9 – Physical and Chemical Properties <br />Physical State: <br />Appearance/Color: <br />Odor:</p> <p>Fluid <br />Light Brown <br />Characteristic <br />Page 3 of 6</p> <p>OSHA/PEL <br />0.02 ppm (Ceiling)</p> <p>ACGIH/TLV <br />0.005 ppm</p> <p>IDENTITY:</p> <p>SAFETY DATA SHEET</p> <p>InjectProECO-CombiGrout</p> <p>Solubility in water: <br />Boiling Point: <br />Melting Point: <br />Flash Point: <br />Auto ignition: <br />pH (in water): <br />VOC Concentration:</p> <p>SDS No. E.1.1</p> <p>Not miscible or difficult to mix <br />Undetermined <br />Undetermined. <br />Not applicable. <br />Product is not self-igniting. <br />Reacts with water. <br />0.0 g/l / 0.00 lb/gl</p> <p>Section 10 – Stability and Reactivity <br />Chemical Stability:</p> <p>Stable under normal temperatures and pressures.</p> <p>Conditions to Avoid:</p> <p>No further relevant information available</p> <p>Hazardous Decomposition Products: No dangerous decomposition products known. <br />Incompatibilities:</p> <p>No further relevant information available</p> <p>Section 11 – Toxicological Information <br />Primary irritant effect: <br />On the skin: Irritant to skin and mucous membranes. <br />On the eye: <br />Irritating effect. · <br />Sensitization: Sensitization possible through inhalation. Sensitization possible through skin contact. <br />Additional toxicological information: <br />The product shows the following dangers according to internally approved calculation methods for <br />preparations: Harmful, Irritant <br />LD/LC50 values that are relevant for classification: <br />9016-87-9 <br />diphenylmethanediisocyanate, isomeres and homologues <br />Oral <br />LD50 >10000 mg/kg (rat) <br />Dermal LD50 >9400 mg/kg (rabbit) <br />101-68-8</p> <p>4,4'-methylenediphenyl diisocyanate <br />Oral <br />LD50 2200 mg/kg (mouse) >10000 mg/kg (rat) <br />Dermal LD50 >9400 mg/kg (rabbit)</p> <p>53862-89-8</p> <p>Isocyanic acid, polymethylenepolyphenylene ester, polymer with .alpha.-hydro-.omega.hydroxypolyoxy(methyl-1,2-ethanediyl) <br />Oral <br />LD50 >10000 mg/kg (rat) <br />Dermal LD50 >9400 mg/kg (rabbit)</p> <p>Reaction mass of 4,4'-methylenediphenyldiisocyanate and o-(p-isocyanatobenzyl)phenylisocyanaat <br />Oral <br />LD50 >10000 mg/kg (rat) <br />Dermal LD50 >9400 mg/kg (rabbit) <br />Carcinogenic categories: <br />IARC (International Agency for Research on Cancer) <br />9016-87-9 <br />diphenylmethanediisocyanate, isomeres and homologues <br />101-68-8</p> <p>4,4'-methylenediphenyl diisocyanate</p> <p>NTP:</p> <p>None of the ingredients is listed.</p> <p>OSHA-Ca:</p> <p>None of the ingredients is listed. <br />Page 4 of 6</p> <p>IDENTITY:</p> <p>SAFETY DATA SHEET</p> <p>InjectProECO-CombiGrout</p> <p>SDS No. E.1.1</p> <p>Section 12 – Ecological Information <br />General notes:</p> <p>Water hazard class 1 (Self-assessment): slightly hazardous for water. Do not allow <br />undiluted product or large quantities of it to reach ground water, water course or sewage <br />system.</p> <p>Toxicity <br />Aquatic toxicity: <br />9016-87-9 diphenylmethanediisocyanate, isomeres and homologues <br />EC50/24 h >1000 mg/l (daphnia) <br />EC50/96 h >1000 mg/l (fish) <br />EC50/72 h >1640 mg/l (algae) <br />101-68-8 4,4'-methylenediphenyl diisocyanate <br />LC50/96 h >1000 mg/l (fish) <br />EC50/24 h >1000 mg/l (daphnia) 53862-89-8 <br />Isocyanic acid, polymethylenepolyphenylene ester, polymer with .alpha.-hydro-.omega.hydroxypolyoxy(methyl-1,2-ethanediyl) <br />LC50/96 h >1000 mg/l (fish) <br />Reaction mass of 4,4'-methylenediphenyldiisocyanate and o-(p-isocyanatobenzyl)phenylisocyanaat <br />LC50/96 h >1000 mg/l (fish) <br />EC50/24 h >1000 mg/l (daphnia)</p> <p>Section 13 – Disposal Considerations <br />Waste Disposal Method:</p> <p>Must not be disposed of together with household garbage. Do not allow product <br />to reach sewage system.</p> <p>Container disposal:</p> <p>Disposal must be made according to official regulations.</p> <p>Section 14 – Transport Information <br />RCRA Hazard Class:</p> <p>Non-hazardous</p> <p>USDOT (Domestic Surface) <br />IMDG (Ocean) Hazard Class or Division: <br />IATA/ICAO (Air) Hazard Class or Division: <br />TDG (Canada): <br />UN Number:</p> <p>Not regulated <br />Not regulated <br />Not regulated <br />Not regulated <br />Not regulated</p> <p>Section 15 – Regulatory Information <br />SARA 311/312 (RTK): Hazard Categories:</p> <p>Acute Health: <br />Chronic Health:</p> <p>YES <br />YES</p> <p>SARA Section 313 Notification:</p> <p>9016-87-9 diphenylmethanediisocyanate, isomeres and homologues <br />101-68-8 4,4'-methylenediphenyl diisocyanate</p> <p>CERCLA:</p> <p>No CERCLA chemicals exist in this product above reportable <br />concentrations.</p> <p>TSCA Section 12(b) Export Notification: <br />Page 5 of 6</p> <p>IDENTITY:</p> <p>9016-87-9 <br />101-68-8 <br />53862-89-8</p> <p>SAFETY DATA SHEET</p> <p>InjectProECO-CombiGrout</p> <p>SDS No. E.1.1</p> <p>diphenylmethanediisocyanate, isomeres and homologues <br />4,4'-methylenediphenyl diisocyanate <br />Isocyanic acid, polymethylenepolyphenylene ester, polymer with .alpha.-hydro-.omega.hydroxypolyoxy(methyl-1,2-ethanediyl)</p> <p>California Proposition 65:</p> <p>None of the ingredients is listed.</p> <p>EPA (Environmental Protection Agency) <br />9016-87-9 <br />diphenylmethanediisocyanate, isomeres and homologues <br />101-68-8 <br />4,4'-methylenediphenyl diisocyanate</p> <p>Section 16 – Other Information <br />Abbreviations and acronyms: <br />USDOT: <br />IMDG: <br />IATA: <br />ACGIH: <br />CAS: <br />VOC: <br />LC50: <br />LD50: <br />PEL: <br />REL:</p> <p>United States Department of Transportation. <br />International Maritime Code for Dangerous Goods. <br />International Air Transport Association. <br />American Conference of Governmental Industrial Hygienist <br />Chemical Abstracts Service (Division of the American Chemical Society). <br />Volatile Organic Compounds (USA, EU) <br />Lethal concentration, 50 percent. <br />Lethal dose, 50 percent. <br />Permissible Exposure Limit <br />Recommended Exposure Limit</p> <p>SDS prepared by:</p> <p>Aquafin product safety department.</p> <p>DISCLAIMER: <br />We believe the statements, technical information and recommendations contained herein are reliable, but they are <br />given without warranty or guarantee of any kind, expressed or implied, and we assume no responsibility for any <br />loss, damage, or expense, direct or consequential, arising out of their use. Aquafin shall not be responsible for the <br />use of this product in a manner to infringe on any patent or any other intellectual property rights held by others. <br />END OFsafety <br />MSDS <br />(April 09, 2015) <br />User is responsible for determining appropriate <br />measures and for applying the legislation <br />covering his own <br />activities. We recommend that user makes tests to determine the suitability of a product for its particular purpose <br />prior to use. <br />END OF SDS</p> <p>Page 6 of 6</p> <p>(January 25, 2019)</p>
