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<h1>SDS_InjectProECO-Polygel(A)_071125.pdf</h1> <p>Safety Data Sheet (SDS)</p> <p>Page 1/16</p> <p>OSHA HazCom Standard 29 CFR 1910.1200(g) and GHS Rev 03.</p> <p>Printing date 07/11/2025</p> <p>Reviewed on 07/11/2025</p> <p>SECTION 1: Identification</p> <p>IDENTITY:</p> <p>Product Name: InjectProECO-Polygel <br />Product Use Description:</p> <p>AQUAFIN, INC. <br />505 BLUE BALL RD. #160 <br />ELKTON, MD 21921</p> <p>Chemical Injection Grout, For Further Information, Refer to the <br />Product Technical Data Sheet. <br />24 hr Emergency Phone: Chem-Tel (800) 255-3924 <br />Information Phone No: (410) 392-2300</p> <p>info@aquafin.net</p> <p>www.aquafin.net</p> <p>SECTION 2: Hazard(s) identification <br />2.1. Classification of the substance or mixture <br />GHS US classification <br />Acute toxicity (inhalation:dust,mist) Category 4 <br />Skin corrosion/irritation Category 2 <br />Serious eye damage/eye irritation Category 2 <br />Respiratory sensitization, Category 1 <br />Skin sensitization, Category 1 <br />Carcinogenicity Category 2 <br />Specific target organ toxicity – Single exposure, Category 3, <br />Respiratory tract irritation <br />Specific target organ toxicity (repeated exposure) Category 2</p> <p>Harmful if inhaled <br />Causes skin irritation <br />Causes serious eye irritation <br />May cause allergy or asthma symptoms or breathing difficulties if <br />inhaled. <br />May cause an allergic skin reaction <br />Suspected of causing cancer <br />May cause respiratory irritation <br />May cause damage to organs (respiratory system) through <br />prolonged or repeated exposure (Inhalation)</p> <p>Full text of H statements : see section 16</p> <p>2.2. GHS Label elements, including precautionary statements <br />GHS US labeling <br />Hazard pictograms (GHS US)</p> <p>:</p> <p>Signal word (GHS US) <br />Hazard statements (GHS US)</p> <p>: Danger <br />: Causes skin irritation <br />May cause an allergic skin reaction <br />Causes serious eye irritation <br />Harmful if inhaled <br />May cause allergy or asthma symptoms or breathing difficulties if inhaled.</p> <p>SDS InjectProECO-Polygel <br />SDS DATE: 11-JULY-25</p> <p>Page 1 of 16</p> <p>Precautionary statements (GHS US)</p> <p>May cause respiratory irritation <br />Suspected of causing cancer <br />May cause damage to organs (respiratory system) through prolonged or repeated exposure <br />(Inhalation) <br />: Obtain special instructions before use. <br />Do not handle until all safety precautions have been read and understood. <br />Do not breathe mist, spray, vapors, gas. <br />Wash hands, forearms and face thoroughly after handling. <br />Use only outdoors or in a well-ventilated area. <br />Contaminated work clothing must not be allowed out of the workplace. <br />Wear eye protection, face protection, protective clothing, protective gloves. <br />[In case of inadequate ventilation] wear respiratory protection. <br />If on skin: Wash with plenty of water. <br />If skin irritation or rash occurs: Get medical advice/attention. <br />Take off contaminated clothing and wash it before reuse. <br />If inhaled: If breathing is difficult, remove person to fresh air and keep comfortable for breathing. <br />If experiencing respiratory symptoms: Call a poison center or doctor. <br />IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present <br />and easy to do. Continue rinsing. <br />If eye irritation persists: Get medical advice/attention. <br />If exposed or concerned: Get medical advice/attention. <br />Store in a well-ventilated place. Keep container tightly closed. <br />Store locked up. <br />Dispose of contents/container to hazardous or special waste collection point, in accordance with <br />local, regional, national and/or international regulation.</p> <p>2.3. Other hazards which do not result in classification <br />No additional information available.</p> <p>2.4. Unknown acute toxicity (GHS US) <br />No additional information available.</p> <p>SECTION 3: Composition/Information on ingredients <br />3.1. Substances <br />Not applicable</p> <p>3.2. Mixtures <br />Name</p> <p>Product identifier</p> <p>%</p> <p>GHS US classification</p> <p>Dimethyl Glutarate</p> <p>CAS-No.: 1119-40-0</p> <p>14 – 22</p> <p>Eye Irrit. 2A, H319</p> <p>4,4'-Methylenediphenyl diisocyanate</p> <p>CAS-No.: 101-68-8</p> <p>1–5</p> <p>Acute Tox. 4 (Inhalation), H332 <br />Skin Irrit. 2, H315 <br />Eye Irrit. 2A, H319 <br />Resp. Sens. 1, H334 <br />Skin Sens. 1, H317 <br />Carc. 2, H351 <br />STOT SE 3, H335 <br />STOT RE 2, H373</p> <p>Dimethyl Adipate</p> <p>CAS-No.: 627-93-0</p> <p>1.5 – 7.5</p> <p>Eye Irrit. 2, H319</p> <p>Dimethyl Succinate</p> <p>CAS-No.: 106-65-0</p> <p>1.5 – 7.5</p> <p>Eye Irrit. 2, H319</p> <p>SDS InjectProECO-Polygel <br />SDS DATE: 11-JULY-25</p> <p>Page 2 of 16</p> <p>Name</p> <p>Product identifier</p> <p>%</p> <p>GHS US classification</p> <p>Diphenylmethane Diisocyanate, isomers and homologues</p> <p>CAS-No.: 9016-87-9</p> <p>1–5</p> <p>Acute Tox. 4 (Inhalation:dust,mist), <br />H332 <br />Skin Irrit. 2, H315 <br />Eye Irrit. 2B, H320 <br />Resp. Sens. 1, H334 <br />Skin Sens. 1, H317 <br />Carc. 2, H351 <br />STOT SE 3, H335 <br />STOT RE 2, H373</p> <p>Toluene-diisocyanate (mixed isomers)</p> <p>CAS-No.: 26471-62-5</p> <p>0.5 – 2</p> <p>Acute Tox. 2 (Inhalation), H330 <br />Skin Irrit. 2, H315 <br />Eye Irrit. 2, H319 <br />Resp. Sens. 1, H334 <br />Skin Sens. 1, H317 <br />Carc. 2, H351 <br />STOT SE 3, H335 <br />Aquatic Chronic 3, H412</p> <p>4-Isocyanatosulphonyltoluene</p> <p>CAS-No.: 4083-64-1</p> <p>> 0.6</p> <p>Skin Irrit. 2, H315 <br />Eye Irrit. 2, H319 <br />Resp. Sens. 1, H334 <br />STOT SE 3, H335 <br />Aquatic Chronic 3, H412</p> <p>2,4'-Diphenylmethane Diisocyanate (MDI)</p> <p>CAS-No.: 5873-54-1</p> <p>0.1 – 1</p> <p>Acute Tox. 4 (Inhalation), H332 <br />Skin Irrit. 2, H315 <br />Eye Irrit. 2, H319 <br />Resp. Sens. 1, H334 <br />Skin Sens. 1, H317 <br />Carc. 2, H351 <br />STOT SE 3, H335 <br />STOT RE 2, H373</p> <p>Full text of hazard classes and H-statements : see section 16</p> <p>SECTION 4: First-aid measures <br />4.1. Description of first aid measures <br />First-aid measures general</p> <p>First-aid measures after inhalation</p> <p>First-aid measures after skin contact</p> <p>First-aid measures after eye contact <br />First-aid measures after ingestion</p> <p>SDS InjectProECO-Polygel <br />SDS DATE: 11-JULY-25</p> <p>: First aider: Pay attention to self-protection. Never give anything by mouth to an unconscious <br />person. Give artificial respiration if necessary. Induce artificial respiration with mask fitted with <br />one-way valve or other suitable device but not mouth-to-mouth. IF exposed or concerned: Get <br />medical advice/attention. <br />: If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for <br />breathing. If the victim is unconscious : Lay in a stable manner on victim's side. Induce artificial <br />respiration with mask fitted with one-way valve or other suitable device; not mouth-to-mouth. Call <br />a physician immediately. <br />: Remove affected clothing and wash all exposed skin area with mild soap and water, followed by <br />warm water rinse. If skin irritation or rash occurs: Get medical advice/attention. Wash <br />contaminated clothing before reuse. <br />: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to <br />do. Continue rinsing. If eye irritation persists: Get medical advice/attention. <br />: Rinse mouth out with water. If the person is fully conscious, make him/her drink water (8 ounces <br />/ 240mL). Never give an unconscious person anything to drink. Do NOT induce vomiting. If <br />vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Call a <br />poison center/doctor/physician if you feel unwell.</p> <p>Page 3 of 16</p> <p>4.2. Most important symptoms and effects (acute and delayed) <br />Symptoms/effects after inhalation <br />Symptoms/effects after skin contact <br />Symptoms/effects after eye contact <br />Symptoms/effects after ingestion</p> <p>: May cause respiratory irritation. May cause allergy or asthma symptoms or breathing difficulties <br />if inhaled. <br />: May cause an allergic skin reaction. Irritation (itching, redness, blistering). <br />: Stinging, redness, itching, tears, blurred vision, swelling. <br />: Not expected to present a significant ingestion hazard under anticipated conditions of normal <br />use. Ingestion may cause nausea and vomiting.</p> <p>4.3. Immediate medical attention and special treatment, if necessary <br />Treat symptomatically.</p> <p>SECTION 5: Fire-fighting measures <br />5.1. Suitable (and unsuitable) extinguishing media <br />Suitable extinguishing media <br />Unsuitable extinguishing media</p> <p>: Dry chemical, CO2, dry sand, or alcohol-resistant foam. Use extinguishing agent suitable for <br />surrounding fire. <br />: Do not use a heavy water stream.</p> <p>5.2. Specific hazards arising from the chemical <br />Fire hazard <br />Hazardous decomposition products in case of fire</p> <p>: No fire hazard. <br />: Toxic fumes may be released. Thermal decomposition generates: Carbon dioxide. Carbon <br />monoxide. Nitrogen oxides.</p> <p>5.3. Special protective equipment and precautions for fire-fighters <br />Firefighting instructions</p> <p>Protection during firefighting</p> <p>: Fight fire from safe distance and protected location. Do not enter fire area without proper <br />protective equipment, including respiratory protection. Move containers from fire area if it can be <br />done without personal risk. Use water spray or fog for cooling exposed containers. Use <br />extinguishing media appropriate for surrounding fire. Prevent fire-fighting water from entering <br />environment. <br />: Do not attempt to take action without suitable protective equipment. Self-contained breathing <br />apparatus. Complete protective clothing.</p> <p>SECTION 6: Accidental release measures <br />6.1. Personal precautions, protective equipment and emergency procedures <br />General measures</p> <p>: Avoid all personal contact including breathing in the mist, spray, vapors, gas. Do not take actions <br />involving personal risks. Stop leak if safe to do so. Absorb spillage to prevent material-damage. <br />Notify authorities if product enters sewers or public waters.</p> <p>6.1.1. For non-emergency personnel <br />Protective equipment <br />Emergency procedures</p> <p>: Wear recommended personal protective equipment. <br />: Evacuate the danger area. If outdoors, move to an area upwind of the danger area. If possible <br />without taking personal risks, remove ignition sources, ventilate area. Avoid contact with skin and <br />eyes. Avoid breathing mist, spray, vapors, gas. Prevent other non-emergency personnel from <br />entering the danger area.</p> <p>6.1.2. For emergency responders <br />Protective equipment <br />Emergency procedures</p> <p>: Wear the recommended personal protective equipment. <br />: Evacuate unnecessary personnel. Ventilate spillage area. Stop leak if safe to do so. Remove all <br />sources of ignition.</p> <p>6.2. Environmental precautions <br />Do not let the product reach soil, drains, sewers, or surface and ground water.</p> <p>SDS InjectProECO-Polygel <br />SDS DATE: 11-JULY-25</p> <p>Page 4 of 16</p> <p>6.3. Methods and material for containment and cleaning up <br />For containment</p> <p>Methods for cleaning up</p> <p>: Stop leak, if possible without risk. Small spills: Contain with non-combustible inert absorbent. In <br />case of large spillages: Contain any spills with dikes or absorbents to prevent migration and <br />entry into sewers or streams. Absorb spilled material with sand or earth. <br />: Take up in non-combustible inert absorbent and place into container for disposal. Contaminated <br />absorbent material may pose the same hazard as the spilt product. Decontaminate surfaces and <br />equipment with water and detergent. Until a sufficient level of dilution is achieved, the <br />decontamination water may pose the same hazards as the product. Dispose of collected material <br />as soon as possible in accordance with applicable local/regional/national/international <br />regulations.</p> <p>6.4. Reference to other sections <br />For further information refer to section 8: "Exposure controls/personal protection". For further information refer to section 13.</p> <p>SECTION 7: Handling and storage <br />7.1. Precautions for safe handling <br />Precautions for safe handling</p> <p>Hygiene measures</p> <p>: Obtain special instructions before use. Do not handle until all safety precautions have been read <br />and understood. Wear personal protective equipment. Use only outdoors or in a well-ventilated <br />area. Avoid breathing mist, spray, vapors, gas. Avoid contact with skin, eyes and clothing. Take <br />precautionary measures against static discharge. <br />: Do not eat, drink or smoke when using this product. Always wash hands after handling the <br />product. Contaminated work clothing should not be allowed out of the workplace.</p> <p>7.2. Conditions for safe storage, including any incompatibilities <br />Storage conditions</p> <p>Incompatible products <br />Packaging materials</p> <p>: Store in a cool, dry and well-ventilated area away from incompatible substances. Store locked <br />up. Store tightly closed until ready for use. Containers that have been opened must be carefully <br />resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use <br />appropriate containment to avoid environmental contamination. <br />: Oxidizing agents. <br />: Store always product in container of same material as original container.</p> <p>SECTION 8: Exposure controls/personal protection <br />8.1. Control parameters</p> <p>No additional information available.</p> <p>4,4'-Methylenediphenyl diisocyanate (101-68-8) <br />USA - ACGIH - Occupational Exposure Limits <br />Local name</p> <p>Methylene bisphenyl isocyanate (MDI)</p> <p>ACGIH OEL TWA</p> <p>0.005 ppm</p> <p>Remark (ACGIH)</p> <p>TLV® Basis: Resp sens</p> <p>Regulatory reference</p> <p>ACGIH 2024</p> <p>USA - OSHA - Occupational Exposure Limits <br />Local name</p> <p>Methylene bisphenyl isocyanate (MDI)</p> <p>OSHA PEL C</p> <p>0.2 mg/m³</p> <p>SDS InjectProECO-Polygel <br />SDS DATE: 11-JULY-25</p> <p>Page 5 of 16</p> <p>4,4'-Methylenediphenyl diisocyanate (101-68-8) <br />0.02 ppm <br />Regulatory reference (US-OSHA)</p> <p>OSHA Annotated Table Z-1</p> <p>Toluene-diisocyanate (mixed isomers) (26471-62-5) <br />No additional information available.</p> <p>4-Isocyanatosulphonyltoluene (4083-64-1) <br />No additional information available.</p> <p>2,4'-Diphenylmethane Diisocyanate (MDI) (5873-54-1) <br />No additional information available.</p> <p>Dimethyl Glutarate (1119-40-0) <br />No additional information available.</p> <p>Dimethyl Adipate (627-93-0) <br />No additional information available.</p> <p>Dimethyl Succinate (106-65-0) <br />No additional information available.</p> <p>Diphenylmethane Diisocyanate, isomers and homologues (9016-87-9) <br />No additional information available.</p> <p>8.2. Appropriate engineering controls <br />Appropriate engineering controls <br />Environmental exposure controls</p> <p>: Ensure good ventilation of the work station. Use general ventilation, local exhaust ventilation, or <br />process enclosure to keep the airborne concentrations below the permissible exposure limits. <br />: Avoid release to the environment. Take measures to reduce or limit air emissions and releases <br />to soil and the aquatic environment.</p> <p>8.3. Individual protection measures/Personal protective equipment <br />Personal protective equipment: <br />Personal protective equipment should be chosen according to national standards and in discussion with the supplier of the protective equipment. Wear <br />recommended personal protective equipment. <br />Materials for protective clothing: <br />Personal protective equipment should be chosen according to national standards and in discussion with the supplier of the protective equipment. <br />Hand protection: <br />Wear protective gloves. Wear suitable gloves resistant to chemical penetration. Discard contaminated gloves and wash contaminated clothing before <br />reuse <br />Eye protection: <br />Chemical goggles or safety glasses <br />Skin and body protection: <br />Long sleeved protective clothing. Body protection should be chosen depending on activity and possible exposure</p> <p>SDS InjectProECO-Polygel <br />SDS DATE: 11-JULY-25</p> <p>Page 6 of 16</p> <p>Respiratory protection: <br />In case of inadequate ventilation wear respiratory protection. Select a respirator that meets the appropriate standard or certification. Respirators must <br />be used according to a respiratory protection program to ensure proper fitting, training, and other important aspects of use. <br />Personal protective equipment symbol(s):</p> <p>SECTION 9: Physical and chemical properties <br />9.1. Information on basic physical and chemical properties <br />Physical state <br />Appearance <br />Color <br />Odor <br />Odor threshold <br />pH <br />Melting point <br />Freezing point <br />Boiling point <br />Flash point <br />Relative evaporation rate (butyl acetate=1) <br />Flammability (solid, gas) <br />Vapor pressure <br />Relative vapor density at 20°C <br />Relative density <br />Solubility <br />Partition coefficient n-octanol/water (Log Pow) <br />Auto-ignition temperature <br />Decomposition temperature <br />Viscosity, kinematic <br />Viscosity, dynamic <br />Explosion limits <br />Explosive properties <br />Oxidizing properties</p> <p>: <br />: <br />: <br />: <br />: <br />: <br />: <br />: <br />: <br />: <br />: <br />: <br />: <br />: <br />: <br />: <br />: <br />: <br />: <br />: <br />: <br />: <br />: <br />:</p> <p>Liquid. <br />Clear liquid. <br />Amber Light brown <br />No data available <br />No data available <br />No data available <br />Not applicable <br />No data available <br />No data available <br />> 93.3 °C / 200 °F <br />No data available <br />Non flammable. <br />No data available <br />No data available <br />1.09 – 1.12 <br />No data available <br />No data available <br />No data available <br />No data available <br />No data available <br />725 – 1025 cP (25 °C/ 77 °F) <br />No data available <br />No data available <br />No data available</p> <p>9.2. Other information <br />No additional information available.</p> <p>SECTION 10: Stability and reactivity <br />10.1. Reactivity <br />The product is non-reactive under normal conditions of use, storage and transport.</p> <p>10.2. Chemical stability <br />Stable under normal conditions of use.</p> <p>10.3. Possibility of hazardous reactions <br />No dangerous reactions known under normal conditions of use.</p> <p>SDS InjectProECO-Polygel <br />SDS DATE: 11-JULY-25</p> <p>Page 7 of 16</p> <p>10.4. Conditions to avoid <br />Incompatible materials.</p> <p>10.5. Incompatible materials <br />Oxidizing agents.</p> <p>10.6. Hazardous decomposition products <br />Under normal conditions of storage and use, hazardous decomposition products should not be produced. Thermal decomposition generates: Carbon <br />dioxide. Carbon monoxide. Nitrogen oxides.</p> <p>SECTION 11: Toxicological information <br />11.1. Information on toxicological effects <br />Acute toxicity (oral) <br />Acute toxicity (dermal) <br />Acute toxicity (inhalation)</p> <p>ATE US (dust, mist)</p> <p>: Not classified <br />: Not classified <br />: Inhalation:dust,mist: Harmful if inhaled.</p> <p>1.566 mg/l/4h</p> <p>4,4'-Methylenediphenyl diisocyanate <br />LD50 oral rat</p> <p>9200 mg/kg body weight</p> <p>Toluene-diisocyanate (mixed isomers) <br />LD50 dermal rabbit</p> <p>> 9400 mg/kg body weight</p> <p>4-Isocyanatosulphonyltoluene <br />LD50 oral rat</p> <p>2330 mg/kg body weight</p> <p>LD50 dermal rat</p> <p>> 2000 mg/kg body weight</p> <p>Dimethyl Glutarate <br />LD50 oral rat</p> <p>8900 mg/kg body weight</p> <p>LD50 dermal rat</p> <p>> 2000 mg/kg body weight</p> <p>LC50 Inhalation - Rat</p> <p>Based on a related compound: not expected to be an inhalation hazard</p> <p>Dimethyl Adipate <br />LD50 oral</p> <p>8500 mg/kg body weight (mouse)</p> <p>LD50 dermal rat</p> <p>> 2000 mg/kg body weight</p> <p>LD50 dermal rabbit</p> <p>> 5000 mg/kg body weight</p> <p>LC50 Inhalation - Rat</p> <p>Based on a related compound: not expected to be an inhalation hazard</p> <p>Dimethyl Succinate <br />LD50 oral rat</p> <p>> 5000 mg/kg</p> <p>LD50 dermal rat</p> <p>> 2000 mg/kg body weight</p> <p>LD50 dermal rabbit</p> <p>> 5000 mg/kg</p> <p>SDS InjectProECO-Polygel <br />SDS DATE: 11-JULY-25</p> <p>Page 8 of 16</p> <p>Diphenylmethane Diisocyanate, isomers and homologues <br />LD50 oral rat</p> <p>49 g/kg</p> <p>LD50 dermal rabbit</p> <p>> 9400 mg/kg body weight</p> <p>LC50 Inhalation - Rat</p> <p>490 mg/m³</p> <p>Skin corrosion/irritation</p> <p>: Causes skin irritation.</p> <p>Serious eye damage/irritation</p> <p>: Causes serious eye irritation.</p> <p>Dimethyl Adipate <br />Serious eye damage/irritation, rabbit</p> <p>Moderately irritating</p> <p>Diphenylmethane Diisocyanate, isomers and homologues <br />Serious eye damage/irritation, rabbit</p> <p>Mildly irritating</p> <p>Respiratory or skin sensitization</p> <p>: May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause an allergic <br />skin reaction.</p> <p>Germ cell mutagenicity</p> <p>: Not classified</p> <p>Carcinogenicity</p> <p>: Suspected of causing cancer.</p> <p>4,4'-Methylenediphenyl diisocyanate <br />IARC group</p> <p>3 - Not classifiable</p> <p>Toluene-diisocyanate (mixed isomers) <br />IARC group</p> <p>2B - Possibly carcinogenic to humans</p> <p>National Toxicity Program (NTP) Status</p> <p>Reasonably anticipated to be Human Carcinogen.</p> <p>Diphenylmethane Diisocyanate, isomers and homologues <br />IARC group</p> <p>3 - Not classifiable</p> <p>Reproductive toxicity</p> <p>: Not classified</p> <p>STOT-single exposure</p> <p>: May cause respiratory irritation.</p> <p>4,4'-Methylenediphenyl diisocyanate <br />STOT-single exposure</p> <p>May cause respiratory irritation.</p> <p>Toluene-diisocyanate (mixed isomers) <br />STOT-single exposure</p> <p>May cause respiratory irritation.</p> <p>4-Isocyanatosulphonyltoluene <br />STOT-single exposure</p> <p>May cause respiratory irritation.</p> <p>2,4'-Diphenylmethane Diisocyanate (MDI) <br />STOT-single exposure</p> <p>May cause respiratory irritation.</p> <p>Diphenylmethane Diisocyanate, isomers and homologues <br />STOT-single exposure <br />STOT-repeated exposure</p> <p>May cause respiratory irritation. <br />: May cause damage to organs (respiratory system) through prolonged or repeated exposure <br />(Inhalation).</p> <p>4,4'-Methylenediphenyl diisocyanate <br />STOT-repeated exposure</p> <p>SDS InjectProECO-Polygel <br />SDS DATE: 11-JULY-25</p> <p>May cause damage to organs (respiratory system) through prolonged or repeated exposure <br />(Inhalation).</p> <p>Page 9 of 16</p> <p>2,4'-Diphenylmethane Diisocyanate (MDI) <br />STOT-repeated exposure</p> <p>May cause damage to organs through prolonged or repeated exposure.</p> <p>Diphenylmethane Diisocyanate, isomers and homologues <br />STOT-repeated exposure <br />Aspiration hazard <br />Viscosity, kinematic</p> <p>May cause damage to organs through prolonged or repeated exposure. <br />: Not classified <br />: No data available</p> <p>Toluene-diisocyanate (mixed isomers) <br />Viscosity, kinematic</p> <p>2.221 mm²/s Temp.: '20°C' Parameter: 'kinematic viscosity (in mm²/s)'</p> <p>2,4'-Diphenylmethane Diisocyanate (MDI) <br />Viscosity, kinematic <br />Symptoms/effects after inhalation <br />Symptoms/effects after skin contact <br />Symptoms/effects after eye contact <br />Symptoms/effects after ingestion</p> <p>4.002 mm²/s Temp.: 'other:' Parameter: 'kinematic viscosity (in mm²/s)' <br />: May cause respiratory irritation. May cause allergy or asthma symptoms or breathing difficulties <br />if inhaled. <br />: May cause an allergic skin reaction. Irritation (itching, redness, blistering). <br />: Stinging, redness, itching, tears, blurred vision, swelling. <br />: Not expected to present a significant ingestion hazard under anticipated conditions of normal <br />use. Ingestion may cause nausea and vomiting.</p> <p>SECTION 12: Ecological information <br />12.1. Toxicity <br />Ecology - general</p> <p>: The product is not considered harmful to aquatic organisms or to cause long-term adverse <br />effects in the environment.</p> <p>4,4'-Methylenediphenyl diisocyanate <br />NOEC (chronic)</p> <p>≥ 10 mg/l</p> <p>Toluene-diisocyanate (mixed isomers) <br />LC50 - Fish [1]</p> <p>133 mg/l</p> <p>EC50 - Crustacea [1]</p> <p>12.5 mg/l</p> <p>EC50 - Other aquatic organisms [1]</p> <p>18.3 mg/l</p> <p>EC50 96h - Algae [1]</p> <p>3230 mg/l</p> <p>EC50 96h - Algae [2]</p> <p>4300 mg/l</p> <p>LOEC (chronic)</p> <p>2.2 mg/l</p> <p>NOEC (chronic)</p> <p>1.1 mg/l</p> <p>4-Isocyanatosulphonyltoluene <br />LC50 - Fish [1]</p> <p>> 45 mg/l</p> <p>EC50 - Crustacea [1]</p> <p>> 100 mg/l</p> <p>EC50 72h - Algae [1]</p> <p>30 mg/l</p> <p>EC50 72h - Algae [2]</p> <p>25 mg/l</p> <p>2,4'-Diphenylmethane Diisocyanate (MDI) <br />NOEC (chronic)</p> <p>SDS InjectProECO-Polygel <br />SDS DATE: 11-JULY-25</p> <p>≥ 10 mg/l</p> <p>Page 10 of 16</p> <p>Dimethyl Glutarate <br />LC50 - Fish [1]</p> <p>13400 mg/l</p> <p>EC50 - Crustacea [1]</p> <p>3940 – 4670 mg/l</p> <p>Dimethyl Adipate <br />LC50 - Fish [1]</p> <p>87.095 mg/l</p> <p>EC50 - Crustacea [1]</p> <p>72 mg/l</p> <p>EC50 72h - Algae [1]</p> <p>> 100 mg/l</p> <p>EC50 96h - Algae [1]</p> <p>6.691 mg/l</p> <p>Dimethyl Succinate <br />LC50 - Fish [1]</p> <p>50 mg/l</p> <p>EC50 - Crustacea [1]</p> <p>> 100 mg/l</p> <p>EC50 72h - Algae [1]</p> <p>> 100 mg/l</p> <p>EC50 96h - Algae [1]</p> <p>11.917 mg/l</p> <p>NOEC (chronic)</p> <p>358.6 mg/l</p> <p>12.2. Persistence and degradability</p> <p>Persistence and degradability</p> <p>Not established.</p> <p>12.3. Bioaccumulative potential</p> <p>Bioaccumulative potential</p> <p>Not established.</p> <p>Dimethyl Glutarate <br />Partition coefficient n-octanol/water (Log Pow)</p> <p>0.62</p> <p>Dimethyl Adipate <br />Partition coefficient n-octanol/water (Log Pow)</p> <p>1.03</p> <p>Dimethyl Succinate <br />Partition coefficient n-octanol/water (Log Pow)</p> <p>0.35</p> <p>12.4. Mobility in soil <br />Dimethyl Adipate <br />Mobility in soil</p> <p>10.9</p> <p>12.5. Other adverse effects <br />No additional information available.</p> <p>SDS InjectProECO-Polygel <br />SDS DATE: 11-JULY-25</p> <p>Page 11 of 16</p> <p>SECTION 13: Disposal considerations <br />13.1. Disposal methods <br />Regional waste regulation <br />Waste treatment methods <br />Sewage disposal recommendations <br />Product/Packaging disposal recommendations <br />Additional information <br />Ecological waste information</p> <p>: <br />: <br />: <br />:</p> <p>Disposal must be done according to official regulations. <br />Dispose of contents/container in accordance with licensed collector’s sorting instructions. <br />Disposal must be done according to official regulations. <br />Disposal must be done according to official regulations. Refer to all applicable national, <br />international and local regulations or provisions. <br />: Do not re-use empty containers. <br />: Avoid release to the environment.</p> <p>SECTION 14: Transport information <br />In accordance with DOT / TDG / IMDG / IATA</p> <p>DOT</p> <p>TDG</p> <p>IMDG</p> <p>IATA</p> <p>Not regulated</p> <p>Not regulated</p> <p>Not regulated</p> <p>Not regulated</p> <p>Not regulated</p> <p>Not regulated</p> <p>Not regulated</p> <p>Not regulated</p> <p>Not regulated</p> <p>Not regulated</p> <p>Not regulated</p> <p>Not regulated</p> <p>14.1. UN number <br />Not regulated for transport</p> <p>14.2. Proper Shipping Name <br />Not regulated</p> <p>14.3. Transport hazard class(es) <br />Not regulated</p> <p>14.4. Packing group <br />Not regulated</p> <p>14.5. Environmental hazards <br />Not regulated <br />No supplementary information available</p> <p>14.6. Special precautions for user <br />DOT <br />Not regulated <br />TDG <br />Not regulated <br />IMDG <br />Not regulated <br />IATA <br />Not regulated</p> <p>14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code <br />Not applicable</p> <p>SDS InjectProECO-Polygel <br />SDS DATE: 11-JULY-25</p> <p>Page 12 of 16</p> <p>SECTION 15: Regulatory information <br />15.1. US Federal regulations</p> <p>SARA Section 311/312 Hazard Classes</p> <p>Health hazard - Acute toxicity (any route of exposure) <br />Health hazard - Carcinogenicity <br />Health hazard - Respiratory or skin sensitization <br />Health hazard - Skin corrosion or Irritation <br />Health hazard - Serious eye damage or eye irritation <br />Health hazard - Specific target organ toxicity (single or repeated exposure)</p> <p>All components of this product are present and listed as Active on the United States Environmental Protection Agency Toxic Substances Control Act <br />(TSCA) inventory. <br />Contains chemical(s) subject to TSCA 12b export notification if product is shipped outside the U.S <br />Toluene-diisocyanate (mixed isomers)</p> <p>CAS-No. 26471-62-5</p> <p>0.5 – 2%</p> <p>Chemical(s) subject to the reporting requirements of Section 313 or Title III of the Superfund Amendments and Reauthorization Act (SARA) of 1986 <br />and 40 CFR Part 372. <br />4,4'-Methylenediphenyl diisocyanate</p> <p>CAS-No. 101-68-8</p> <p>1 – 5%</p> <p>Toluene-diisocyanate (mixed isomers)</p> <p>CAS-No. 26471-62-5</p> <p>0.5 – 2%</p> <p>Diphenylmethane Diisocyanate, isomers and <br />homologues</p> <p>CAS-No. 9016-87-9</p> <p>1 – 5%</p> <p>4,4'-Methylenediphenyl diisocyanate (101-68-8) <br />Listed on EPA Hazardous Air Pollutant (HAPS) <br />CERCLA RQ</p> <p>5000 lb</p> <p>Toluene-diisocyanate (mixed isomers) (26471-62-5) <br />CERCLA RQ</p> <p>100 lb</p> <p>15.2. International regulations <br />CANADA</p> <p>4,4'-Methylenediphenyl diisocyanate (101-68-8) <br />Listed on the Canadian DSL (Domestic Substances List)</p> <p>Toluene-diisocyanate (mixed isomers) (26471-62-5) <br />Listed on the Canadian DSL (Domestic Substances List)</p> <p>4-Isocyanatosulphonyltoluene (4083-64-1) <br />Listed on the Canadian DSL (Domestic Substances List)</p> <p>2,4'-Diphenylmethane Diisocyanate (MDI) (5873-54-1) <br />Listed on the Canadian DSL (Domestic Substances List)</p> <p>SDS InjectProECO-Polygel <br />SDS DATE: 11-JULY-25</p> <p>Page 13 of 16</p> <p>Dimethyl Glutarate (1119-40-0) <br />Listed on the Canadian DSL (Domestic Substances List)</p> <p>Dimethyl Adipate (627-93-0) <br />Listed on the Canadian DSL (Domestic Substances List)</p> <p>Dimethyl Succinate (106-65-0) <br />Listed on the Canadian DSL (Domestic Substances List)</p> <p>Diphenylmethane Diisocyanate, isomers and homologues (9016-87-9) <br />Listed on the Canadian DSL (Domestic Substances List) <br />EU-Regulations <br />No additional information available. <br />National regulations</p> <p>4,4'-Methylenediphenyl diisocyanate (101-68-8) <br />Listed on INSQ (Mexican National Inventory of Chemical Substances)</p> <p>Toluene-diisocyanate (mixed isomers) (26471-62-5) <br />Listed on IARC (International Agency for Research on Cancer) <br />Listed as carcinogen on NTP (National Toxicology Program) <br />Listed on INSQ (Mexican National Inventory of Chemical Substances)</p> <p>Dimethyl Glutarate (1119-40-0) <br />Listed on INSQ (Mexican National Inventory of Chemical Substances)</p> <p>Dimethyl Succinate (106-65-0) <br />Listed on INSQ (Mexican National Inventory of Chemical Substances)</p> <p>Diphenylmethane Diisocyanate, isomers and homologues (9016-87-9) <br />Listed on INSQ (Mexican National Inventory of Chemical Substances)</p> <p>15.3. US State regulations <br />WARNING:</p> <p>This product can expose you to Toluene-diisocyanate (mixed isomers), which is known to the State of California to cause <br />cancer. For more information go to www.P65Warnings.ca.gov.</p> <p>SECTION 16: Other information</p> <p>According to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations</p> <p>SDS InjectProECO-Polygel <br />SDS DATE: 11-JULY-25</p> <p>Page 14 of 16</p> <p>Full text of hazard classes and H-statements <br />H315</p> <p>Causes skin irritation</p> <p>H317</p> <p>May cause an allergic skin reaction</p> <p>H319</p> <p>Causes serious eye irritation</p> <p>H320</p> <p>Causes eye irritation</p> <p>H330</p> <p>Fatal if inhaled</p> <p>H332</p> <p>Harmful if inhaled</p> <p>H334</p> <p>May cause allergy or asthma symptoms or breathing difficulties if inhaled.</p> <p>H335</p> <p>May cause respiratory irritation</p> <p>H351</p> <p>Suspected of causing cancer</p> <p>H373</p> <p>May cause damage to organs through prolonged or repeated exposure</p> <p>H412</p> <p>Harmful to aquatic life with long lasting effects</p> <p>Abbreviations and acronyms <br />ADN</p> <p>European Agreement concerning the International Carriage of Dangerous Goods by Inland Waterways</p> <p>ADR</p> <p>European Agreement concerning the International Carriage of Dangerous Goods by Road</p> <p>ATE</p> <p>Acute Toxicity Estimate</p> <p>BCF</p> <p>Bioconcentration factor</p> <p>BLV</p> <p>Biological limit value</p> <p>BOD</p> <p>Biochemical oxygen demand (BOD)</p> <p>COD</p> <p>Chemical oxygen demand (COD)</p> <p>DMEL</p> <p>Derived Minimal Effect level</p> <p>DNEL</p> <p>Derived-No Effect Level</p> <p>EC-No.</p> <p>European Community number</p> <p>EC50</p> <p>Median effective concentration</p> <p>EN</p> <p>European Standard</p> <p>IARC</p> <p>International Agency for Research on Cancer</p> <p>IATA</p> <p>International Air Transport Association</p> <p>IMDG</p> <p>International Maritime Dangerous Goods</p> <p>LC50</p> <p>Median lethal concentration</p> <p>LD50</p> <p>Median lethal dose</p> <p>LOAEL</p> <p>Lowest Observed Adverse Effect Level</p> <p>NOAEC</p> <p>No-Observed Adverse Effect Concentration</p> <p>NOAEL</p> <p>No-Observed Adverse Effect Level</p> <p>NOEC</p> <p>No-Observed Effect Concentration</p> <p>OECD</p> <p>Organisation for Economic Co-operation and Development</p> <p>OEL</p> <p>Occupational Exposure Limit</p> <p>SDS InjectProECO-Polygel <br />SDS DATE: 11-JULY-25</p> <p>Page 15 of 16</p> <p>Abbreviations and acronyms <br />PBT</p> <p>Persistent Bioaccumulative Toxic</p> <p>PNEC</p> <p>Predicted No-Effect Concentration</p> <p>RID</p> <p>Regulations concerning the International Carriage of Dangerous Goods by Rail</p> <p>SDS</p> <p>Safety Data Sheet</p> <p>STP</p> <p>Sewage treatment plant</p> <p>ThOD</p> <p>Theoretical oxygen demand (ThOD)</p> <p>TLM</p> <p>Median Tolerance Limit</p> <p>VOC</p> <p>Volatile Organic Compounds</p> <p>CAS-No.</p> <p>Chemical Abstract Service number</p> <p>N.O.S.</p> <p>Not Otherwise Specified</p> <p>vPvB</p> <p>Very Persistent and Very Bioaccumulative</p> <p>ED</p> <p>Endocrine disruptor</p> <p>NFPA health hazard <br />NFPA fire hazard</p> <p>NFPA reactivity</p> <p>: 2 - Materials that, under emergency conditions, can cause temporary <br />incapacitation or residual injury. <br />: 0 - Materials that will not burn under typical fire conditions, including <br />intrinsically noncombustible materials such as concrete, stone, and <br />sand. <br />: 0 - Material that in themselves are normally stable, even under fire <br />conditions.</p> <p>This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental <br />requirements only. It should not therefore be construed as guaranteeing any specific property of the product.</p> <p>SDS InjectProECO-Polygel <br />SDS DATE: 11-JULY-25</p> <p>Page 16 of 16</p>
