SDS_AQUAFIN-InjectProECO-SEAL_031119.pdf
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<h1>SDS_AQUAFIN-InjectProECO-SEAL_031119.pdf</h1> <p>IDENTITY:</p> <p>SAFETY DATA SHEET</p> <p>InjectProECO-SEAL</p> <p>Date prepared: <br />Date revised:</p> <p>SDS No. E.1.6.1</p> <p>JULY 2017 <br />JANUARY 2019</p> <p>SDS No. E.1.6.1</p> <p>Section 1 – Product Identification <br />IDENTITY:</p> <p>Product Name: <br />Product Use Description:</p> <p>InjectProECO-SEAL</p> <p>Hydrophilic Polyurethane Injection Grout</p> <p>AQUAFIN, INC. <br />505 BLUE BALL RD. #160 <br />ELKTON, MD 21921</p> <p>24 hr Emergency Phone: Chem-Tel (800) 255-3924</p> <p>Recommended use of the chemical and restriction on use:</p> <p>Refer to the product technical data sheet. <br />For industrial and professional users.</p> <p>Information Phone No.</p> <p>Section 2 – Hazards Identification <br />GHS Classification: <br />Resp. Sens. 1 <br />Carc. 2 <br />STOT RE 2 <br />Acute Tox. 4 <br />Skin Irrit. 2 <br />Eye Irrit. 2A <br />Skin Sens. 1 <br />STOT SE 3</p> <p>H334 <br />H351 <br />H373 <br />H332 <br />H315 <br />H319 <br />H317 <br />H335</p> <p>May cause allergy or asthma symptoms or breathing difficulties if inhaled. <br />Suspected of causing cancer. <br />May cause damage to organs through prolonged or repeated exposure. <br />Harmful if inhaled. <br />Causes skin irritation. <br />Causes serious eye irritation. <br />May cause an allergic skin reaction. <br />May cause respiratory irritation.</p> <p>GHS Label element: <br />Hazard Pictograms <br />GHS07 <br />Signal Word:</p> <p>(410) 392-2300</p> <p>www.aquafin.net info@aquafin.net</p> <p>GHS08</p> <p>Danger</p> <p>Hazard Statements: <br />H332: <br />Harmful if inhaled. <br />H315: <br />Causes skin irritation. <br />H319: <br />Causes serious eye irritation. <br />H334: <br />May cause allergy or asthma symptoms or breathing difficulties if inhaled. <br />H317: <br />May cause an allergic skin reaction. <br />H351: <br />Suspected of causing cancer. <br />H335: <br />May cause respiratory irritation. <br />H371: <br />May cause damage to organs through prolonged or repeated exposure. <br />Precautionary Statements: <br />Prevention: <br />P102: <br />Keep out of reach of children. <br />P260: <br />Do not breathe mist, vapors or spray. <br />P264: <br />Wash skin thoroughly after handling. <br />P271: <br />Use only outdoors or in a well-ventilated area. <br />P270: <br />Do not eat, drink or smoke when using this product. <br />P280: <br />Wear protective gloves/protective clothing/eye protection/face protection. <br />P285: <br />In case of inadequate ventilation wear respiratory protection. <br />P201: <br />Obtain special instructions before use. <br />Page 1 of 6</p> <p>IDENTITY:</p> <p>SAFETY DATA SHEET</p> <p>InjectProECO-SEAL</p> <p>P202: <br />P272: <br />Response: <br />P302 + P352: <br />P333 + P313: <br />P362: <br />P304 + P340: <br />P342 + P311: <br />P305 + P351 + P338: <br />P337 + P313 <br />P309 + P310 + P313:</p> <p>SDS No. E.1.6.1</p> <p>Do not handle until all safety precautions have been read and understood. <br />Contaminated work clothing must not be allowed out of the workplace. <br />IF ON SKIN:</p> <p>Wash with plenty of soap and water. <br />IF SKIN irritation or rash occurs, get medical attention. <br />Take off contaminated clothing and wash before reuse. <br />IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable <br />for breathing. <br />If experiencing respiratory symptoms, call a POISON CENTER or <br />physician. <br />IF IN EYES: <br />Rinse cautiously with water for several minutes. Remove contact <br />lenses, if present and easy to do. Continue rinsing. <br />IF eye irritation persists, get medical advice/attention. <br />IF exposed or concerned: Get medical advice/attention. Call a POISON <br />CENTER/doctor if you feel unwell. Get medical advice/attention if you <br />feel unwell.</p> <p>Storage: <br />P403 + P410: <br />P405:</p> <p>Store in a well-ventilated place. Protect from sunlight. <br />Store locked up.</p> <p>Disposal: <br />P501:</p> <p>Dispose of contents/container to an approved waste disposal site.</p> <p>Section 3 – Composition / Information on Hazardous Ingredients <br />Component: <br />CAS No. <br />Prepolymeer, reactieproduct van methyldifenyldiisocyanaat en polyetherpolyol <br />triethyl phosphate <br />78-40-0 <br />4,4'-Methylenediphenyldiisocyanate, oligomers <br />101-68-8 <br />diphenylmethanediisocyanate, isomeres and homologues <br />9016-87-9</p> <p>% (Weight) <br />50-100% <br />10 - 25% <br />10 - 25% <br />2.5 - 10 %</p> <p>Note: There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations <br />applicable, are classified as hazardous to health or the environment and hence require reporting in this section.</p> <p>Section 4 – First Aid Measures <br />General information: Symptoms of poisoning may even occur after several hours; therefore medical <br />observation for at least 48 hours after the accident. <br />Inhalation:</p> <p>Supply fresh air and consult a physician if breathing becomes difficult. In case of <br />unconsciousness place patient stably in side position for transportation.</p> <p>Ingestion:</p> <p>Immediately drink plenty of milk or water and get medical attention.</p> <p>Skin Contact:</p> <p>Immediately wash with water and soap and rinse thoroughly. Do not use solvents or <br />thinners. Remove contaminated clothing and shoes. Seek medical advice if irritation <br />or rash occurs. Wash clothing before reuse.</p> <p>Eye Contact:</p> <p>Immediately flush eyes with plenty of water for at least 15 minutes, lifting upper and <br />lower eyelids occasionally. Remove contact lenses, if present. Seek medical attention <br />if irritation persists.</p> <p>Page 2 of 6</p> <p>IDENTITY:</p> <p>SAFETY DATA SHEET</p> <p>InjectProECO-SEAL</p> <p>SDS No. E.1.6.1</p> <p>Section 5 – Fire Fighting Measures <br />Extinguishing Media:</p> <p>Use water fog, foam, dry chemical or carbon dioxide.</p> <p>Fire Fighting Procedures:</p> <p>Standard. As in any fire, wear self-contained breathing apparatus <br />pressure-demand, MSHA/NIOSH (approved or equivalent) and full <br />protective gear. Containers can build up pressure if exposed to heat <br />(fire). Cool with water spray. Do not scatter material with high pressure <br />water streams.</p> <p>Hazardous Combustion Products:</p> <p>Product does not present an explosion hazard.</p> <p>Unusual Fire and Explosion Hazards: Product does not present an explosion hazard.</p> <p>Section 6 – Accidental Release Measures <br />Person-related Safety Precautions:</p> <p>Provide plenty of fresh air. Avoid eye and skin contact. Avoid inhalation <br />of vapors. Wear personal protective equipment.</p> <p>Methods for cleaning-up:</p> <p>Prevent from entering into soil, ditches, sewers, waterways and/or <br />groundwater. Small spills: Absorb with liquid-binding material (sand, <br />diatomite, acid binders, universal binders, sawdust). Dispose <br />contaminated material as waste according to item 13. Large spills: <br />Create a dike or trench to contain product. Follow same procedure as <br />for a small spill.</p> <p>Waste Disposal Method:</p> <p>Dispose in accordance with local, state and federal regulations.</p> <p>Ecological Information:</p> <p>Do not allow product to reach ground water, bodies of water, or storm <br />water or sewage systems.</p> <p>Section 7 – Handling and Storage <br />Handling:</p> <p>Avoid contact with eyes, skin and clothing. Wash skin thoroughly after <br />handling. Ensure good ventilation/exhaustion at the workplace. Prevent <br />formation of aerosols. Keep container closed when not in use.</p> <p>Storage:</p> <p>Keep container tightly closed when not in use. Do not store in direct sunlight.</p> <p>Storage Temperature:</p> <p>4 C – 32 C (~40 F - ~90 F).</p> <p>o</p> <p>o</p> <p>o</p> <p>o</p> <p>Section 8 – Exposure Controls / Personal Protection <br />Engineering Controls:</p> <p>Use adequate ventilation.</p> <p>Respiratory Protection:</p> <p>Use local exhaust ventilation. In case of brief exposure or low pollution use <br />respiratory filter device. In case of intensive or longer exposure use respiratory <br />protective device that is independent of circulating air.</p> <p>Skin Protection:</p> <p>Wear chemical resistant protective clothing and footwear impervious to the <br />product if there is a potential for skin contact.</p> <p>Page 3 of 6</p> <p>IDENTITY:</p> <p>SAFETY DATA SHEET</p> <p>InjectProECO-SEAL</p> <p>SDS No. E.1.6.1</p> <p>Hand Protection:</p> <p>Glove(s): neoprene. The glove material has to be impermeable and resistant to <br />the product/ the substance/ the preparation.</p> <p>Eye Protection:</p> <p>Use tightly sealed safety goggles.</p> <p>Other Protective Equipment: A safety shower and eye wash fountain should be readily available. <br />Work/Hygienic Practices:</p> <p>Keep away from foodstuffs, beverages and feed. Immediately remove all <br />soiled and contaminated clothing. Wash hands before breaks and at the end <br />of work. Avoid contact with the eyes and skin.</p> <p>Section 9 – Physical and Chemical Properties <br />Physical state: <br />Color: <br />Odor: <br />Solubility in water: <br />Flash point: <br />Flammability: <br />o <br />Viscosity at 25 C: <br />Ignition temperature: <br />Danger of explosion: <br />Solvent content (reactive diluent):</p> <p>Liquid <br />Light Yellow <br />Sweetish <br />Insoluble, reacts with water <br />401°F (205°C) <br />N/A <br />Not Determined. <br />855°F (457°C) <br />Product does not present an explosion hazard. <br />Organic solvents: 20.5 % <br />VOC content: 20.5 % <br />204.8 g/l / 1.71 lb/gl</p> <p>Section 10 – Stability and Reactivity <br />Reactivity:</p> <p>No dangerous reaction known under conditions of normal use.</p> <p>Chemical Stability:</p> <p>Stable under normal temperatures and pressures. Keep away from heat <br />sources.</p> <p>Hazardous decomposition:</p> <p>No decomposition if used according to specifications.</p> <p>Conditions To Avoid:</p> <p>No further relevant information available.</p> <p>Incompatibilities:</p> <p>This product will react with any materials containing active hydrogens <br />such as water, alcohol, amines, bases and acids. The reaction with <br />o <br />o <br />water is very slow under 50 C (122 F), but is accelerated at higher <br />temperatures.</p> <p>Section 11 – Toxicological Information <br />Acute toxicity: <br />LD/LC50 values that are relevant for classification: <br />78-40-0 triethyl phosphate <br />Oral <br />LD50 <br />1311 mg/kg (rat) <br />Dermal <br />LD50 <br />>2000 mg/kg (rat) <br />Inhalative LC50/4 h >8.817 mg/l (rat)</p> <p>Page 4 of 6</p> <p>IDENTITY:</p> <p>SAFETY DATA SHEET</p> <p>InjectProECO-SEAL</p> <p>SDS No. E.1.6.1</p> <p>4,4'-Methylenediphenyldiisocyanate <br />Oral <br />LD50 <br />>5000 mg/kg (rat) <br />Dermal <br />LD50 <br />>9400 mg/kg (rabbit) <br />9016-87-9 diphenylmethanediisocyanate <br />Oral <br />LD50 <br />>10000 mg/kg (rat) <br />Dermal <br />LD50 <br />>9400 mg/kg (rabbit) <br />Carcinogenity: <br />IARC: 9016-87-9 diphenylmethanediisocyanate, (3) <br />NTP: Not regulated as a carcinogen. <br />OSHA: Not regulated as a carcinogen.</p> <p>Section 12 – Ecological Information <br />Ecotoxicological Information:</p> <p>Aquatic toxicity: <br />78-40-0 triethyl phosphate <br />EC50/48 h 350 mg/l (daphnia) <br />EC50/72 h 900 mg/l (algae) <br />4,4'-Methylenediphenyldiisocyanate <br />LC50/96 h >1000 mg/l (fish) <br />EC50/24 h >1000 mg/l (daphnia) <br />EC50/72 h >1640 mg/l (algae) <br />9016-87-9 diphenylmethanediisocyanate <br />EC50/24 h >1000 mg/l (daphnia) <br />EC50/96 h >1000 mg/l (fish) <br />EC50/72 h >1640 mg/l (algae) <br />General notes:</p> <p>Water hazard class 1 (Self-assessment): slightly hazardous for water. Do not allow undiluted <br />product or large quantities of it to reach ground water, water course or sewage system.</p> <p>Section 13 – Disposal Considerations <br />Product waste:</p> <p>Must be disposed of in a manner consistent with federal, state and local regulations.</p> <p>Packaging waste:</p> <p>Decontaminate and pass to an approved drum recycler or destroy and dispose of in a <br />manner consistent with federal, state and local regulations.</p> <p>RCRA/EPA Waste Information: If discarded in its purchased form, this material is not a RCRA hazardous <br />waste.</p> <p>Section 14 – Transport Information <br />USDOT (Domestic Surface): <br />IMO (Ocean): <br />IATA/ICAO (Air):</p> <p>Not regulated <br />Not regulated <br />Not regulated</p> <p>Section 15 – Regulatory Information <br />Safety, health and environmental regulations/legislation specific for the substance or mixture <br />Page 5 of 6</p> <p>IDENTITY:</p> <p>SAFETY DATA SHEET</p> <p>InjectProECO-SEAL</p> <p>SDS No. E.1.6.1</p> <p>Sara <br />Section 355 (extremely hazardous substances): None of the ingredients is listed. <br />Section 313 (Specific toxic chemical listings): <br />9016-87-9 <br />diphenylmethanediisocyanate, isomeres and homologues <br />TSCA (Toxic Substances Control Act): <br />78-40-0 <br />triethyl phosphate <br />4,4'-Methylenediphenyldiisocyanate, oligomers <br />9016-87-9 <br />diphenylmethanediisocyanate, isomeres and homologues <br />Proposition 65: <br />Chemicals known to cause cancer: None of the ingredients is listed. <br />Chemicals known to cause reproductive toxicity for females, males and developmental toxicity: <br />None of the ingredients is listed. <br />Carcinogenic categories: <br />EPA (Environmental Protection Agency): 9016-87-9 diphenylmethanediisocyanate <br />TLV (Threshold Limit Value established by ACGIH): None of the ingredients is listed. <br />NIOSH-Ca (National Institute for Occupational Safety and Health): None of the ingredients is listed. <br />National Response Center: <br />Any spill or release to the environment above RQ must be reported to the <br />National Response Center (800-424-8802).</p> <p>Section 16 – Other Information <br />Abbreviations and acronyms: <br />USDOT: <br />IMDG: <br />IATA:</p> <p>United States Department of Transportation. <br />International Maritime Code for Dangerous Goods. <br />International Air Transport Association.</p> <p>CAS: <br />LC50: <br />LD50: <br />RQ:</p> <p>Chemical Abstracts Service (Division of the American Chemical Society). <br />Lethal concentration, 50 percent. <br />Lethal dose, 50 percent. <br />Reportable quantity.</p> <p>SDS prepared by:</p> <p>Aquafin product safety department.</p> <p>DISCLAIMER: <br />We believe the statements, technical information and recommendations contained herein are reliable, but they are <br />given without warranty or guarantee of any kind, expressed or implied, and we assume no responsibility for any <br />loss, damage, or expense, direct or consequential, arising out of their use. Aquafin shall not be responsible for the <br />use of this product in a manner to infringe on any patent or any other intellectual property rights held by others. <br />User is responsible for determining appropriate safety measures and for applying the legislation covering his own <br />activities. We recommend that user makes tests to determine the suitability of a product for its particular purpose <br />prior to use. <br />END OF SDS</p> <p>Page 6 of 6</p> <p>(January 30, 2019)</p>
