SDS_AQUAFIN-InjectProECO-SOIL 031119.pdf
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<h1>SDS_AQUAFIN-InjectProECO-SOIL 031119.pdf</h1> <p>IDENTITY:</p> <p>SAFETY DATA SHEET</p> <p>InjectProECO-SOIL</p> <p>Date prepared: <br />Date revised:</p> <p>SDS No. E.1.7.1</p> <p>JANUARY 2017 <br />JANUARY 2019</p> <p>SDS No. E.1.7.1.</p> <p>Section 1 – Product Identification <br />IDENTITY:</p> <p>Product Name: <br />Product Use Description:</p> <p>InjectProECO-SOIL</p> <p>Hydrophobic Polyurethane Injection Grout Ground Stabilizer</p> <p>AQUAFIN, INC. <br />505 BLUE BALL RD. #160 <br />ELKTON, MD 21921</p> <p>24 hr Emergency Phone: Chem-Tel (800) 255-3924</p> <p>Recommended use of the chemical and restriction on use:</p> <p>Refer to the product technical data sheet. <br />For industrial and professional users.</p> <p>Information Phone No.</p> <p>Section 2 – Hazards Identification <br />GHS Classification: <br />Resp. Sens. 1 <br />Carc. 2 <br />STOT RE 2 <br />Acute Tox. 4 <br />Skin Irrit. 2 <br />Eye Irrit. 2A <br />Skin Sens. 1 <br />STOT SE 3</p> <p>H334 <br />H351 <br />H373 <br />H332 <br />H315 <br />H319 <br />H317 <br />H335</p> <p>(410) 392-2300</p> <p>www.aquafin.net info@aquafin.net</p> <p>May cause allergy or asthma symptoms or breathing difficulties if inhaled. <br />Suspected of causing cancer. <br />May cause damage to organs through prolonged or repeated exposure. <br />Harmful if inhaled. <br />Causes skin irritation. <br />Causes serious eye irritation. <br />May cause an allergic skin reaction. <br />May cause respiratory irritation.</p> <p>GHS Label element: <br />Hazard Pictograms <br />GHS07</p> <p>GHS08</p> <p>Signal Word:</p> <p>Danger</p> <p>Hazard Statements: <br />H315: <br />H317: <br />H319: <br />H332: <br />H334: <br />H335: <br />H351 <br />H373:</p> <p>Causes skin irritation. <br />May cause an allergic skin reaction. <br />Causes serious eye irritation. <br />Harmful if inhaled. <br />May cause allergy or asthma symptoms or breathing difficulties if inhaled. <br />May cause respiratory irritation. <br />Suspected of causing cancer. <br />May cause damage to organs through prolonged or repeated exposure.</p> <p>Precautionary Statements: <br />Prevention: <br />P102: <br />Keep out of reach of children. <br />P260: <br />Do not breath mist, vapors or spray. <br />P264: <br />Wash skin thoroughly after handling. <br />P271: <br />Use only outdoors or in a well-ventilated area. <br />P270: <br />Do not eat, drink or smoke when using this product. <br />P280: <br />Wear protective gloves/protective clothing/eye protection/face protection. <br />P285: <br />In case of inadequate ventilation wear respiratory protection.</p> <p>Page 1 of 6</p> <p>IDENTITY:</p> <p>SAFETY DATA SHEET</p> <p>InjectProECO-SOIL</p> <p>Response: <br />P302 + P352: <br />P333 + P313: <br />P362: <br />P304 + P340:</p> <p>IF ON SKIN: <br />IF INHALED:</p> <p>P342 + P311: <br />P305 + P351 + P338: <br />P337 + P313 <br />Storage: <br />P403 + P410: <br />P405: <br />Disposal: <br />P501:</p> <p>IF IN EYES:</p> <p>SDS No. E.1.7.1</p> <p>Wash with plenty of soap and water. <br />IF SKIN irritation or rash occurs: Get medical attention. <br />Take off contaminated clothing and wash before reuse. <br />Remove victim to fresh air and keep at rest in a position comfortable <br />for breathing. <br />If experiencing respiratory symptoms: call a POISON CENTER or <br />physician. <br />Rinse cautiously with water for several minutes. Remove contact <br />lenses, if present and easy to do. Continue rinsing. <br />IF eye irritation persists, get medical advice/attention.</p> <p>Store in a well-ventilated place. Keep container tightly closed. <br />Store locked up. <br />Dispose of contents/container in accordance with local/regional/national/international <br />regulations.</p> <p>Section 3 – Composition / Information on Hazardous Ingredients <br />Component: <br />4,4'-methylenediphenyl diisocyanate <br />Diphenylmethanediisocyanate, isomeres and <br />homologues <br />Reaction mass of 4,4'-methylenediphenyldiisocyanate <br />and o-(p-isocyanatobenzyl) phenylisocyanaat</p> <p>CAS No. <br />101-68-8 <br />9016-87-9</p> <p>% (Weight) <br />10 - 25 <br />25 - 50 <br />2.5 - 10</p> <p>Note: There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations <br />applicable, are classified as hazardous to health or the environment and hence require reporting in this section.</p> <p>Section 4 – First Aid Measures <br />General information: Symptoms of poisoning may even occur after several hours; therefore medical <br />observation for at least 48 hours after the accident. <br />Inhalation:</p> <p>Supply fresh air and to be sure call for a doctor. In case of unconsciousness, place <br />patient stably in side position for transportation.</p> <p>Ingestion:</p> <p>If person is conscious, wash out mouth with water. Do not induce vomiting unless <br />instructed to do so by a poison center or physician.</p> <p>Skin Contact:</p> <p>Immediately wash with water and soap and rinse thoroughly. Do not use solvents or <br />thinners. Remove contaminated clothing and shoes. Seek medical advice if irritation or <br />rash occurs. Wash clothing before reuse.</p> <p>Eye Contact:</p> <p>Rinse opened eye for several minutes under running water. If symptoms persist, consult <br />a doctor. Remove contact lenses, if present. Seek medical attention if irritation persists.</p> <p>Section 5 – Fire Fighting Measures <br />Extinguishing Media:</p> <p>CO2, extinguishing powder or water spray. Fight larger fires with water <br />spray or alcohol resistant foam. <br />Page 2 of 6</p> <p>IDENTITY:</p> <p>SAFETY DATA SHEET</p> <p>InjectProECO-SOIL</p> <p>SDS No. E.1.7.1</p> <p>Fire Fighting Procedures:</p> <p>Standard. As in any fire, wear self-contained breathing apparatus <br />pressure-demand, MSHA/NIOSH (approved or equivalent) and full <br />protective gear. Containers can build up pressure if exposed to heat <br />(fire). Cool with water spray. Do not scatter material with high pressure <br />water streams.</p> <p>Hazardous Combustion Products:</p> <p>Carbon oxides, nitrogen oxides, isocyanates and trace amounts of <br />hydrogen cyanide.</p> <p>Unusual Fire and Explosion Hazards: Water contamination produces carbon dioxide gas. This may cause <br />pressurization or explosion of containers.</p> <p>Section 6 – Accidental Release Measures <br />Person-related Safety Precautions:</p> <p>Provide plenty of fresh air. Avoid eye and skin contact. Avoid inhalation <br />of vapors. Wear personal protective equipment. Remove or eliminate all <br />ignition sources.</p> <p>Methods for cleaning-up:</p> <p>Prevent from entering into soil, ditches, sewers, waterways and/or <br />groundwater. Absorb with liquid-binding material (sand, diatomite, acid <br />binders, universal binders, sawdust). Dispose contaminated material <br />as waste according to item 13. Ensure adequate ventilation.</p> <p>Waste Disposal Method:</p> <p>Dispose in accordance with local, state and federal regulations.</p> <p>Ecological Information:</p> <p>Do not allow product to reach ground water, bodies of water, or storm <br />water or sewage systems.</p> <p>Section 7 – Handling and Storage <br />Handling:</p> <p>Avoid contact with eyes, skin and clothing. Wash thoroughly after handling. <br />Follow all SDS/label precautions even after the container is emptied because it <br />may retain product residues. Use only with adequate ventilation. Keep container <br />closed when not in use. Do not reseal if contaminated. Keep away from heat and <br />flame.</p> <p>Storage:</p> <p>Keep container tightly closed when not in use. Do not store in direct sunlight. <br />Avoid UV light.</p> <p>Storage Temperature:</p> <p>~40 F - ~90 F. (4 C – 32 C)</p> <p>o</p> <p>o</p> <p>o</p> <p>o</p> <p>Section 8 – Exposure Controls / Personal Protection <br />Exposure Limits: <br />COMPONENT <br />4,4'-methylenediphenyl diisocyanate</p> <p>CAS NUMBER <br />101-68-8</p> <p>OSHA/PEL <br />0.02 ppm (Ceiling)</p> <p>ACGIH/TLV <br />0.005 ppm</p> <p>Engineering Controls:</p> <p>Use adequate ventilation.</p> <p>Respiratory Protection:</p> <p>Use local exhaust ventilation. For airborne exposure above exposure limit(s), <br />wear a NIOSH approved air-purifying respirator equipped with organic vapor <br />cartridges. For situations where the atmospheric levels may exceed the level for <br />which an air-purifying respirator is effective, use a positive-pressure air-supplying <br />respirator. <br />Page 3 of 6</p> <p>IDENTITY:</p> <p>SAFETY DATA SHEET</p> <p>InjectProECO-SOIL</p> <p>SDS No. E.1.7.1</p> <p>Skin Protection:</p> <p>Wear chemical resistant protective clothing and footwear impervious to the <br />product if there is a potential for skin contact.</p> <p>Hand Protection:</p> <p>Glove(s): neoprene. The glove material has to be impermeable and resistant to <br />the product/ the substance/ the preparation.</p> <p>Eye Protection:</p> <p>Use tightly sealed safety goggles or face shield.</p> <p>Other Protective Equipment: A safety shower and eye wash fountain should be readily available. <br />Work/Hygienic Practices:</p> <p>Wash hands before breaks and after work, and before eating, drinking or <br />smoking.</p> <p>Section 9 – Physical and Chemical Properties <br />Physical state: <br />Color: <br />Odor: <br />Solubility in water: <br />Boiling point: <br />Flash point: <br />Vapor Pressure: <br />Flammability: <br />o <br />Specific Gravity (water = 1) at 25 C: <br />Viscosity, (kinematic, dynamic: <br />Auto ignition Temperature: <br />Ignition Temperature: <br />Lower explosion Limit: <br />Upper explosion Limit: <br />Organic solvent content: <br />VOC content:</p> <p>Liquid <br />Light Brown <br />Characteristic <br />Not difficult to mix. Reacts with water. <br />No data. <br />Not Applicable. <br />No data. <br />Not Applicable. <br />3 <br />1.09 -1.11 g/cm <br />Not determined. <br />Product is not self-igniting. <br />o <br />o <br />752 F (400 C) <br />0.3 Vol % <br />12.5 Vol % <br />0.0% <br />0.0 g/l (0.00 lb./gal)</p> <p>Section 10 – Stability and Reactivity <br />Reactivity:</p> <p>No dangerous reaction known under conditions of normal use.</p> <p>Hazardous Decomposition Products: No dangerous decomposition products known. <br />Chemical Stability:</p> <p>Stable under normal temperatures and pressures. Keep away from heat <br />sources. Contains the following stabilizer(s): MEHQ.</p> <p>Conditions To Avoid:</p> <p>Heat and light.</p> <p>Incompatibilities:</p> <p>This product will react with any materials containing active hydrogens <br />such as water, alcohol, amines, bases and acids. The reaction with <br />o <br />o <br />water is very slow under 50 C (122 F), but is accelerated at higher <br />temperatures.</p> <p>Section 11 – Toxicological Information <br />Acute toxicity: <br />4,4'-methylenediphenyl diisocyanate</p> <p>Dermal: <br />Oral: <br />Page 4 of 6</p> <p>LD50 <br />LD50</p> <p>>9400 mg/kg (rabbit). <br />2200 mg/kg (mouse)</p> <p>IDENTITY:</p> <p>SAFETY DATA SHEET</p> <p>InjectProECO-SOIL</p> <p>diphenylmethanediisocyanate, isomeres <br />and homologues</p> <p>SDS No. E.1.7.1</p> <p>Dermal: <br />Oral:</p> <p>LD50</p> <p>>10000 mg/kg (rat).</p> <p>LD50 <br />LD50</p> <p>>9400 mg/kg (rabbit). <br />>10000 mg/kg (rat).</p> <p>Carcinogenity: <br />IARC: 9016-87-9 <br />101-68-8 <br />NTP:</p> <p>diphenylmethanediisocyanate, isomeres and homologues <br />4,4'-methylenediphenyl diisocyanate</p> <p>None of the ingredients is listed.</p> <p>OSHA: None of the ingredients is listed.</p> <p>Section 12 – Ecological Information <br />Aquatic toxicity: <br />9016-87-9 diphenylmethanediisocyanate, isomeres and homologues <br />EC50/24 h >1000 mg/l (daphnia) <br />EC50/96 h >1000 mg/l (fish) <br />EC50/72 h >1640 mg/l (algae) <br />101-68-8 4,4'-methylenediphenyl diisocyanate <br />LC50/96 h >1000 mg/l (fish) <br />EC50/24 h >1000 mg/l (daphnia) <br />Reaction mass of 4,4'-methylenediphenyldiisocyanate and o-(p-isocyanatobenzyl)phenylisocyanaat <br />LC50/96 h >1000 mg/l (fish) <br />EC50/24 h >1000 mg/l (daphnia) <br />Persistence and degradability:</p> <p>No further relevant information available.</p> <p>Behavior in environmental systems: <br />Bioaccumulative potential <br />No further relevant information available. <br />Mobility in soil <br />No further relevant information available. <br />Additional ecological information: <br />General notes</p> <p>Water hazard class 1 (Self-assessment): slightly hazardous for water. <br />Do not allow undiluted product or large quantities of it to reach ground <br />water, water course or sewage system.</p> <p>Section 13 – Disposal Considerations <br />Product waste: <br />Packaging waste:</p> <p>Must not be disposed of together with household garbage. Do not allow product to <br />reach sewage system. <br />Disposal must be made according to official regulations.</p> <p>Section 14 – Transport Information <br />USDOT (Domestic Surface): <br />IMO (Ocean): <br />IATA/ICAO (Air):</p> <p>Not regulated when shipped below regulated quantity (RQ). <br />Not regulated <br />Not regulated</p> <p>Page 5 of 6</p> <p>IDENTITY:</p> <p>SAFETY DATA SHEET</p> <p>InjectProECO-SOIL</p> <p>SDS No. E.1.7.1</p> <p>Section 15 – Regulatory Information <br />TSCA (Toxic Substances Control Act): <br />All components are on TSCA inventory. <br />RCRA Status: <br />If discarded in its purchased form, this material is not a RCRA hazardous waste. <br />US Federal Regulatory Information: <br />SARA Title III (Superfund Amendments and Reauthorization Act:</p> <p>311/312 Hazard Categories:</p> <p>Acute, Chronic, Reactive.</p> <p>313 Reportable Components: <br />Diphenylmethane 4,4’-diisocyanate (Category Diisocyanate Compounds) <br />Polymeric diphenylmethane diisocyanate (Category Diisocyanate Compounds) <br />di-''isononyl'' phthalate</p> <p>CAS NUMBER <br />101-68-8 <br />9016-87-9 <br />28553-12-0</p> <p>335 Extremely Hazardous Substances: None of the ingredients is listed. <br />Proposition 65: <br />Chemicals known to cause cancer: 28553-12-0 <br />di-“isononyl” phthalate <br />Chemicals known to cause reproductive toxicity for males and/or females: None of the ingredients is listed <br />Chemicals known to cause developmental toxicity: None of the ingredients is listed <br />Chemical safety assessment: A Chemical Safety Assessment has not been carried out. <br />National Response Center:</p> <p>Any spill or release to the environment must be reported to the National <br />Response Center (800-424-8802).</p> <p>Section 16 – Other Information <br />Abbreviations and acronyms: <br />USDOT: <br />IMDG: <br />IATA: <br />CAS: <br />LC50: <br />LD50: <br />Carc. 2: <br />STOT SE 3: <br />STOT RE 2:</p> <p>United States Department of Transportation. <br />International Maritime Code for Dangerous Goods. <br />International Air Transport Association. <br />Chemical Abstracts Service (Division of the American Chemical Society). <br />Lethal concentration, 50 percent. <br />Lethal dose, 50 percent. <br />Carcinogenicity – Category 2 <br />Specific target organ toxicity (single exposure) – Category 3 <br />Specific target organ toxicity (repeated exposure) – Category 2</p> <p>SDS prepared by:</p> <p>Aquafin product safety department.</p> <p>DISCLAIMER: <br />We believe the statements, technical information and recommendations contained herein are reliable, but they are <br />given without warranty or guarantee of any kind, expressed or implied, and we assume no responsibility for any <br />loss, damage, or expense, direct or consequential, arising out of their use. Aquafin shall not be responsible for the <br />use of this product in a manner to infringe on any patent or any other intellectual property rights held by others. <br />User is responsible for determining appropriate safety measures and for applying the legislation covering his own <br />activities. We recommend that user makes tests to determine the suitability of a product for its particular purpose <br />prior to use. <br />END OF SDS</p> <p>Page 6 of 6</p> <p>(January 28, 2019)</p>
