SDS_Pavemend Set Retandant 040319.pdf
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<h1>SDS_Pavemend Set Retandant 040319.pdf</h1> <p>IDENTITY:</p> <p>SAFETY DATA SHEET</p> <p>Pavemend SET RETARDANT</p> <p>Date prepared: <br />Date revised:</p> <p>SDS No. P.V. 1.1.1</p> <p>AUGUST 2016 <br />FEBRUARY 2019</p> <p>SDS No. P.V. 1.1.1</p> <p>Section 1 – Product Identification <br />IDENTITY:</p> <p>Pavemend SET RETARDANT</p> <p>Product Name:</p> <p>AQUAFIN, INC. <br />505 BLUE BALL RD. #160 <br />ELKTON, MD 21921</p> <p>Emergency Phone No. <br />Information Phone No.</p> <p>info@aquafin.net</p> <p>Recommended use of the chemical and restriction on use:</p> <p>(800) 394-1410 <br />(410) 392-2300</p> <p>www.aquafin.net</p> <p>Refer to the product technical data sheet. <br />For industrial and professional users.</p> <p>Section 2 – Hazards Identification <br />GHS Classification: <br />Reproductive toxicity (Category 2) <br />(Category 2) <br />Acute Oral (Category 5)</p> <p>H361 <br />H319 <br />H303</p> <p>Suspected of damaging fertility or the unborn child Eye irritant <br />Causes serious eye irritation. <br />May be harmful if swallowed.</p> <p>GHS Label element: <br />Hazard Pictograms <br />GHS07 <br />Signal Word:</p> <p>GHS08</p> <p>WARNING</p> <p>Hazard Statements: <br />H361 <br />Suspected of damaging fertility or the unborn child <br />H319 <br />Causes serious eye irritation. <br />H303 <br />May be harmful if swallowed. <br />Precautionary Statements: <br />Prevention: <br />P201 <br />Obtain special instructions before use. <br />P202 <br />Do not handle until all safety precautions have been read and understood. <br />P264 <br />Wash thoroughly after handling. <br />P280 <br />Wear protective gloves/protective clothing/eye protection/face protection. <br />P281 <br />Use personal protective equipment as required. <br />Response: <br />P305+313+338 <br />P308+313</p> <p>If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present <br />and easy to do. Continue rinsing. <br />If exposed or concerned: Get medical advice/ attention.</p> <p>Storage: <br />P405</p> <p>Store locked up.</p> <p>Disposal: <br />P501:</p> <p>Dispose of contents/container to an approved waste disposal site.</p> <p>Page 1 of 7</p> <p>IDENTITY:</p> <p>SAFETY DATA SHEET</p> <p>Pavemend SET RETARDANT</p> <p>SDS No. P.V. 1.1.1</p> <p>Additional information: <br />For Full text of R-S phrases as well as Hazard Class/Statements and Precautionary Statements see Section <br />16. <br />Other Hazards Emergency overview: <br />White odorless, powdered substance that is not flammable, combustible, or explosive, and has low acute oral <br />and dermal toxicity. <br />Potential health effects: <br />Inhalation is the most significant route of exposure in occupational and other settings. Dermal exposure is not <br />usually a concern because it is poorly absorbed through intact skin. Inhalation Occasional mild irritation effects <br />to nose and throat may occur from inhalation at levels higher than 10 mg/m3. <br />Eye contact: <br />A serious eye irritant. <br />Skin contact: <br />Does not cause irritation to intact skin. <br />Ingestion: <br />Not intended for ingestion. Has low acute toxicity. Small amounts (e.g. a teaspoonful) swallowed accidentally <br />are not likely to cause effects; swallowing amounts larger than that may cause gastrointestinal symptoms. <br />Reproductive/Developmental: <br />Animal ingestion studies in several species, at high doses, cause reproductive and developmental effects. A <br />human study of occupational exposure had no adverse effect on reproduction. A recent epidemiological study <br />and a peer reviewing report of the past epidemiological studies conducted in China didn’t show any negative <br />effect of boron on human fertility (10, 11). <br />Potential ecological effects: <br />Large amounts can be harmful to plants and other species. Therefore releases to the environment should be <br />minimized. <br />Signs and symptoms of exposure: <br />Symptoms of accidental over-exposure have been associated with ingestion or absorption through large areas <br />of damaged skin. These may include nausea, vomiting, and diarrhea, with delayed effects of skin redness and <br />peeling (see Section 11).</p> <p>Section 3 – Composition / Information on Ingredients <br />3.1. Substances: <br />The product contains greater than 99.9 percent (%) Retarder Na2B4O7. 10H20</p> <p>Chemical Name <br />Retarder</p> <p>Purity <br />99.9%</p> <p>CAS <br />ECN <br />1303-96-4 215-540-4</p> <p>REACH Registration No. <br />01-2119490790-32-0002</p> <p>Hazard Statements <br />H361 / H319 / H303</p> <p>There are no additional ingredients present which, within the current knowledge of the supplier and in the <br />concentrations applicable, are classified as hazardous to health or the environment and hence not require reporting <br />in this section.</p> <p>Section 4 – First Aid Measures <br />After Inhalation:</p> <p>If symptoms such as nose or throat irritation are observed, remove person to fresh air. If</p> <p>not breathing, give artificial respiration. Seek medical attention. <br />Page 2 of 7</p> <p>IDENTITY:</p> <p>SAFETY DATA SHEET</p> <p>Pavemend SET RETARDANT</p> <p>SDS No. P.V. 1.1.1</p> <p>After Ingestion:</p> <p>Immediately seek medical attention. Do not induce vomiting without medical advice. If <br />conscious, drink plenty of water.</p> <p>After Skin Contact:</p> <p>Instantly wash skin with plenty of soap and water for at least 15 minutes. Wash clothing <br />before reuse. Seek medical attention if symptoms persist.</p> <p>After Eye Contact:</p> <p>Rinse opened eye with plenty of running water for at least 15 minutes, lifting upper and <br />lower eyelids occasionally. Consult physician.</p> <p>Section 5 – Fire Fighting Measures <br />Extinguishing Media:</p> <p>Use dry chemical fire extinguisher. Do not use water or halogenated <br />compounds.</p> <p>Special Fire Fighting Procedures:</p> <p>As in any fire, wear full protective gear and NIOSH-approved selfcontained breathing apparatus with full face-piece operated in the <br />pressure demand or other positive pressure mode.</p> <p>Unusual Fire and Explosion Hazards: No unusual fire or explosion hazards. Material is itself a flame retardant.</p> <p>Section 6 – Accidental Release Measures <br />Person-related Safety Precautions: Avoid dust formation. In case of exposure to prolonged or high level of <br />airborne dust, wear a personal respirator in compliance with national legislation. <br />Environmental precautions: Borax decahydrate is a water-soluble white powder that may, at high <br />concentrations cause damage to trees or vegetation by root absorption (see section 12). <br />Methods and materials for containment and cleaning up Land spill: Vacuum, shovel or sweep up borax <br />and place in containers for disposal in accordance with applicable local regulations. Avoid contamination of <br />water bodies during clean up and disposal. No personal protective equipment is needed to clean up land spills. <br />Spillage into water: Where possible, remove any intact containers from the water. Advise local water <br />authority that none of the affected water should be used for irrigation or for the abstraction of potable water until <br />natural dilution returns the boron value to its normal environmental background level (see sections 12, 13 and <br />15). <br />Reference to other sections: See sections 8 and 13 for further information.</p> <p>Section 7 – Handling and Storage <br />Handling:</p> <p>Avoid causing dust. Avoid eye and skin contact. Keep out of reach of children.</p> <p>Storage:</p> <p>Store in a cool, dry enclosed area off the ground in tightly closed containers. Protect against <br />wetness and water. No special measures required against explosion and fires. Store away from <br />foodstuffs.</p> <p>Section 8 – Exposure Controls / Personal Protection <br />Control parameters: <br />Occupational exposure limits for dust (total and resizable) are treated by OSHA, Cal OSHA and ACGIH as <br />“Particulate Not Otherwise Classified” or “Nuisance Dust” <br />Respect regulatory provisions for dust (total and respirable). <br />3 <br />ACGIH/TLV 10 mg/m <br />Page 3 of 7</p> <p>IDENTITY:</p> <p>SAFETY DATA SHEET</p> <p>Pavemend SET RETARDANT</p> <p>SDS No. P.V. 1.1.1</p> <p>3</p> <p>Cal OSHA/PEL 10 mg/ m <br />3 <br />OSHA/PEL (total dust) 15 m <br />3 <br />OSHA/PEL (respirable dust) 5 m <br />DNEL values <br />Exposure pattern <br />DNELs for workers: <br />Acute <br />Long-term <br />Long-term</p> <p>Type/site of effect</p> <p>Exposure route</p> <p>DNEL value</p> <p>Local <br />Systemic <br />Systemic</p> <p>Inhalation <br />Inhalation <br />Dermal</p> <p>22.3 mg/ m <br />3 <br />12.8 mg/ m <br />42478 mg/day</p> <p>Oral <br />3 <br />Inhalation 22.3 mg/ m <br />Dermal (external) <br />Dermal (systemic) <br />Inhalation <br />Oral <br />Inhalation</p> <p>1.5 mg/kg bw/day</p> <p>DNELs for the general public: <br />Acute <br />Systemic <br />Acute <br />Local <br />Long-term <br />Systemic <br />Long-term <br />Systemic <br />Long-term <br />Systemic <br />Long-term <br />Systemic <br />Long-term <br />Local <br />Source: Chemical Safety Report of disodium tetraborate</p> <p>3</p> <p>303.5 mg/kg bw/day <br />1.5 mg/kg bw/day <br />3 <br />6.5 mg/ m <br />1.5 mg/kg bw/day <br />3 <br />22.3 mg/ m</p> <p>PNEC values <br />PNEC add, freshwater, marine water = 1.35 mg B/L <br />PNEC add aqua intermittent = 9.1 mg B/L <br />PNEC add freshwater sediment, marine water sediment = 1.8 mg B/kg sediment dry weight <br />PNEC soil = 5.4 mg B/kg soil dry weight <br />PNEC add, STP = 1.75 mg B/L Source: Chemical Safety Report of Boric Acid <br />Exposure controls: <br />Appropriate engineering controls: Maintain air concentrations below occupational exposure standards. Use <br />local exhaust ventilation to keep airborne concentrations of borax decahydrate dust below permissible <br />exposure levels. Wash hands before breaks and at the end of the workday. Remove and wash soiled clothing. <br />Individual protection measures, such as personal protective equipment: <br />Respiratory protection: Where risk assessment shows air-purifying respirators are appropriate use a fullface particle respirator type N100 (US) or type P3 (EN 143) respirator cartridges as a backup to engineering <br />controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators <br />and components tested and approved under appropriate government standards such as NIOSH (US) or CEN <br />(EU). <br />Eyes and hand protection: Handle with gloves. Wear eye protection suitable for job tasks. <br />Environmental exposure: No special requirement.</p> <p>Section 9 – Physical and Chemical Properties <br />Physical State: <br />Powder or crystalline solid <br />Appearance/Color: <br />White <br />Odor: <br />Odorless <br />Solubility in water: <br />4.7 % @ 68°F (20°C); 65.6% @ 212°F (100°C) <br />Partition Coefficient: n-octanol/water: Log Kow (Pow): 1.53 +/- 0.05 (@ 22 + / - 1°C) pH 7.5 <br />Boiling Point: <br />2,867°F (1575°C) <br />Melting Point: <br />1,365.8°F (741°C) (heated in closed space) <br />Flash Point: <br />Not applicable <br />Flammability: <br />Not flammable <br />not applicable <br />Auto-ignition Temperature: <br />Page 4 of 7</p> <p>IDENTITY:</p> <p>SAFETY DATA SHEET</p> <p>Pavemend SET RETARDANT</p> <p>Decomposition Temperature: <br />Specific Gravity:</p> <p>pH (in water):</p> <p>Bulk density:</p> <p>SDS No. P.V. 1.1.1</p> <p>Dehydration begins at 140°F (60°C, complete at 608°F (320°C) <br />3 <br />1.71-1.73 gr/cm @ 20°C <br />pH @ 20°C 9.3 (0.1% solution) <br />9.2 (1% solution) <br />9.3 (4.7% solution) <br />3 <br />3 <br />62.43 lbs/ft (1.0 ton/m )</p> <p>Section 10 – Stability and Reactivity <br />Chemical Stability:</p> <p>Retarder is stable under normal ambient and anticipated storage and <br />handling conditions of temperature and pressure. When heated it <br />losses water, eventually forming anhydrous borax (Na2 B4 O7).</p> <p>Conditions to Avoid: <br />Hazardous Decomposition Products: <br />Hazardous Polymerization: <br />Incompatibilities:</p> <p>Exposure to moisture and incompatible materials. <br />Boranes, hydrogen, boron oxides <br />Will not occur. <br />Avoid contact with strong reducing agents such as metal hydrides, <br />acetic anhydride or alkali metals.</p> <p>Section 11 – Toxicological Information <br />Information on toxicological effect: <br />Acute toxicity: Low acute oral toxicity; LD50 in rats is 6,000 mg/kg of body weight. <br />Skin corrosion / irritation: Low acute dermal toxicity; LD50 in rabbits is greater than 2,000 mg/kg of body <br />weight. Borax decahydrate is poorly absorbed through intact skin. Non-irritant. <br />Serious eye damage/ irritation: Borax decahydrate is a serious eye irritant. <br />Respiratory or skin sensitization: Borax is not a skin sensitizer. <br />Germ cell mutagenicity / carcinogenicity: <br />IARC: No component of this product present at levels greater than or equal to 0.1% is identified as probable, <br />possible or confirmed human carcinogen by IARC. ACGIH: No component of this product present at levels <br />greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by ACGIH. NTP: No <br />component of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated <br />carcinogen by NTP. OSHA: No component of this product present at levels greater than or equal to 0.1% is <br />identified as a carcinogen or potential carcinogen by OSHA. <br />Reproductive toxicity: Animal feeding studies in rat, mouse and dog, at high doses, have demonstrated <br />effects on fertility and testes (2). Studies with chemically related boric acid in rat, mouse and rabbit, at high <br />doses, demonstrate developmental effects on the fetus including fetal weight loss and minor skeletal variations. <br />The doses administered were many times in excess of those which humans would normally be exposed to (3, <br />4, 5). Human epidemiological studies show no increase in pulmonary disease in occupational populations with <br />chronic exposures to boric acid dust and sodium borate dust. A recent epidemiology study under the conditions <br />of normal occupational exposure to borate dusts indicated no effect on fertility. <br />STOT-single exposure: N.A <br />. <br />STOT-repeated exposure: N.A <br />. <br />Aspiration hazard: Low acute inhalation toxicity; LC50 in rats is greater than 2.0 mg/l (or g/m3). <br />Page 5 of 7</p> <p>IDENTITY:</p> <p>SAFETY DATA SHEET</p> <p>Pavemend SET RETARDANT</p> <p>SDS No. P.V. 1.1.1</p> <p>Section 12 – Ecological Information <br />Ecological Information: The unused product is slight water pollutant. Large quantities may be toxic to fish. Do</p> <p>not allow undiluted product or large quantities to reach into waterways or drains.</p> <p>Section 13 – Disposal Considerations <br />Waste Disposal Method:</p> <p>Dispose of in a manner consistent with federal, state and local regulations. <br />Do not dispose together with household garbage. Do not allow product to <br />reach sewage system.</p> <p>Unused Residue or Dry Spillage: Pick up dry material. Possibly reuse depending on amount of contamination. <br />Prevent dust exposure. In case of disposal, harden with water and dispose in <br />accordance to local regulations. <br />Slurries:</p> <p>Allow to harden and dispose of as described above.</p> <p>Container disposal:</p> <p>Completely emptied packaging can be given for recycling.</p> <p>Section 14 – Transport Information <br />RCRA Hazard Class:</p> <p>Non-hazardous</p> <p>USDOT (Domestic Surface) <br />IMDG (Ocean) Hazard Class or Division: <br />IATA/ICAO (Air) Hazard Class or Division: <br />TDG (Canada): <br />UN Number:</p> <p>Not regulated <br />Not regulated <br />Not regulated <br />Not regulated <br />Not listed</p> <p>Section 15 – Regulatory Information <br />Safety, health and environmental regulations/substance specific legislation: <br />It should be noted that borates are safe under conditions of normal handling and use, besides, they are essential <br />nutrients to plants, and research shows that they play a beneficial role in human health. <br />Chemical inventory listing: <br />U.S. EPA TSCA Inventory 1330-96-4 <br />Canadian DSL 1330-96-4 ECN 215-540-4 <br />South Korea 9212-848 <br />Japanese MITI (1)-69 <br />Ensure all national/local regulations are observed. <br />SARA 302: No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302. <br />SARA 313: This material does not contain any chemical components with known CAS numbers that exceed the <br />threshold (De Minimis) reporting levels established by SARA Title III, Section 313. <br />SARA 311/312 Hazards: Chronic Health Hazard <br />Massachusetts Right to Know Components: <br />Disodium tetraborate decahydrate CAS-No 1303-96-4 Revision Date 2007-03-01 <br />Page 6 of 7</p> <p>IDENTITY:</p> <p>SAFETY DATA SHEET</p> <p>Pavemend SET RETARDANT</p> <p>SDS No. P.V. 1.1.1</p> <p>Pennsylvania Right to Know Components: <br />Disodium tetraborate decahydrate CAS-No 1303-96-4 Revision Date 2007-03-01 <br />New Jersey Right To Know Components: <br />Disodium tetraborate decahydrate CAS-No 1303-96-4 Revision Date 2007-03-01 <br />California Prop. 65 Components: <br />This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any <br />other reproductive harm. <br />Clean Air Act (Montreal Protocol): <br />Borax decahydrate was not manufactured with and does not contain any Class I or Class II ozone depleting <br />substances. <br />EU Reach Regulation: <br />Disodium tetraborates are listed in the Candidate List of Substances of Very High Concern “SVHC” for eventual <br />inclusion in Annex XIV to REACH Regulation 1907/2006 (“Authorization List”) (18.06.2010- ED/30/2010). <br />Disodium tetraborates are listed in the Annex XVII of REACH Regulation 1907/2006 (EU No.109/2012) and its use <br />in consumer products above specific concentration limits is restricted. Note that this restriction is only specific to <br />consumer products and do not cover its industrial and/or professional applications. Disodium Tetraborates can be <br />used in consumer products below specific concentration limits (which is C ≥8.5% for Borax decahydrate).</p> <p>Section 16 – Other Information <br />Full text of H-Statements referred to under sections 2 and 3. <br />H361 <br />Suspected of damaging fertility or the unborn child <br />H319 <br />Causes serious eye irritation. <br />H303 <br />May be harmful if swallowed. <br />Abbreviations and acronyms: <br />USDOT: <br />United States Department of Transportation. <br />IMDG: <br />International Maritime Code for Dangerous Goods. <br />IATA: <br />International Air Transport Association. <br />CAS: <br />Chemical Abstracts Service (Division of the American Chemical Society). <br />LC50: <br />Lethal concentration, 50 percent. <br />LD50: <br />Lethal dose, 50 percent. <br />SDS prepared by:</p> <p>Aquafin product safety department.</p> <p>DISCLAIMER: <br />We believe the statements, technical information and recommendations contained herein are reliable, but they are <br />given without warranty or guarantee of any kind, expressed or implied, and we assume no responsibility for any <br />loss, damage, or expense, direct or consequential, arising out of their use. Aquafin shall not be responsible for the <br />use of this product in a manner to infringe on any patent or any other intellectual property rights held by others. <br />END OFsafety <br />MSDS <br />(April 09, 2015) <br />User is responsible for determining appropriate <br />measures and for applying the legislation <br />covering his own <br />activities. We recommend that user makes tests to determine the suitability of a product for its particular purpose <br />prior to use. <br />END OF SDS</p> <p>Page 7 of 7</p> <p>(February 18, 2019)</p>
