Safety Data Sheet (SDS)
OSHA HazCom Standard 29 CFR 1910.1200(g) and GHS Rev 03.
Printing date 09/29/2022
Reviewed on 09/29/2022
SECTION 1) CHEMICAL PRODUCT AND SUPPLIER'S IDENTIFICATION
Product Name: PRO-Tekt Caulk COMPONENT B
Product Use Description:
505 BLUE BALL RD. #160
ELKTON, MD 21921
Urethane-polyurea Caulk, For Further Information, Refer to the Product Technical
24 hr Emergency Phone: Chem-Tel (800) 255-3924
Information Phone No: (410) 392-2300
SECTION 2) HAZARDS IDENTIFICATION
Specific Target Organ Toxicity - Single Exposure - Category 1
Specific Target Organ Toxicity - Repeated Exposure - Category 2
Skin Irritation - Category 3
Carcinogenicity - Category 2
Eye Irritation - Category 2
Acute aquatic toxicity - Category 3
Chronic aquatic toxicity - Category 3
Hazardous Statements - Health:
H370 - Causes damage to organs.
H373 - May cause damage to organs through prolonged or repeated exposure.
H316 - Causes mild skin irritation
H351 - Suspected of causing cancer.
H319 - Causes serious eye irritation
Hazardous Statements - Environmental:
H402 - Harmful to aquatic life
H412 - Harmful to aquatic life with long lasting effects
Precautionary Statements - General:
P101 - If medical advice is needed, have product container or label at hand.
P102 - Keep out of reach of children.
P103 - Read label before use.
SDS PRO-Tekt Caulk Comp B SDS
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Precautionary Statements - Prevention:
P260 - Do not breathe dust/fume/gas/mist/vapors/spray.
P264 - Wash thoroughly after handling.
P270 - Do not eat, drink or smoke when using this product.
P201 - Obtain special instructions before use.
P202 - Do not handle until all safety precautions have been read and understood.
P280 - Wear protective gloves/protective clothing/eye protection/face protection.
P273 - Avoid release to the environment.
Precautionary Statements - Response:
P308 + P311 - IF exposed or concerned: Call a POISON CENTER/doctor.
P321 - Specific treatment (see section 4 on this SDS).
P314 - Get Medical advice/attention if you feel unwell.
P332 + P313 - If skin irritation occurs: Get medical advice/attention.
P308 + P313 - IF exposed or concerned: Get medical advice/attention.
P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue
P337 + P313 - If eye irritation persists: Get medical advice/attention.
Precautionary Statements - Storage:
P405 - Store locked up.
Precautionary Statements - Disposal:
P501 - Dispose of contents/ container to an approved waste disposal plant.
SECTION 3) COMPOSITION / INFORMATION ON INGREDIENTS
% By Weight
16% - 28%
5% - 10%
4% - 7%
0.4% - 0.7%
0.2% - 0.4%
SECTION 4) FIRST-AID MEASURES
Remove source of exposure or move person to fresh air and keep comfortable for breathing. If experiencing respiratory symptoms: Call a
POISON CENTER/doctor. If breathing is difficult, trained personnel should administer emergency oxygen if advised to do so by the
If exposed/feel unwell/concerned: Call a POISON CENTER/doctor.
Take off contaminated clothing, shoes and leather goods (e.g. watchbands, belts). Gently blot or brush away excess product. Wash with
plenty of lukewarm, gently flowing water for a duration of 15-20 minutes. If skin irritation or rash occurs: Get medical advice/attention. Wash
contaminated clothing before re-use or discard.
IF exposed or concerned: Get medical advice/attention.
Remove source of exposure or move person to fresh air. Rinse eyes cautiously with lukewarm, gently flowing water for several minutes,
while holding the eyelids open. Remove contact lenses, if present and easy to do. Continue rinsing for a duration of 15-20 minutes. Take
care not to rinse contaminated water into the unaffected eye or onto the face. If eye irritation persists: Get medical advice/attention.
Immediately call a POISON CENTER/doctor. Do NOT induce vomiting. If vomiting occurs naturally, lie on your side, in the recovery
Give 1 or 2 glasses of milk or water to drink and refer person to medical personnel. Do not give anything by mouth to an unconscious
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IF exposed or concerned: Get medical advice/attention.
SECTION 5) FIRE-FIGHTING MEASURES
Suitable Extinguishing Media:
Dry chemical, foam, carbon dioxide water spray or fog is recommended. Water spray is recommended to cool or protect exposed materials
or structures. Carbon dioxide can displace oxygen. Use caution when applying carbon dioxide in confined spaces. Simultaneous use of
foam and water on the same surface is to be avoided as water destroys the foam. Sand or earth may be used for small fires only.
Specific Hazards in Case of Fire:
Sudden reaction and fire may result when the product is exposed to oxidizing agents.
Isolate immediate hazard area and keep unauthorized personnel out. Stop spill/release if it can be done safely. Move undamaged
containers from immediate hazard area if it can be done safely. Water spray may be useful in minimizing or dispersing vapors and to
protect personnel. Water may be ineffective but can be used to cool containers exposed to heat or flame. Caution should be exercised
when using water or foam as frothing may occur, especially if sprayed into containers of hot, burning liquid.
Dispose of fire debris and contaminated extinguishing water in accordance with official regulations.
Special Protective Actions:
Wear NIOSH approved self-contained breathing apparatus in positive pressure mode with full-face piece. Boots, gloves (neoprene),
googles, and full protective clothing are also required.
Care should always be exercised in dust/mist areas.
SECTION 6) ACCIDENTAL RELEASE MEASURES
Keep unnecessary people away; isolate hazard area and deny entry. Do not touch or walk through spilled material. Clean up immediately.
ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area).
Positive pressure, full-face piece self-contained breathing apparatus(SCBA), or positive pressure supplied air respirator with escape SCBA
Avoid breathing vapors. Avoid contact with skin, eyes or clothing. Do not touch damaged containers or spilled materials unless wearing
appropriate protective clothing.
Stop spill/release if it can be done safely. Prevent spilled material from entering sewers, storm drains, other unauthorized drainage systems
and natural waterways by using sand, earth, or other appropriate barriers.
Methods and Materials for Containment and Cleaning up:
Soak up material with absorbent and shovel into a chemical waste container. Cover container, but do not seal, and remove from work area.
Residues from spill cleanup may continue to be regulated under provisions of RCRA and require storage and disposal as hazardous
waste. For major spills, call CHEMTREC (Chemical Transportation Emergency Center) at 800-424-9300.
SECTION 7) HANDLING AND STORAGE
Wash hands after use.
Do not get in eyes, on skin or on clothing.
Do not breathe vapors or mists.
Use good personal hygiene practices.
Eating, drinking and smoking in work areas is prohibited.
Remove contaminated clothing and protective equipment before entering eating areas.
Eyewash stations and showers should be available in areas where this material is used and stored.
Use only with adequate ventilation to control air contaminants to their exposure limits. The use of local ventilation is recommended to
control emissions near the source.
Storage Room Requirements:
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Keep container(s) tightly closed and properly labeled. Store in cool, dry, well-ventilated areas away from heat, direct sunlight, strong
oxidizers and any incompatibilities. Store in approved containers and protect against physical damage. Keep containers securely sealed
when not in use. Indoor storage should meet OSHA standards and appropriate fire codes. Containers that have been opened must be
carefully resealed to prevent leakage. Empty container retain residue and may be dangerous.
Use non-sparking ventilation systems, approved explosion-proof equipment and intrinsically safe electrical systems in areas where this
product is used and stored.
Store in tightly sealed containers to protect from atmospheric moisture. Store in a cool dry area. Store liquid in containers above ground
and surround by dikes to contain spills or leaks.
Ground and bond containers and receiving equipment. Avoid static electricity by grounding.
SECTION 8) EXPOSURE CONTROLS/PERSONAL PROTECTION
Wear eye protection with side shields or goggles. Wear indirect-vent, impact and splash resistant goggles when working with liquids. If
additional protection is needed for entire face, use in combination with a face shield.
Use of gloves approved to relevant standards made from the following materials may provide suitable chemical protection: PVC, neoprene
or nitrile rubber gloves. Suitability and durability of a glove is dependent on usage, e.g. frequency and duration of contact, chemical
resistance of glove material, glove thickness, dexterity. Always seek advice from glove suppliers. Contaminated gloves should be replaced.
Use of an apron and over- boots of chemically impervious materials such as neoprene or nitrile rubber is recommended to avoid skin
sensitization. The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at
the specific workplace. Launder soiled clothes or properly disposed of contaminated material, which cannot be decontaminated.
If engineering controls do not maintain airborne concentrations to a level which is adequate to protect worker, a respiratory protection
program that meets or is equivalent to OSHA 29 CFR 1910.134 and ANSI Z88.2 should be followed. Check with respiratory protective
When airborne concentrations exceed or are expected to exceed the TLV, use MSHA/NIOSH approved positive pressure supplied air
respirator with a full-face piece or an air supplied hood. For emergencies, use a positive pressure self-container breathing apparatus.
Appropriate Engineering Controls:
Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors below their respective threshold
Tables (Z1, OSHA
Z2, Z3) Carcinogen designation
(I) - Inhalable fraction
SECTION 9) PHYSICAL AND CHEMICAL PROPERTIES
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VOC Part A & B Combined
Flash Point Symbol
Lower Explosion Level
Upper Explosion Level
Heavier than air
Low Boiling Point
High Boiling Point
Auto Ignition Temp
Slower than ether
SECTION 10) STABILITY AND REACTIVITY
Material is stable at standard temperature and pressure.
Conditions to Avoid:
Heat, high temperature, open flame, and moisture. Avoid contact with incompatible materials.
Will not occur.
This product will react with any material containing isocyanate. Some reactions can be violent.
Hazardous Decomposition Products:
Combustion products: organic vapors and thermal decomposition fragments.
SECTION 11) TOXICOLOGICAL INFORMATION
Product may be absorbed through skin and cause nausea, headache, and general discomfort.
Causes mild skin irritation
Serious Eye Damage/Irritation:
Vapors can irritate the eyes. Chemical burns may result due to overexposure. Affects of exposure may be delayed.
Causes serious eye irritation
Inhalation : Severe overexposure may induce respiratory sensitization with asthma like symptoms. These symptoms may be immediate or
delayed up to several hours after exposure. Chronic exposures may result in permanent decreases in lung function.
Skin sensitization may develop after repeated and/or prolonged contact.
Suspected of causing cancer.
Germ Cell Mutagenicity:
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No data available
No data available
Specific Target Organ Toxicity - Single Exposure:
Causes damage to organs.
Specific Target Organ Toxicity - Repeated Exposure:
May cause damage to organs through prolonged or repeated exposure.
No data available
If ingested : In humans, irritation or chemical burns of the mouth, pharynx, esophagus and stomach can develop following ingestion, and
injury may be severe and cause death.
Repeated and prolonged exposure at low levels may result in adverse skin and eye effects, liver and kidney disorders.
LC50 (rat): 6750 mg/m3 (4-hour exposure); cited as 27000 mg/m3 (27 mg/L) (1-hour exposure) (3)
CARCINOGENIC EFFECTS: In 1996, the IARC reevaluated Carbon Black as a Group 2B carcinogen. This evaluation is given to
carbon black for which there is inadequate human evidence, but sufficient animal evidence.
Prolonged inhalation of Carbon black can result in lung disease. Symptoms include coughing, shortness of breath, wheezing and
reduced pulmonary function.
Prolonged inhalation of respirable crystalline silica dust can result in lung disease (i.e. silicosis and/or lung cancer). Symptoms
include coughing, shortness of breath, wheezing and reduced pulmonary function.
Potential Health Effects - Miscellaneous
Is an IARC, NTP or OSHA carcinogen. Has shown carcinogenic activity in laboratory animals at high doses. Significance to man is
unknown. The following medical conditions may be aggravated by exposure: asthma, respiratory disease. WARNING: This
chemical is known to the State of California to cause cancer.
Is an IARC, NTP or OSHA carcinogen. In a lifetime inhalation test, lung cancers were found in some rats exposed to 250 mg/m3
respirable titanium dust. Analysis of the titanium dioxide concentrations in the rat?s lungs showed that the lung clearance
mechanism was overwhelmed and that the results at the massive 250 mg/m3 level are not relevant to the workplace.?Results of a
DuPont epidemiology study showed that employees who had been exposed to Titanium Dioxide were at no greater risk of
developing lung cancer than were employees who had not been exposed to Titanium dioxide. No pulmonary fibrosis was found in
any of the employees and no association was observed between Titanium dioxide exposure and chronic respiratory disease or xray abnormalities. Based on the results of this study DuPont concludes that titanium dioxide will not cause lung cancer or chronic
respiratory disease in humans at concentrations experienced in the workplace.?
Is an IARC, NTP or OSHA carcinogen. Repeated overexposure to crystalline silica may lead to x-ray changes and chronic lung
disease. Inhalation of high dust concentrations may cause: breathing difficulties, lung injury. WARNING: This chemical is known to
the State of California to cause cancer.
SECTION 12) ECOLOGICAL INFORMATION
Harmful to aquatic life
Harmful to aquatic life with long lasting effects
Mobility in Soil:
No data available.
Other Adverse Effects:
No data available.
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A relevant bioaccumulation potential of carbon black is not expected based on its insolubility in organic solvents and in water.
Furthermore, since the aggregate diameter of carbon black varies between 80 nm and 810 nm, bioaccumulation of particulate
carbon black is not likely oweing to the large diameter of the solid aggregate particles.
Persistence and Degradability
Carbon Black's insolubility in water results in it not being biodegradable in any medium or by biota. It is considered persistent in
the natural environment.
SECTION 13) DISPOSAL CONSIDERATIONS
Under RCRA, it is the responsibility of the user of the product, to determine a the time of disposal whether the product meets RCRA criteria
for hazardous waste. Waste management should be in full compliance with federal, state, and local laws.
Empty containers retain product residue which may exhibit hazards of material, therefore do not pressurize, cut, glaze, weld or use for any
other purposes. Return drums to reclamation centers for proper cleaning and reuse.
SECTION 14) TRANSPORT INFORMATION
U.S. DOT Information:
SECTION 15) REGULATORY INFORMATION
0.4% - 0.7% DSL,SARA312,TSCA,California Proposition 65
0.2% - 0.4% DSL,SARA312,TSCA,California Proposition 65
16% - 28% DSL,SARA312,TSCA
5% - 10% DSL,SARA312,TSCA,California Proposition 65
4% - 7% DSL,SARA312,VOC,TSCA
SECTION 16) OTHER INFORMATION
* There are points of differences between OSHA GHS and UN GHS. In 90% of the categories, they can be used interchangeably, but for
the Skin Corrosion/Irritant Category and the Specific Target Organ Toxicity (Single and Repeated Exposure) Categories. In these cases,
our system will say UN GHS.
ACGIH- American Conference of Governmental Industrial Hygienists; ANSI- American National Standards Institute; Canadian TDGCanadian Transportation of Dangerous Goods; CAS- Chemical Abstract Service; Chemtrec- Chemical Transportation Emergency Center
(US); CHIP- Chemical Hazard Information and Packaging; DSL- Domestic Substances List; EC- Equivalent Concentration; EH40 (UK)HSE Guidance Note EH40 Occupational Exposure Limits; EPCRA- Emergency Planning and Community Right-To-Know Act; ESL- Effects
screening levels; HMIS- Hazardous Material Information Service; LC- Lethal Concentration; LD- Lethal Dose; NFPA- National Fire
Protection Association; OEL- Occupational Exposure Limits; OSHA- Occupational Safety and Health Administration, US Department of
Labor; PEL- Permissible Exposure Limit; SARA (Title III)- Superfund Amendments and Reauthorization Act; SARA 313- Superfund
Amendments and Reauthorization Act, Section 313; SCBA- Self-Contained Breathing Apparatus; STEL- Short Term Exposure Limit; TCEQ
- Texas Commission on Environmental Quality; TLV- Threshold Limit Value; TSCA- Toxic Substances Control Act Public Law 94-469; TWA
- Time Weighted Value; US DOT- US Department of Transportation; WHMIS- Workplace Hazardous Materials Information System.
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To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its subsidiaries
assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any
material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain
hazards are described herein, we cannot guarantee that these are the only hazards that exist. The above information pertains to this product as
currently formulated, and is based on the information available at this time. Addition of reducers or other additives to this product may substantially
alter the composition and hazards of the product. Since conditions of use are outside our control, we make no warranties, express or implied, and
assume no liability in connection with any use of this information.
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