SDS_AQUAFIN-PRO-Tekt FLEXCOAT_A-Component-Poly.pdf
15 Pages
276 KB
Download
<h1>SDS_AQUAFIN-PRO-Tekt FLEXCOAT_A-Component-Poly.pdf</h1> <p>SAFETY DATA SHEET</p> <p>IDENTITY: PRO-Tekt Flexcoat, Component A</p> <p>SDS No. PRO F.1.1</p> <p>Date prepared: AUGUST 2017 <br />Date revised: FEBRUARY 2019</p> <p>SDS No. PRO F.1.1</p> <p>Section 1 – Product Identification <br />IDENTITY: Product Name:</p> <p>PRO-TEKT FLEXCOAT, Component A</p> <p>AQUAFIN, INC. <br />505 BLUE BALL RD. #160 <br />ELKTON, MD 21921</p> <p>Emergency Phone No. <br />Information Phone No.</p> <p>info@aquafin.net</p> <p>Recommended use of the chemical and restriction on use:</p> <p>(800) 394-1410 <br />(410) 392-2300</p> <p>www.aquafin.net</p> <p>Refer to the product technical data sheet. <br />For industrial and professional users.</p> <p>Section 2 – Hazards Identification <br />GHS Classification: <br />This material is hazardous under the criteria of the Federal OSHA Hazard Communication Standard 29CFR <br />1910.1200. <br />Acute toxicity - Category 4 - Oral <br />Eye irritation - Category 2A <br />Skin sensitization - Category 1 <br />Carcinogenicity - Category 2 <br />Specific target organ toxicity - repeated exposure - Category 2 - Oral</p> <p>GHS Label element: <br />Hazard Pictograms <br />GHS07 <br />Signal Word:</p> <p>GHS08</p> <p>WARNING!</p> <p>Hazard Statements: <br />H302 <br />Harmful if swallowed. <br />H317 <br />May cause an allergic skin reaction. <br />H319 <br />Causes serious eye irritation. <br />H351 <br />Suspected of causing cancer. <br />H373 <br />May cause damage to organs through prolonged or repeated exposure. <br />Precautionary Statements: <br />Prevention: <br />P201 <br />Obtain special instructions before use. <br />P202 <br />Do not handle until all safety precautions have been read and understood. <br />P260 <br />Do not breathe dust/ fume/ gas/ mist/ vapors/ spray. <br />P264 <br />Wash skin thoroughly after handling. <br />P270 <br />Do not eat, drink or smoke when using this product. <br />P271 <br />Use only outdoors or in a well-ventilated area. <br />P272 <br />Contaminated work clothing should not be allowed out of the workplace. <br />P280 <br />Wear protective gloves/ protective clothing/ eye protection/ face protection. <br />Response: <br />P301+312 <br />P302+352 <br />P305+351+338</p> <p>IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. <br />IF ON SKIN: Wash with plenty of soap and water. <br />IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if <br />Page 1 of 15</p> <p>IDENTITY: PRO-Tekt Flexcoat, Component A</p> <p>SAFETY DATA SHEET <br />SDS No. PRO F.1.1</p> <p>P308+313 <br />P333+313 <br />P337+313 <br />P363</p> <p>present and easy to do. Continue rinsing. <br />IF exposed or concerned: Get medical advice/ attention. <br />If skin irritation or rash occurs: Get medical advice/ attention. <br />If eye irritation persists: Get medical advice/ attention. <br />Wash contaminated clothing before reuse.</p> <p>Storage: <br />P405</p> <p>Store locked up.</p> <p>Disposal: <br />P501:</p> <p>Dispose of contents/container to an approved waste disposal site.</p> <p>Other hazards:</p> <p>No data available.</p> <p>Section 3 – Composition / Information on Ingredients <br />This product is a mixture.</p> <p>Hazardous Components</p> <p>CAS No.</p> <p>Weight %</p> <p>2,2,4-Trimethyl-1, 3-pentanediol diisobutyrate</p> <p>6846-50-0</p> <p>>= 15.0 - <= 40.0 %</p> <p>Diethyltoluenediamine (DETDA)</p> <p>68479-98-1</p> <p>>= 15.0 - <= 40.0 %</p> <p>N,N'-Dialkylaminodiphenylmethane</p> <p>5285-60-9</p> <p>>= 10.0 - <= 30.0 %</p> <p>Propylene carbonate</p> <p>108-32-7</p> <p>>= 7.0 - <= 13.0 %</p> <p>6-Methyl-2,4-bis(methylthio)phenylene-1,3- diamine</p> <p>106264-79-3</p> <p>>= 7.0 - <= 13.0 %</p> <p>Unknowns</p> <p>Not available</p> <p>>= 5.0 - <= 10.0 %</p> <p>Titanium dioxide</p> <p>13463-67-7</p> <p>>= 3.0 - <= 7.0 %</p> <p>Carbon black</p> <p>1333-86-4</p> <p>>= 0.5 - <= 1.5 %</p> <p>There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations <br />applicable, are classified as hazardous to health or the environment and hence not require reporting in this section.</p> <p>Section 4 – First Aid Measures <br />General Advice:</p> <p>First Aid responders should pay attention to self-protection and use the recommended <br />protective clothing (chemical resistant gloves, splash protection). If potential for <br />exposure exists refer to Section 8 for specific personal protective equipment.</p> <p>After Inhalation:</p> <p>Move person to fresh air. If effects occur, consult a physician.</p> <p>After Eye Contact:</p> <p>Immediately flush eyes with water; remove contact lenses, if present, after the first 5 <br />minutes, then continue flushing eyes for at least 15 minutes. Obtain medical attention <br />without delay, preferably from an ophthalmologist. Suitable emergency eye wash <br />facility should be immediately available. Flush eyes thoroughly with water for several <br />minutes. Remove contact lenses after the initial 1-2 minutes and continue flushing for</p> <p>After Skin Contact:</p> <p>several additional minutes. If effects occur, consult a physician, preferably an <br />ophthalmologist. Suitable emergency eye wash facility should be available in work <br />area. <br />Remove material from skin immediately by washing with soap and plenty of water. <br />Page 2 of 15</p> <p>IDENTITY: PRO-Tekt Flexcoat, Component A</p> <p>After Ingestion:</p> <p>SAFETY DATA SHEET <br />SDS No. PRO F.1.1</p> <p>Remove contaminated clothing and shoes while washing. Seek medical attention if <br />irritation persists. Wash clothing before reuse. Discard items which cannot be <br />decontaminated, including leather articles such as shoes, belts and watchbands. <br />If swallowed, seek medical attention. Do not induce vomiting unless directed to do so <br />by medical personnel.</p> <p>Most important symptoms and effects, both acute and delayed: Aside from the information found under <br />Description of first aid measures (above) and Indication of immediate medical attention and special treatment <br />needed (below), any additional important symptoms and effects are described in Section 11: Toxicology <br />Information. <br />Indication of any immediate medical attention and special treatment needed <br />Notes to physician: No Specific antidote. Treatment of exposure should be directed at the control of symptoms <br />and the clinical condition of the patient.</p> <p>Section 5 – Fire Fighting Measures <br />Suitable Extinguishing Media: Water fog or fine spray. Dry chemical fire extinguishers. Carbon dioxide fire <br />extinguishers. Foam. Alcohol resistant foams (ATC type) are preferred. General purpose synthetic foams <br />(including AFFF) or protein foams may function, but will be less effective. <br />Unsuitable extinguishing media: Do not use direct water stream. May spread fire. <br />Special hazards arising from the substance or mixture: <br />Hazardous combustion products: During a fire, smoke may contain the original material in addition to <br />combustion products of varying composition which may be toxic and/or irritating. Combustion products may <br />include and are not limited to: Nitrogen oxides. Isocyanates. Hydrogen cyanide. Carbon monoxide. Carbon <br />dioxide. <br />Unusual Fire and Explosion Hazards: Product reacts with water. Reaction may produce heat and/or gases. <br />This reaction may be violent. Container may rupture from gas generation in a fire situation. Violent steam <br />generation or eruption may occur upon application of direct water stream to hot liquids. Dense smoke is <br />produced when product burns. <br />Advice for firefighters <br />Fire Fighting Procedures: Keep people away. Isolate fire and deny unnecessary entry. Stay upwind. Keep <br />out of low areas where gases (fumes) can accumulate. Water is not recommended, but may be applied in large <br />quantities as a fine spray when other extinguishing agents are not available. Do not use direct water stream. <br />May spread fire. Move container from fire area if this is possible without hazard. Fight fire from protected <br />location or safe distance. Consider the use of unmanned hose holders or monitor nozzles. Immediately <br />withdraw all personnel from the area in case of rising sound from venting safety device or discoloration of the <br />container. Move container from fire area if this is possible without hazard. Use water spray to cool fire-exposed <br />containers and fire-affected zone until fire is out. Contain fire water run-off if possible. Fire water run-off, if not <br />contained, may cause environmental damage. Review the "Accidental Release Measures" and the "Ecological <br />Information" sections of this (M)SDS. <br />Special protective equipment for firefighters: Wear positive-pressure self-contained breathing apparatus <br />(SCBA) and protective fire-fighting clothing (includes fire-fighting helmet, coat, trousers, boots, and gloves). <br />Avoid contact with this material during fire fighting operations. If contact is likely, change to full chemical <br />resistant fire-fighting clothing with self-contained breathing apparatus. If this is not available, wear full chemical <br />resistant clothing with self-contained breathing apparatus and fight fire from a remote location. For protective <br />equipment in post-fire or non-fire clean-up situations, refer to the relevant sections.</p> <p>Page 3 of 15</p> <p>SAFETY DATA SHEET</p> <p>IDENTITY: PRO-Tekt Flexcoat, Component A</p> <p>SDS No. PRO F.1.1</p> <p>Section 6 – Accidental Release Measures <br />Personal precautions, protective equipment and emergency procedures: Isolate area. Keep unnecessary <br />and unprotected personnel from entering the area. Refer to section 7, Handling, for additional precautionary <br />measures. Keep personnel out of low areas. See Section 10 for more specific information. Use appropriate <br />safety equipment. For additional information, refer to Section 8, Exposure Controls and Personal Protection. <br />Environmental precautions: Prevent from entering into soil, ditches, sewers, waterways and/or groundwater. <br />See Section 12, Ecological Information. <br />Methods and materials for containment and cleaning up: Contain spilled material if possible. Collect in <br />suitable and properly labeled containers. See Section 13, Disposal Considerations, for additional information.</p> <p>Section 7 – Handling and Storage <br />Precautions for safe handling: Avoid contact with eyes. Avoid prolonged or repeated contact with skin. Do <br />not swallow. Wash thoroughly after handling. Spills of these organic materials on hot fibrous insulations may <br />lead to lowering of the auto-ignition temperatures possibly resulting in spontaneous combustion. See Section 8, <br />EXPOSURE CONTROLS AND PERSONAL PROTECTION. <br />Conditions for safe storage: Protect from atmospheric moisture. Store in a dry place. Do not store product <br />contaminated with water to prevent potential hazardous reaction. Avoid temperatures above 50°C (122°F) See <br />Section 10 for more specific information. Store in accordance with good manufacturing practices.</p> <p>Section 8 – Exposure Controls / Personal Protection <br />Control parameters <br />Exposure limits are listed below, if they exist. <br />Component</p> <p>Regulation</p> <p>Type of listing</p> <p>Value/Notation</p> <p>Diethyltoluenediamine (DETDA)</p> <p>Dow IHG</p> <p>TWA</p> <p>0.02 ppm</p> <p>Titanium dioxide</p> <p>Dow IHG <br />OSHA Z-1 <br />ACGIH</p> <p>TWA <br />TWA total dust <br />TWA</p> <p>2.4 mg/m <br />3 <br />15 mg/ m <br />3 <br />10 mg/ m , Titanium dioxide</p> <p>Carbon black</p> <p>ACGIH <br />OSHA Z-1</p> <p>TWA inhalable fraction <br />TWA</p> <p>3 mg/ m <br />3 <br />3.5 mg/ m</p> <p>3</p> <p>3</p> <p>Exposure controls: <br />Engineering controls: Use local exhaust ventilation, or other engineering controls to maintain airborne levels <br />below exposure limit requirements or guidelines. If there are no applicable exposure limit requirements or <br />guidelines, general ventilation should be sufficient for most operations. Local exhaust ventilation may be <br />necessary for some operations. <br />Individual protection measures: <br />Eye/face protection: Use chemical goggles. <br />Skin protection <br />Hand protection: Use gloves chemically resistant to this material. <br />Other protection: Use protective clothing chemically resistant to this material. Selection of specific <br />items such as face shield, boots, apron, or full body suit will depend on the task.</p> <p>Page 4 of 15</p> <p>IDENTITY: PRO-Tekt Flexcoat, Component A</p> <p>SAFETY DATA SHEET <br />SDS No. PRO F.1.1</p> <p>Respiratory protection: Respiratory protection should be worn when there is a potential to exceed the exposure <br />limit requirements or guidelines. If there are no applicable exposure limit requirements or guidelines, wear <br />respiratory protection when adverse effects, such as respiratory irritation or discomfort have been experienced, or <br />where indicated by your risk assessment process. For most conditions no respiratory protection should be needed; <br />however, if discomfort is experienced, use an approved air-purifying respirator. <br />Section</p> <p>9 – Physical and Chemical Properties</p> <p>Appearance: <br />Physical State <br />Color <br />Odor: <br />Odor Threshhold: <br />pH: <br />Melting point/range: <br />Freezing point: <br />Boiling point (760 mmHg): <br />Flash point:</p> <p>Liquid <br />Gray <br />Sulfur-like <br />No test data available. <br />No data available. <br />No data available. <br />No data available. <br />No data available. <br />Closed cup >=93.3°C (>=199.9°F) Estimated. <br />Open cup >= 93.3°C (>=199.9°F) Estimated. <br />Evaporation Rate (Butyl Acetate =1): Not available. <br />Flammability (solid, gas): <br />Not applicable. <br />Lower explosion limit: <br />Liquid <br />Upper explosion limit: <br />Liquid <br />Vapor Pressure: <br />No data available. <br />Relative Vapor Density (air = 1): <br />No data available. <br />Relative Density (water = 1): <br />No data available. <br />Water Solubility: <br />No data available. <br />Partition coefficient: <br />This product is a mixture. See Section 12 for individual component <br />n-octanol/water <br />data. <br />Auto-ignition temperature <br />No data available. <br />Decomposition temperature <br />No data available. <br />Kinematic Viscosity <br />No information available. <br />Explosive properties <br />No data available. <br />Oxidizing properties <br />No data available. <br />Molecular weight <br />Not reported. <br />NOTE: The physical data presented above are typical values and should not be construed as a specification.</p> <p>Section 10 – Stability and Reactivity <br />Reactivity: Diisocyanates react with many materials and the rate of reaction increases with temperature as <br />well as increased contact; these reactions can become violent. Contact is increased by stirring or if the other <br />material mixes with the diisocyanate. Diisocyanates are not soluble in water and sink to the bottom, but react <br />slowly at the interface. The reaction forms carbon dioxide gas and a layer of solid polyurea. Reaction with water <br />will generate carbon dioxide and heat. <br />Chemical stability: Stable under recommended storage conditions. See Storage, Section 7. <br />Possibility of hazardous reactions: Can occur. Exposure to elevated temperatures can cause product to <br />decompose and generate gas. This can cause pressure build-up and/or rupturing of closed containers. <br />Polymerization can be catalyzed by: Strong bases. Water.</p> <p>Page 5 of 15</p> <p>IDENTITY: PRO-Tekt Flexcoat, Component A</p> <p>SAFETY DATA SHEET <br />SDS No. PRO F.1.1</p> <p>Conditions to avoid: Exposure to elevated temperatures can cause product to decompose. Generation of gas <br />during decomposition can cause pressure in closed systems. Pressure build-up can be rapid. Avoid moisture. <br />Material reacts slowly with water, releasing carbon dioxide which can cause pressure buildup and rupture of <br />closed containers. Elevated temperatures accelerate this reaction. <br />Incompatible materials: Avoid contact with: Acids. Alcohols. Amines. Water. Ammonia. Bases. Metal <br />compounds. Moist air. Strong oxidizers. Diisocyanates react with many materials and the rate of reaction <br />increases with temperature as well as increased contact; these reactions can become violent. Contact is <br />increased by stirring or if the other material mixes with the diisocyanate. Diisocyanates are not soluble in water <br />and sink to the bottom, but react slowly at the interface. The reaction forms carbon dioxide gas and a layer of <br />solid polyurea. Reaction with water will generate carbon dioxide and heat. Avoid contact with metals such as: <br />Aluminum. Zinc. Brass. Tin. Copper. Galvanized metals. Avoid contact with absorbent materials such as: Moist <br />organic absorbents. Avoid unintended contact with polyols. The reaction of polyols and isocyanates generate <br />heat. <br />Hazardous decomposition products: Decomposition products depend upon temperature, air supply and the <br />presence of other materials. Gases are released during decomposition.</p> <p>Section 11 – Toxicological Information <br />Toxicological information appears in this section when such data is available. <br />Acute toxicity <br />Acute oral toxicity: <br />Low toxicity if swallowed. Small amounts swallowed incidentally as a result of normal handling operations <br />are not likely to cause injury; however, swallowing larger amounts may cause injury. <br />As product: Single dose oral LD50 has not been determined. <br />Based on information for component(s): <br />LD50, Rat, 1,430 mg/kg Estimated. <br />Acute dermal toxicity: <br />Prolonged skin contact is unlikely to result in absorption of harmful amounts. <br />As product: The dermal LD50 has not been determined. <br />Based on information for component(s): <br />LD50, Rabbit, 3,800 mg/kg Estimated. <br />Acute inhalation toxicity: <br />At room temperature, exposure to vapor is minimal due to low volatility; single exposure is not likely to be <br />hazardous. Vapor from heated material or mist may cause respiratory irritation. <br />As product: The LC50 has not been determined. <br />Skin corrosion/irritation <br />Prolonged contact may cause slight skin irritation with local redness. <br />Serious eye damage/eye irritation <br />May cause moderate eye irritation. <br />May cause moderate corneal injury. <br />Sensitization <br />Based on information for component(s): <br />For skin sensitization: <br />Has caused allergic skin reactions when tested in guinea pigs. <br />Page 6 of 15</p> <p>IDENTITY: PRO-Tekt Flexcoat, Component A</p> <p>SAFETY DATA SHEET <br />SDS No. PRO F.1.1</p> <p>For respiratory sensitization: <br />No relevant data found. <br />Specific Target Organ Systemic Toxicity (Single Exposure) <br />Evaluation of available data suggests that this material is not an STOT-SE toxicant. <br />Specific Target Organ Systemic Toxicity (Repeated Exposure) <br />Based on information for component(s): <br />In animals, effects have been reported on the following organs: <br />Kidney. <br />Liver. <br />Lung. <br />In rats, repeated dietary ingestion of diethyltoluenediamine (DETDA) has caused pancreatic, eye, liver and <br />thyroid effects. <br />May cause methemoglobinemia, thereby impairing the blood's ability to transport oxygen. <br />Carcinogenicity <br />Diethyltoluenediamine (DETDA) has caused cancer in long-term animal studies. Increased numbers of tumors <br />in the liver, thyroid and possibly the mammary glands were observed in rats given DETDA in their diet at <br />exaggerated doses for 2 years. Lung fibrosis and tumors have been observed in rats exposed to titanium <br />dioxide in two lifetime inhalation studies. Effects are believed to be due to overloading of the normal respiratory <br />clearance mechanisms caused by the extreme study conditions. Workers exposed to titanium dioxide in the <br />workplace have not shown an unusual incidence of chronic respiratory disease or lung cancer. Titanium <br />dioxide was not carcinogenic in laboratory animals in lifetime feeding studies. Lung fibrosis and tumors have <br />been observed in rats exposed to high concentrations of very fine carbon black particles for their lifetime. <br />Effects are believed to be due to overloading of the normal respiratory clearance mechanisms caused by the <br />extreme study conditions. Rats may be particularly susceptible to particle clearance overload, resulting in lung <br />injury and tumors. No increases in tumors were observed in male or female mice exposed under the same <br />conditions. <br />Teratogenicity <br />No relevant data found. <br />Reproductive toxicity <br />Based on information for component(s): In animal studies, has been shown to interfere with reproduction. <br />Mutagenicity <br />Based on information for component(s): In vitro genetic toxicity studies were negative in some cases and <br />positive in other cases. Animal genetic toxicity studies were predominantly negative. <br />Aspiration Hazard <br />Based on available information, aspiration hazard could not be determined. <br />COMPONENTS INFLUENCING TOXICOLOGY: <br />2,2,4-Trimethyl-1,3-pentanediol diisobutyrate <br />Acute inhalation toxicity <br />No adverse effects are anticipated from inhalation. <br />Maximum attainable concentration. LC50, Rat, 4 Hour, dust/mist, >6.067 mg/l No deaths occurred at this <br />concentration. <br />Diethyltoluenediamine (DETDA) <br />Acute inhalation toxicity <br />The LC50 value is greater than the Maximum Attainable Concentration. <br />Page 7 of 15</p> <p>IDENTITY: PRO-Tekt Flexcoat, Component A</p> <p>SAFETY DATA SHEET <br />SDS No. PRO F.1.1</p> <p>N,N'-Dialkylaminodiphenylmethane <br />Acute inhalation toxicity <br />At room temperature, exposure to vapor is minimal due to low volatility; vapor from heated material may <br />cause respiratory irritation. <br />The LC50 has not been determined. <br />Propylene carbonate <br />Acute inhalation toxicity <br />No adverse effects are anticipated from single exposure to vapor. <br />The LC50 has not been determined. <br />6-Methyl-2,4-bis(methylthio)phenylene-1,3-diamine <br />Acute inhalation toxicity <br />The LC50 has not been determined. <br />Unknowns <br />Acute inhalation toxicity <br />The LC50 has not been determined. <br />Titanium dioxide <br />Acute inhalation toxicity <br />LC50, Rat, male, 4 Hour, dust/mist, > 6.82 mg/l No deaths occurred at this concentration. <br />Carbon black <br />Acute inhalation toxicity <br />LC50, Rat, 1 Hour, dust/mist, 27 mg/l No deaths occurred at this concentration. <br />Carcinogenicity Component</p> <p>List</p> <p>Classification</p> <p>Titanium dioxide</p> <p>IARC</p> <p>Group 2B: Possibly carcinogenic to humans</p> <p>Carbon Black</p> <p>IARC <br />ACGIH</p> <p>Group 2B: Possibly carcinogenic to humans <br />A3: Confirmed animal carcinogen with unknown <br />relevance to humans.</p> <p>Section 12 – Ecological Information <br />Ecotoxicological information appears in this section when such data is available. <br />Toxicity <br />2,2,4-Trimethyl-1,3-pentanediol diisobutyrate <br />Acute toxicity to fish <br />Not expected to be acutely toxic to aquatic organisms. <br />Toxicity to aquatic species occurs at concentrations above material's water solubility. <br />NOEC, Lepomis macrochirus (Bluegill sunfish), flow-through test, 96 Hour, >= 6 mg/l, OECD <br />Test Guideline 203 <br />Acute toxicity to aquatic invertebrates <br />Toxicity to aquatic species occurs at concentrations above material's water solubility. <br />NOEC, Daphnia magna (Water flea), 48 Hour, >= 1.46 mg/l</p> <p>Page 8 of 15</p> <p>IDENTITY: PRO-Tekt Flexcoat, Component A</p> <p>SAFETY DATA SHEET <br />SDS No. PRO F.1.1</p> <p>Chronic toxicity to aquatic invertebrates <br />NOEC, Daphnia magna (Water flea), flow-through test, 21 d, 0.7 mg/l <br />LOEC, Daphnia magna (Water flea), flow-through test, 21 d, 1.3 mg/l <br />Diethyltoluenediamine (DETDA) <br />Acute toxicity to fish <br />Material is highly toxic to aquatic organisms on an acute basis (LC50/EC50 between 0.1 and 1 mg/L in the <br />most sensitive species tested). <br />LC50, Leuciscus idus (Golden orfe), static test, 48 Hour, 194 mg/l, OECD Test Guideline 203 or Equivalent <br />Acute toxicity to aquatic invertebrates <br />EC50, Daphnia magna (Water flea), static test, 48 Hour, 0.5 mg/l, OECD Test Guideline 202 or Equivalent <br />Acute toxicity to algae/aquatic plants <br />ErC50, Desmodesmus subspicatus (green algae), static test, 72 Hour, Growth rate, 100 mg/l, OECD Test <br />Guideline 201 <br />Toxicity to bacteria <br />EC10, Bacteria, 16 Hour, 170 mg/l <br />N,N'-Dialkylaminodiphenylmethane <br />Acute toxicity to fish <br />Material is highly toxic to aquatic organisms on an acute basis (LC50/EC50 between 0.1 and 1 mg/L in the <br />most sensitive species tested). <br />Acute toxicity to aquatic invertebrates <br />For similar material(s): <br />EC50, Daphnia magna (Water flea), 48 Hour, 0.35 mg/l, OECD Test Guideline 202 <br />Chronic toxicity to aquatic invertebrates <br />For similar material(s): <br />NOEC, Daphnia magna (Water flea), 21 d, 0.0053 mg/l <br />Propylene carbonate <br />Acute toxicity to fish <br />Material is practically non-toxic to aquatic organisms on an acute basis (LC50/EC50/EL50/LL50 >100 mg/L <br />in the most sensitive species tested). <br />LC50, Cyprinus carpio (Carp), semi-static test, 96 Hour, > 1,000 mg/l <br />Acute toxicity to aquatic invertebrates <br />EC50, Daphnia magna (Water flea), 48 Hour, > 1,000 mg/l, OECD Test Guideline 202 or Equivalent <br />Acute toxicity to algae/aquatic plants <br />EC50, alga Scenedesmus sp., 72 Hour, Biomass, > 900 mg/l, Method Not Specified. <br />Toxicity to bacteria <br />EC50, activated sludge, 30 min, > 800 mg/l, OECD 209 Test <br />6-Methyl-2,4-bis(methylthio)phenylene-1,3-diamine <br />Acute toxicity to fish <br />Material is highly toxic to aquatic organisms on an acute basis (LC50/EC50 between 0.1 and 1 mg/L in the <br />most sensitive species tested). <br />LC50, Oncorhynchus mykiss (rainbow trout), 96 Hour, 7.3 mg/l, OECD Test Guideline 203 or Equivalent <br />Acute toxicity to aquatic invertebrates <br />EC50, Daphnia magna (Water flea), 48 Hour, 0.9 mg/l, OECD Test Guideline 202 or Equivalent <br />Page 9 of 15</p> <p>IDENTITY: PRO-Tekt Flexcoat, Component A</p> <p>SAFETY DATA SHEET <br />SDS No. PRO F.1.1</p> <p>Acute toxicity to algae/aquatic plants <br />EC50, Pseudokirchneriella subcapitata (microalgae), 72 Hour, Growth rate inhibition, 7.6 mg/l, OECD Test <br />Guideline 201 <br />Toxicity to bacteria <br />EC50, activated sludge, Respiration inhibition, 3 Hour, 1,000 mg/l, OECD 209 Test <br />Unknowns <br />Acute toxicity to fish <br />No relevant data found. <br />Titanium dioxide <br />Acute toxicity to fish <br />Material is practically non-toxic to aquatic organisms on an acute basis (LC50/EC50/EL50/LL50 >100 mg/L <br />in the most sensitive species tested). <br />NOEC mortality, Leuciscus idus (Golden orfe), static test, 48 Hour, > 1,000 mg/l <br />Acute toxicity to aquatic invertebrates <br />EC50, Daphnia magna (Water flea), static test, 48 Hour, > 1,000 mg/l <br />Carbon black <br />Acute toxicity to fish <br />Material is practically non-toxic to aquatic organisms on an acute basis (LC50/EC50/EL50/LL50 >100 mg/L <br />in the most sensitive species tested). <br />LC50, Leuciscus idus (Golden orfe), static test, 96 Hour, > 1,000 mg/l, OECD Test Guideline 203 or <br />Equivalent <br />Acute toxicity to aquatic invertebrates <br />EC50, Daphnia magna (Water flea), 24 Hour, > 5,600 mg/l, OECD Test Guideline 202 or Equivalent <br />Persistence and degradability <br />2,2,4-Trimethyl-1,3-pentanediol diisobutyrate <br />Biodegradability: Material shows rapid biodegradation. Attains the pass level of 60% biodegradation <br />(based on oxygen consumption or CO2 evolution) or 70% biodegradation (based on dissolved organic <br />carbon loss) within 28 days. <br />10-day Window: Fail <br />Biodegradation: 70.73 % <br />Exposure time: 28 d <br />Method: OECD Test Guideline 301B <br />Theoretical Oxygen Demand: 2.40 mg/mg <br />Stability in Water (1/2-life) <br />Hydrolysis, half-life, 178 d, pH 9, Measured <br />Photodegradation <br />Test Type: Half-life (indirect photolysis) <br />Sensitization: OH radicals <br />Atmospheric half-life: 0.933 d <br />Method: Estimated. <br />Diethyltoluenediamine (DETDA) <br />Biodegradability: Material is not readily biodegradable according to OECD/EEC guidelines. <br />10-day Window: Fail <br />Biodegradation: < 1 % <br />Page 10 of 15</p> <p>IDENTITY: PRO-Tekt Flexcoat, Component A</p> <p>SAFETY DATA SHEET <br />SDS No. PRO F.1.1</p> <p>Exposure time: 28 d <br />Method: OECD Test Guideline 301D or Equivalent <br />Theoretical Oxygen Demand: 3.23 mg/mg <br />N,N'-Dialkylaminodiphenylmethane <br />Theoretical Oxygen Demand: 3.20 mg/mg <br />Photodegradation <br />Test Type: Half-life (indirect photolysis) <br />Sensitization: OH radicals <br />Atmospheric half-life: 0.070 d <br />Method: Estimated. <br />Propylene carbonate <br />Biodegradability: Material is readily biodegradable. Passes OECD test(s) for ready biodegradability. <br />Material is ultimately biodegradable (reaches > 70% mineralization in OECD test(s) for inherent <br />biodegradability). <br />10-day Window: Pass <br />Biodegradation: 94 % <br />Exposure time: 28 d <br />Method: OECD Test Guideline 301E or Equivalent <br />10-day Window: Not applicable <br />Biodegradation: > 97 % <br />Exposure time: 28 d <br />Method: OECD Test Guideline 302B or Equivalent <br />Theoretical Oxygen Demand: 1.25 mg/mg <br />Photodegradation <br />Test Type: Half-life (indirect photolysis) <br />Sensitization: OH radicals <br />Atmospheric half-life: 34 Hour <br />Method: Estimated. <br />6-Methyl-2,4-bis(methylthio)phenylene-1,3-diamine <br />Biodegradability: Material is not readily biodegradable according to OECD/EEC guidelines. <br />10-day Window: Fail <br />Biodegradation: 0 % <br />Exposure time: 28 d <br />Method: OECD Test Guideline 301D or Equivalent <br />Theoretical Oxygen Demand: 2.69 mg/mg <br />Photodegradation <br />Test Type: Half-life (indirect photolysis) <br />Sensitization: OH radicals <br />Atmospheric half-life: 0.053 d <br />Method: Estimated. <br />Unknowns <br />Biodegradability: No relevant data found. <br />Titanium dioxide <br />Page 11 of 15</p> <p>IDENTITY: PRO-Tekt Flexcoat, Component A</p> <p>SAFETY DATA SHEET <br />SDS No. PRO F.1.1</p> <p>Biodegradability: Biodegradation is not applicable. <br />Carbon black <br />Biodegradability: Biodegradation is not applicable. <br />Bioaccumulative potential <br />2,2,4-Trimethyl-1,3-pentanediol diisobutyrate <br />Bioaccumulation: Bioconcentration potential is low (BCF < 100 or Log Pow < 3). <br />Partition coefficient: n-octanol/water(log Pow): > 4.11 at 25 °C OECD Test Guideline 107 or Equivalent <br />Bioconcentration factor (BCF): 5.2 - 31 Cyprinus carpio (Carp) Measured <br />Diethyltoluenediamine (DETDA) <br />Bioaccumulation: Bioconcentration potential is low (BCF < 100 or Log Pow < 3). <br />Partition coefficient: n-octanol/water(log Pow): 1.17 Measured <br />Bioconcentration factor (BCF): 3 Estimated. <br />N,N'-Dialkylaminodiphenylmethane <br />Bioaccumulation: Bioconcentration potential is high (BCF > 3000 or Log Pow between 5 and 7). <br />Partition coefficient: n-octanol/water(log Pow): 6.08 Estimated. <br />Bioconcentration factor (BCF): 9,500 Estimated. <br />Propylene carbonate <br />Bioaccumulation: Bioconcentration potential is low (BCF < 100 or Log Pow < 3). Potential for mobility in <br />soil is very high (Koc between 0 and 50). Given its very low Henry's constant, volatilization from natural <br />bodies of water or moist soil is not expected to be an important fate process. Bioconcentration potential is <br />low (BCF < 100 or Log Pow < 3). <br />Partition coefficient: n-octanol/water(log Pow): -0.41 Measured <br />6-Methyl-2,4-bis(methylthio)phenylene-1,3-diamine <br />Bioaccumulation: Bioconcentration potential is low (BCF < 100 or Log Pow < 3). <br />Partition coefficient: n-octanol/water(log Pow): 2.5 at 20 °C Measured <br />Bioconcentration factor (BCF): 9.8 - 25 Fish No information available. <br />Unknowns <br />Bioaccumulation: No relevant data found. <br />Titanium dioxide <br />Bioaccumulation: Partitioning from water to n-octanol is not applicable. <br />Carbon black <br />Bioaccumulation: No relevant data found. <br />Mobility in soil <br />2,2,4-Trimethyl-1,3-pentanediol diisobutyrate <br />Potential for mobility in soil is low (Koc between 500 and 2000). <br />Partition coefficient (Koc): 610 Estimated. <br />Diethyltoluenediamine (DETDA) <br />Potential for mobility in soil is low (Koc between 500 and 2000). <br />Given its very low Henry's constant, volatilization from natural bodies of water or moist soil is not expected to <br />be an important fate process. <br />Page 12 of 15</p> <p>IDENTITY: PRO-Tekt Flexcoat, Component A</p> <p>SAFETY DATA SHEET <br />SDS No. PRO F.1.1</p> <p>Partition coefficient (Koc): 551.2 Estimated. <br />N,N'-Dialkylaminodiphenylmethane <br />Expected to be relatively immobile in soil (Koc > 5000). <br />Given its very low Henry's constant, volatilization from natural bodies of water or moist soil is not expected <br />to be an important fate process. <br />Partition coefficient (Koc): > 5000 Estimated. <br />Propylene carbonate <br />Potential for mobility in soil is very high (Koc between 0 and 50). <br />Given its very low Henry's constant, volatilization from natural bodies of water or moist soil is not expected <br />to be an important fate process. <br />Partition coefficient (Koc): 15 Estimated. <br />6-Methyl-2,4-bis(methylthio)phenylene-1,3-diamine <br />Potential for mobility in soil is low (Koc between 500 and 2000). <br />Given its very low Henry's constant, volatilization from natural bodies of water or moist soil is not expected <br />to be an important fate process. <br />Partition coefficient (Koc): 1249 Estimated. <br />Unknowns <br />No relevant data found. <br />Titanium dioxide <br />No data available. <br />Carbon black <br />No relevant data found.</p> <p>Section 13 – Disposal Considerations <br />Disposal methods: NOTICE: Research sample for use by qualified personnel only. Upon completion of tests, <br />dispose of material and container safely and in accord with federal, state/provincial and local laws and <br />regulations. If further information is needed on disposal or use, consult your supplier.</p> <p>Section 14 – Transport Information <br />USDOT (Domestic Surface)</p> <p>Not regulated for transport.</p> <p>Classification for SEA transport (IMO-IMDG): <br />Proper shipping name</p> <p>ENVIRONMENTALLY HAZARDOUS SUBSTANCE, <br />LIQUID, N.O.S.(Diethyltoluenediamine, N,N'Dialkylaminodiphenylmethane) <br />UN 3082 <br />9 <br />III <br />Diethyltoluenediamine, N,N'Dialkylaminodiphenylmethane <br />Consult IMO regulations before transporting ocean bulk</p> <p>UN number <br />Class <br />Packing group <br />Marine pollutant <br />Transport in bulk according to Annex I or II <br />of MARPOL 73/78 and the IBC or IGC Code</p> <p>Page 13 of 15</p> <p>IDENTITY: PRO-Tekt Flexcoat, Component A</p> <p>Classification for AIR transport (IATA/ICAO): <br />Proper shipping name <br />UN number <br />Class <br />Packing group</p> <p>SAFETY DATA SHEET <br />SDS No. PRO F.1.1</p> <p>Environmentally hazardous substance, liquid, n.o.s. <br />(Diethyltoluenediamine, N,N'- Dialkylaminodiphenylmethane) <br />UN 3082 <br />9 <br />III</p> <p>This information is not intended to convey all specific regulatory or operational requirements/information <br />relating to this product. Transportation classifications may vary by container volume and may be influenced by <br />regional or country variations in regulations. Additional transportation system information can be obtained <br />through an authorized sales or customer service representative. It is the responsibility of the transporting <br />organization to follow all applicable laws, regulations and rules relating to the transportation of the material.</p> <p>Section 15 – Regulatory Information <br />Superfund Amendments and Reauthorization Act of 1986 Title III (Emergency Planning and Community <br />Right-to-Know Act of 1986) Sections 311 and 312 <br />Acute Health Hazard <br />Chronic Health Hazard <br />Superfund Amendments and Reauthorization Act of 1986 Title III (Emergency Planning and Community <br />Right-to-Know Act of 1986) Section 313 <br />To the best of our knowledge, this product does not contain chemicals at levels which require reporting under <br />this statute. <br />Pennsylvania Worker and Community Right-To-Know Act: <br />The following chemicals are listed because of the additional requirements of Pennsylvania law: <br />Components <br />Titanium dioxide <br />Carbon black</p> <p>CASRN <br />13463-67-7 <br />1333-86-4</p> <p>California Proposition 65 (Safe Drinking Water and Toxic Enforcement Act of 1986) <br />WARNING: This product contains a chemical(s) known to the State of California to cause cancer. <br />Components <br />Titanium dioxide <br />Carbon black <br />Propylene oxide</p> <p>CASRN <br />13463-67-7 <br />1333-86-4 <br />75-56-9</p> <p>United States TSCA Inventory (TSCA) <br />All components of this product are in compliance with the inventory listing requirements of the U.S. Toxic <br />Substances Control Act (TSCA) Chemical Substance Inventory.</p> <p>Section 16 – Other Information <br />Other information <br />For research use only. <br />Revision <br />Identification Number: 103002324 / A001 / Issue Date: 08/02/2017 / Version: 0.0 <br />Page 14 of 15</p> <p>IDENTITY: PRO-Tekt Flexcoat, Component A</p> <p>SAFETY DATA SHEET <br />SDS No. PRO F.1.1</p> <p>Abbreviations and acronyms: <br />USDOT: <br />ACGIH: <br />DOW IHG: <br />IMDG:</p> <p>OSHA Z-1:</p> <p>SKIN: <br />TWA: <br />IATA: <br />CAS: <br />LC50:</p> <p>United States Department of Transportation. <br />USA ACGIH Threshold Limit Vales (TLV) <br />Dow Industrial Hygiene Guideline <br />International Maritime Code for Dangerous Goods. <br />USA. Occupational Exposure Limits (OSHA) - Table Z-1 Limits for Air Contaminants <br />Absorbed via skin <br />Time weighted average <br />International Air Transport Association. <br />Chemical Abstracts Service (Division of the American Chemical Society). <br />Lethal concentration, 50 percent.</p> <p>SDS prepared by:</p> <p>Aquafin product safety department.</p> <p>DISCLAIMER: <br />We believe the statements, technical information and recommendations contained herein are reliable, but they are <br />given without warranty or guarantee of any kind, expressed or implied, and we assume no responsibility for any <br />loss, damage, or expense, direct or consequential, arising out of their use. Aquafin shall not be responsible for the <br />use of this product in a manner to infringe on any patent or any other intellectual property rights held by others. <br />END OFsafety <br />MSDS <br />(April 09, 2015) <br />User is responsible for determining appropriate <br />measures and for applying the legislation <br />covering his own <br />activities. We recommend that user makes tests to determine the suitability of a product for its particular purpose <br />prior to use. <br />END OF SDS</p> <p>Page 15 of 15</p> <p>(February 20, 2019)</p>
