SDS_AQUAFIN-PRO-Tekt FLEXCOAT_B-Component-iso.pdf
11 Pages
226 KB
Download
<h1>SDS_AQUAFIN-PRO-Tekt FLEXCOAT_B-Component-iso.pdf</h1> <p>IDENTITY:</p> <p>SAFETY DATA SHEET</p> <p>PRO-Tekt Flexcoat, Component B</p> <p>SDS No. PRO F.1.2</p> <p>Date prepared: OCTOBER 2017 <br />Date revised: FEBRUARY 2019</p> <p>SDS No. PRO F.1.2</p> <p>Section 1 – Product Identification <br />IDENTITY:</p> <p>Product Name:</p> <p>PRO-TEKT FLEXCOAT, Component B</p> <p>AQUAFIN, INC. <br />505 BLUE BALL RD. #160 <br />ELKTON, MD 21921</p> <p>Emergency Phone No. <br />Information Phone No.</p> <p>info@aquafin.net</p> <p>Recommended use of the chemical and restriction on use:</p> <p>(800) 394-1410 <br />(410) 392-2300</p> <p>www.aquafin.net</p> <p>Refer to the product technical data sheet. <br />For industrial and professional users.</p> <p>Section 2 – Hazards Identification <br />GHS Classification: <br />This material is hazardous under the criteria of the Federal OSHA Hazard Communication Standard 29CFR <br />1910.1200. <br />Acute toxicity - Category 4 - Inhalation <br />Eye irritation - Category 2A <br />Respiratory sensitization - Category 1 <br />Skin sensitization - Category 1 <br />Carcinogenicity - Category 2</p> <p>GHS Label element: <br />Hazard Pictograms <br />GHS07 <br />Signal Word:</p> <p>GHS08</p> <p>DANGER!</p> <p>Hazard Statements: <br />H317 <br />May cause an allergic skin reaction. <br />H319 <br />Causes serious eye irritation. <br />H332 <br />Harmful if inhaled. <br />H334 <br />May cause allergy or asthma symptoms or breathing difficulties if inhaled. <br />H351 <br />Suspected of causing cancer. <br />Precautionary Statements: <br />Prevention: <br />P201 <br />Obtain special instructions before use. <br />P202 <br />Do not handle until all safety precautions have been read and understood. <br />P261 <br />Avoid breathing dust/ fume/ gas/ mist/ vapors/ spray. <br />P264 <br />Wash skin thoroughly after handling. <br />P271 <br />Use only outdoors or in a well-ventilated area. <br />P272 <br />Contaminated work clothing should not be allowed out of the workplace. <br />P280 <br />Wear protective gloves/ protective clothing/ eye protection/ face protection. <br />P285 <br />In case of inadequate ventilation, wear respiratory protection. <br />Response: <br />P302+352</p> <p>IF ON SKIN: Wash with plenty of soap and water. <br />Page 1 of 11</p> <p>IDENTITY:</p> <p>PRO-Tekt Flexcoat, Component B</p> <p>P304+340+312</p> <p>SAFETY DATA SHEET <br />SDS No. PRO F.1.2</p> <p>P308+313 <br />P333+313 <br />P337+313 <br />P363</p> <p>IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a <br />POISON CENTER/doctor if you feel unwell. <br />IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if <br />present and easy to do. Continue rinsing. <br />IF exposed or concerned: Get medical advice/ attention. <br />If skin irritation or rash occurs: Get medical advice/ attention. <br />If eye irritation persists: Get medical advice/ attention. <br />Wash contaminated clothing before reuse.</p> <p>Storage: <br />P405</p> <p>Store locked up.</p> <p>Disposal: <br />P501:</p> <p>Dispose of contents/container to an approved waste disposal site.</p> <p>Other hazards:</p> <p>Water Reactive.</p> <p>P305+351+338</p> <p>Section 3 – Composition / Information on Ingredients <br />This product is a mixture.</p> <p>Hazardous Components <br />TDI Prepolymer <br />2,4-Toluene diisocyanate</p> <p>CAS No.</p> <p>Weight %</p> <p>Trade Secret</p> <p>>95.0%</p> <p>584-84-9</p> <p>>+1.0 - <=3.0%</p> <p>There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations <br />applicable, are classified as hazardous to health or the environment and hence not require reporting in this section.</p> <p>Section 4 – First Aid Measures <br />General Advice:</p> <p>First Aid responders should pay attention to self-protection and use the recommended <br />protective clothing (chemical resistant gloves, splash protection). If potential for <br />exposure exists refer to Section 8 for specific personal protective equipment.</p> <p>After Inhalation:</p> <p>Move person to fresh air. If not breathing, give artificial respiration; if by mouth to <br />mouth use rescuer protection (pocket mask, etc). If breathing is difficult, oxygen <br />should be administered by qualified personnel. Call a physician or transport to a <br />medical facility.</p> <p>After Ingestion:</p> <p>If swallowed, seek medical attention. Do not induce vomiting unless directed to do so <br />by medical personnel.</p> <p>After Skin Contact:</p> <p>Remove material from skin immediately by washing with soap and plenty of water. <br />Remove contaminated clothing and shoes while washing. Seek medical attention if <br />irritation persists. Wash clothing before reuse. An MDI skin decontamination study <br />demonstrated that cleaning very soon after exposure is important, and that a <br />polyglycol-based skin cleanser or corn oil may be more effective than soap and water. <br />This may also apply to other isocyanates. Discard items which cannot be <br />decontaminated, including leather articles such as shoes, belts and watchbands. <br />Safety shower should be located in immediate work area. <br />Page 2 of 11</p> <p>IDENTITY:</p> <p>PRO-Tekt Flexcoat, Component B</p> <p>After Eye Contact:</p> <p>SAFETY DATA SHEET <br />SDS No. PRO F.1.2</p> <p>Immediately flush eyes with water; remove contact lenses, if present, after the first 5 <br />minutes, then continue flushing eyes for at least 15 minutes. Obtain medical attention <br />without delay, preferably from an ophthalmologist. Eye wash fountain should be <br />located in immediate work area.</p> <p>Most important symptoms and effects, both acute and delayed: Aside from the information found under <br />Description of first aid measures (above) and Indication of immediate medical attention and special treatment <br />needed (below), any additional important symptoms and effects are described in Section 11: Toxicology <br />Information. <br />Indication of any immediate medical attention and special treatment needed <br />Notes to physician: <br />Excessive exposure may aggravate preexisting asthma and other respiratory <br />disorders (e.g. emphysema, bronchitis, reactive airways dysfunction syndrome). <br />Maintain adequate ventilation and oxygenation of the patient. May cause respiratory <br />sensitization or asthma-like symptoms. Bronchodilators, expectorants and antitussives <br />may be of help. Treat bronchospasm with inhaled beta2 agonist and oral or parenteral <br />corticosteroids. Respiratory symptoms, including pulmonary edema, may be delayed. <br />Persons receiving significant exposure should be observed 24-48 hours for signs of <br />respiratory distress. If you are sensitized to diisocyanates, consult your physician <br />regarding working with other respiratory irritants or sensitizers. Cholinesterase <br />inhibition has been noted in human exposure but is not of benefit in determining <br />exposure and is not correlated with signs of exposure. Treatment of exposure should <br />be directed at the control of symptoms and the clinical condition of the patient.</p> <p>Section 5 – Fire Fighting Measures <br />Extinguishing Media: Water fog or fine spray. Dry chemical fire extinguishers. Carbon dioxide fire <br />extinguishers. Foam. Alcohol resistant foams (ATC type) are preferred. General purpose synthetic foams <br />(including AFFF) or protein foams may function, but will be less effective. <br />Unsuitable extinguishing media: Do not use direct water stream. May spread fire. <br />Special hazards arising from the substance or mixture: <br />Hazardous combustion products: During a fire, smoke may contain the original material in addition to <br />combustion products of varying composition which may be toxic and/or irritating. Combustion products may <br />include and are not limited to: Nitrogen oxides. Isocyanates. Hydrogen cyanide. Carbon monoxide. Carbon <br />dioxide. <br />Unusual Fire and Explosion Hazards: Material reacts slowly with water, releasing carbon dioxide which can <br />cause pressure buildup and rupture of closed containers. Elevated temperatures accelerate this reaction. <br />Container may rupture from gas generation in a fire situation. Violent steam generation or eruption may occur <br />upon application of direct water stream to hot liquids. Dense smoke is produced when product burns. <br />Electrically ground and bond all equipment. <br />. <br />Advice for firefighters <br />Fire Fighting Procedures: Keep people away. Isolate fire and deny unnecessary entry. Stay upwind. Keep <br />out of low areas where gases (fumes) can accumulate. Water is not recommended, but may be applied in large <br />quantities as a fine spray when other extinguishing agents are not available. Fight fire from protected location <br />or safe distance. Consider the use of unmanned hose holders or monitor nozzles. Immediately withdraw all <br />personnel from the area in case of rising sound from venting safety device or discoloration of the container. Do <br />not use direct water stream. May spread fire. Move container from fire area if this is possible without hazard. <br />Use water spray to cool fire-exposed containers and fire-affected zone until fire is out. Contain fire water run-off <br />if possible. Fire water run-off, if not contained, may cause environmental damage. Review the "Accidental <br />Release Measures" and the "Ecological Information" sections of this (M)SDS. <br />Page 3 of 11</p> <p>IDENTITY:</p> <p>PRO-Tekt Flexcoat, Component B</p> <p>SAFETY DATA SHEET <br />SDS No. PRO F.1.2</p> <p>Special protective equipment for firefighters: Wear positive-pressure self-contained breathing apparatus <br />(SCBA) and protective fire-fighting clothing (includes fire-fighting helmet, coat, trousers, boots, and gloves). <br />Avoid contact with this material during fire fighting operations. If contact is likely, change to full chemical <br />resistant fire-fighting clothing with self-contained breathing apparatus. If this is not available, wear full chemical <br />resistant clothing with self-contained breathing apparatus and fight fire from a remote location. For protective <br />equipment in post-fire or non-fire clean-up situations, refer to the relevant sections.</p> <p>Section 6 – Accidental Release Measures <br />Personal precautions, protective equipment and emergency procedures: Isolate area. Keep unnecessary <br />and unprotected personnel from entering the area. Refer to section 7, Handling, for additional precautionary <br />measures. Keep personnel out of low areas. Keep upwind of spill. Ventilate area of leak or spill. See Section 10 <br />for more specific information. Use appropriate safety equipment. For additional information, refer to Section 8, <br />Exposure Controls and Personal Protection. <br />Environmental precautions: Prevent from entering into soil, ditches, sewers, waterways and/or groundwater. <br />See Section 12, Ecological Information. <br />Methods and materials for containment and cleaning up: Contain spilled material if possible. Absorb with <br />materials such as: Dirt. Vermiculite. Sand. Clay. Do NOT use absorbent materials such as: Cement powder <br />(Note: may generate heat). Collect in suitable and properly labeled open containers. Do not place in sealed <br />containers. Suitable containers include: Metal drums. Plastic drums. Polylined fiber pacs. Wash the spill site <br />with large quantities of water. Attempt to neutralize by adding suitable decontaminant solution: Formulation 1: <br />sodium carbonate 5 - 10%; liquid detergent 0.2 - 2%; water to make up to 100%, OR Formulation 2: <br />concentrated ammonia solution 3 - 8%; liquid detergent 0.2 - 2%; water to make up to 100%. If ammonia is <br />used, use good ventilation to prevent vapor exposure. Contact your supplier for clean-up assistance. See <br />Section 13, Disposal Considerations, for additional information.</p> <p>Section 7 – Handling and Storage <br />Precautions for safe handling: Avoid contact with eyes. Avoid prolonged or repeated contact with skin. Avoid <br />breathing vapor. Wash thoroughly after handling. Keep container closed. Use with adequate ventilation. Spills <br />of these organic materials on hot fibrous insulations may lead to lowering of the auto-ignition temperatures <br />possibly resulting in spontaneous combustion. See Section 8, EXPOSURE CONTROLS AND PERSONAL <br />PROTECTION. <br />Conditions for safe storage: Protect from atmospheric moisture. Store in a dry place. Do not store product <br />contaminated with water to prevent potential hazardous reaction. Avoid moisture. See Section 10 for more <br />specific information. Store in accordance with good manufacturing practices.</p> <p>Section 8 – Exposure Controls / Personal Protection <br />Control Parameters: <br />Exposure limits are listed on next page, if they exist. <br />Component <br />2,4 Toluene diisocyanate</p> <p>Regulation <br />DOW IHG</p> <p>Type of listing <br />TWA Inhalable fraction and vapor <br />Page 4 of 11</p> <p>Value/Notation <br />0.005 ppm</p> <p>IDENTITY:</p> <p>PRO-Tekt Flexcoat, Component B</p> <p>SAFETY DATA SHEET <br />SDS No. PRO F.1.2</p> <p>DOW IHG</p> <p>TWA</p> <p>SKIN, DSEN, RSEN</p> <p>DOW IHG</p> <p>C Inhalable fraction</p> <p>0.002 ppm</p> <p>DOW IHG</p> <p>C</p> <p>SKIN, DSEN, RSEN</p> <p>ACGIH</p> <p>TWA</p> <p>SKIN, DSEN, RSEN</p> <p>ACGIH</p> <p>STEL</p> <p>SKIN, DSEN, RSEN</p> <p>OSHA Z-1</p> <p>C</p> <p>0.14 mg/m 0.02 ppm</p> <p>ACGIH</p> <p>TWA Inhalable fraction and vapor</p> <p>0.001 ppm</p> <p>ACGIH</p> <p>STEL Inhalable fraction and vapor</p> <p>0.005 ppm</p> <p>3</p> <p>Exposure controls: <br />Engineering controls: Use only with adequate ventilation. Local exhaust ventilation may be necessary for <br />some operations. Provide general and/or local exhaust ventilation to control airborne levels below the exposure <br />guidelines. Exhaust systems should be designed to move the air away from the source of vapor/aerosol <br />generation and people working at this point. The odor and irritancy of this material are inadequate to warn of <br />excessive exposure. <br />Eye/face protection: Use chemical goggles. Eye wash fountain should be located in immediate work area. <br />Skin protection: <br />Hand protection: Use gloves chemically resistant to this material. Examples of preferred glove barrier <br />materials include: Butyl rubber. Chlorinated polyethylene. Polyethylene. Ethyl vinyl alcohol laminate <br />("EVAL"). Examples of acceptable glove barrier materials include: Neoprene. Nitrile/butadiene rubber <br />("nitrile" or "NBR"). Polyvinyl chloride ("PVC" or "vinyl"). Viton. NOTICE: The selection of a specific glove for <br />a particular application and duration of use in a workplace should also take into account all relevant <br />workplace factors such as, but not limited to: Other chemicals which may be handled, physical <br />requirements (cut/puncture protection, dexterity, thermal protection), potential body reactions to glove <br />materials, as well as the instructions/specifications provided by the glove supplier. <br />Other protection: Use protective clothing chemically resistant to this material. Selection of specific items such <br />as face shield, boots, apron, or full body suit will depend on the task. Remove contaminated clothing <br />immediately, wash skin area with soap and water. Contaminated clothing should be disposed of properly or <br />decontaminated and laundered before reuse. Items which cannot be decontaminated, such as shoes, belts and <br />watchbands, should be removed and disposed of properly. <br />Respiratory protection: Atmospheric levels should be maintained below the exposure guideline. When <br />atmospheric levels may exceed the exposure guideline, use an approved air-purifying respirator equipped with <br />an organic vapor sorbent and a particle filter. For situations where the atmospheric levels may exceed the level <br />for which an air-purifying respirator is effective, use a positive-pressure air-supplying respirator (air line or selfcontained breathing apparatus). For emergency response or for situations where the atmospheric level is <br />unknown, use an approved positive-pressure self-contained breathing apparatus or positive-pressure air line <br />with auxiliary self-contained air supply. <br />The following should be effective types of air-purifying respirators: Organic vapor cartridge with a particulate <br />pre-filter.</p> <p>Section 9 – Physical and Chemical Properties <br />Appearance: <br />Physical State <br />Color <br />Odor <br />Odor Threshhold</p> <p>Liquid <br />Clear <br />Pungent <br />No test data available. <br />Page 5 of 11</p> <p>IDENTITY:</p> <p>PRO-Tekt Flexcoat, Component B</p> <p>pH <br />Melting point/range <br />Freezing point <br />Boiling point <br />Flash point <br />Evaporation Rate <br />Flammability (solid, gas) <br />Lower explosion limit <br />Upper explosion limit <br />Vapor Pressure <br />Relative Vapor Density <br />Relative Density <br />Water Solubility <br />Partition coefficient: <br />n-octanol/water <br />Auto-ignition temperature <br />Decomposition temperature <br />Kinematic Viscosity <br />Explosive properties <br />Oxidizing properties <br />Molecular weight</p> <p>SAFETY DATA SHEET <br />SDS No. PRO F.1.2</p> <p>No data available. <br />No data available. <br />No data available. <br />No data available. <br />Closed cup >=93.3°C (>=199.9°F) Estimated. <br />Open cup >= 93.3°C (>=199.9°F) Estimated <br />Not available. <br />Not applicable. <br />Liquid <br />Liquid <br />No data available. <br />No data available. <br />No data available. <br />No data available. <br />No data available. <br />No data available. <br />No test data available. <br />No information available. <br />No data available. <br />No data available. <br />Not reported</p> <p>NOTE: The physical data presented above are typical values and should not be construed as a specification.</p> <p>Section 10 – Stability and Reactivity <br />Reactivity: Products based on diisocyanates like TDI and MDI react with many materials to release heat. The <br />reaction rate increases with temperature as well as with increased contact; these reactions can become violent. <br />Contact is increased by stirring or if the other material acts as a solvent. Products based on diisocyanates such <br />as TDI and MDI are not soluble in water and will sink to the bottom, but react slowly at the interface. The <br />reaction forms carbon dioxide gas and a layer of solid polyurea. <br />Chemical stability: Stable under recommended storage conditions. See Storage, Section 7. <br />Possibility of hazardous reactions: Can occur. Exposure to elevated temperatures can cause product to <br />decompose and generate gas. This can cause pressure build-up and/or rupturing of closed containers. <br />Polymerization can be catalyzed by: Strong bases. Water. <br />Conditions to avoid: Exposure to elevated temperatures can cause product to decompose. Generation of gas <br />during decomposition can cause pressure in closed systems. Pressure build-up can be rapid. Avoid moisture. <br />Material reacts slowly with water, releasing carbon dioxide which can cause pressure buildup and rupture of <br />closed containers. Elevated temperatures accelerate this reaction. <br />Incompatible materials: Avoid contact with: Acids. Alcohols. Amines. Water. Ammonia. Bases. Metal <br />compounds. Moist air. Strong oxidizers. Products based on diisocyanates like TDI and MDI react with many <br />materials to release heat. The reaction rate increases with temperature as well as with increased contact; <br />these reactions can become violent. Contact is increased by stirring or if the other material acts as a solvent. <br />Products based on diisocyanates such as TDI and MDI are not soluble in water and will sink to the bottom, but <br />react slowly at the interface. The reaction forms carbon dioxide gas and a layer of solid polyurea. Avoid contact <br />with metals such as: Aluminum. Zinc. Brass. Tin. Copper. Galvanized metals. Avoid contact with absorbent <br />materials such as: Moist organic absorbents. Avoid unintended contact with polyols. The reaction of polyols <br />and isocyanates generate heat. <br />Page 6 of 11</p> <p>IDENTITY:</p> <p>PRO-Tekt Flexcoat, Component B</p> <p>SAFETY DATA SHEET <br />SDS No. PRO F.1.2</p> <p>Hazardous decomposition products: Decomposition products depend upon temperature, air supply and the <br />presence of other materials. Gases are released during decomposition.</p> <p>Section 11 – Toxicological Information <br />Toxicological information appears in this section when such data is available. <br />Acute toxicity <br />Acute oral toxicity <br />Low toxicity if swallowed. Small amounts swallowed incidentally as a result of normal handling operations <br />are not likely to cause injury; however, swallowing larger amounts may cause injury. <br />Single dose oral LD50 has not been determined. <br />Acute dermal toxicity <br />Prolonged skin contact is unlikely to result in absorption of harmful amounts. <br />The dermal LD50 has not been determined. <br />Acute inhalation toxicity <br />Vapor concentrations are attainable which could be hazardous on single exposure. Excessive exposure <br />to TDI may cause severe irritation of the upper respiratory tract and lungs, fluid in the lungs, permanent <br />decrease of lung function, neurologic disorders, cholinesterase depression and gastrointestinal distress. <br />Effects may be delayed. <br />As product: The LC50 has not been determined. <br />Skin corrosion/irritation <br />Prolonged contact may cause slight skin irritation with local redness. <br />May cause more severe response if skin is abraded (scratched or cut). <br />Serious eye damage/eye irritation <br />May cause moderate eye irritation. <br />May cause moderate corneal injury. <br />Sensitization <br />Skin contact may cause an allergic skin reaction. <br />Animal studies have shown that skin contact with isocyanates may play a role in respiratory sensitization. <br />May cause allergic respiratory reaction. <br />Re-exposure to extremely low isocyanate concentrations may cause allergic respiratory reactions in individuals <br />already sensitized. <br />Asthma-like symptoms may include coughing, difficult breathing and a feeling of tightness in the chest. <br />Occasionally, breathing difficulties may be life threatening. <br />Specific Target Organ Systemic Toxicity (Single Exposure) <br />Evaluation of available data suggests that this material is not an STOT-SE toxicant. <br />Specific Target Organ Systemic Toxicity (Repeated Exposure) <br />No relevant data found. <br />Carcinogenicity <br />An oral study in which high doses of TDI were reported to cause cancer in animals has been found to contain <br />numerous deficiencies which compromise the validity of the study. TDI did not cause cancer in laboratory <br />animals exposed by inhalation, the most likely route of exposure.</p> <p>Page 7 of 11</p> <p>IDENTITY:</p> <p>PRO-Tekt Flexcoat, Component B</p> <p>SAFETY DATA SHEET <br />SDS No. PRO F.1.2</p> <p>Teratogenicity <br />No relevant data found. <br />Reproductive toxicity <br />No relevant data found. <br />Mutagenicity <br />In vitro genetic toxicity studies were negative for component(s) tested. <br />Aspiration Hazard <br />Based on physical properties, not likely to be an aspiration hazard. <br />COMPONENTS INFLUENCING TOXICOLOGY: <br />TDI Prepolymer <br />Acute oral toxicity <br />Single dose oral LD50 has not been determined. LD50, Rat, > 5,000 mg/kg Estimated. <br />Acute dermal toxicity <br />The dermal LD50 has not been determined. LD50, Rabbit, > 5,000 mg/kg Estimated. <br />Acute inhalation toxicity <br />At room temperature, exposure to vapor is minimal due to low volatility; single exposure is not likely to be <br />hazardous. <br />As product: The LC50 has not been determined. <br />2,4-Toluene diisocyanate <br />Acute oral toxicity <br />LD50, Rat, female, 4,130 mg/kg <br />Acute dermal toxicity <br />LD50, Rabbit, male and female, > 9,400 mg/kg <br />Acute inhalation toxicity <br />Easily attainable vapor concentrations may cause serious adverse effects, even death. Excessive <br />exposure to TDI may cause severe irritation of the upper respiratory tract and lungs, fluid in the lungs, <br />permanent decrease of lung function, neurologic disorders, cholinesterase depression and gastrointestinal <br />distress. <br />LC50, Rat, 1 Hour, vapor, 0.48 mg/l <br />LC50, Mouse, 6 Hour, dust/mist, 0.1 mg/l <br />Carcinogenicity: <br />Component</p> <p>2,4 Toluene diisocyanate</p> <p>List</p> <p>IARC <br />US NTP <br />ACGIH</p> <p>Classification</p> <p>Group 2B: Possibly carcinogenic to humans <br />Reasonably anticipated to be a human carcinogen <br />A3: Confirmed animal carcinogen with unknown relevance to <br />humans.</p> <p>Page 8 of 11</p> <p>IDENTITY:</p> <p>PRO-Tekt Flexcoat, Component B</p> <p>SAFETY DATA SHEET <br />SDS No. PRO F.1.2</p> <p>Section 12 – Ecological Information <br />Ecotoxicological information appears in this section when such date is available.</p> <p>Toxicity: <br />TDI Prepolymer <br />Acute toxicity to fish <br />For similar material(s): <br />Not expected to be acutely toxic to aquatic organisms. <br />2,4-Toluene diisocyanate <br />Acute toxicity to fish <br />Material is slightly toxic to aquatic organisms on an acute basis (LC50/EC50 between 10 and 100 mg/L in <br />the most sensitive species tested). <br />LC50, Oncorhynchus mykiss (rainbow trout), static test, 96 Hour, 133 mg/l, OECD Test Guideline 203 or <br />Equivalent <br />Acute toxicity to aquatic invertebrates <br />EC50, Daphnia magna (Water flea), static test, 48 Hour, 12.5 mg/l, OECD Test Guideline 202 or <br />Equivalent <br />EC50, saltwater mysid Mysidopsis bahia, static test, 48 Hour, 18.3 mg/l, OECD Test Guideline 202 or <br />Equivalent <br />Acute toxicity to algae/aquatic plants <br />EC50, Skeletonema costatum (marine diatom), static test, 96 Hour, 3,230 mg/l, OECD Test Guideline 201 <br />or Equivalent <br />EC50, Chlorella vulgaris (Fresh water algae), static test, 96 Hour, 4,300 mg/l, OECD Test Guideline 201 or <br />Equivalent <br />Toxicity to bacteria <br />EC50, activated sludge, Respiration inhibition, 3 Hour, > 100 mg/l, OECD 209 Test <br />Chronic toxicity to aquatic invertebrates <br />NOEC, Daphnia magna (Water flea), static test, 21 d, number of offspring, 1.1 mg/l <br />LOEC, Daphnia magna (Water flea), static test, 21 d, number of offspring, 2.2 mg/l <br />Persistence and degradability: <br />TDI Prepolymer <br />Biodegradability: For similar material(s): In the aquatic and terrestrial environment, material reacts with <br />water forming predominantly insoluble polyureas which appear to be stable. <br />2,4-Toluene diisocyanate <br />Biodegradability: In the aquatic and terrestrial environment, material reacts with water forming <br />predominantly insoluble polyureas which appear to be stable. In the atmospheric environment, material is <br />expected to have a short tropospheric half-life, based on calculations and by analogy with related <br />diisocyanates. <br />Bioaccumulative potential: <br />TDI Prepolymer</p> <p>Page 9 of 11</p> <p>IDENTITY:</p> <p>PRO-Tekt Flexcoat, Component B</p> <p>SAFETY DATA SHEET <br />SDS No. PRO F.1.2</p> <p>Bioaccumulation: No data available for this product. For similar material(s): In the aquatic and terrestrial <br />environment, movement is expected to be limited by its reaction with water forming predominantly insoluble <br />polyureas. <br />2,4-Toluene diisocyanate <br />Bioaccumulation: No data available. Reacts with water. In the aquatic and terrestrial environment, <br />movement is expected to be limited by its reaction with water forming predominantly insoluble polyureas. <br />Mobility in soil: <br />TDI Prepolymer <br />For similar material(s): <br />In the aquatic and terrestrial environment, movement is expected to be limited by its reaction with water <br />forming predominantly insoluble polyureas. <br />2,4-Toluene diisocyanate <br />In the aquatic and terrestrial environment, movement is expected to be limited by its reaction with water <br />forming predominantly insoluble polyureas.</p> <p>Section 13 – Disposal Considerations <br />Disposal methods: NOTICE: Research sample for use by qualified personnel only. Upon completion of tests, <br />dispose of material and container safely and in accord with federal, state/provincial and local laws and <br />regulations. If further information is needed on disposal or use, consult your supplier.</p> <p>Section 14 – Transport Information <br />USDOT (Domestic Surface)</p> <p>Not regulated for transport</p> <p>Classification for SEA transport (IMO-IMDG):</p> <p>Not regulated for transport</p> <p>Transport in bulk according to Annex <br />I or II of MARPOL 73/78 and the IBC <br />or IGC Code</p> <p>Consult IMO regulations before <br />transporting ocean bulk</p> <p>Classification for AIR transport (IATC/ICAO)</p> <p>Not regulated for transport</p> <p>This information is not intended to convey all specific regulatory or operational requirements/information <br />relating to this product. Transportation classifications may vary by container volume and may be influenced by <br />regional or country variations in regulations. Additional transportation system information can be obtained <br />through an authorized sales or customer service representative. It is the responsibility of the transporting <br />organization to follow all applicable laws, regulations and rules relating to the transportation of the material.</p> <p>Section 15 – Regulatory Information <br />Superfund Amendments and Reauthorization Act of 1986 Title III (Emergency Planning and Community <br />Right-to-Know Act of 1986) Sections 311 and 312 <br />Acute Health Hazard <br />Chronic Health Hazard</p> <p>Page 10 of 11</p> <p>IDENTITY:</p> <p>PRO-Tekt Flexcoat, Component B</p> <p>SAFETY DATA SHEET <br />SDS No. PRO F.1.2</p> <p>Superfund Amendments and Reauthorization Act of 1986 Title III (Emergency Planning and Community <br />Right-to-Know Act of 1986) Section 313 <br />This product contains the following substances which are subject to the reporting requirements of Section 313 <br />of Title III of the Superfund Amendments and Reauthorization Act of 1986 and which are listed in 40 CFR 372. <br />Components <br />CASRN <br />2,4-Toluene diisocyanate <br />584-84-9 <br />2,6-Toluene diisocyanate <br />91-08-7 <br />Pennsylvania Worker and Community Right-To-Know Act: <br />The following chemicals are listed because of the additional requirements of Pennsylvania law: <br />Components <br />CASRN <br />2,4-Toluene diisocyanate <br />584-84-9 <br />2,6-Toluene diisocyanate <br />91-08-7 <br />California Proposition 65 (Safe Drinking Water and Toxic Enforcement Act of 1986) <br />WARNING: This product contains a chemical(s) known to the State of California to cause cancer. <br />Components <br />CASRN <br />2,4-Toluene diisocyanate <br />584-84-9 <br />2,6-Toluene diisocyanate <br />91-08-7 <br />United States TSCA Inventory (TSCA) <br />All components of this product are in compliance with the inventory listing requirements of the U.S. Toxic <br />Substances Control Act (TSCA) Chemical Substance Inventory.</p> <p>Section 16 – Other Information <br />Abbreviations and acronyms: <br />ACGIH <br />C <br />Dow IHG <br />OSHA Z-1 <br />SKIN, DSEN, RSEN <br />STEL <br />TWA</p> <p>USA. ACGIH Threshold Limit Values (TLV) <br />Ceiling limit <br />Dow Industrial Hygiene Guideline <br />USA. Occupational Exposure Limits (OSHA) - Table Z-1 Limits for Air <br />Contaminants <br />Absorbed via Skin, Skin Sensitizer, Respiratory sensitizer <br />Short-term exposure limit <br />Time weighted average</p> <p>SDS prepared by:</p> <p>Aquafin product safety department.</p> <p>DISCLAIMER:</p> <p>We believe the statements, technical information and recommendations contained herein are reliable, but they are given <br />without warranty or guarantee of any kind, expressed or implied, and we assume no responsibility for any loss, damage, or <br />expense, direct or consequential, arising out of their use. Aquafin shall not be responsible for the use of this product in a <br />manner to infringe on any patent or any other intellectual property rights held by others. <br />User is responsible for determining appropriate <br />safety <br />measures and for applying the legislation covering <br />activities. <br />END <br />OF MSDS <br />(Aprilhis <br />09,own <br />2015) <br />We recommend that user makes tests to determine the suitability of a product for its particular purpose prior to use. <br />END OF SDS</p> <p>Page 11 of 11</p> <p>(February 19, 2019)</p>
