Safety Data Sheet (SDS)
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OSHA HazCom Standard 29 CFR 1910.1200(g) and GHS Rev 03.
Printing date 08/18/2022
Reviewed on 08/18/2022
SECTION 1) CHEMICAL PRODUCT AND MANUFACTURER'S IDENTIFICATION
IDENTITY:
Product Name: PRO-Tekt Joint Sealant COMPONENT A Product Use Description:
Polyurethane Sealant, For Further Information, Refer to the Product Technical Data Sheet.
AQUAFIN, INC. 505 BLUE BALL RD. #160 ELKTON, MD 21921
24 hr Emergency Phone: Chem-Tel (800) 255-3924 Information Phone No: (410) 392-2300
info@aquafin.net
www.aquafin.net
SECTION 2) HAZARDS IDENTIFICATION Classification Aspiration Hazard - Category 1 Carcinogenicity - Category 1B Flammable Liquids - Category 3 Germ Cell Mutagenicity - Category 1B Reproductive Toxicity - Category 2 Specific Target Organ Toxicity - Repeated Exposure - Category 2
Pictograms
Signal Word Danger
Hazardous Statements - Physical H226 - Flammable liquid and vapor
Hazardous Statements - Health H304 - May be fatal if swallowed and enters airways H350 - May cause cancer. H340 - May cause genetic defects. H361 - Suspected of damaging fertility or the unborn child H373 - May cause damage to organs through prolonged or repeated exposure.
Precautionary Statements - General P101 - If medical advice is needed, have product container or label at hand. P102 - Keep out of reach of children.
SDS PRO-Tekt Joint Sealant Comp A SDS DATE: 22-AUG-18
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P102 - Keep out of reach of children. P103 - Read label before use.
Precautionary Statements - Prevention P201 - Obtain special instructions before use. P202 - Do not handle until all safety precautions have been read and understood. P280 - Wear protective gloves/protective clothing/eye protection/face protection. P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P233 - Keep container tightly closed. P240 - Ground/bond container and receiving equipment. P241 - Use explosion-proof [electrical/ventilating/lighting/...] equipment. P242 - Use only non-sparking tools. P243 - Take action to prevent static discharges. P260 - Do not breathe dust/fume/gas/mist/vapors/spray.
Precautionary Statements - Response P301 + P310 - IF SWALLOWED: Immediately call a POISON CENTER or doctor. P331 - Do NOT induce vomiting. P308 + P313 - IF exposed or concerned: Get medical advice/attention. P303 + P361 + P353 - IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water [or shower]. P370 + P378 - In case of fire: Use dry chemical, carbon dioxide, foam to extinguish. For detailed information, see Section-5 (Fire Fighting Measures) P314 - Get Medical advice/attention if you feel unwell.
Precautionary Statements - Storage P405 - Store locked up. P403 + P235 - Store in a well-ventilated place. Keep cool.
Precautionary Statements - Disposal P501 - Dispose of contents/ container to an approved waste disposal plant.
SECTION 3) COMPOSITION/INFORMATION ON INGREDIENTS CAS
Chemical Name
% By Weight
0068092-58-0
POLYURETHANE PREPOLYMER
28% - 52%
0014808-60-7
SILICA, CRYSTALLINE
19% - 35%
0064742-95-6
AROMATIC HYDROCARBON MIXTURE >C9
13% - 23%
0000108-32-7
4-METHYL-1,3-DIOXOLAN-2-ONE
1.5% - 3%
0001333-86-4
CARBON BLACK
0.5% - 0.9%
0001330-20-7
XYLENE
0.5% - 0.8%
Specific chemical identity and/or exact percentage (concentration) of the composition has been withheld to protect confidentiality.
SECTION 4) FIRST-AID MEASURES Inhalation Remove source of exposure or move person to fresh air and keep comfortable for breathing. If experiencing respiratory symptoms: Call a POISON CENTER/doctor. If breathing is difficult, trained personnel should administer emergency oxygen if advised to do so by the POISON CENTER/doctor. If exposed/feel unwell/concerned: Call a POISON CENTER/doctor.
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Eliminate all ignition sources if safe to do so.
Skin Contact Take off contaminated clothing, shoes and leather goods (e.g. watchbands, belts). Gently blot or brush away excess product. Wash with plenty of lukewarm, gently flowing water for a duration of 15-20 minutes. If skin irritation or rash occurs: Get medical advice/attention. Wash contaminated clothing before re-use or discard. IF exposed or concerned: Get medical advice/attention.
Eye Contact Avoid direct contact. Wear chemical protective gloves, if necessary. Rinse eyes cautiously with lukewarm, gently flowing water for several minutes, while holding the eyelids open. Remove contact lenses, if present and easy to do. Continue rinsing for 15-20 minutes. Take care not to rinse contaminated water into the unaffected eye or onto the face. If eye irritation persists: Get medical advice/attention.
Ingestion IF exposed or concerned: Get medical advice/attention. Rinse mouth. Do NOT induce vomiting. Immediately call a POISON CENTER/doctor. If vomiting occurs naturally, lie on your side, in the recovery position.
SECTION 5) FIRE-FIGHTING MEASURES Suitable Extinguishing Media Dry chemical, foam, carbon dioxide is recommended. Water spray is recommended to cool or protect exposed materials or structures. Carbon dioxide can displace oxygen. Use caution when applying carbon dioxide in confined spaces. Simultaneous use of foam and water on the same surface is to be avoided as water destroys the foam. Sand or earth may be used for small fires only.
Unsuitable Extinguishing Media If water is used, use very large quantities of cold water. The reaction between water and hot isocyanate may be vigorous.
Specific Hazards in Case of Fire Vapors may accumulate and travel to ignition sources distant from the handling site; flash fire can occur. Excessive pressure or temperature may cause explosive rupture of containers. Water contamination will produce carbon dioxide. Do not reseal contaminated containers as pressure buildup may rupture them.
Fire-fighting Procedures Isolate immediate hazard area and keep unauthorized personnel out. Stop spill/release if it can be done safely. Move undamaged containers from immediate hazard area if it can be done safely. Water spray may be useful in minimizing or dispersing vapors and to protect personnel. Water may be ineffective but can be used to cool containers exposed to heat or flame. Caution should be exercised when using water or foam as frothing may occur, especially if sprayed into containers of hot, burning liquid. Dispose of fire debris and contaminated extinguishing water in accordance with official regulations.
Special Protective Actions Wear NIOSH approved self-contained breathing apparatus in positive pressure mode with full-face piece. Boots, gloves (neoprene), goggles, and full protective clothing are also required. Care should always be exercised in dust/mist areas.
SECTION 6) ACCIDENTAL RELEASE MEASURES Emergency Procedure ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area). Do not touch or walk through spilled material. Isolate hazard area and keep unnecessary people away. Remove all possible sources of ignition in the surrounding area. Notify authorities if any exposure to the general public or the environment occurs or is likely to occur. If spilled material is cleaned up using a regulated solvent, the resulting waste mixture may be regulated.
Recommended Equipment Appropriate dust or face mask to eliminate breathing foam dust particulates.
Personal Precautions Avoid breathing vapors. Avoid contact with skin, eyes or clothing. Do not touch damaged containers or spilled materials unless wearing appropriate protective clothing.
Environmental Precautions Stop spill/release if it can be done safely. Prevent spilled material from entering sewers, storm drains, other unauthorized drainage
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systems and natural waterways by using sand, earth, or other appropriate barriers.
Methods and Materials for Containment and Cleaning up Cover container, but do not seal, and remove from work area. Prepare a decontamination solution of 2.0% liquid detergent and 3-8% concentrated ammonium hydroxide in water (5-10% sodium carbonate may be substituted for the ammonium hydroxide). Follow the precautions on the supplier's safety data sheets. Treat the spill area with the decontamination solution, using about 10 parts of the solution for each part of the spill, and allow it to react for at least 15 minutes. Carbon dioxide will be evolved, leaving insoluble polyureas. Residues from spill cleanup, even when treated as described may continue to be regulated under provisions of RCRA and require storage and disposal as hazardous waste. Slowly stir the isocyanate waste into the decontamination solution described above. Let stand for 48 hours, allowing the evolved carbon dioxide to vent away, residues may still be subject to RCRA storage and disposal requirements. Dispose off in compliance with all relevant local, state, and federal laws and regulations regarding treatment.
SECTION 7) HANDLING AND STORAGE General Wash hands after use. Do not get in eyes, on skin or on clothing. Do not breathe vapors or mists. Use good personal hygiene practices. Eating, drinking and smoking in work areas is prohibited. Remove contaminated clothing and protective equipment before entering eating areas.
Ventilation Requirements Use only with adequate ventilation to control air contaminants to their exposure limits. The use of local ventilation is recommended to control emissions near the source.
Storage Room Requirements Keep container(s) tightly closed and properly labeled. Store in cool, dry, well-ventilated areas away from heat, direct sunlight, strong oxidizers and any incompatibilities. Store in approved containers and protect against physical damage. Keep containers securely sealed when not in use. Indoor storage should meet OSHA standards and appropriate fire codes. Containers that have been opened must be carefully resealed to prevent leakage. Empty container retain residue and may be dangerous. Use non-sparking ventilation systems, approved explosion-proof equipment and intrinsically safe electrical systems in areas where this product is used and stored. Ground and bond containers and receiving equipment. Avoid static electricity by grounding. Do not cut, drill, grind, weld, or perform similar operations on or near containers. Do not pressurize containers to empty them. Ground all structures, transfer containers and equipment to conform to the national electrical code. Use procedures that prevent static electrical sparks. Static electricity may accumulate and create a fire hazard.
SECTION 8) EXPOSURE CONTROLS/PERSONAL PROTECTION Eye Protection Wear eye protection with side shields or goggles. Wear indirect-vent, impact and splash resistant goggles when working with liquids. If additional protection is needed for entire face, use in combination with a face shield.
Skin Protection Use of gloves approved to relevant standards made from the following materials may provide suitable chemical protection: PVC, neoprene or nitrile rubber gloves. Suitability and durability of a glove is dependent on usage, e.g. frequency and duration of contact, chemical resistance of glove material, glove thickness, dexterity. Always seek advice from glove suppliers. Contaminated gloves should be replaced. Use of an apron and over- boots of chemically impervious materials such as neoprene or nitrile rubber is recommended to avoid skin sensitization. The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Launder soiled clothes or properly disposed of contaminated material, which cannot be decontaminated. Depending on conditions of use, additional protection may be required such as apron, arm covers, or full body suit. Wash contaminated clothing before re-wearing.
Respiratory Protection If airborne concentrations exceed or are expected to exceed the TLV, use MSHA/NIOSH approved positive pressure supplied pressure supplied air respiratory with a full face piece or an air supplied hood. For emergencies, use a positive pressure self-contained breathing apparatus. Air purifying (cartridge type) respirators are not approved for protection against isocyanates.
Appropriate Engineering Controls Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors below their respective threshold limit value. Chemical Name
OSHA TWA (ppm)
OSHA TWA (mg/m3)
OSHA STEL (ppm)
OSHA STEL (mg/m3)
OSHA Tables (Z1, Z2, Z3)
OSHA Carcinogen
OSHA Skin designation
NIOSH TWA (ppm)
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AROMATIC HYDROCARBO N MIXTURE >C9
500
2000
1
3.5
a
[10 mg/m3 percent SiO2+2 / 250 percent SiO2+5 mppcf]; [30 mg/m3 percent SiO2+2];
[1,3]; [3];
100
435
CARBON BLACK SILICA, CRYSTALLINE
NIOSH TWA (mg/m3)
NIOSH STEL NIOSH STEL (ppm) (mg/m3)
NIOSH Carcinogen
ACGIH TWA (ppm) (L)[N159](L) [N800]
ACGIH TWA (mg/m3) [(L)[N159](L) [N800]]; [5 (I) [N159]5 (I) [N800]];
3.5a
3 (I)
0.05e
0.025 (R)
150
655
ACGIH STEL ACGIH STEL (ppm) (mg/m3)
(I) - Inhalable fraction, (R) - Respirable fraction
SECTION 9) PHYSICAL AND CHEMICAL PROPERTIES Physical and Chemical Properties Density
8.80 lb/gal
Specific Gravity
1.05
VOC Regulatory
0.00 lb/gal
VOC Part A & B Combined
0.42 lb/gal
Appearance
Liquid
Odor Threshold
N.A.
Odor Description
Aromatic
pH
Water Solubility
Flammability
N/A
Flash Point Symbol
Flash Point
43 °C
Viscosity
Lower Explosion Level
Upper Explosion Level
Vapor Pressure
Vapor Density
Heavier than air
Freezing Point
Melting Point
Low Boiling Point
150 °C
High Boiling Point
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Auto Ignition Temp
Decomposition Pt
Evaporation Rate
Slower than ether
Coefficient Water/Oil
SECTION 10) STABILITY AND REACTIVITY Stability Material is stable at standard temperature and pressure.
Conditions to Avoid Heat, high temperature, open flame, sparks, and moisture. Contact with incompatible materials in a closed system will cause liberation of carbon dioxide and buildup of pressure.
Hazardous Reactions/Polymerization Will not occur under normal conditions but under high temperatures in the presence of alkalis,tertiary amines, and metal compounds will accelerate polymerization. Possible evolution of carbon dioxide gas may rupture closed containers.
Incompatible Materials This product will react with any material containing active hydrogens, such as water, alcohol, ammonia, amines, alkalis and acids, the reaction with water is slow under 50°C, but is accelerated at higher temperature and in the presence of alkalis, tertiary amines, and metal compounds. Some reactions can be violent. Material can react with strong oxidizing agents.
Hazardous Decomposition Products Carbon dioxide, carbon monoxide, nitrogen oxides, trace amounts of hydrogen cyanide and unidentified organic compounds may be formed during combustion.
SECTION 11) TOXICOLOGICAL INFORMATION Skin Corrosion/Irritation Isocyanates react with skin protein and moisture and can cause irritation. Prolonged contact can cause reddening, swelling, rash, scaling, blistering, and, in some cases, skin sensitization. Individuals who have developed a skin sensitization can develop these symptoms as a result of contact with very small amounts of liquid material or as a result of exposure to vapor. No data available.
Serious Eye Damage/Irritation Liquid, aerosols or vapors are severely irritating and can cause pain, tearing, reddening and swelling. Prolonged vapor contact may cause conjunctivitis. Any level of contact should not be left untreated. No data available.
Respiratory/Skin Sensitization No data available.
Carcinogenicity May cause cancer.
Germ Cell Mutagenicity May cause genetic defects.
Reproductive Toxicity Suspected of damaging fertility or the unborn child
Specific Target Organ Toxicity - Single Exposure No data available.
Specific Target Organ Toxicity - Repeated Exposure May cause damage to organs through prolonged or repeated exposure.
Aspiration Hazard May be fatal if swallowed and enters airways
Acute Toxicity No data available.
Likely Routes of Exposure
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Likely Routes of Exposure Inhalation, Ingestion, Skin contact, Eye contact Aspiration into the lungs when swallowed or vomited may cause chemical pneumonitis which can be fatal.
Chronic Exposure 0001330-20-7 XYLENE High exposure to Xylenes in some animal studies have been reported to cause health effects on the developing embryo/fetus. Xylene in high concentrations has caused embryotoxic effects in laboratory animals. 0001333-86-4 CARBON BLACK CARCINOGENIC EFFECTS: In 1996, the IARC reevaluated Carbon Black as a Group 2B carcinogen. This evaluation is given to carbon black for which there is inadequate human evidence, but sufficient animal evidence. Prolonged inhalation of Carbon black can result in lung disease. Symptoms include coughing, shortness of breath, wheezing and reduced pulmonary function. 0014808-60-7 SILICA, CRYSTALLINE Prolonged inhalation of respirable crystalline silica dust can result in lung disease (i.e. silicosis and/or lung cancer). Symptoms include coughing, shortness of breath, wheezing and reduced pulmonary function.
Potential Health Effects - Miscellaneous 0001330-20-7 XYLENE Increased susceptibility to the effects of this material may be observed in people with preexisting disease of any of the following: bone marrow, cardiovascular system, central nervous system, kidneys, liver, lungs. Recurrent overexposure may result in liver and kidney injury. High exposures may produce irregular heart beats. Canada classifies Xylene as a developmental toxin as high exposures to xylenes in some animal studies have been reported to cause health effects on the developing fetus/embryo. These effects were often at levels toxic to the adult animal. The significance of these effects to humans is not known. Repeated or prolonged skin contact may cause any of the following: irritation, dryness, cracking of the skin. 0001333-86-4 CARBON BLACK Is an IARC, NTP or OSHA carcinogen. Has shown carcinogenic activity in laboratory animals at high doses. Significance to man is unknown. The following medical conditions may be aggravated by exposure: asthma, respiratory disease. WARNING: This chemical is known to the State of California to cause cancer. 0014808-60-7 SILICA, CRYSTALLINE Is an IARC, NTP or OSHA carcinogen. Repeated overexposure to crystalline silica may lead to x-ray changes and chronic lung disease. Inhalation of high dust concentrations may cause: breathing difficulties, lung injury. WARNING: This chemical is known to the State of California to cause cancer. 0064742-95-6 AROMATIC HYDROCARBON MIXTURE >C9 The following medical conditions may be aggravated by exposure: skin disorders. Laboratory studies with rats have shown that petroleum distillates can cause kidney damage and kidney or liver tumors. These effects were not seen in similar studies with guinea pigs, dogs, or monkeys. Several studies evaluating petroleum workers have not shown a significant increase of kidney damage or an increase in kidney or liver tumors. 0001333-86-4
LC50 (rat): 6750 mg/m3 (4-hour exposure); cited as 27000 mg/m3 (27 mg/L) (1-hour exposure) (3) 0001330-20-7
LC50 (rat): 6350 ppm (4-hour exposure) (unspecified isomers and ethylbenzene) (1)LC50 (rat): 6700 ppm (4-hour exposure) (65% m-xylene, 7.6% o-xylene, 7.8% p-xylene, 19.3% ethylbenzene) (2) ethylbenzene) (1) LC50 (rat): 6700 ppm (4-hour exposure) (65% m-xylene, 7.6% o-xylene, 7.8% p-xylene, 19.3% ethylbenzene)(2) LD50 (oral, rat): 5400 mg/kg (52% m-, 19% o-, 24% p-) (1)LD50 (oral, female mouse): 5251 mg/kg (60.2% m-, 9.1% o-, 14.6% p-, 17.0% ethylbenzene) (4) LD50 (oral, male mouse): 5627 mg/kg (60.2% m-, 9.1% o-, 14.6% p-, 17.0% ethylbenzene) (4) LD50 (dermal, rabbit): 12180 mg/kg (m-xylene); greater than 1700 mg/kg (mixed xylenes - undefined composition) (3) LD50 (oral, female mouse): 5251 mg/kg (60.2% m-, 9.1% o-, 14.6% p-, 17.0% ethylbenzene) (4) LD50 (oral, male mouse): 5627 mg/kg (60.2% m-, 9.1% o-, 14.6% p-, 17.0% ethylbenzene) (4) LD50 (dermal, rabbit): 12180 mg/kg (m-xylene); greater than 1700 mg/kg (mixed xylenes - undefined composition) (3)
SECTION 12) ECOLOGICAL INFORMATION Toxicity No data available.
Mobility in Soil No data available.
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Other Adverse Effects No data available.
Bio-accumulative Potential No data available.
Persistence and Degradability 0001330-20-7 XYLENE 50% of applied radiolabelled o-xylene was mineralised in 23 days, and 50% p-xylene was mineralised in 13 days. 0001333-86-4 CARBON BLACK Carbon Black's insolubility in water results in it not being biodegradable in any medium or by biota. It is considered persistent in the natural environment.
SECTION 13) DISPOSAL CONSIDERATIONS Waste Disposal Under RCRA, it is the responsibility of the user of the product, to determine a the time of disposal whether the product meets RCRA criteria for hazardous waste. Waste management should be in full compliance with federal, state, and local laws. Empty containers retain product residue which may exhibit hazards of material, therefore do not pressurize, cut, glaze, weld or use for any other purposes. Return drums to reclamation centers for proper cleaning and reuse.
SECTION 14) TRANSPORT INFORMATION U.S. DOT Information Not Regulated
IMDG Information UN/NA #: 1263 UN Proper Shipping Name: PAINT Hazard Class: 3 Packing Group: III Placard: Flammable Marine Pollutant: No data available
IATA Information UN/NA #: 1263 UN Proper Shipping Name: PAINT Hazard Class: 3 Packing Group: III Placard: Flammable
SECTION 15) REGULATORY INFORMATION
CAS
Regulation List
DSL,SARA312,TSCA
DSL,SARA312,TSCA,CA_Prop65 California Proposition 65
DSL,SARA312,VOC,TSCA
SARA313, DSL,CERCLA,HAPS,SARA312,VHA
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PS,VOC,TSCA,RCRA
SECTION 16) OTHER INFORMATION OTHER INFORMATION Note: As per GHS, category 1 is the greatest level of hazard within each class.
GLOSSARY ACGIH- American Conference of Governmental Industrial Hygienists; ANSI- American National Standards Institute; CA Prop65- California Proposition 65; Canadian TDG- Canadian Transportation of Dangerous Goods; CAS- Chemical Abstract Service; Chemtrec- Chemical Transportation Emergency Center (US); CHIP- Chemical Hazard Information and Packaging; DSL- Domestic Substances List; ECEquivalent Concentration; EH40 (UK)- HSE Guidance Note EH40 Occupational Exposure Limits; EPCRA- Emergency Planning and Community Right-To-Know Act; ESL- Effects screening levels; HMIS- Hazardous Material Information Service; LC- Lethal Concentration; LD- Lethal Dose; NFPA- National Fire Protection Association; OEL- Occupational Exposure Limits; OSHA- Occupational Safety and Health Administration, US Department of Labor; PEL- Permissible Exposure Limit; SARA (Title III)- Superfund Amendments and Reauthorization Act; SARA 313- Superfund Amendments and Reauthorization Act, Section 313; SCBA- Self-Contained Breathing Apparatus; STEL- Short Term Exposure Limit; TCEQ- Texas Commission on Environmental Quality; TLV- Threshold Limit Value; TSCAToxic Substances Control Act Public Law 94-469; TWA- Time Weighted Value; US DOT- US Department of Transportation; WHMISWorkplace Hazardous Materials Information System. ACGIH - American Conference of Governmental Industrial Hygienists; CAS - Chemical Abstracts Service ; Chemtrec - Chemical Transportation Emergency Center; DSL - Domestic Substances List; ESL- Effects screening levels; GHS - "Globally Harmonized System of Classification and Labelling of Chemicals" developed by the United Nations; HMIS - Hazardous Material Information Service; IATA Dangerous Goods Regulations (DGR) for the air transport (IATA); IMDG - International Maritime Dangerous Goods Code; LC - Lethal Concentration; LD - Lethal Dose; NFPA - National Fire Protection Association; OEL - Occupational Exposure Limits; OSHA- Occupational Safety and Health Administration, US Department of Labor; PEL - Permissible Exposure Limit; SARA 313 - Superfund Amendments and Reauthorization Act, Section 313; SCBA - Self Contained Breathing Apparatus; ppm - parts per million; STEL - Short-term exposure limit; TLV - Threshold Limit Value; TSCA - Toxic Substances Control Act Public Law 94-469; TWA - Time-weighted average; US DOT- US Department of Transportation.
DISCLAIMER To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist. The above information pertains to this product as currently formulated, and is based on the information available at this time. Addition of reducers or other additives to this product may substantially alter the composition and hazards of the product. Since conditions of use are outside our control, we make no warranties, express or implied, and assume no liability in connection with any use of this information.
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