SDS_RE-ROOF Acrylic Base Coat_020623.pdf
7 Pages
1.35 MB
Download
<h1>SDS_RE-ROOF Acrylic Base Coat_020623.pdf</h1> <p>Safety Data Sheet (SDS)</p> <p>Page 1/7</p> <p>OSHA HazCom Standard 29 CFR 1910.1200(g) and GHS Rev 03.</p> <p>Printing date 02/06/23</p> <p>Reviewed on 02/06/23</p> <p>SECTION 1) CHEMICAL PRODUCT AND SUPPLIER'S IDENTIFICATION</p> <p>IDENTITY:</p> <p>Product Name: RE-ROOF Acrylic Base Coat <br />Product Use Description:</p> <p>AQUAFIN, INC. <br />505 BLUE BALL RD. #160 <br />ELKTON, MD 21921</p> <p>Acrylic-based Liquid Roof Coating, For Further Information, Refer to the <br />Product Technical Data Sheet.</p> <p>info@aquafin.net</p> <p>24 hr Emergency Phone: Chem-Tel (800) 255-3924 <br />Information Phone No: (410) 392-2300</p> <p>www.aquafin.net</p> <p>SECTION 2) HAZARDS IDENTIFICATION <br />Classification: <br />Specific Target Organ Toxicity - Single Exposure - Category 1 <br />Carcinogenicity - Category 2</p> <p>Pictograms:</p> <p>Signal Word: <br />Danger</p> <p>Hazardous Statements - Health: <br />H351 - Suspected of causing cancer. <br />H370 - Causes damage to organs.</p> <p>Precautionary Statements - General: <br />P101 - If medical advice is needed, have product container or label at hand. <br />P102 - Keep out of reach of children. <br />P103 - Read label before use.</p> <p>Precautionary Statements - Prevention: <br />P201 - Obtain special instructions before use. <br />P202 - Do not handle until all safety precautions have been read and understood. <br />P280 - Wear protective gloves/protective clothing/eye protection/face protection. <br />P260 - Do not breathe dust/fume/gas/mist/vapors/spray. <br />P264 - Wash thoroughly after handling. <br />P270 - Do not eat, drink or smoke when using this product.</p> <p>Precautionary Statements - Response: <br />P308 + P313 - IF exposed or concerned: Get medical advice/attention. <br />P308 + P311 - IF exposed or concerned: Call a POISON CENTER/doctor. <br />P321 - Specific treatment (see section 4 on this SDS).</p> <p>SDS RE-ROOF Acrylic Base Coat <br />SDS DATE: 23-FEB-6</p> <p>Page 1 of 7</p> <p>Precautionary Statements - Storage: <br />P405 - Store locked up.</p> <p>Precautionary Statements - Disposal: <br />P501 - Dispose of contents/ container to an approved waste disposal plant.</p> <p>SECTION 3) COMPOSITION / INFORMATION ON INGREDIENTS <br />CAS</p> <p>Chemical Name</p> <p>0013463-67-7</p> <p>TITANIUM DIOXIDE</p> <p>0000107-21-1</p> <p>ETHYLENE GLYCOL</p> <p>1.3% - 2.2%</p> <p>0014808-60-7</p> <p>SILICA, CRYSTALLINE</p> <p>0.3% - 0.6%</p> <p>0001333-86-4</p> <p>CARBON BLACK</p> <p>% by Weight <br />3% - 6%</p> <p>Trace</p> <p>SECTION 4) FIRST-AID MEASURES <br />Inhalation: <br />Remove source of exposure or move person to fresh air and keep comfortable for breathing. <br />If exposed/feel unwell/concerned: Call a POISON CENTER/doctor.</p> <p>Skin Contact: <br />Rinse/wash with lukewarm, gently flowing water and mild soap for 15-20 minutes or until product is removed. If skin irritation occurs or you <br />feel unwell: Get medical advice/attention.</p> <p>Eye Contact: <br />Remove source of exposure or move person to fresh air. Rinse eyes cautiously with lukewarm, gently flowing water for several minutes, <br />while holding the eyelids open. Remove contact lenses, if present and easy to do. Continue rinsing for a duration of 15-20 minutes. Take <br />care not to rinse contaminated water into the unaffected eye or onto the face. If eye irritation persists: Get medical advice/attention.</p> <p>Ingestion: <br />Rinse mouth. If you feel unwell/If concerned: Get medical advice/attention.</p> <p>SECTION 5) FIRE-FIGHTING MEASURES <br />Suitable Extinguishing Media: <br />Dry chemical, foam, carbon dioxide is recommended. Water spray is recommended to cool or protect exposed materials or structures. <br />Carbon dioxide can displace oxygen. Use caution when applying carbon dioxide in confined spaces. Simultaneous use of foam and water <br />on the same surface is to be avoided as water destroys the foam. Sand or earth may be used for small fires only.</p> <p>Unsuitable Extinguishing Media: <br />Water and foam may cause violent frothing and possibly endanger the life of the fire fighter, especially if sprayed into containers of hot, <br />burning material.</p> <p>Specific Hazards in Case of Fire: <br />Hazardous combustion products include oxides of carbon and nitrogen, various hydrocarbons.</p> <p>Fire-fighting Procedures: <br />Isolate immediate hazard area and keep unauthorized personnel out. Stop spill/release if it can be done safely. Move undamaged <br />containers from immediate hazard area if it can be done safely. Water spray may be useful in minimizing or dispersing vapors and to <br />protect personnel. Water may be ineffective but can be used to cool containers exposed to heat or flame. Caution should be exercised <br />when using water or foam as frothing may occur, especially if sprayed into containers of hot, burning liquid. <br />Dispose of fire debris and contaminated extinguishing water in accordance with official regulations.</p> <p>Special Protective Actions: <br />Care should always be exercised in dust/mist areas. <br />Wear protective pressure self-contained breathing apparatus (SCBA)and full turnout gear.</p> <p>SECTION 6) ACCIDENTAL RELEASE MEASURES <br />Emergency Procedure: <br />Keep unnecessary people away; isolate hazard area and deny entry. Do not touch or walk through spilled material. Clean up immediately.</p> <p>SDS RE-ROOF Acrylic Base Coat <br />SDS DATE: 23-FEB-6</p> <p>Page 2 of 7</p> <p>Recommended Equipment: <br />Positive pressure, full-face piece self-contained breathing apparatus(SCBA), or positive pressure supplied air respirator with escape SCBA <br />(NIOSH approved).</p> <p>Personal Precautions: <br />Avoid breathing vapors. Avoid contact with skin, eyes or clothing. Do not touch damaged containers or spilled materials unless wearing <br />appropriate protective clothing.</p> <p>Environmental Precautions: <br />Stop spill/release if it can be done safely. Prevent spilled material from entering sewers, storm drains, other unauthorized drainage systems <br />and natural waterways by using sand, earth, or other appropriate barriers.</p> <p>Methods and Materials for Containment and Cleaning up: <br />Confine spillage and absorb on sand, sawdust, or other suitable absorbent material and transfer to a sealed container.</p> <p>SECTION 7) HANDLING AND STORAGE <br />General: <br />Wash hands after use. <br />Do not get in eyes, on skin or on clothing. <br />Do not breathe vapors or mists. <br />Use good personal hygiene practices. <br />Eating, drinking and smoking in work areas is prohibited. <br />Remove contaminated clothing and protective equipment before entering eating areas. <br />Vent containers before melting the material.</p> <p>Ventilation Requirements: <br />Use only with adequate ventilation to control air contaminants to their exposure limits. The use of local ventilation is recommended to <br />control emissions near the source.</p> <p>Storage Room Requirements: <br />Keep container(s) tightly closed and properly labeled. Store in cool, dry, well-ventilated areas away from heat, direct sunlight, strong <br />oxidizers and any incompatibilities. Store in approved containers and protect against physical damage. Keep containers securely sealed <br />when not in use. Indoor storage should meet OSHA standards and appropriate fire codes. Containers that have been opened must be <br />carefully resealed to prevent leakage. Empty container retain residue and may be dangerous.</p> <p>SECTION 8) EXPOSURE CONTROLS/PERSONAL PROTECTION <br />Eye Protection: <br />Wear eye protection with side shields or goggles.</p> <p>Skin Protection: <br />Use of gloves approved to relevant standards made from the following materials may provide suitable chemical protection: PVC, neoprene <br />or nitrile rubber gloves. Suitability and durability of a glove is dependent on usage, e.g. frequency and duration of contact, chemical <br />resistance of glove material, glove thickness, dexterity. Always seek advice from glove suppliers. Contaminated gloves should be replaced. <br />Use of an apron and over- boots of chemically impervious materials such as neoprene or nitrile rubber is recommended to avoid skin <br />sensitization. The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at <br />the specific workplace. Launder soiled clothes or properly disposed of contaminated material, which cannot be decontaminated.</p> <p>Respiratory Protection: <br />If engineering controls do not maintain airborne concentrations to a level which is adequate to protect worker, a respiratory protection <br />program that meets or is equivalent to OSHA 29 CFR 1910.134 and ANSI Z88.2 should be followed. Check with respiratory protective <br />equipment suppliers. Where air-filtering respirators are suitable, select an appropriate combination of mask and filter.</p> <p>Appropriate Engineering Controls: <br />Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors below their respective threshold <br />limit value.</p> <p>Chemical Name</p> <p>CARBON BLACK</p> <p>OSHA <br />TWA <br />(ppm)</p> <p>OSHA <br />TWA <br />(mg/m3)</p> <p>OSHA <br />STEL <br />(ppm)</p> <p>3.5</p> <p>OSHA <br />STEL <br />(mg/m3)</p> <p>OSHATablesZ1,2,3 <br />1</p> <p>OSHA <br />NIOSH <br />OSHA <br />Skin <br />TWA <br />Carcinogen designation <br />(ppm)</p> <p>NIOSH <br />TWA <br />(mg/m3) <br />3.5a</p> <p>NIOSH <br />STEL <br />(ppm)</p> <p>NIOSH <br />STEL <br />(mg/m3)</p> <p>NIOSH <br />Carcinogen <br />1</p> <p>ETHYLENE GLYCOL</p> <p>SDS RE-ROOF Acrylic Base Coat <br />SDS DATE: 23-FEB-6</p> <p>Page 3 of 7</p> <p>SILICA, <br />CRYSTALLINE</p> <p>a</p> <p>[10 mg/m3 <br />percent <br />SiO2+2 / <br />250 <br />percent <br />SiO2+5 <br />mppcf]; [30 <br />mg/m3 <br />percent <br />SiO2+2];</p> <p>1,3</p> <p>15</p> <p>1</p> <p>TITANIUM DIOXIDE</p> <p>Chemical Name</p> <p>ACGIH <br />TWA <br />(ppm)</p> <p>ACGIH <br />TWA <br />(mg/m3)</p> <p>CARBON BLACK</p> <p>ACGIH <br />STEL <br />(ppm)</p> <p>0.05e</p> <p>b</p> <p>1</p> <p>1</p> <p>ACGIH <br />STEL <br />(mg/m3)</p> <p>3 (I)</p> <p>ETHYLENE GLYCOL <br />SILICA, <br />CRYSTALLINE</p> <p>C 100 <br />0.025 (R)</p> <p>TITANIUM DIOXIDE</p> <p>10</p> <p>SECTION 9) PHYSICAL AND CHEMICAL PROPERTIES</p> <p>Physical and Chemical Properties <br />Density</p> <p>11.59 lb/gal</p> <p>Specific Gravity</p> <p>1.39</p> <p>VOC Regulatory</p> <p>0.42 lb/gal</p> <p>VOC Part A & B Combined</p> <p>N.A.</p> <p>Appearance</p> <p>Pigmented Viscous Liquid</p> <p>Odor Threshold</p> <p>N.A.</p> <p>Odor Description</p> <p>Mild Chemical</p> <p>pH</p> <p>N.A.</p> <p>Water Solubility</p> <p>N.A.</p> <p>Flammability</p> <p>N/A</p> <p>Flash Point Symbol</p> <p>N.A.</p> <p>Flash Point</p> <p>230 °C</p> <p>Viscosity</p> <p>N.A.</p> <p>Lower Explosion Level</p> <p>N.A.</p> <p>Upper Explosion Level</p> <p>N.A.</p> <p>Vapor Pressure</p> <p>N.A.</p> <p>Vapor Density</p> <p>N.A.</p> <p>Freezing Point</p> <p>N.A.</p> <p>Melting Point</p> <p>N.A.</p> <p>Low Boiling Point</p> <p>100 °C</p> <p>High Boiling Point</p> <p>N.A.</p> <p>Auto Ignition Temp</p> <p>N.A.</p> <p>Decomposition Pt</p> <p>N.A.</p> <p>Evaporation Rate</p> <p>N.A.</p> <p>Coefficient Water/Oil</p> <p>N.A.</p> <p>SECTION 10) STABILITY AND REACTIVITY <br />Stability: <br />Material is stable at standard temperature and pressure.</p> <p>SDS RE-ROOF Acrylic Base Coat <br />SDS DATE: 23-FEB-6</p> <p>Page 4 of 7</p> <p>Conditions to Avoid: <br />Avoid storage at low or high temperatures.</p> <p>Hazardous Reactions/Polymerization: <br />Contact with isocyanates and strong oxidizers may cause highly exothermic polymerization reaction, which can be violent.</p> <p>Incompatible Materials: <br />Strong mineral acids and strong alkalis will seriously degrade material. Heat may be involved.</p> <p>Hazardous Decomposition Products: <br />Combustion by-products: Oxides of carbon, various hydrocarbons.</p> <p>SECTION 11) TOXICOLOGICAL INFORMATION <br />Skin Corrosion/Irritation: <br />No data available</p> <p>Serious Eye Damage/Irritation: <br />No data available</p> <p>Respiratory/Skin Sensitization: <br />No data available</p> <p>Carcinogenicity: <br />Suspected of causing cancer.</p> <p>Germ Cell Mutagenicity: <br />No data available</p> <p>Reproductive Toxicity: <br />No data available</p> <p>Specific Target Organ Toxicity - Single Exposure: <br />Causes damage to organs.</p> <p>Specific Target Organ Toxicity - Repeated Exposure: <br />No data available</p> <p>Aspiration Hazard: <br />No data available</p> <p>Acute Toxicity: <br />No data available</p> <p>0001333-86-4</p> <p>CARBON BLACK</p> <p>LC50 (rat): 6750 mg/m3 (4-hour exposure); cited as 27000 mg/m3 (27 mg/L) (1-hour exposure) (3) <br />0000107-21-1</p> <p>ETHYLENE GLYCOL</p> <p>LD50 (oral, rat): 5.89 g/kg; 8.54 g/kg; 13.0 g/kg (5) <br />LD50 (oral, mouse): 7.5 g/kg; 15.28 g/kg (5,6) <br />LD50 (oral, guinea pig): 6.6 g/kg; 11.0 g/kg (5) <br />LD50 (oral, rabbit): 5.0 g/kg (5) <br />LD50 (dermal, rabbit): 9.5 g/kg (6)</p> <p>Chronic Exposure <br />0001333-86-4</p> <p>CARBON BLACK</p> <p>CARCINOGENIC EFFECTS: In 1996, the IARC reevaluated Carbon Black as a Group 2B carcinogen. This evaluation is given to <br />carbon black for which there is inadequate human evidence, but sufficient animal evidence. <br />Prolonged inhalation of Carbon black can result in lung disease. Symptoms include coughing, shortness of breath, wheezing and <br />reduced pulmonary function. <br />0014808-60-7</p> <p>SILICA, CRYSTALLINE</p> <p>Prolonged inhalation of respirable crystalline silica dust can result in lung disease (i.e. silicosis and/or lung cancer). Symptoms include <br />coughing, shortness of breath, wheezing and reduced pulmonary function.</p> <p>Potential Health Effects - Miscellaneous</p> <p>SDS RE-ROOF Acrylic Base Coat <br />SDS DATE: 23-FEB-6</p> <p>Page 5 of 7</p> <p>0001333-86-4</p> <p>CARBON BLACK</p> <p>Is an IARC, NTP or OSHA carcinogen. Has shown carcinogenic activity in laboratory animals at high doses. Significance to man is <br />unknown. The following medical conditions may be aggravated by exposure: asthma, respiratory disease. WARNING: This chemical is <br />known to the State of California to cause cancer. <br />0013463-67-7</p> <p>TITANIUM DIOXIDE</p> <p>Is an IARC, NTP or OSHA carcinogen. In a lifetime inhalation test, lung cancers were found in some rats exposed to 250 mg/m3 <br />respirable titanium dust. Analysis of the titanium dioxide concentrations in the rat?s lungs showed that the lung clearance mechanism <br />was overwhelmed and that the results at the massive 250 mg/m3 level are not relevant to the workplace.?Results of a DuPont <br />epidemiology study showed that employees who had been exposed to Titanium Dioxide were at no greater risk of developing lung <br />cancer than were employees who had not been exposed to Titanium dioxide. No pulmonary fibrosis was found in any of the employees <br />and no association was observed between Titanium dioxide exposure and chronic respiratory disease or x-ray abnormalities. Based on <br />the results of this study DuPont concludes that titanium dioxide will not cause lung cancer or chronic respiratory disease in humans at <br />concentrations experienced in the workplace.? <br />0014808-60-7</p> <p>SILICA, CRYSTALLINE</p> <p>Is an IARC, NTP or OSHA carcinogen. Repeated overexposure to crystalline silica may lead to x-ray changes and chronic lung disease. <br />Inhalation of high dust concentrations may cause: breathing difficulties, lung injury. WARNING: This chemical is known to the State of <br />California to cause cancer.</p> <p>SECTION 12) ECOLOGICAL INFORMATION <br />Toxicity: <br />No data available</p> <p>Persistence and Degradability: <br />No data available.</p> <p>Bioaccumulative Potential: <br />No data available.</p> <p>Mobility in Soil: <br />No data available.</p> <p>Other Adverse Effects: <br />No data available.</p> <p>Bio-accumulative Potential <br />0001333-86-4</p> <p>CARBON BLACK</p> <p>A relevant bioaccumulation potential of carbon black is not expected based on its insolubility in organic solvents and in water. <br />Furthermore, since the aggregate diameter of carbon black varies between 80 nm and 810 nm, bioaccumulation of particulate carbon <br />black is not likely oweing to the large diameter of the solid aggregate particles.</p> <p>Persistence and Degradability <br />0001333-86-4</p> <p>CARBON BLACK</p> <p>Carbon Black's insolubility in water results in it not being biodegradable in any medium or by biota. It is considered persistent in the <br />natural environment.</p> <p>SECTION 13) DISPOSAL CONSIDERATIONS <br />Waste Disposal: <br />Under RCRA, it is the responsibility of the user of the product, to determine a the time of disposal whether the product meets RCRA criteria <br />for hazardous waste. Waste management should be in full compliance with federal, state, and local laws. <br />Empty containers retain product residue which may exhibit hazards of material, therefore do not pressurize, cut, glaze, weld or use for any <br />other purposes. Return drums to reclamation centers for proper cleaning and reuse.</p> <p>SECTION 14) TRANSPORT INFORMATION <br />U.S. DOT Information: <br />Not regulated.</p> <p>IMDG Information: <br />Not regulated.</p> <p>IATA Information: <br />Not regulated.</p> <p>SDS RE-ROOF Acrylic Base Coat <br />SDS DATE: 23-FEB-6</p> <p>Page 6 of 7</p> <p>SECTION 15) REGULATORY INFORMATION</p> <p>CAS</p> <p>Chemical Name</p> <p>0000107-21-1</p> <p>ETHYLENE GLYCOL</p> <p>0001333-86-4</p> <p>CARBON BLACK</p> <p>0013463-67-7</p> <p>TITANIUM DIOXIDE</p> <p>0014808-60-7</p> <p>SILICA, CRYSTALLINE</p> <p>% By Weight</p> <p>Regulation List <br />1.3% - 2.2% CERCLA,HAPS,SARA312,SARA313,VHAPS,VOC,TSCA <br />0.1% SARA312,TSCA,California Proposition 65 <br />3% - 6% SARA312,TSCA,California Proposition 65 <br />0.3% - 0.6% SARA312,TSCA,California Proposition 65</p> <p>SECTION 16) OTHER INFORMATION <br />OTHER INFORMATION: <br />Note: As per GHS, category 1 is the greatest level of hazard within each class.</p> <p>GLOSSARY: <br />ACGIH- American Conference of Governmental Industrial Hygienists; ANSI- American National Standards Institute; Canadian TDGCanadian Transportation of Dangerous Goods; CAS- Chemical Abstract Service; Chemtrec- Chemical Transportation Emergency Center <br />(US); CHIP- Chemical Hazard Information and Packaging; DSL- Domestic Substances List; EC- Equivalent Concentration; EH40 (UK)HSE Guidance Note EH40 Occupational Exposure Limits; EPCRA- Emergency Planning and Community Right-To-Know Act; ESL- Effects <br />screening levels; HMIS- Hazardous Material Information Service; LC- Lethal Concentration; LD- Lethal Dose; NFPA- National Fire <br />Protection Association; OEL- Occupational Exposure Limits; OSHA- Occupational Safety and Health Administration, US Department of <br />Labor; PEL- Permissible Exposure Limit; SARA (Title III)- Superfund Amendments and Reauthorization Act; SARA 313- Superfund <br />Amendments and Reauthorization Act, Section 313; SCBA- Self-Contained Breathing Apparatus; STEL- Short Term Exposure Limit; TCEQ <br />- Texas Commission on Environmental Quality; TLV- Threshold Limit Value; TSCA- Toxic Substances Control Act Public Law 94-469; TWA <br />- Time Weighted Value; US DOT- US Department of Transportation; WHMIS- Workplace Hazardous Materials Information System.</p> <p>DISCLAIMER <br />To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its subsidiaries <br />assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any <br />material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain <br />hazards are described herein, we cannot guarantee that these are the only hazards that exist. The above information pertains to this product as <br />currently formulated, and is based on the information available at this time. Addition of reducers or other additives to this product may substantially <br />alter the composition and hazards of the product. Since conditions of use are outside our control, we make no warranties, express or implied, and <br />assume no liability in connection with any use of this information.</p> <p>SDS RE-ROOF Acrylic Base Coat <br />SDS DATE: 23-FEB-6</p> <p>Page 7 of 7</p>
