SDS_RE-ROOF Acrylic Flashing_020623.pdf
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<h1>SDS_RE-ROOF Acrylic Flashing_020623.pdf</h1> <p>Safety Data Sheet (SDS)</p> <p>Page 1/7</p> <p>OSHA HazCom Standard 29 CFR 1910.1200(g) and GHS Rev 03.</p> <p>Printing date 02/06/23</p> <p>Reviewed on 02/06/23</p> <p>SECTION 1) CHEMICAL PRODUCT AND SUPPLIER'S IDENTIFICATION</p> <p>IDENTITY:</p> <p>Product Name: RE-ROOF Acrylic Flashing <br />Product Use Description:</p> <p>AQUAFIN, INC. <br />505 BLUE BALL RD. #160 <br />ELKTON, MD 21921</p> <p>Water-based Acrylic Liquid Roof Flashing, For Further Information, Refer to the <br />Product Technical Data Sheet.</p> <p>info@aquafin.net</p> <p>24 hr Emergency Phone: Chem-Tel (800) 255-3924 <br />Information Phone No: (410) 392-2300</p> <p>www.aquafin.net</p> <p>SECTION 2) HAZARDS IDENTIFICATION <br />Classification: <br />Specific Target Organ Toxicity - Single Exposure - Category 1 <br />Skin Irritation - Category 3 <br />Carcinogenicity - Category 2 <br />Eye Irritation - Category 2 <br />Acute aquatic toxicity - Category 3 <br />Chronic aquatic toxicity - Category 3</p> <p>Pictograms:</p> <p>Signal Word: <br />Danger</p> <p>Hazardous Statements - Health: <br />H370 - Causes damage to organs. <br />H316 - Causes mild skin irritation <br />H351 - Suspected of causing cancer. <br />H319 - Causes serious eye irritation</p> <p>Hazardous Statements - Environmental: <br />H402 - Harmful to aquatic life <br />H412 - Harmful to aquatic life with long lasting effects</p> <p>Precautionary Statements - General: <br />P101 - If medical advice is needed, have product container or label at hand. <br />P102 - Keep out of reach of children. <br />P103 - Read label before use.</p> <p>Precautionary Statements - Prevention: <br />P260 - Do not breathe dust/fume/gas/mist/vapors/spray.</p> <p>SDS RE-ROOF Acrylic Flashing <br />SDS DATE: 23-FEB-6</p> <p>Page 1 of 7</p> <p>P264 - Wash thoroughly after handling. <br />P270 - Do not eat, drink or smoke when using this product. <br />P201 - Obtain special instructions before use. <br />P202 - Do not handle until all safety precautions have been read and understood. <br />P280 - Wear protective gloves/protective clothing/eye protection/face protection. <br />P273 - Avoid release to the environment.</p> <p>Precautionary Statements - Response: <br />P308 + P311 - IF exposed or concerned: Call a POISON CENTER/doctor. <br />P321 - Specific treatment (see section 4 on this SDS). <br />P332 + P313 - If skin irritation occurs: Get medical advice/attention. <br />P308 + P313 - IF exposed or concerned: Get medical advice/attention. <br />P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue <br />rinsing. <br />P337 + P313 - If eye irritation persists: Get medical advice/attention.</p> <p>Precautionary Statements - Storage: <br />P405 - Store locked up.</p> <p>Precautionary Statements - Disposal: <br />P501 - Dispose of contents/ container to an approved waste disposal plant.</p> <p>SECTION 3) COMPOSITION / INFORMATION ON INGREDIENTS <br />CAS</p> <p>Chemical Name</p> <p>% By Weight</p> <p>0013463-67-7</p> <p>TITANIUM DIOXIDE</p> <p>4% - 8%</p> <p>0000107-21-1</p> <p>ETHYLENE GLYCOL</p> <p>1.0% - 1.7%</p> <p>0001314-13-2</p> <p>ZINC OXIDE</p> <p>0.0% - 5%</p> <p>0001333-86-4</p> <p>CARBON BLACK</p> <p>0.1% - 0.2%</p> <p>SECTION 4) FIRST-AID MEASURES <br />Inhalation: <br />Remove source of exposure or move person to fresh air and keep comfortable for breathing. <br />If exposed/feel unwell/concerned: Call a POISON CENTER/doctor.</p> <p>Skin Contact: <br />Rinse/wash with lukewarm, gently flowing water and mild soap for 15-20 minutes or until product is removed. If skin irritation occurs or you <br />feel unwell: Get medical advice/attention.</p> <p>Eye Contact: <br />Remove source of exposure or move person to fresh air. Rinse eyes cautiously with lukewarm, gently flowing water for several minutes, <br />while holding the eyelids open. Remove contact lenses, if present and easy to do. Continue rinsing for a duration of 15-20 minutes. Take <br />care not to rinse contaminated water into the unaffected eye or onto the face. If eye irritation persists: Get medical advice/attention.</p> <p>Ingestion: <br />Rinse mouth. If you feel unwell/If concerned: Get medical advice/attention.</p> <p>SECTION 5) FIRE-FIGHTING MEASURES <br />Suitable Extinguishing Media: <br />Dry chemical, foam, carbon dioxide is recommended. Water spray is recommended to cool or protect exposed materials or structures. <br />Carbon dioxide can displace oxygen. Use caution when applying carbon dioxide in confined spaces. Simultaneous use of foam and water <br />on the same surface is to be avoided as water destroys the foam. Sand or earth may be used for small fires only.</p> <p>Unsuitable Extinguishing Media: <br />Water and foam may cause violent frothing and possibly endanger the life of the fire fighter, especially if sprayed into containers of hot, <br />burning material.</p> <p>Specific Hazards in Case of Fire: <br />Hazardous combustion products include oxides of carbon and nitrogen, various hydrocarbons.</p> <p>SDS RE-ROOF Acrylic Flashing <br />SDS DATE: 23-FEB-6</p> <p>Page 2 of 7</p> <p>Fire-fighting Procedures: <br />Isolate immediate hazard area and keep unauthorized personnel out. Stop spill/release if it can be done safely. Move undamaged <br />containers from immediate hazard area if it can be done safely. Water spray may be useful in minimizing or dispersing vapors and to <br />protect personnel. Water may be ineffective but can be used to cool containers exposed to heat or flame. Caution should be exercised <br />when using water or foam as frothing may occur, especially if sprayed into containers of hot, burning liquid. <br />Dispose of fire debris and contaminated extinguishing water in accordance with official regulations.</p> <p>Special Protective Actions: <br />Care should always be exercised in dust/mist areas. <br />Wear protective pressure self-contained breathing apparatus (SCBA)and full turnout gear.</p> <p>SECTION 6) ACCIDENTAL RELEASE MEASURES <br />Emergency Procedure: <br />Keep unnecessary people away; isolate hazard area and deny entry. Do not touch or walk through spilled material. Clean up immediately.</p> <p>Recommended Equipment: <br />Positive pressure, full-face piece self-contained breathing apparatus(SCBA), or positive pressure supplied air respirator with escape SCBA <br />(NIOSH approved).</p> <p>Personal Precautions: <br />Avoid breathing vapors. Avoid contact with skin, eyes or clothing. Do not touch damaged containers or spilled materials unless wearing <br />appropriate protective clothing.</p> <p>Environmental Precautions: <br />Stop spill/release if it can be done safely. Prevent spilled material from entering sewers, storm drains, other unauthorized drainage systems <br />and natural waterways by using sand, earth, or other appropriate barriers.</p> <p>Methods and Materials for Containment and Cleaning up: <br />Confine spillage and absorb on sand, sawdust, or other suitable absorbent material and transfer to a sealed container.</p> <p>SECTION 7) HANDLING AND STORAGE <br />General: <br />Wash hands after use. <br />Do not get in eyes, on skin or on clothing. <br />Do not breathe vapors or mists. <br />Use good personal hygiene practices. <br />Eating, drinking and smoking in work areas is prohibited. <br />Remove contaminated clothing and protective equipment before entering eating areas. <br />Vent containers before melting the material.</p> <p>Ventilation Requirements: <br />Use only with adequate ventilation to control air contaminants to their exposure limits. The use of local ventilation is recommended to <br />control emissions near the source.</p> <p>Storage Room Requirements: <br />Keep container(s) tightly closed and properly labeled. Store in cool, dry, well-ventilated areas away from heat, direct sunlight, strong <br />oxidizers and any incompatibilities. Store in approved containers and protect against physical damage. Keep containers securely sealed <br />when not in use. Indoor storage should meet OSHA standards and appropriate fire codes. Containers that have been opened must be <br />carefully resealed to prevent leakage. Empty container retain residue and may be dangerous.</p> <p>SECTION 8) EXPOSURE CONTROLS/PERSONAL PROTECTION <br />Eye Protection: <br />Wear eye protection with side shields or goggles.</p> <p>Skin Protection: <br />Use of gloves approved to relevant standards made from the following materials may provide suitable chemical protection: PVC, neoprene <br />or nitrile rubber gloves. Suitability and durability of a glove is dependent on usage, e.g. frequency and duration of contact, chemical <br />resistance of glove material, glove thickness, dexterity. Always seek advice from glove suppliers. Contaminated gloves should be replaced. <br />Use of an apron and over- boots of chemically impervious materials such as neoprene or nitrile rubber is recommended to avoid skin <br />sensitization. The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at <br />the specific workplace. Launder soiled clothes or properly disposed of contaminated material, which cannot be decontaminated.</p> <p>Respiratory Protection: <br />If engineering controls do not maintain airborne concentrations to a level which is adequate to protect worker, a respiratory protection <br />program that meets or is equivalent to OSHA 29 CFR 1910.134 and ANSI Z88.2 should be followed. Check with respiratory protective <br />equipment suppliers. Where air-filtering respirators are suitable, select an appropriate combination of mask and filter.</p> <p>SDS RE-ROOF Acrylic Flashing <br />SDS DATE: 23-FEB-6</p> <p>Page 3 of 7</p> <p>Appropriate Engineering Controls: <br />Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors below their respective threshold <br />limit value. <br />Chemical Name</p> <p>OSHA <br />TWA <br />(ppm)</p> <p>OSHA <br />TWA <br />(mg/m3)</p> <p>CARBON BLACK</p> <p>OSHA <br />STEL <br />(ppm)</p> <p>OSHA <br />STEL <br />(mg/m3)</p> <p>OSHA <br />OSHA <br />NIOSH <br />Tables (Z1, OSHA <br />Skin <br />TWA <br />Z2, Z3) Carcinogen designation <br />(ppm)</p> <p>3.5</p> <p>1</p> <p>15</p> <p>1</p> <p>[15]; [5];</p> <p>1</p> <p>NIOSH <br />TWA <br />(mg/m3)</p> <p>NIOSH <br />STEL <br />(ppm)</p> <p>NIOSH <br />STEL <br />(mg/m3)</p> <p>3.5a</p> <p>NIOSH <br />Carcinogen <br />1</p> <p>ETHYLENE GLYCOL <br />TITANIUM DIOXIDE <br />ZINC OXIDE</p> <p>Chemical Name</p> <p>ACGIH <br />TWA <br />(ppm)</p> <p>ACGIH <br />TWA <br />(mg/m3)</p> <p>CARBON BLACK</p> <p>ACGIH <br />STEL <br />(ppm)</p> <p>b</p> <p>1 <br />5,5c</p> <p>10d</p> <p>ACGIH <br />STEL <br />(mg/m3)</p> <p>3 (I)</p> <p>ETHYLENE GLYCOL</p> <p>C 100</p> <p>TITANIUM DIOXIDE <br />ZINC OXIDE</p> <p>10 <br />2 (R)</p> <p>10 (R)</p> <p>(I) - Inhalable fraction</p> <p>SECTION 9) PHYSICAL AND CHEMICAL PROPERTIES <br />Physical and Chemical Properties <br />Density</p> <p>12.15 lb/gal</p> <p>Specific Gravity</p> <p>1.46</p> <p>VOC Regulatory</p> <p>0.40 lb/gal</p> <p>VOC Part A & B Combined</p> <p>N.A.</p> <p>Appearance</p> <p>Pigmented Viscous Liquid</p> <p>Odor Threshold</p> <p>N.A.</p> <p>Odor Description</p> <p>Mild Chemical</p> <p>pH</p> <p>N.A.</p> <p>Water Solubility</p> <p>N.A.</p> <p>Flammability</p> <p>N/A</p> <p>Flash Point Symbol</p> <p>N.A.</p> <p>Flash Point</p> <p>230 °C</p> <p>Viscosity</p> <p>N.A.</p> <p>Lower Explosion Level</p> <p>N.A.</p> <p>Upper Explosion Level</p> <p>N.A.</p> <p>Vapor Pressure</p> <p>N.A.</p> <p>Vapor Density</p> <p>Heavier than air</p> <p>Freezing Point</p> <p>N.A.</p> <p>Melting Point</p> <p>N.A.</p> <p>Low Boiling Point</p> <p>100 °C</p> <p>High Boiling Point</p> <p>N.A.</p> <p>Auto Ignition Temp</p> <p>N.A.</p> <p>Decomposition Pt</p> <p>N.A.</p> <p>Evaporation Rate</p> <p>Slower than ether</p> <p>Coefficient Water/Oil</p> <p>N.A.</p> <p>SECTION 10) STABILITY AND REACTIVITY <br />SDS RE-ROOF Acrylic Flashing <br />SDS DATE: 23-FEB-6</p> <p>Page 4 of 7</p> <p>Stability: <br />Material is stable at standard temperature and pressure.</p> <p>Conditions to Avoid: <br />Avoid storage at low or high temperatures.</p> <p>Hazardous Reactions/Polymerization: <br />Contact with isocyanates and strong oxidizers may cause highly exothermic polymerization reaction, which can be violent.</p> <p>Incompatible Materials: <br />Strong mineral acids and strong alkalis will seriously degrade material. Heat may be involved.</p> <p>Hazardous Decomposition Products: <br />Combustion by-products: Oxides of carbon, various hydrocarbons.</p> <p>SECTION 11) TOXICOLOGICAL INFORMATION <br />Skin Corrosion/Irritation: <br />Causes mild skin irritation</p> <p>Serious Eye Damage/Irritation: <br />Causes serious eye irritation</p> <p>Respiratory/Skin Sensitization: <br />No data available</p> <p>Carcinogenicity: <br />Suspected of causing cancer.</p> <p>Germ Cell Mutagenicity: <br />No data available</p> <p>Reproductive Toxicity: <br />No data available</p> <p>Specific Target Organ Toxicity - Single Exposure: <br />Causes damage to organs.</p> <p>Specific Target Organ Toxicity - Repeated Exposure: <br />No data available</p> <p>Aspiration Hazard: <br />No data available</p> <p>Acute Toxicity: <br />No data available <br />0001333-86-4</p> <p>CARBON BLACK</p> <p>LC50 (rat): 6750 mg/m3 (4-hour exposure); cited as 27000 mg/m3 (27 mg/L) (1-hour exposure) (3) <br />0000107-21-1</p> <p>ETHYLENE GLYCOL</p> <p>LD50 (oral, rat): 5.89 g/kg; 8.54 g/kg; 13.0 g/kg (5) <br />LD50 (oral, mouse): 7.5 g/kg; 15.28 g/kg (5,6) <br />LD50 (oral, guinea pig): 6.6 g/kg; 11.0 g/kg (5) <br />LD50 (oral, rabbit): 5.0 g/kg (5) <br />LD50 (dermal, rabbit): 9.5 g/kg (6) <br />0001314-13-2</p> <p>ZINC OXIDE</p> <p>LD50 (oral, mouse): 7950 mg/kg body weight (9)</p> <p>Chronic Exposure <br />0001333-86-4</p> <p>CARBON BLACK</p> <p>CARCINOGENIC EFFECTS: In 1996, the IARC reevaluated Carbon Black as a Group 2B carcinogen. This evaluation is given to <br />carbon black for which there is inadequate human evidence, but sufficient animal evidence. <br />Prolonged inhalation of Carbon black can result in lung disease. Symptoms include coughing, shortness of breath, wheezing and <br />reduced pulmonary function.</p> <p>Potential Health Effects - Miscellaneous</p> <p>SDS RE-ROOF Acrylic Flashing <br />SDS DATE: 23-FEB-6</p> <p>Page 5 of 7</p> <p>0001333-86-4</p> <p>CARBON BLACK</p> <p>Is an IARC, NTP or OSHA carcinogen. Has shown carcinogenic activity in laboratory animals at high doses. Significance to man is <br />unknown. The following medical conditions may be aggravated by exposure: asthma, respiratory disease. WARNING: This <br />chemical is known to the State of California to cause cancer. <br />0013463-67-7</p> <p>TITANIUM DIOXIDE</p> <p>Is an IARC, NTP or OSHA carcinogen. In a lifetime inhalation test, lung cancers were found in some rats exposed to 250 mg/m3 <br />respirable titanium dust. Analysis of the titanium dioxide concentrations in the rat?s lungs showed that the lung clearance <br />mechanism was overwhelmed and that the results at the massive 250 mg/m3 level are not relevant to the workplace.?Results of a <br />DuPont epidemiology study showed that employees who had been exposed to Titanium Dioxide were at no greater risk of <br />developing lung cancer than were employees who had not been exposed to Titanium dioxide. No pulmonary fibrosis was found in <br />any of the employees and no association was observed between Titanium dioxide exposure and chronic respiratory disease or xray abnormalities. Based on the results of this study DuPont concludes that titanium dioxide will not cause lung cancer or chronic <br />respiratory disease in humans at concentrations experienced in the workplace.?</p> <p>SECTION 12) ECOLOGICAL INFORMATION <br />Toxicity: <br />Harmful to aquatic life <br />Harmful to aquatic life with long lasting effects</p> <p>Mobility in Soil: <br />No data available.</p> <p>Other Adverse Effects: <br />No data available.</p> <p>Bio-accumulative Potential <br />0001333-86-4</p> <p>CARBON BLACK</p> <p>A relevant bioaccumulation potential of carbon black is not expected based on its insolubility in organic solvents and in water. <br />Furthermore, since the aggregate diameter of carbon black varies between 80 nm and 810 nm, bioaccumulation of particulate <br />carbon black is not likely oweing to the large diameter of the solid aggregate particles.</p> <p>Persistence and Degradability <br />0001333-86-4</p> <p>CARBON BLACK</p> <p>Carbon Black's insolubility in water results in it not being biodegradable in any medium or by biota. It is considered persistent in <br />the natural environment.</p> <p>SECTION 13) DISPOSAL CONSIDERATIONS <br />Waste Disposal: <br />Under RCRA, it is the responsibility of the user of the product, to determine a the time of disposal whether the product meets RCRA criteria <br />for hazardous waste. Waste management should be in full compliance with federal, state, and local laws. <br />Empty containers retain product residue which may exhibit hazards of material, therefore do not pressurize, cut, glaze, weld or use for any <br />other purposes. Return drums to reclamation centers for proper cleaning and reuse.</p> <p>SECTION 14) TRANSPORT INFORMATION <br />U.S. DOT Information: <br />Not Regulated</p> <p>IMDG Information: <br />Not Regulated</p> <p>IATA Information: <br />Not Regulated</p> <p>SDS RE-ROOF Acrylic Flashing <br />SDS DATE: 23-FEB-6</p> <p>Page 6 of 7</p> <p>SECTION 15) REGULATORY INFORMATION <br />CAS</p> <p>Chemical Name</p> <p>0013463-67-7</p> <p>TITANIUM DIOXIDE</p> <p>0000107-21-1</p> <p>ETHYLENE GLYCOL</p> <p>0001314-13-2</p> <p>ZINC OXIDE</p> <p>0001333-86-4</p> <p>CARBON BLACK</p> <p>% By Weight</p> <p>Regulation List <br />4% - 8% DSL,SARA312,TSCA,California Proposition 65 <br />1.0% - 1.7% DSL,CERCLA,HAPS,SARA312,SARA313,VHAPS,VOC,TSCA,California Proposition 65 <br />0.0% - 5% DSL,CERCLA,SARA312,SARA313,TSCA <br />0.1% - 0.2% DSL,SARA312,TSCA,California Proposition 65</p> <p>SECTION 16) OTHER INFORMATION <br />OTHER INFORMATION: <br />Note: As per GHS, category 1 is the greatest level of hazard within each class.</p> <p>GLOSSARY: <br />ACGIH- American Conference of Governmental Industrial Hygienists; ANSI- American National Standards Institute; Canadian TDGCanadian Transportation of Dangerous Goods; CAS- Chemical Abstract Service; Chemtrec- Chemical Transportation Emergency Center <br />(US); CHIP- Chemical Hazard Information and Packaging; DSL- Domestic Substances List; EC- Equivalent Concentration; EH40 (UK)HSE Guidance Note EH40 Occupational Exposure Limits; EPCRA- Emergency Planning and Community Right-To-Know Act; ESL- Effects <br />screening levels; HMIS- Hazardous Material Information Service; LC- Lethal Concentration; LD- Lethal Dose; NFPA- National Fire <br />Protection Association; OEL- Occupational Exposure Limits; OSHA- Occupational Safety and Health Administration, US Department of <br />Labor; PEL- Permissible Exposure Limit; SARA (Title III)- Superfund Amendments and Reauthorization Act; SARA 313- Superfund <br />Amendments and Reauthorization Act, Section 313; SCBA- Self-Contained Breathing Apparatus; STEL- Short Term Exposure Limit; TCEQ <br />- Texas Commission on Environmental Quality; TLV- Threshold Limit Value; TSCA- Toxic Substances Control Act Public Law 94-469; TWA <br />- Time Weighted Value; US DOT- US Department of Transportation; WHMIS- Workplace Hazardous Materials Information System.</p> <p>DISCLAIMER <br />To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its subsidiaries <br />assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any <br />material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain <br />hazards are described herein, we cannot guarantee that these are the only hazards that exist. The above information pertains to this product as <br />currently formulated, and is based on the information available at this time. Addition of reducers or other additives to this product may substantially <br />alter the composition and hazards of the product. Since conditions of use are outside our control, we make no warranties, express or implied, and <br />assume no liability in connection with any use of this information.</p> <p>SDS RE-ROOF Acrylic Flashing <br />SDS DATE: 23-FEB-6</p> <p>Page 7 of 7</p>
