SDS_RE-ROOF Primer PO_B-Component - 112822.pdf
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<h1>SDS_RE-ROOF Primer PO_B-Component - 112822.pdf</h1> <p>Safety Data Sheet (SDS)</p> <p>Page 1/8</p> <p>OSHA HazCom Standard 29 CFR 1910.1200(g) and GHS Rev 03.</p> <p>Printing date 11/28/2022</p> <p>Reviewed on 11/28/2022</p> <p>SECTION 1) CHEMICAL PRODUCT AND SUPPLIER'S IDENTIFICATION</p> <p>IDENTITY:</p> <p>Product Name: RE-ROOF Primer PO COMPONENT B <br />Product Use Description:</p> <p>AQUAFIN, INC. <br />505 BLUE BALL RD. #160 <br />ELKTON, MD 21921</p> <p>Polyurethane Primer, For Further Information, Refer to the Product <br />Technical Data Sheet.</p> <p>info@aquafin.net</p> <p>24 hr Emergency Phone: Chem-Tel (800) 255-3924 <br />Information Phone No: (410) 392-2300</p> <p>www.aquafin.net</p> <p>SECTION 2) HAZARDS IDENTIFICATION <br />Classification <br />Carcinogenicity - Category 2 <br />Eye Irritation - Category 2 <br />Reproductive Toxicity - Category 1B <br />Skin Irritation - Category 2 <br />Specific Target Organ Toxicity - Repeated Exposure - Category 2</p> <p>Pictograms</p> <p>Signal Word <br />Danger</p> <p>Hazardous Statements - Health <br />H351 - Suspected of causing cancer. <br />H319 - Causes serious eye irritation <br />H360 - May damage fertility or the unborn child. <br />H315 - Causes skin irritation <br />H373 - May cause damage to organs through prolonged or repeated exposure.</p> <p>Precautionary Statements - General <br />P101 - If medical advice is needed, have product container or label at hand. <br />P102 - Keep out of reach of children. <br />P103 - Read label before use.</p> <p>Precautionary Statements - Prevention <br />P201 - Obtain special instructions before use. <br />P202 - Do not handle until all safety precautions have been read and understood. <br />P280 - Wear protective gloves/protective clothing/eye protection/face protection.</p> <p>SDS RE-ROOF Primer PO Comp B <br />SDS DATE: 22-NOV-28</p> <p>www.aquafin.net</p> <p>Page 1 of 8</p> <p>P264 - Wash thoroughly after handling. <br />P260 - Do not breathe dust/fume/gas/mist/vapors/spray.</p> <p>Precautionary Statements - Response <br />P308 + P313 - IF exposed or concerned: Get medical advice/attention. <br />P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. <br />Continue rinsing. <br />P337 + P313 - If eye irritation persists: Get medical advice/attention. <br />P302 + P352 - IF ON SKIN: Wash with plenty of water. <br />P321 - Specific treatment (see section 4 on this SDS). <br />P332 + P313 - If skin irritation occurs: Get medical advice/attention. <br />P362 + P364 - Take off contaminated clothing. And wash it before reuse. <br />P314 - Get Medical advice/attention if you feel unwell.</p> <p>Precautionary Statements - Storage <br />P405 - Store locked up.</p> <p>Precautionary Statements - Disposal <br />P501 - Dispose of contents/ container to an approved waste disposal plant.</p> <p>SECTION 3) COMPOSITION/INFORMATION ON INGREDIENTS <br />CAS</p> <p>Chemical Name</p> <p>% By Weight</p> <p>0000872-50-4</p> <p>M-PYROL</p> <p>4% - 7%</p> <p>0013463-67-7</p> <p>TITANIUM DIOXIDE</p> <p>1.5% - 3%</p> <p>0014808-60-7</p> <p>SILICA, CRYSTALLINE</p> <p>0.9% - 1.5%</p> <p>0006864-37-5</p> <p>CYCLOHEXANAMINE, 4,4'-METHYLENEBIS[2-METHYL-</p> <p>0.4% - 0.7%</p> <p>Specific chemical identity and/or exact percentage (concentration) of the composition has been withheld to protect confidentiality.</p> <p>SECTION 4) FIRST-AID MEASURES <br />Inhalation <br />Remove source of exposure or move person to fresh air and keep comfortable for breathing. If experiencing respiratory symptoms: Call a <br />POISON CENTER/doctor. If breathing is difficult, trained personnel should administer emergency oxygen if advised to do so by the <br />POISON CENTER/doctor. <br />If exposed/feel unwell/concerned: Call a POISON CENTER/doctor.</p> <p>Skin Contact <br />Take off contaminated clothing, shoes and leather goods (e.g. watchbands, belts). Gently blot or brush away excess product. Wash with <br />plenty of lukewarm, gently flowing water for a duration of 15-20 minutes. If skin irritation or rash occurs: Get medical advice/attention. <br />Wash contaminated clothing before re-use or discard. <br />IF exposed or concerned: Get medical advice/attention.</p> <p>Eye Contact <br />Remove source of exposure or move person to fresh air. Rinse eyes cautiously with lukewarm, gently flowing water for several minutes, <br />while holding the eyelids open. Remove contact lenses, if present and easy to do. Continue rinsing for a duration of 15-20 minutes. Take <br />care not to rinse contaminated water into the unaffected eye or onto the face. If eye irritation persists: Get medical advice/attention.</p> <p>Ingestion <br />Immediately call a POISON CENTER/doctor. Do NOT induce vomiting. If vomiting occurs naturally, lie on your side, in the recovery <br />position. <br />Give 1 or 2 glasses of milk or water to drink and refer person to medical personnel. Do not give anything by mouth to an unconscious <br />person. <br />IF exposed or concerned: Get medical advice/attention.</p> <p>SECTION 5) FIRE-FIGHTING MEASURES <br />SDS RE-ROOF Primer PO Comp B <br />SDS DATE: 22-NOV-28</p> <p>www.aquafin.net</p> <p>Page 2 of 8</p> <p>Suitable Extinguishing Media <br />Dry chemical, foam, carbon dioxide water spray or fog is recommended. Water spray is recommended to cool or protect exposed <br />materials or structures. Carbon dioxide can displace oxygen. Use caution when applying carbon dioxide in confined spaces. Simultaneous <br />use of foam and water on the same surface is to be avoided as water destroys the foam. Sand or earth may be used for small fires only.</p> <p>Specific Hazards in Case of Fire <br />Sudden reaction and fire may result when the product is exposed to oxidizing agents.</p> <p>Fire-fighting Procedures <br />Isolate immediate hazard area and keep unauthorized personnel out. Stop spill/release if it can be done safely. Move undamaged <br />containers from immediate hazard area if it can be done safely. Water spray may be useful in minimizing or dispersing vapors and to <br />protect personnel. Water may be ineffective but can be used to cool containers exposed to heat or flame. Caution should be exercised <br />when using water or foam as frothing may occur, especially if sprayed into containers of hot, burning liquid. <br />Dispose of fire debris and contaminated extinguishing water in accordance with official regulations.</p> <p>Special Protective Actions <br />Wear NIOSH approved self-contained breathing apparatus in positive pressure mode with full-face piece. Boots, gloves (neoprene), <br />googles, and full protective clothing are also required. <br />Care should always be exercised in dust/mist areas.</p> <p>SECTION 6) ACCIDENTAL RELEASE MEASURES <br />Emergency Procedure <br />Keep unnecessary people away; isolate hazard area and deny entry. Do not touch or walk through spilled material. Clean up immediately. <br />ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area).</p> <p>Recommended Equipment <br />Appropriate dust or face mask to eliminate breathing foam dust particulates.</p> <p>Personal Precautions <br />Avoid breathing vapors. Avoid contact with skin, eyes or clothing. Do not touch damaged containers or spilled materials unless wearing <br />appropriate protective clothing.</p> <p>Environmental Precautions <br />Stop spill/release if it can be done safely. Prevent spilled material from entering sewers, storm drains, other unauthorized drainage <br />systems and natural waterways by using sand, earth, or other appropriate barriers.</p> <p>Methods and Materials for Containment and Cleaning up <br />Soak up material with absorbent and shovel into a chemical waste container. Cover container, but do not seal, and remove from work <br />area. Residues from spill cleanup may continue to be regulated under provisions of RCRA and require storage and disposal as hazardous <br />waste. For major spills, call CHEMTREC (Chemical Transportation Emergency Center) at 800-424-9300.</p> <p>SECTION 7) HANDLING AND STORAGE <br />General <br />Wash hands after use. <br />Do not get in eyes, on skin or on clothing. <br />Do not breathe vapors or mists. <br />Use good personal hygiene practices. <br />Eating, drinking and smoking in work areas is prohibited. <br />Remove contaminated clothing and protective equipment before entering eating areas. <br />Eyewash stations and showers should be available in areas where this material is used and stored.</p> <p>Ventilation Requirements <br />Use only with adequate ventilation to control air contaminants to their exposure limits. The use of local ventilation is recommended to <br />control emissions near the source.</p> <p>Storage Room Requirements <br />Keep container(s) tightly closed and properly labeled. Store in cool, dry, well-ventilated areas away from heat, direct sunlight, strong <br />oxidizers and any incompatibilities. Store in approved containers and protect against physical damage. Keep containers securely sealed <br />when not in use. Indoor storage should meet OSHA standards and appropriate fire codes. Containers that have been opened must be <br />carefully resealed to prevent leakage. Empty container retain residue and may be dangerous.</p> <p>SDS RE-ROOF Primer PO Comp B <br />SDS DATE: 22-NOV-28</p> <p>www.aquafin.net</p> <p>Page 3 of 8</p> <p>Use non-sparking ventilation systems, approved explosion-proof equipment and intrinsically safe electrical systems in areas where this <br />product is used and stored. <br />Store in tightly sealed containers to protect from atmospheric moisture. Store in a cool dry area. Store liquid in containers above ground <br />and surround by dikes to contain spills or leaks. <br />Ground and bond containers and receiving equipment. Avoid static electricity by grounding.</p> <p>SECTION 8) EXPOSURE CONTROLS/PERSONAL PROTECTION <br />Eye Protection <br />Wear eye protection with side shields or goggles. Wear indirect-vent, impact and splash resistant goggles when working with liquids. If <br />additional protection is needed for entire face, use in combination with a face shield.</p> <p>Skin Protection <br />Use of gloves approved to relevant standards made from the following materials may provide suitable chemical protection: PVC, <br />neoprene or nitrile rubber gloves. Suitability and durability of a glove is dependent on usage, e.g. frequency and duration of contact, <br />chemical resistance of glove material, glove thickness, dexterity. Always seek advice from glove suppliers. Contaminated gloves should <br />be replaced. Use of an apron and over- boots of chemically impervious materials such as neoprene or nitrile rubber is recommended to <br />avoid skin sensitization. The type of protective equipment must be selected according to the concentration and amount of the dangerous <br />substance at the specific workplace. Launder soiled clothes or properly disposed of contaminated material, which cannot be <br />decontaminated.</p> <p>Respiratory Protection <br />If engineering controls do not maintain airborne concentrations to a level which is adequate to protect worker, a respiratory protection <br />program that meets or is equivalent to OSHA 29 CFR 1910.134 and ANSI Z88.2 should be followed. Check with respiratory protective <br />equipment suppliers. <br />When airborne concentrations exceed or are expected to exceed the TLV, use MSHA/NIOSH approved positive pressure supplied air <br />respirator with a full-face piece or an air supplied hood. For emergencies, use a positive pressure self-container breathing apparatus.</p> <p>Appropriate Engineering Controls <br />Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors below their respective threshold <br />limit value. <br />Chemical Name</p> <p>OSHA <br />TWA <br />(ppm)</p> <p>OSHA <br />TWA <br />(mg/m3)</p> <p>a</p> <p>[10 mg/m3 <br />percent <br />SiO2+2 / <br />250 <br />percent <br />SiO2+5 <br />mppcf]; [30 <br />mg/m3 <br />percent <br />SiO2+2];</p> <p>[1,3]; [3];</p> <p>15</p> <p>1</p> <p>SILICA, <br />CRYSTALLINE</p> <p>TITANIUM DIOXIDE</p> <p>Chemical Name</p> <p>ACGIH <br />TWA <br />(ppm)</p> <p>SILICA, <br />CRYSTALLINE</p> <p>ACGIH <br />TWA <br />(mg/m3)</p> <p>OSHA <br />STEL <br />(ppm)</p> <p>ACGIH <br />STEL <br />(ppm)</p> <p>OSHA <br />STEL <br />(mg/m3)</p> <p>OSHA <br />OSHA <br />NIOSH <br />Tables (Z1, OSHA <br />Skin <br />TWA <br />Z2, Z3) Carcinogen designation <br />(ppm)</p> <p>NIOSH <br />TWA <br />(mg/m3) <br />0.05e</p> <p>b</p> <p>NIOSH <br />STEL <br />(ppm)</p> <p>NIOSH <br />STEL <br />(mg/m3)</p> <p>NIOSH <br />Carcinogen <br />1</p> <p>1</p> <p>ACGIH <br />STEL <br />(mg/m3)</p> <p>0.025 (R)</p> <p>TITANIUM DIOXIDE</p> <p>10</p> <p>(R) - Respirable fraction</p> <p>SECTION 9) PHYSICAL AND CHEMICAL PROPERTIES <br />Physical and Chemical Properties <br />Density</p> <p>SDS RE-ROOF Primer PO Comp B <br />SDS DATE: 22-NOV-28</p> <p>8.20 lb/gal</p> <p>www.aquafin.net</p> <p>Page 4 of 8</p> <p>Specific Gravity</p> <p>0.98</p> <p>VOC Regulatory(lb/gal)</p> <p>0.00 lb/gal</p> <p>VOC Part A & B Combined</p> <p>0.21 lb/gal</p> <p>Appearance</p> <p>Clear Liquid</p> <p>Odor Threshold</p> <p>N.A.</p> <p>Odor Description</p> <p>Fruity-like</p> <p>pH</p> <p>N.A.</p> <p>Water Solubility</p> <p>N.A.</p> <p>Flammability</p> <p>N/A</p> <p>Flash Point Symbol</p> <p>N.A.</p> <p>Flash Point</p> <p>302 °F</p> <p>Viscosity</p> <p>N.A.</p> <p>Lower Explosion Level</p> <p>N.A.</p> <p>Upper Explosion Level</p> <p>N.A.</p> <p>Vapor Pressure</p> <p>N.A.</p> <p>Vapor Density</p> <p>N.A.</p> <p>Freezing Point</p> <p>N.A.</p> <p>Melting Point</p> <p>N.A.</p> <p>Low Boiling Point</p> <p>392 °F</p> <p>High Boiling Point</p> <p>N.A.</p> <p>Auto Ignition Temp</p> <p>N.A.</p> <p>Decomposition Pt</p> <p>N.A.</p> <p>Evaporation Rate</p> <p>N.A.</p> <p>Coefficient Water/Oil</p> <p>N.A.</p> <p>SECTION 10) STABILITY AND REACTIVITY <br />Stability <br />Material is stable at standard temperature and pressure.</p> <p>Conditions to Avoid <br />Heat, high temperature, open flame, and moisture. Avoid contact with incompatible materials.</p> <p>Hazardous Reactions/Polymerization <br />Will not occur.</p> <p>Incompatible Materials <br />This product will react with any material containing isocyanate. Some reactions can be violent.</p> <p>Hazardous Decomposition Products <br />Combustion products: organic vapors and thermal decomposition fragments.</p> <p>SECTION 11) TOXICOLOGICAL INFORMATION <br />Skin Corrosion/Irritation <br />Product may be absorbed through skin and cause nausea, headache, and general discomfort. <br />Causes skin irritation</p> <p>Serious Eye Damage/Irritation <br />Vapors can irritate the eyes. Chemical burns may result due to overexposure. Affects of exposure may be delayed. <br />Causes serious eye irritation</p> <p>Respiratory/Skin Sensitization</p> <p>SDS RE-ROOF Primer PO Comp B <br />SDS DATE: 22-NOV-28</p> <p>www.aquafin.net</p> <p>Page 5 of 8</p> <p>Inhalation : Severe overexposure may induce respiratory sensitization with asthma like symptoms. These symptoms may be immediate or <br />delayed up to several hours after exposure. Chronic exposures may result in permanent decreases in lung function. <br />Skin sensitization may develop after repeated and/or prolonged contact. <br />No data available</p> <p>Carcinogenicity <br />Suspected of causing cancer.</p> <p>Germ Cell Mutagenicity <br />No data available</p> <p>Reproductive Toxicity <br />Specific Target Organ Toxicity - Single Exposure <br />No data available</p> <p>Specific Target Organ Toxicity - Repeated Exposure <br />May cause damage to organs through prolonged or repeated exposure.</p> <p>Aspiration Hazard <br />No data available</p> <p>Acute Toxicity <br />If ingested : In humans, irritation or chemical burns of the mouth, pharynx, esophagus and stomach can develop following ingestion, and <br />injury may be severe and cause death. <br />Repeated and prolonged exposure at low levels may result in adverse skin and eye effects, liver and kidney disorders. <br />No data available</p> <p>Potential Health Effects - Miscellaneous <br />0000872-50-4 M-PYROL <br />The following medical conditions may be aggravated by exposure: skin disorders. Tests in some laboratory animals indicate this <br />compound may have embryotoxic activity. Tests in laboratory animals have shown effects on any of the following organs/systems: <br />kidneys, liver. WARNING: This chemical is known to the State of California to cause birth defects or other reproductive harm. <br />0013463-67-7 TITANIUM DIOXIDE <br />Is an IARC, NTP or OSHA carcinogen. In a lifetime inhalation test, lung cancers were found in some rats exposed to 250 mg/m3 <br />respirable titanium dust. Analysis of the titanium dioxide concentrations in the rat’s lungs showed that the lung clearance mechanism was <br />overwhelmed and that the results at the massive 250 mg/m3 level are not relevant to the workplace.‘Results of a DuPont epidemiology <br />study showed that employees who had been exposed to Titanium Dioxide were at no greater risk of developing lung cancer than were <br />employees who had not been exposed to Titanium dioxide. No pulmonary fibrosis was found in any of the employees and no association <br />was observed between Titanium dioxide exposure and chronic respiratory disease or x-ray abnormalities. Based on the results of this <br />study DuPont concludes that titanium dioxide will not cause lung cancer or chronic respiratory disease in humans at concentrations <br />experienced in the workplace.‘ <br />0014808-60-7 SILICA, CRYSTALLINE <br />Is an IARC, NTP or OSHA carcinogen. Repeated overexposure to crystalline silica may lead to x-ray changes and chronic lung disease. <br />Inhalation of high dust concentrations may cause: breathing difficulties, lung injury. WARNING: This chemical is known to the State of <br />California to cause cancer.</p> <p>Chronic Exposure <br />0014808-60-7 SILICA, CRYSTALLINE <br />Prolonged inhalation of respirable crystalline silica dust can result in lung disease (i.e. silicosis and/or lung cancer). Symptoms include <br />coughing, shortness of breath, wheezing and reduced pulmonary function.</p> <p>SECTION 12) ECOLOGICAL INFORMATION <br />Toxicity <br />No data available</p> <p>Persistence and Degradability <br />No data available.</p> <p>Bioaccumulative Potential <br />No data available.</p> <p>SDS RE-ROOF Primer PO Comp B <br />SDS DATE: 22-NOV-28</p> <p>www.aquafin.net</p> <p>Page 6 of 8</p> <p>Mobility in Soil <br />No data available.</p> <p>Other Adverse Effects <br />No data available.</p> <p>SECTION 13) DISPOSAL CONSIDERATIONS <br />Waste Disposal <br />Under RCRA, it is the responsibility of the user of the product, to determine a the time of disposal whether the product meets RCRA <br />criteria for hazardous waste. Waste management should be in full compliance with federal, state, and local laws. <br />Empty containers retain product residue which may exhibit hazards of material, therefore do not pressurize, cut, glaze, weld or use for any <br />other purposes. Return drums to reclamation centers for proper cleaning and reuse.</p> <p>SECTION 14) TRANSPORT INFORMATION <br />U.S. DOT Information <br />Not regulated.</p> <p>IMDG Information <br />Not regulated.</p> <p>IATA Information <br />Not regulated.</p> <p>SECTION 15) REGULATORY INFORMATION</p> <p>CAS</p> <p>Chemical Name</p> <p>% By Weight</p> <p>Regulation List</p> <p>0000872-50-4</p> <p>M-PYROL</p> <p>4% - 7%</p> <p>DSL,SARA312,VOC,TSCA,CA_Prop65 - California Proposition 65</p> <p>0013463-67-7</p> <p>TITANIUM DIOXIDE</p> <p>1.5% - 3%</p> <p>DSL,SARA312,TSCA,CA_Prop65 - California Proposition 65</p> <p>0014808-60-7</p> <p>SILICA, CRYSTALLINE</p> <p>0.9% - 1.5%</p> <p>DSL,SARA312,TSCA,CA_Prop65 - California Proposition 65</p> <p>0006864-37-5</p> <p>CYCLOHEXANAMINE, <br />4,4'-METHYLENEBIS[2METHYL-</p> <p>0.4% - 0.7%</p> <p>DSL,SARA312,TSCA</p> <p>SECTION 16) OTHER INFORMATION <br />OTHER INFORMATION <br />* There are points of differences between OSHA GHS and UN GHS. In 90% of the categories, they can be used interchangeably, but for <br />the Skin Corrosion/Irritant Category and the Specific Target Organ Toxicity (Single and Repeated Exposure) Categories. In these cases, <br />our system will say UN GHS.</p> <p>GLOSSARY <br />ACGIH- American Conference of Governmental Industrial Hygienists; ANSI- American National Standards Institute; CA Prop65- California <br />Proposition 65; Canadian TDG- Canadian Transportation of Dangerous Goods; CAS- Chemical Abstract Service; Chemtrec- Chemical <br />Transportation Emergency Center (US); CHIP- Chemical Hazard Information and Packaging; DSL- Domestic Substances List; ECEquivalent Concentration; EH40 (UK)- HSE Guidance Note EH40 Occupational Exposure Limits; EPCRA- Emergency Planning and <br />Community Right-To-Know Act; ESL- Effects screening levels; HMIS- Hazardous Material Information Service; LC- Lethal Concentration;</p> <p>SDS RE-ROOF Primer PO Comp B <br />SDS DATE: 22-NOV-28</p> <p>www.aquafin.net</p> <p>Page 7 of 8</p> <p>LD- Lethal Dose; NFPA- National Fire Protection Association; OEL- Occupational Exposure Limits; OSHA- Occupational Safety and <br />Health Administration, US Department of Labor; PEL- Permissible Exposure Limit; SARA (Title III)- Superfund Amendments and <br />Reauthorization Act; SARA 313- Superfund Amendments and Reauthorization Act, Section 313; SCBA- Self-Contained Breathing <br />Apparatus; STEL- Short Term Exposure Limit; TCEQ- Texas Commission on Environmental Quality; TLV- Threshold Limit Value; TSCAToxic Substances Control Act Public Law 94-469; TWA- Time Weighted Value; US DOT- US Department of Transportation; WHMISWorkplace Hazardous Materials Information System.</p> <p>DISCLAIMER <br />To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its subsidiaries assumes <br />any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole <br />responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we <br />cannot guarantee that these are the only hazards that exist. The above information pertains to this product as currently formulated, and is based on the <br />information available at this time. Addition of reducers or other additives to this product may substantially alter the composition and hazards of the product. <br />Since conditions of use are outside our control, we make no warranties, express or implied, and assume no liability in connection with any use of this <br />information.</p> <p>SDS RE-ROOF Primer PO Comp B <br />SDS DATE: 22-NOV-28</p> <p>www.aquafin.net</p> <p>Page 8 of 8</p>
