SDS_RE-ROOF White Silicone Flashing_122122.pdf
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<h1>SDS_RE-ROOF White Silicone Flashing_122122.pdf</h1> <p>Safety Data Sheet (SDS)</p> <p>Page 1/7</p> <p>OSHA HazCom Standard 29 CFR 1910.1200(g) and GHS Rev 03.</p> <p>Printing date 12/21/2022</p> <p>Reviewed on 12/21/2022</p> <p>SECTION 1) CHEMICAL PRODUCT AND SUPPLIER'S IDENTIFICATION</p> <p>IDENTITY:</p> <p>Product Name: RE-ROOF White Silicone Flashing <br />Product Use Description:</p> <p>AQUAFIN, INC. <br />505 BLUE BALL RD. #160 <br />ELKTON, MD 21921</p> <p>Silicone Liquid Roof Flashing, For Further Information, Refer to the Product <br />Technical Data Sheet.</p> <p>info@aquafin.net</p> <p>24 hr Emergency Phone: Chem-Tel (800) 255-3924 <br />Information Phone No: (410) 392-2300</p> <p>www.aquafin.net</p> <p>SECTION 2) HAZARDS IDENTIFICATION <br />Classification: <br />Specific Target Organ Toxicity - Repeated Exposure - Category 2 <br />Skin Irritation - Category 3 <br />Eye Irritation - Category 2A <br />Carcinogenicity - Category 2 <br />Reproductive Toxicity - Category 2 <br />Flammable Liquids - Category 4</p> <p>Pictograms:</p> <p>Signal Word: <br />Warning</p> <p>Hazardous Statements - Physical: <br />H227 - Combustible Liquid</p> <p>Hazardous Statements - Health: <br />H373 - May cause damage to organs through prolonged or repeated exposure. <br />H316 - Causes mild skin irritation <br />H319 - Causes serious eye irritation <br />H351 - Suspected of causing cancer. <br />H361 - Suspected of damaging fertility or the unborn child.</p> <p>Precautionary Statements - General: <br />P101 - If medical advice is needed, have product container or label at hand. <br />P102 - Keep out of reach of children. <br />P103 - Read label before use.</p> <p>Precautionary Statements - Prevention: <br />P260 - Do not breathe dust/fume/gas/mist/vapors/spray.</p> <p>SDS RE-ROOF White Silicone Flashing SDS <br />DATE: 22-DEC-21</p> <p>Page 1 of 7</p> <p>P264 - Wash thoroughly after handling. <br />P280 - Wear protective gloves/protective clothing/eye protection/face protection. <br />P201 - Obtain special instructions before use. <br />P202 - Do not handle until all safety precautions have been read and understood. <br />P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.</p> <p>Precautionary Statements - Response: <br />P314 - Get Medical advice/attention if you feel unwell. <br />P332 + P313 - If skin irritation occurs: Get medical advice/attention. <br />P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue <br />rinsing. <br />P337 + P313 - If eye irritation persists: Get medical advice/attention. <br />P308 + P313 - IF exposed or concerned: Get medical advice/attention. <br />P370 + P378 - In case of fire: Use dry chemical, carbon dioxide, foam to extinguish. <br />For detailed information, see Section-5 (Fire Fighting Measures)</p> <p>Precautionary Statements - Storage: <br />P405 - Store locked up. <br />P403 - Store in a well-ventilated place.</p> <p>Precautionary Statements - Disposal: <br />P501 - Dispose of contents/ container to an approved waste disposal plant.</p> <p>SECTION 3) COMPOSITION / INFORMATION ON INGREDIENTS <br />CAS</p> <p>Chemical Name</p> <p>% By Weight</p> <p>0014808-60-7</p> <p>SILICA, CRYSTALLINE</p> <p>19% - 36%</p> <p>0013463-67-7</p> <p>TITANIUM DIOXIDE</p> <p>8% - 14%</p> <p>0022984-54-9</p> <p>METHYLTRIS(METHYLETHYLKETOXIME)SILANE</p> <p>5% - 12%</p> <p>0000556-67-2</p> <p>OCTAMETHYLCYCLOTETRASILO</p> <p>2% - 4%</p> <p>0000096-29-7</p> <p>2-BUTANONE OXIME</p> <p>Trace</p> <p>Specific chemical identity and/or exact percentage (concentration) of the composition has been withheld to protect confidentiality.</p> <p>SECTION 4) FIRST-AID MEASURES <br />Inhalation: <br />Remove source of exposure or move person to fresh air and keep comfortable for breathing. If experiencing respiratory symptoms: Call a <br />POISON CENTER/doctor. If breathing is difficult, trained personnel should administer emergency oxygen if advised to do so by the <br />POISON CENTER/doctor. <br />If exposed/feel unwell/concerned: Call a POISON CENTER/doctor. <br />Eliminate all ignition sources if safe to do so.</p> <p>Skin Contact: <br />Take off contaminated clothing, shoes and leather goods (e.g. watchbands, belts). Gently blot or brush away excess product. Wash with <br />plenty of lukewarm, gently flowing water for a duration of 15-20 minutes. If skin irritation or rash occurs: Get medical advice/attention. Wash <br />contaminated clothing before re-use or discard. <br />IF exposed or concerned: Get medical advice/attention.</p> <p>Eye Contact: <br />Avoid direct contact. Wear chemical protective gloves, if necessary. <br />Rinse eyes cautiously with lukewarm, gently flowing water for several minutes, while holding the eyelids open. Remove contact lenses, if <br />present and easy to do. Continue rinsing for 15-20 minutes. Take care not to rinse contaminated water into the unaffected eye or onto the <br />face. If eye irritation persists: Get medical advice/attention.</p> <p>Ingestion: <br />Rinse mouth. Do NOT induce vomiting. Immediately call a POISON CENTER/doctor. If vomiting occurs naturally, lie on your side, in the <br />recovery position. <br />IF exposed or concerned: Get medical advice/attention.</p> <p>SDS RE-ROOF White Silicone Flashing SDS <br />DATE: 22-DEC-21</p> <p>Page 2 of 7</p> <p>SECTION 5) FIRE-FIGHTING MEASURES <br />Suitable Extinguishing Media: <br />Dry chemical, foam, carbon dioxide is recommended. Water spray is recommended to cool or protect exposed materials or structures. <br />Carbon dioxide can displace oxygen. Use caution when applying carbon dioxide in confined spaces. Simultaneous use of foam and water <br />on the same surface is to be avoided as water destroys the foam. Sand or earth may be used for small fires only.</p> <p>Unsuitable Extinguishing Media: <br />If water is used, use very large quantities of cold water.</p> <p>Specific Hazards in Case of Fire: <br />Vapors may accumulate and travel to ignition sources distant from the handling site; flash fire can occur. <br />Excessive pressure or temperature may cause explosive rupture of containers. <br />Water contamination will produce carbon dioxide. Do not reseal contaminated containers as pressure buildup may rupture them.</p> <p>Fire-fighting Procedures: <br />Isolate immediate hazard area and keep unauthorized personnel out. Stop spill/release if it can be done safely. Move undamaged <br />containers from immediate hazard area if it can be done safely. Water spray may be useful in minimizing or dispersing vapors and to <br />protect personnel. Water may be ineffective but can be used to cool containers exposed to heat or flame. Caution should be exercised <br />when using water or foam as frothing may occur, especially if sprayed into containers of hot, burning liquid. <br />Dispose of fire debris and contaminated extinguishing water in accordance with official regulations.</p> <p>Special Protective Actions: <br />Wear NIOSH approved self-contained breathing apparatus in positive pressure mode with full-face piece. Boots, gloves (neoprene), <br />googles, and full protective clothing are also required. <br />Care should always be exercised in dust/mist areas.</p> <p>SECTION 6) ACCIDENTAL RELEASE MEASURES <br />Emergency Procedure: <br />ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area). <br />Do not touch or walk through spilled material. <br />Isolate hazard area and keep unnecessary people away. Remove all possible sources of ignition in the surrounding area. Notify authorities <br />if any exposure to the general public or the environment occurs or is likely to occur. <br />If spilled material is cleaned up using a regulated solvent, the resulting waste mixture may be regulated.</p> <p>Recommended Equipment: <br />Appropriate dust or face mask to eliminate breathing foam dust particulates.</p> <p>Personal Precautions: <br />Avoid breathing vapors. Avoid contact with skin, eyes or clothing. Do not touch damaged containers or spilled materials unless wearing <br />appropriate protective clothing.</p> <p>Environmental Precautions: <br />Stop spill/release if it can be done safely. Prevent spilled material from entering sewers, storm drains, other unauthorized drainage systems <br />and natural waterways by using sand, earth, or other appropriate barriers.</p> <p>Methods and Materials for Containment and Cleaning up: <br />Soak up material with absorbent and shovel into a chemical waste container. Residues from spill cleanup may continue to be regulated <br />under provisions of RCRA and require storage and disposal as hazardous waste. For major spills, call CHEMTREC (Chemical <br />Transportation Emergency Center) at 800-424-9300.</p> <p>SECTION 7) HANDLING AND STORAGE <br />General: <br />Wash hands after use. <br />Do not get in eyes, on skin or on clothing. <br />Do not breathe vapors or mists. <br />Use good personal hygiene practices. <br />Eating, drinking and smoking in work areas is prohibited. <br />Remove contaminated clothing and protective equipment before entering eating areas.</p> <p>Ventilation Requirements: <br />Use only with adequate ventilation to control air contaminants to their exposure limits. The use of local ventilation is recommended to <br />control emissions near the source.</p> <p>Storage Room Requirements:</p> <p>SDS RE-ROOF White Silicone Flashing SDS <br />DATE: 22-DEC-21</p> <p>Page 3 of 7</p> <p>Keep container(s) tightly closed and properly labeled. Store in cool, dry, well-ventilated areas away from heat, direct sunlight, strong <br />oxidizers and any incompatibilities. Store in approved containers and protect against physical damage. Keep containers securely sealed <br />when not in use. Indoor storage should meet OSHA standards and appropriate fire codes. Containers that have been opened must be <br />carefully resealed to prevent leakage. Empty container retain residue and may be dangerous. <br />Use non-sparking ventilation systems, approved explosion-proof equipment and intrinsically safe electrical systems in areas where this <br />product is used and stored.</p> <p>SECTION 8) EXPOSURE CONTROLS/PERSONAL PROTECTION <br />Eye Protection: <br />Wear eye protection with side shields or goggles. Wear indirect-vent, impact and splash resistant goggles when working with liquids. If <br />additional protection is needed for entire face, use in combination with a face shield.</p> <p>Skin Protection: <br />Use of gloves approved to relevant standards made from the following materials may provide suitable chemical protection: PVC, neoprene <br />or nitrile rubber gloves. Suitability and durability of a glove is dependent on usage, e.g. frequency and duration of contact, chemical <br />resistance of glove material, glove thickness, dexterity. Always seek advice from glove suppliers. Contaminated gloves should be replaced. <br />Use of an apron and over- boots of chemically impervious materials such as neoprene or nitrile rubber is recommended to avoid skin <br />sensitization. The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at <br />the specific workplace. Launder soiled clothes or properly disposed of contaminated material, which cannot be decontaminated. <br />Depending on conditions of use, additional protection may be required such as apron, arm covers, or full body suit. <br />Wash contaminated clothing before re-wearing.</p> <p>Respiratory Protection: <br />If airborne concentrations exceed or are expected to exceed the TLV, use MSHA/NIOSH approved positive pressure supplied pressure <br />supplied air respiratory with a full face piece or an air supplied hood. For emergencies, use a positive pressure self-contained breathing <br />apparatus.</p> <p>Appropriate Engineering Controls: <br />Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors below their respective threshold <br />limit value. <br />Chemical Name</p> <p>OSHA <br />TWA <br />(ppm)</p> <p>OSHA <br />TWA <br />(mg/m3)</p> <p>a</p> <p>[10 mg/m3 <br />percent <br />SiO2+2 / <br />250 <br />percent <br />SiO2+5 <br />mppcf]; [30 <br />mg/m3 <br />percent <br />SiO2+2];</p> <p>[1,3]; [3];</p> <p>15</p> <p>1</p> <p>SILICA, <br />CRYSTALLINE</p> <p>TITANIUM DIOXIDE</p> <p>Chemical Name</p> <p>ACGIH <br />TWA <br />(ppm)</p> <p>SILICA, <br />CRYSTALLINE</p> <p>ACGIH <br />TWA <br />(mg/m3)</p> <p>OSHA <br />STEL <br />(ppm)</p> <p>ACGIH <br />STEL <br />(ppm)</p> <p>OSHA <br />STEL <br />(mg/m3)</p> <p>OSHA <br />OSHA <br />NIOSH <br />Tables (Z1, OSHA <br />Skin <br />TWA <br />Z2, Z3) Carcinogen designation <br />(ppm)</p> <p>NIOSH <br />TWA <br />(mg/m3) <br />0.05e</p> <p>b</p> <p>NIOSH <br />STEL <br />(ppm)</p> <p>NIOSH <br />STEL <br />(mg/m3)</p> <p>NIOSH <br />Carcinogen <br />1</p> <p>1</p> <p>ACGIH <br />STEL <br />(mg/m3)</p> <p>0.025 (R)</p> <p>TITANIUM DIOXIDE</p> <p>10</p> <p>(R) - Respirable fraction</p> <p>SECTION 9) PHYSICAL AND CHEMICAL PROPERTIES <br />Physical and Chemical Properties <br />Density</p> <p>10.92 lb/gal</p> <p>Specific Gravity</p> <p>1.31</p> <p>VOC Regulatory</p> <p>0.33 lb/gal</p> <p>VOC Part A & B Combined</p> <p>N.A.</p> <p>Appearance</p> <p>Pigmented Viscous Liquid</p> <p>SDS RE-ROOF White Silicone Flashing SDS <br />DATE: 22-DEC-21</p> <p>Page 4 of 7</p> <p>Odor Threshold</p> <p>N.A.</p> <p>Odor Description</p> <p>Chemical</p> <p>pH</p> <p>N.A.</p> <p>Water Solubility</p> <p>N.A.</p> <p>Flammability</p> <p>N/A</p> <p>Flash Point Symbol</p> <p>N.A.</p> <p>Flash Point</p> <p>61 °C</p> <p>Viscosity</p> <p>N.A.</p> <p>Lower Explosion Level</p> <p>N.A.</p> <p>Upper Explosion Level</p> <p>N.A.</p> <p>Vapor Pressure</p> <p>N.A.</p> <p>Vapor Density</p> <p>Heavier than air</p> <p>Freezing Point</p> <p>N.A.</p> <p>Melting Point</p> <p>N.A.</p> <p>Low Boiling Point</p> <p>118 °C</p> <p>High Boiling Point</p> <p>N.A.</p> <p>Auto Ignition Temp</p> <p>N.A.</p> <p>Decomposition Pt</p> <p>N.A.</p> <p>Evaporation Rate</p> <p>Slower than ether</p> <p>Coefficient Water/Oil</p> <p>N.A.</p> <p>SECTION 10) STABILITY AND REACTIVITY <br />Stability: <br />Material is stable at standard temperature and pressure.</p> <p>Conditions to Avoid: <br />Heat, high temperature, open flame, sparks, and moisture. Contact with incompatible materials in a closed system will cause liberation of <br />carbon dioxide and buildup of pressure.</p> <p>Hazardous Reactions/Polymerization: <br />Will not occur under normal conditions but under high temperatures in the presence of alkalis,tertiary amines, and metal compounds will <br />accelerate polymerization. Possible evolution of carbon dioxide gas may rupture closed containers.</p> <p>Incompatible Materials: <br />Strong acids and isocyanates.</p> <p>Hazardous Decomposition Products: <br />Toxic levels of ammonia, combustion products of nitrogen, carbon monoxide, carbon dioxide, irritating aldehydes and ketones may be <br />formed on burning in a limited air supply.</p> <p>SECTION 11) TOXICOLOGICAL INFORMATION <br />Skin Corrosion/Irritation: <br />Causes severe irritation with pain, severe excess redness and swelling with chemical burns, blister formation, and possible tissue <br />destruction. Other than the potential skin irritation effects noted above, acute (short term) adverse effects are not expected from brief skin <br />contact. <br />Causes mild skin irritation</p> <p>Serious Eye Damage/Irritation: <br />Causes irritation experienced as pain, with excess blinking and tear production, and as seen extreme redness and swelling of the eye and <br />chemical burns of the eye. Severe eye damage may cause blindness. <br />Causes serious eye irritation</p> <p>Respiratory/Skin Sensitization: <br />No data available</p> <p>Carcinogenicity: <br />Suspected of causing cancer.</p> <p>Germ Cell Mutagenicity: <br />No data available</p> <p>SDS RE-ROOF White Silicone Flashing SDS <br />DATE: 22-DEC-21</p> <p>Page 5 of 7</p> <p>Reproductive Toxicity: <br />Suspected of damaging fertility or the unborn child.</p> <p>Specific Target Organ Toxicity - Single Exposure: <br />No data available</p> <p>Specific Target Organ Toxicity - Repeated Exposure: <br />May cause damage to organs through prolonged or repeated exposure.</p> <p>Aspiration Hazard: <br />No data available</p> <p>Acute Toxicity: <br />Oral : Causes burning of mouth, throat, and stomach with abdominal and chest pain, nausea, vomiting, diarrhea, thirst, weakness, and <br />collapse. Aspiration may occur during swallowing or vomiting, resulting in lung damage.</p> <p>Potential Health Effects - Miscellaneous <br />0013463-67-7</p> <p>TITANIUM DIOXIDE</p> <p>Is an IARC, NTP or OSHA carcinogen. In a lifetime inhalation test, lung cancers were found in some rats exposed to 250 mg/m3 <br />respirable titanium dust. Analysis of the titanium dioxide concentrations in the rat’s lungs showed that the lung clearance <br />mechanism was overwhelmed and that the results at the massive 250 mg/m3 level are not relevant to the workplace.‘Results of a <br />DuPont epidemiology study showed that employees who had been exposed to Titanium Dioxide were at no greater risk of <br />developing lung cancer than were employees who had not been exposed to Titanium dioxide. No pulmonary fibrosis was found in <br />any of the employees and no association was observed between Titanium dioxide exposure and chronic respiratory disease or xray abnormalities. Based on the results of this study DuPont concludes that titanium dioxide will not cause lung cancer or chronic <br />respiratory disease in humans at concentrations experienced in the workplace.‘ <br />0014808-60-7</p> <p>SILICA, CRYSTALLINE</p> <p>Is an IARC, NTP or OSHA carcinogen. Repeated overexposure to crystalline silica may lead to x-ray changes and chronic lung <br />disease. Inhalation of high dust concentrations may cause: breathing difficulties, lung injury. WARNING: This chemical is known to <br />the State of California to cause cancer.</p> <p>Chronic Exposure <br />0014808-60-7</p> <p>SILICA, CRYSTALLINE</p> <p>Prolonged inhalation of respirable crystalline silica dust can result in lung disease (i.e. silicosis and/or lung cancer). Symptoms <br />include coughing, shortness of breath, wheezing and reduced pulmonary function.</p> <p>SECTION 12) ECOLOGICAL INFORMATION <br />Toxicity: <br />No data available.</p> <p>Persistence and Degradability: <br />No data available.</p> <p>Bioaccumulative Potential: <br />No data available.</p> <p>Mobility in Soil: <br />No data available.</p> <p>Other Adverse Effects: <br />No data available.</p> <p>SECTION 13) DISPOSAL CONSIDERATIONS <br />Waste Disposal: <br />Under RCRA, it is the responsibility of the user of the product, to determine a the time of disposal whether the product meets RCRA criteria <br />for hazardous waste. Waste management should be in full compliance with federal, state, and local laws. <br />Empty containers retain product residue which may exhibit hazards of material, therefore do not pressurize, cut, glaze, weld or use for any <br />other purposes. Return drums to reclamation centers for proper cleaning and reuse.</p> <p>SECTION 14) TRANSPORT INFORMATION <br />U.S. DOT Information:</p> <p>SDS RE-ROOF White Silicone Flashing SDS <br />DATE: 22-DEC-21</p> <p>Page 6 of 7</p> <p>Not regulated.</p> <p>IMDG Information: <br />Not regulated.</p> <p>IATA Information: <br />Not regulated.</p> <p>SECTION 15) REGULATORY INFORMATION <br />CAS</p> <p>Chemical Name</p> <p>% By Weight</p> <p>Regulation List</p> <p>0014808-60-7</p> <p>SILICA, CRYSTALLINE</p> <p>0013463-67-7</p> <p>TITANIUM DIOXIDE</p> <p>8% - 14% DSL,SARA312,TSCA,CA_Prop65 - California Proposition 65</p> <p>0022984-54-9</p> <p>METHYLTRIS(METHYLET <br />HYLKETOXIME)SILANE</p> <p>5% - 12% DSL,SARA312,VOC,TSCA</p> <p>0000556-67-2</p> <p>OCTAMETHYLCYCLOTET <br />RASILO</p> <p>0000096-29-7</p> <p>2-BUTANONE OXIME</p> <p>19% - 36% DSL,SARA312,TSCA,CA_Prop65 - California Proposition 65</p> <p>2% - 4% DSL,SARA312,TSCA <br />Trace DSL,SARA312,VOC,TSCA</p> <p>SECTION 16) OTHER INFORMATION <br />OTHER INFORMATION: <br />* There are points of differences between OSHA GHS and UN GHS. In 90% of the categories, they can be used interchangeably, but for <br />the Skin Corrosion/Irritant Category and the Specific Target Organ Toxicity (Single and Repeated Exposure) Categories. In these cases, <br />our system will say UN GHS.</p> <p>GLOSSARY: <br />ACGIH- American Conference of Governmental Industrial Hygienists; ANSI- American National Standards Institute; CA Prop65- California <br />Proposition 65; Canadian TDG- Canadian Transportation of Dangerous Goods; CAS- Chemical Abstract Service; Chemtrec- Chemical <br />Transportation Emergency Center (US); CHIP- Chemical Hazard Information and Packaging; DSL- Domestic Substances List; ECEquivalent Concentration; EH40 (UK)- HSE Guidance Note EH40 Occupational Exposure Limits; EPCRA- Emergency Planning and <br />Community Right-To-Know Act; ESL- Effects screening levels; HMIS- Hazardous Material Information Service; LC- Lethal Concentration; <br />LD- Lethal Dose; NFPA- National Fire Protection Association; OEL- Occupational Exposure Limits; OSHA- Occupational Safety and Health <br />Administration, US Department of Labor; PEL- Permissible Exposure Limit; SARA (Title III)- Superfund Amendments and Reauthorization <br />Act; SARA 313- Superfund Amendments and Reauthorization Act, Section 313; SCBA- Self-Contained Breathing Apparatus; STEL- Short <br />Term Exposure Limit; TCEQ- Texas Commission on Environmental Quality; TLV- Threshold Limit Value; TSCA- Toxic Substances Control <br />Act Public Law 94-469; TWA- Time Weighted Value; US DOT- US Department of Transportation; WHMIS- Workplace Hazardous Materials <br />Information System.</p> <p>Version 1.0: <br />Revision Date: Mar 28, 2017 <br />Version 1.0</p> <p>DISCLAIMER <br />To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its subsidiaries <br />assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any <br />material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain <br />hazards are described herein, we cannot guarantee that these are the only hazards that exist. The above information pertains to this product as <br />currently formulated, and is based on the information available at this time. Addition of reducers or other additives to this product may substantially <br />alter the composition and hazards of the product. Since conditions of use are outside our control, we make no warranties, express or implied, and <br />assume no liability in connection with any use of this information.</p> <p>SDS RE-ROOF White Silicone Flashing SDS <br />DATE: 22-DEC-21</p> <p>Page 7 of 7</p>
