SDS_RE-ROOF White Urethane Top Coat_122722.pdf
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<h1>SDS_RE-ROOF White Urethane Top Coat_122722.pdf</h1> <p>Safety Data Sheet (SDS)</p> <p>Page 1/9</p> <p>OSHA HazCom Standard 29 CFR 1910.1200(g) and GHS Rev 03.</p> <p>Printing date 12/27/2022</p> <p>Reviewed on 12/27/2022</p> <p>SECTION 1) CHEMICAL PRODUCT AND SUPPLIER'S IDENTIFICATION</p> <p>IDENTITY:</p> <p>Product Name: RE-ROOF White Urethane Top Coat <br />Product Use Description:</p> <p>AQUAFIN, INC. <br />505 BLUE BALL RD. #160 <br />ELKTON, MD 21921</p> <p>Urethane-based Liquid Roof Coating, For Further Information, Refer to the <br />Product Technical Data Sheet.</p> <p>info@aquafin.net</p> <p>24 hr Emergency Phone: Chem-Tel (800) <br />255-3924 Information Phone No: (410) 392-2300</p> <p>www.aquafin.net</p> <p>SECTION 2) HAZARDS IDENTIFICATION <br />Classification: <br />Specific Target Organ Toxicity - Repeated Exposure - Category 2 <br />Skin Irritation - Category 2 <br />Respiratory Sensitizer (Solid/Liquid) - Category 1 <br />Skin Sensitizer - Category 1 <br />Carcinogenicity - Category 2 <br />Reproductive Toxicity - Category 2 <br />Eye Irritation - Category 2 <br />Flammable Liquids - Category 4 <br />Acute aquatic toxicity - Category 3</p> <p>Pictograms:</p> <p>Signal Word: <br />Danger</p> <p>Hazardous Statements - Physical: <br />H227 - Combustible Liquid</p> <p>Hazardous Statements - Health: <br />H373 - May cause damage to organs through prolonged or repeated exposure. <br />H315 - Causes skin irritation <br />H334 - May cause allergy or asthma symptoms or breathing difficulties if inhaled <br />H317 - May cause an allergic skin reaction <br />H351 - Suspected of causing cancer. <br />H361 - Suspected of damaging fertility or the unborn child. <br />H319 - Causes serious eye irritation</p> <p>SDS RE-ROOF White Urethane Top Coat <br />SDS DATE: 22-DEC-27</p> <p>Page 1 of 9</p> <p>Hazardous Statements - Environmental: <br />H402 - Harmful to aquatic life</p> <p>Precautionary Statements - General: <br />P101 - If medical advice is needed, have product container or label at hand. <br />P102 - Keep out of reach of children. <br />P103 - Read label before use.</p> <p>Precautionary Statements - Prevention: <br />P260 - Do not breathe dust/fume/gas/mist/vapors/spray. <br />P264 - Wash thoroughly after handling. <br />P280 - Wear protective gloves/protective clothing/eye protection/face protection. <br />P261 - Avoid breathing dust/fume/gas/mist/vapors/spray. <br />P284 - [In case of inadequate ventilation] wear respiratory protection. <br />P272 - Contaminated work clothing should not be allowed out of the workplace. <br />P201 - Obtain special instructions before use. <br />P202 - Do not handle until all safety precautions have been read and understood. <br />P273 - Avoid release to the environment. <br />P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.</p> <p>Precautionary Statements - Response: <br />P314 - Get Medical advice/attention if you feel unwell. <br />P302 + P352 - IF ON SKIN: Wash with plenty of water. <br />P321 - Specific treatment (see section 4 on this SDS). <br />P332 + P313 - If skin irritation occurs: Get medical advice/attention. <br />P362 + P364 - Take off contaminated clothing. And wash it before reuse. <br />P304 + P340 - IF INHALED: Remove person to fresh air and keep comfortable for breathing. <br />P342 + P311 - If experiencing respiratory symptoms: Call a POISON CENTER/doctor. <br />P333 + P313 - If skin irritation or a rash occurs: Get medical advice/attention. <br />P308 + P313 - IF exposed or concerned: Get medical advice/attention. <br />P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue <br />rinsing. <br />P337 + P313 - If eye irritation persists: Get medical advice/attention. <br />P370 + P378 - In case of fire: Use dry chemical, carbon dioxide, foam to extinguish. <br />For detailed information, see Section-5 (Fire Fighting Measures)</p> <p>Precautionary Statements - Storage: <br />P405 - Store locked up. <br />P403 - Store in a well-ventilated place.</p> <p>Precautionary Statements - Disposal: <br />P501 - Dispose of contents/ container to an approved waste disposal plant.</p> <p>SECTION 3) COMPOSITION / INFORMATION ON INGREDIENTS <br />CAS</p> <p>Chemical Name</p> <p>% By Weight</p> <p>0053880-05-0</p> <p>POLYURETHANE PREPOLYMER</p> <p>27% - 50%</p> <p>0013463-67-7</p> <p>TITANIUM DIOXIDE</p> <p>14% - 26%</p> <p>0000098-56-6</p> <p>BENZENE-1-CHLORO-4(TRIFLUOROMETHYL)-</p> <p>10% - 18%</p> <p>0014808-60-7</p> <p>SILICA, CRYSTALLINE</p> <p>8% - 15%</p> <p>0001330-20-7</p> <p>XYLENE</p> <p>2% - 4%</p> <p>0054914-37-3</p> <p>ALDIMINE</p> <p>1.7% - 3%</p> <p>0000100-41-4</p> <p>ETHYLBENZENE</p> <p>0.7% - 1.2%</p> <p>SDS RE-ROOF White Urethane Top Coat <br />SDS DATE: 22-DEC-27</p> <p>Page 2 of 9</p> <p>0004098-71-9</p> <p>ISOPHORONE DIISOCYANATE</p> <p>0.2% - 0.3%</p> <p>0000108-88-3</p> <p>TOLUENE</p> <p>Trace</p> <p>Specific chemical identity and/or exact percentage (concentration) of the composition has been withheld to protect confidentiality.</p> <p>SECTION 4) FIRST-AID MEASURES <br />Inhalation: <br />Remove source of exposure or move person to fresh air and keep comfortable for breathing. If experiencing respiratory symptoms: Call a <br />POISON CENTER/doctor. If breathing is difficult, trained personnel should administer emergency oxygen if advised to do so by the <br />POISON CENTER/doctor. <br />If exposed/feel unwell/concerned: Call a POISON CENTER/doctor. <br />Eliminate all ignition sources if safe to do so.</p> <p>Skin Contact: <br />Take off contaminated clothing, shoes and leather goods (e.g. watchbands, belts). Gently blot or brush away excess product. Wash with <br />plenty of lukewarm, gently flowing water for a duration of 15-20 minutes. If skin irritation or rash occurs: Get medical advice/attention. Wash <br />contaminated clothing before re-use or discard. <br />IF exposed or concerned: Get medical advice/attention.</p> <p>Eye Contact: <br />Avoid direct contact. Wear chemical protective gloves, if necessary. <br />Rinse eyes cautiously with lukewarm, gently flowing water for several minutes, while holding the eyelids open. Remove contact lenses, if <br />present and easy to do. Continue rinsing for 15-20 minutes. Take care not to rinse contaminated water into the unaffected eye or onto the <br />face. If eye irritation persists: Get medical advice/attention.</p> <p>Ingestion: <br />Rinse mouth. Do NOT induce vomiting. Immediately call a POISON CENTER/doctor. If vomiting occurs naturally, lie on your side, in the <br />recovery position. <br />IF exposed or concerned: Get medical advice/attention.</p> <p>SECTION 5) FIRE-FIGHTING MEASURES <br />Suitable Extinguishing Media: <br />Dry chemical, foam, carbon dioxide is recommended. Water spray is recommended to cool or protect exposed materials or structures. <br />Carbon dioxide can displace oxygen. Use caution when applying carbon dioxide in confined spaces. Simultaneous use of foam and water <br />on the same surface is to be avoided as water destroys the foam. Sand or earth may be used for small fires only.</p> <p>Unsuitable Extinguishing Media: <br />If water is used, use very large quantities of cold water. The reaction between water and hot isocyanate may be vigorous.</p> <p>Specific Hazards in Case of Fire: <br />Vapors may accumulate and travel to ignition sources distant from the handling site; flash fire can occur. <br />Excessive pressure or temperature may cause explosive rupture of containers. <br />Water contamination will produce carbon dioxide. Do not reseal contaminated containers as pressure buildup may rupture them.</p> <p>Fire-fighting Procedures: <br />Isolate immediate hazard area and keep unauthorized personnel out. Stop spill/release if it can be done safely. Move undamaged <br />containers from immediate hazard area if it can be done safely. Water spray may be useful in minimizing or dispersing vapors and to <br />protect personnel. Water may be ineffective but can be used to cool containers exposed to heat or flame. Caution should be exercised <br />when using water or foam as frothing may occur, especially if sprayed into containers of hot, burning liquid. <br />Dispose of fire debris and contaminated extinguishing water in accordance with official regulations.</p> <p>Special Protective Actions: <br />Wear NIOSH approved self-contained breathing apparatus in positive pressure mode with full-face piece. Boots, gloves (neoprene), <br />googles, and full protective clothing are also required. <br />Care should always be exercised in dust/mist areas.</p> <p>SECTION 6) ACCIDENTAL RELEASE MEASURES <br />Emergency Procedure:</p> <p>SDS RE-ROOF White Urethane Top Coat <br />SDS DATE: 22-DEC-27</p> <p>Page 3 of 9</p> <p>ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area). <br />Do not touch or walk through spilled material. <br />Isolate hazard area and keep unnecessary people away. Remove all possible sources of ignition in the surrounding area. Notify authorities <br />if any exposure to the general public or the environment occurs or is likely to occur. <br />If spilled material is cleaned up using a regulated solvent, the resulting waste mixture may be regulated.</p> <p>Recommended Equipment: <br />Appropriate dust or face mask to eliminate breathing foam dust particulates.</p> <p>Personal Precautions: <br />Avoid breathing vapors. Avoid contact with skin, eyes or clothing. Do not touch damaged containers or spilled materials unless wearing <br />appropriate protective clothing.</p> <p>Environmental Precautions: <br />Stop spill/release if it can be done safely. Prevent spilled material from entering sewers, storm drains, other unauthorized drainage systems <br />and natural waterways by using sand, earth, or other appropriate barriers.</p> <p>Methods and Materials for Containment and Cleaning up: <br />Cover container, but do not seal, and remove from work area. Prepare a decontamination solution of 2.0% liquid detergent and 3-8% <br />concentrated ammonium hydroxide in water (5-10% sodium carbonate may be substituted for the ammonium hydroxide). Follow the <br />precautions on the supplier's safety data sheets. <br />Treat the spill area with the decontamination solution, using about 10 parts of the solution for each part of the spill, and allow it to react for <br />at least 15 minutes. Carbon dioxide will be evolved, leaving insoluble polyureas. Residues from spill cleanup, even when treated as <br />described may continue to be regulated under provisions of RCRA and require storage and disposal as hazardous waste. <br />Slowly stir the isocyanate waste into the decontamination solution described above. Let stand for 48 hours, allowing the evolved carbon <br />dioxide to vent away, residues may still be subject to RCRA storage and disposal requirements. Dispose off in compliance with all relevant <br />local, state, and federal laws and regulations regarding treatment.</p> <p>SECTION 7) HANDLING AND STORAGE <br />General: <br />Wash hands after use. <br />Do not get in eyes, on skin or on clothing. <br />Do not breathe vapors or mists. <br />Use good personal hygiene practices. <br />Eating, drinking and smoking in work areas is prohibited. <br />Remove contaminated clothing and protective equipment before entering eating areas.</p> <p>Ventilation Requirements: <br />Use only with adequate ventilation to control air contaminants to their exposure limits. The use of local ventilation is recommended to <br />control emissions near the source.</p> <p>Storage Room Requirements: <br />Keep container(s) tightly closed and properly labeled. Store in cool, dry, well-ventilated areas away from heat, direct sunlight, strong <br />oxidizers and any incompatibilities. Store in approved containers and protect against physical damage. Keep containers securely sealed <br />when not in use. Indoor storage should meet OSHA standards and appropriate fire codes. Containers that have been opened must be <br />carefully resealed to prevent leakage. Empty container retain residue and may be dangerous. <br />Use non-sparking ventilation systems, approved explosion-proof equipment and intrinsically safe electrical systems in areas where this <br />product is used and stored. <br />Ground and bond containers and receiving equipment. Avoid static electricity by grounding. <br />Do not cut, drill, grind, weld, or perform similar operations on or near containers. Do not pressurize containers to empty them. Ground all <br />structures, transfer containers and equipment to conform to the national electrical code. Use procedures that prevent static electrical <br />sparks. Static electricity may accumulate and create a fire hazard.</p> <p>SECTION 8) EXPOSURE CONTROLS/PERSONAL PROTECTION <br />Eye Protection: <br />Wear eye protection with side shields or goggles. Wear indirect-vent, impact and splash resistant goggles when working with liquids. If <br />additional protection is needed for entire face, use in combination with a face shield.</p> <p>Skin Protection: <br />Use of gloves approved to relevant standards made from the following materials may provide suitable chemical protection: PVC, neoprene <br />or nitrile rubber gloves. Suitability and durability of a glove is dependent on usage, e.g. frequency and duration of contact, chemical <br />resistance of glove material, glove thickness, dexterity. Always seek advice from glove suppliers. Contaminated gloves should be replaced. <br />Use of an apron and over- boots of chemically impervious materials such as neoprene or nitrile rubber is recommended to avoid skin <br />sensitization. The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at <br />the specific workplace. Launder soiled clothes or properly disposed of contaminated material, which cannot be decontaminated. <br />Depending on conditions of use, additional protection may be required such as apron, arm covers, or full body suit. <br />Wash contaminated clothing before re-wearing.</p> <p>Respiratory Protection:</p> <p>SDS RE-ROOF White Urethane Top Coat <br />SDS DATE: 22-DEC-27</p> <p>Page 4 of 9</p> <p>If airborne concentrations exceed or are expected to exceed the TLV, use MSHA/NIOSH approved positive pressure supplied pressure <br />supplied air respiratory with a full face piece or an air supplied hood. For emergencies, use a positive pressure self-contained breathing <br />apparatus. Air purifying (cartridge type) respirators are not approved for protection against isocyanates.</p> <p>Appropriate Engineering Controls: <br />Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors below their respective threshold <br />limit value. <br />Chemical Name</p> <p>OSHA <br />TWA <br />(ppm)</p> <p>OSHA <br />TWA <br />(mg/m3)</p> <p>BENZENE-1-CHLORO <br />-4 <br />(TRIFLUOROMETHYL <br />)ETHYLBENZENE</p> <p>100</p> <p>OSHA <br />STEL <br />(ppm)</p> <p>OSHA <br />STEL <br />(mg/m3)</p> <p>OSHA <br />OSHA <br />NIOSH <br />Tables (Z1, OSHA <br />Skin <br />TWA <br />Z2, Z3) Carcinogen designation <br />(ppm)</p> <p>2.5</p> <p>1</p> <p>435</p> <p>1</p> <p>ISOPHORONE <br />DIISOCYANATE <br />SILICA, <br />CRYSTALLINE</p> <p>a</p> <p>Chemical Name</p> <p>NIOSH <br />STEL <br />(mg/m3)</p> <p>100</p> <p>435</p> <p>125</p> <p>545</p> <p>0.005</p> <p>0.045</p> <p>0.02</p> <p>0.180</p> <p>[1,3]; [3];</p> <p>15</p> <p>1</p> <p>b</p> <p>1,2</p> <p>100</p> <p>375</p> <p>150</p> <p>560</p> <p>1</p> <p>100</p> <p>435</p> <p>150</p> <p>655</p> <p>200 (a)/ <br />300 ceiling</p> <p>0.2</p> <p>100</p> <p>435</p> <p>ACGIH <br />TWA <br />(ppm)</p> <p>ACGIH <br />TWA <br />(mg/m3)</p> <p>XYLENE</p> <p>NIOSH <br />STEL <br />(ppm)</p> <p>[10 mg/m3 <br />percent <br />SiO2+2 / <br />250 <br />percent <br />SiO2+5 <br />mppcf]; [30 <br />mg/m3 <br />percent <br />SiO2+2];</p> <p>TITANIUM DIOXIDE <br />TOLUENE</p> <p>NIOSH <br />TWA <br />(mg/m3)</p> <p>BENZENE-1-CHLORO <br />-4 <br />(TRIFLUOROMETHYL <br />)-</p> <p>500ppm <br />/10 minutes <br />(a)</p> <p>ACGIH <br />STEL <br />(ppm)</p> <p>ACGIH <br />STEL <br />(mg/m3)</p> <p>150</p> <p>651</p> <p>0.05e</p> <p>NIOSH <br />Carcinogen</p> <p>1</p> <p>1</p> <p>2.5</p> <p>ETHYLBENZENE</p> <p>20</p> <p>ISOPHORONE <br />DIISOCYANATE</p> <p>0.005</p> <p>SILICA, <br />CRYSTALLINE</p> <p>0.045 <br />0.025 (R)</p> <p>TITANIUM DIOXIDE</p> <p>10</p> <p>TOLUENE</p> <p>20</p> <p>0.2</p> <p>XYLENE</p> <p>100</p> <p>434</p> <p>SECTION 9) PHYSICAL AND CHEMICAL PROPERTIES <br />Physical and Chemical Properties <br />Density</p> <p>11.20 lb/gal</p> <p>Specific Gravity</p> <p>1.34</p> <p>VOC Regulatory</p> <p>0.42 lb/gal</p> <p>VOC Part A & B Combined</p> <p>N.A.</p> <p>Appearance</p> <p>Pigmented Liquid</p> <p>SDS RE-ROOF White Urethane Top Coat <br />SDS DATE: 22-DEC-27</p> <p>Page 5 of 9</p> <p>Odor Threshold</p> <p>N.A.</p> <p>Odor Description</p> <p>Mild Chemical</p> <p>pH</p> <p>N.A.</p> <p>Water Solubility</p> <p>Reacts with Water</p> <p>Flammability</p> <p>N/A</p> <p>Flash Point Symbol</p> <p>N.A.</p> <p>Flash Point</p> <p>68 °C</p> <p>Viscosity</p> <p>N.A.</p> <p>Lower Explosion Level</p> <p>N.A.</p> <p>Upper Explosion Level</p> <p>N.A.</p> <p>Vapor Pressure</p> <p>N.A.</p> <p>Vapor Density</p> <p>Heavier than air</p> <p>Freezing Point</p> <p>N.A.</p> <p>Melting Point</p> <p>N.A.</p> <p>Low Boiling Point</p> <p>110 °C</p> <p>High Boiling Point</p> <p>N.A.</p> <p>Auto Ignition Temp</p> <p>N.A.</p> <p>Decomposition Pt</p> <p>N.A.</p> <p>Evaporation Rate</p> <p>Slower than ether</p> <p>Coefficient Water/Oil</p> <p>N.A.</p> <p>SECTION 10) STABILITY AND REACTIVITY <br />Stability: <br />Material is stable at standard temperature and pressure.</p> <p>Conditions to Avoid: <br />Heat, high temperature, open flame, sparks, and moisture. Contact with incompatible materials in a closed system will cause liberation of <br />carbon dioxide and buildup of pressure.</p> <p>Hazardous Reactions/Polymerization: <br />Will not occur under normal conditions but under high temperatures in the presence of alkalis,tertiary amines, and metal compounds will <br />accelerate polymerization. Possible evolution of carbon dioxide gas may rupture closed containers.</p> <p>Incompatible Materials: <br />This product will react with any material containing active hydrogens, such as water, alcohol, ammonia, amines, alkalis and acids, the <br />reaction with water is slow under 50°C, but is accelerated at higher temperature and in the presence of alkalis, tertiary amines, and metal <br />compounds. Some reactions can be violent. Material can react with strong oxidizing agents.</p> <p>Hazardous Decomposition Products: <br />Carbon dioxide, carbon monoxide, nitrogen oxides, trace amounts of hydrogen cyanide and unidentified organic compounds may be <br />formed during combustion.</p> <p>SECTION 11) TOXICOLOGICAL INFORMATION <br />Skin Corrosion/Irritation: <br />Isocyanates react with skin protein and moisture and can cause irritation. Prolonged contact can cause reddening, swelling, rash, scaling, <br />blistering, and, in some cases, skin sensitization. Individuals who have developed a skin sensitization can <br />develop these symptoms as a result of contact with very small amounts of liquid material or as a result of exposure to vapor. <br />Causes skin irritation</p> <p>Serious Eye Damage/Irritation: <br />Liquid, aerosols or vapors are severely irritating and can cause pain, tearing, reddening and swelling. Prolonged vapor contact may cause <br />conjunctivitis. Any level of contact should not be left untreated. <br />Causes serious eye irritation</p> <p>Carcinogenicity: <br />Suspected of causing cancer.</p> <p>Respiratory/Skin Sensitization: <br />May cause allergy or asthma symptoms or breathing difficulties if inhaled</p> <p>SDS RE-ROOF White Urethane Top Coat <br />SDS DATE: 22-DEC-27</p> <p>Page 6 of 9</p> <p>May cause an allergic skin reaction</p> <p>Germ Cell Mutagenicity: <br />No data available</p> <p>Reproductive Toxicity: <br />Suspected of damaging fertility or the unborn child.</p> <p>Specific Target Organ Toxicity - Single Exposure: <br />No data available</p> <p>Specific Target Organ Toxicity - Repeated Exposure: <br />May cause damage to organs through prolonged or repeated exposure.</p> <p>Aspiration Hazard: <br />No data available</p> <p>Acute Toxicity: <br />No data available <br />0004098-71-9</p> <p>ISOPHORONE DIISOCYANATE</p> <p>LC50 (rat): 123-160 mg/m3 (13.6-17.6 ppm) (4-hour exposure) (aerosol) (1,2) <br />LD50 (oral, male rat): greater than 2,500 mg/kg (1) <br />LD50 (oral, male mouse): greater than 2,500 mg/kg (1) <br />LD50 (dermal, male rat): approx. 1,000 mg/kg (4-hour exposure); approx. 500 mg/kg (4-day exposure) (1) <br />0001330-20-7</p> <p>XYLENE</p> <p>LC50 (rat): 6350 ppm (4-hour exposure) (unspecified isomers and ethylbenzene) (1)LC50 (rat): 6700 ppm (4-hour exposure) (65% m <br />-xylene, 7.6% o-xylene, 7.8% p-xylene, 19.3% ethylbenzene) (2) ethylbenzene) (1) <br />LC50 (rat): 6700 ppm (4-hour exposure) (65% m-xylene, 7.6% o-xylene, 7.8% p-xylene, 19.3% ethylbenzene)(2) <br />LD50 (oral, rat): 5400 mg/kg (52% m-, 19% o-, 24% p-) (1)LD50 (oral, female mouse): 5251 mg/kg (60.2% m-, 9.1% o-, 14.6% p-, <br />17.0% ethylbenzene) (4) <br />LD50 (oral, male mouse): 5627 mg/kg (60.2% m-, 9.1% o-, 14.6% p-, 17.0% ethylbenzene) (4) <br />LD50 (dermal, rabbit): 12180 mg/kg (m-xylene); greater than 1700 mg/kg (mixed xylenes - undefined composition) (3) <br />LD50 (oral, female mouse): 5251 mg/kg (60.2% m-, 9.1% o-, 14.6% p-, 17.0% ethylbenzene) (4) <br />LD50 (oral, male mouse): 5627 mg/kg (60.2% m-, 9.1% o-, 14.6% p-, 17.0% ethylbenzene) (4) <br />LD50 (dermal, rabbit): 12180 mg/kg (m-xylene); greater than 1700 mg/kg (mixed xylenes - undefined composition) (3) <br />0000108-88-3</p> <p>TOLUENE</p> <p>LC50 (rat): 8800 ppm (4-hour exposure) (2) <br />LC50 (rat): 6000 ppm (6-hour exposure) (3) <br />LD50 (oral, rat): 2600 to 7500 mg/kg (3,5,11,17) <br />LD50 (oral, neonatal rat): less than 870 mg/kg (3) <br />LD50 (dermal, rabbit): 12,225 mg/kg (reported as 14.1 ml/kg) (1) <br />0000100-41-4</p> <p>ETHYLBENZENE</p> <p>LC50 (inhalation, rat): 4000 ppm; 4-hour exposure (3) <br />LD50 (oral, rat): 3.5 g/kg (1,3,5,10) <br />LD50 (oral, rat): 4.72 g/kg (3,5,7,8) <br />LD50 (dermal, rabbit): 17.8 g/kg (11) <br />0054914-37-3</p> <p>ALDIMINE</p> <p>LD50 (rat,oral): 4150 mg/kg (based on raw material SDS) <br />LD50 (rat,dermal): >5000 mg/kg (based on raw material SDS)</p> <p>Potential Health Effects - Miscellaneous <br />0000098-56-6</p> <p>BENZENE-1-CHLORO-4(TRIFLUOROMETHYL)-</p> <p>Increased susceptibility to the effects of this material may be observed in people with preexisting disease of any of the following: <br />skin. Prolonged or repeated exposure may cause damage to any of the following organs/systems: kidneys, liver, thyroid. Potential <br />skin sensitizer that may cause allergic reactions and contact dermatitis resulting in severe irritation, dryness, and cracking of the <br />skin. Ingestion may cause any of the following: gastrointestinal irritation. Eye contact may cause any of the following: permanent <br />eye injury. Inhalation may cause any of the following: stupor (central nervous system depression), respiratory tract irritation. <br />0000100-41-4</p> <p>ETHYLBENZENE</p> <p>Is an IARC, NTP or OSHA carcinogen. Increased susceptibility to the effects of this material may be observed in people with <br />preexisting disease of any of the following: central nervous system, kidneys, liver, lungs. Recurrent overexposure may result in <br />liver and kidney injury. Studies in laboratory animals have shown reproductive, embryotoxic and developmental effects. <br />WARNING: This chemical is known to the State of California to cause cancer.</p> <p>SDS RE-ROOF White Urethane Top Coat <br />SDS DATE: 22-DEC-27</p> <p>Page 7 of 9</p> <p>0000108-88-3</p> <p>TOLUENE</p> <p>Increased susceptibility to the effects of this material may be observed in people with preexisting disease of any of the following: <br />central nervous system, kidneys, liver, respiratory system, skin. Can be absorbed through the skin in harmful amounts. Recurrent <br />overexposure may result in liver and kidney injury. High airborne levels have produced irregular heart beats in animals and <br />occasional palpitations in humans. Rats exposed to very high airborne levels have exhibited high frequency hearing deficits. The <br />significance of this to man is unknown. WARNING: This chemical is known to the State of California to cause birth defects or <br />other reproductive harm. <br />0001330-20-7</p> <p>XYLENE</p> <p>Increased susceptibility to the effects of this material may be observed in people with preexisting disease of any of the following: <br />bone marrow, cardiovascular system, central nervous system, kidneys, liver, lungs. Recurrent overexposure may result in liver <br />and kidney injury. High exposures may produce irregular heart beats. Canada classifies Xylene as a developmental toxin as high <br />exposures to xylenes in some animal studies have been reported to cause health effects on the developing fetus/embryo. These <br />effects were often at levels toxic to the adult animal. The significance of these effects to humans is not known. Repeated or <br />prolonged skin contact may cause any of the following: irritation, dryness, cracking of the skin. <br />0013463-67-7</p> <p>TITANIUM DIOXIDE</p> <p>Is an IARC, NTP or OSHA carcinogen. In a lifetime inhalation test, lung cancers were found in some rats exposed to 250 mg/m3 <br />respirable titanium dust. Analysis of the titanium dioxide concentrations in the rat?s lungs showed that the lung clearance <br />mechanism was overwhelmed and that the results at the massive 250 mg/m3 level are not relevant to the workplace.?Results of a <br />DuPont epidemiology study showed that employees who had been exposed to Titanium Dioxide were at no greater risk of <br />developing lung cancer than were employees who had not been exposed to Titanium dioxide. No pulmonary fibrosis was found in <br />any of the employees and no association was observed between Titanium dioxide exposure and chronic respiratory disease or xray abnormalities. Based on the results of this study DuPont concludes that titanium dioxide will not cause lung cancer or chronic <br />respiratory disease in humans at concentrations experienced in the workplace.? <br />0014808-60-7</p> <p>SILICA, CRYSTALLINE</p> <p>Is an IARC, NTP or OSHA carcinogen. Repeated overexposure to crystalline silica may lead to x-ray changes and chronic lung <br />disease. Inhalation of high dust concentrations may cause: breathing difficulties, lung injury. WARNING: This chemical is known to <br />the State of California to cause cancer.</p> <p>Chronic Exposure <br />0000100-41-4</p> <p>ETHYLBENZENE</p> <p>CARCINOGENIC EFFECTS: Ethyl Benzene has been listed by IARC as Group 2B, Possibly Carcinogenic to Humans. <br />TERATOGENIC EFFECTS: Ethyl Benzene has been Classified as POSSIBLE for humans. <br />0000108-88-3</p> <p>TOLUENE</p> <p>TERATOGENIC EFFECTS:Toluene has been Classified as POSSIBLE for humans. <br />0001330-20-7</p> <p>XYLENE</p> <p>High exposure to Xylenes in some animal studies have been reported to cause health effects on the developing embryo/fetus. <br />Xylene in high concentrations has caused embryotoxic effects in laboratory animals. <br />0014808-60-7</p> <p>SILICA, CRYSTALLINE</p> <p>Prolonged inhalation of respirable crystalline silica dust can result in lung disease (i.e. silicosis and/or lung cancer). Symptoms <br />include coughing, shortness of breath, wheezing and reduced pulmonary function.</p> <p>SECTION 12) ECOLOGICAL INFORMATION <br />Toxicity: <br />No data available. <br />Harmful to aquatic life</p> <p>Other Adverse Effects: <br />No data available.</p> <p>SECTION 13) DISPOSAL CONSIDERATIONS <br />Waste Disposal: <br />Under RCRA, it is the responsibility of the user of the product, to determine a the time of disposal whether the product meets RCRA criteria <br />for hazardous waste. Waste management should be in full compliance with federal, state, and local laws. <br />Empty containers retain product residue which may exhibit hazards of material, therefore do not pressurize, cut, glaze, weld or use for any <br />other purposes. Return drums to reclamation centers for proper cleaning and reuse.</p> <p>SDS RE-ROOF White Urethane Top Coat <br />SDS DATE: 22-DEC-27</p> <p>Page 8 of 9</p> <p>SECTION 14) TRANSPORT INFORMATION <br />U.S. DOT Information: <br />Not regulated.</p> <p>IMDG Information: <br />Not regulated.</p> <p>IATA Information: <br />Not regulated.</p> <p>SECTION 15) REGULATORY INFORMATION <br />CAS</p> <p>Chemical Name</p> <p>% By Weight</p> <p>Regulation List</p> <p>0053880-05-0</p> <p>POLYURETHANE <br />PREPOLYMER</p> <p>27% - 50% DSL,SARA312,TSCA</p> <p>0013463-67-7</p> <p>TITANIUM DIOXIDE</p> <p>14% - 26% DSL,SARA312,TSCA,CA_Prop65 - California Proposition 65</p> <p>0000098-56-6</p> <p>BENZENE-1-CHLORO-4 <br />(TRIFLUOROMETHYL)-</p> <p>10% - 18% DSL,SARA312,TSCA</p> <p>0014808-60-7</p> <p>SILICA, CRYSTALLINE</p> <p>0001330-20-7</p> <p>XYLENE</p> <p>0054914-37-3</p> <p>ALDIMINE</p> <p>0000100-41-4</p> <p>ETHYLBENZENE</p> <p>0.7% - 1.2% SARA313, DSL,CERCLA,HAPS,SARA312,VHAPS,VOC,TSCA,CA_Prop65 - California Proposition 65</p> <p>0004098-71-9</p> <p>ISOPHORONE <br />DIISOCYANATE</p> <p>0.2% - 0.3% SARA313, DSL,SARA312,VOC,TSCA</p> <p>0000108-88-3</p> <p>TOLUENE</p> <p>8% - 15% DSL,SARA312,TSCA,CA_Prop65 - California Proposition 65 <br />2% - 4% SARA313, DSL,CERCLA,HAPS,SARA312,VHAPS,VOC,TSCA,RCRA <br />1.7% - 3% DSL,SARA312,TSCA</p> <p>Trace SARA313, DSL,CERCLA,HAPS,SARA312,VHAPS,VOC,TSCA,RCRA,CA_Prop65 - California Proposition <br />65</p> <p>SECTION 16) OTHER INFORMATION <br />OTHER INFORMATION: <br />* There are points of differences between OSHA GHS and UN GHS. In 90% of the categories, they can be used interchangeably, but for <br />the Skin Corrosion/Irritant Category and the Specific Target Organ Toxicity (Single and Repeated Exposure) Categories. In these cases, <br />our system will say UN GHS.</p> <p>GLOSSARY: <br />ACGIH- American Conference of Governmental Industrial Hygienists; ANSI- American National Standards Institute; CA Prop65- California <br />Proposition 65; Canadian TDG- Canadian Transportation of Dangerous Goods; CAS- Chemical Abstract Service; Chemtrec- Chemical <br />Transportation Emergency Center (US); CHIP- Chemical Hazard Information and Packaging; DSL- Domestic Substances List; ECEquivalent Concentration; EH40 (UK)- HSE Guidance Note EH40 Occupational Exposure Limits; EPCRA- Emergency Planning and <br />Community Right-To-Know Act; ESL- Effects screening levels; HMIS- Hazardous Material Information Service; LC- Lethal Concentration; <br />LD- Lethal Dose; NFPA- National Fire Protection Association; OEL- Occupational Exposure Limits; OSHA- Occupational Safety and Health <br />Administration, US Department of Labor; PEL- Permissible Exposure Limit; SARA (Title III)- Superfund Amendments and Reauthorization <br />Act; SARA 313- Superfund Amendments and Reauthorization Act, Section 313; SCBA- Self-Contained Breathing Apparatus; STEL- Short <br />Term Exposure Limit; TCEQ- Texas Commission on Environmental Quality; TLV- Threshold Limit Value; TSCA- Toxic Substances Control <br />Act Public Law 94-469; TWA- Time Weighted Value; US DOT- US Department of Transportation; WHMIS- Workplace Hazardous Materials <br />Information System.</p> <p>Version 1.0: <br />Revision Date: Nov 22, 2016 <br />First Edition.</p> <p>DISCLAIMER <br />To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its subsidiaries <br />assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any <br />material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain <br />hazards are described herein, we cannot guarantee that these are the only hazards that exist. The above information pertains to this product as <br />currently formulated, and is based on the information available at this time. Addition of reducers or other additives to this product may substantially <br />alter the composition and hazards of the product. Since conditions of use are outside our control, we make no warranties, express or implied, and <br />assume no liability in connection with any use of this information.</p> <p>SDS RE-ROOF White Urethane Top Coat <br />SDS DATE: 22-DEC-27</p> <p>Page 9 of 9</p>
