SDS_RE-ROOF White Urethane Top Coat FR_122722.pdf
11 Pages
893 KB
Download
<h1>SDS_RE-ROOF White Urethane Top Coat FR_122722.pdf</h1> <p>Safety Data Sheet (SDS)</p> <p>Page 1/11</p> <p>OSHA HazCom Standard 29 CFR 1910.1200(g) and GHS Rev 03.</p> <p>Printing date 12/27/2022</p> <p>Reviewed on 12/27/2022</p> <p>SECTION 1) CHEMICAL PRODUCT AND MANUFACTURER'S IDENTIFICATION</p> <p>IDENTITY:</p> <p>Product Name: RE-ROOF White Urethane Top Coat FR <br />Product Use Description:</p> <p>AQUAFIN, INC. <br />505 BLUE BALL RD. #160 <br />ELKTON, MD 21921</p> <p>Urethane-based Liquid Roof Coating, For Further Information, Refer to the <br />Product Technical Data Sheet.</p> <p>info@aquafin.net</p> <p>24 hr Emergency Phone: Chem-Tel (800) 255-3924 <br />Information Phone No: (410) 392-2300</p> <p>www.aquafin.net</p> <p>SECTION 2) HAZARDS IDENTIFICATION <br />Classification <br />Acute aquatic toxicity - Category 2 <br />Carcinogenicity - Category 1B <br />Chronic aquatic toxicity - Category 2 <br />Eye Irritation - Category 2 <br />Flammable Liquids - Category 4 <br />Germ Cell Mutagenicity - Category 1B <br />Reproductive Toxicity - Category 2 <br />Respiratory Sensitizer (Solid/Liquid) - Category 1 <br />Skin Irritation - Category 2 <br />Skin Sensitizer - Category 1 <br />Specific Target Organ Toxicity - Repeated Exposure - Category 2 <br />Specific Target Organ Toxicity - Single Exposure - Category 1</p> <p>Pictograms</p> <p>Signal Word <br />Danger</p> <p>Hazardous Statements - Physical <br />H227 - Combustible Liquid</p> <p>Hazardous Statements - Health <br />H350 - May cause cancer. <br />H319 - Causes serious eye irritation</p> <p>SDS RE-ROOF White Urethane Top Coat FR <br />SDS DATE: 22-DEC-27</p> <p>Page 1 of 11</p> <p>H340 - May cause genetic defects. <br />H361 - Suspected of damaging fertility or the unborn child. <br />H334 - May cause allergy or asthma symptoms or breathing difficulties if inhaled <br />H315 - Causes skin irritation <br />H317 - May cause an allergic skin reaction <br />H373 - May cause damage to organs through prolonged or repeated exposure. <br />H370 - Causes damage to organs.</p> <p>Hazardous Statements - Environmental <br />H401 - Toxic to aquatic life <br />H411 - Toxic to aquatic life with long lasting effects</p> <p>Precautionary Statements - General <br />P101 - If medical advice is needed, have product container or label at hand. <br />P102 - Keep out of reach of children. <br />P103 - Read label before use.</p> <p>Precautionary Statements - Prevention <br />P273 - Avoid release to the environment. <br />P201 - Obtain special instructions before use. <br />P202 - Do not handle until all safety precautions have been read and understood. <br />P280 - Wear protective gloves/protective clothing/eye protection/face protection. <br />P264 - Wash thoroughly after handling. <br />P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. <br />P261 - Avoid breathing dust/fume/gas/mist/vapors/spray. <br />P284 - [In case of inadequate ventilation] wear respiratory protection. <br />P272 - Contaminated work clothing should not be allowed out of the workplace. <br />P260 - Do not breathe dust/fume/gas/mist/vapors/spray. <br />P270 - Do not eat, drink or smoke when using this product.</p> <p>Precautionary Statements - Response <br />P308 + P313 - IF exposed or concerned: Get medical advice/attention. <br />P391 - Collect spillage. <br />P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. <br />Continue rinsing. <br />P337 + P313 - If eye irritation persists: Get medical advice/attention. <br />P370 + P378 - In case of fire: Use dry chemical, carbon dioxide, foam to extinguish. <br />For detailed information, see Section-5 (Fire Fighting Measures) <br />P304 + P340 - IF INHALED: Remove person to fresh air and keep comfortable for breathing. <br />P342 + P311 - If experiencing respiratory symptoms: Call a POISON CENTER/doctor. <br />P302 + P352 - IF ON SKIN: Wash with plenty of water. <br />P321 - Specific treatment (see section 4 on this SDS). <br />P332 + P313 - If skin irritation occurs: Get medical advice/attention. <br />P362 + P364 - Take off contaminated clothing. And wash it before reuse. <br />P333 + P313 - If skin irritation or a rash occurs: Get medical advice/attention. <br />P314 - Get Medical advice/attention if you feel unwell. <br />P308 + P311 - IF exposed or concerned: Call a POISON CENTER/doctor.</p> <p>Precautionary Statements - Storage <br />P405 - Store locked up.</p> <p>SDS RE-ROOF White Urethane Top Coat FR <br />SDS DATE: 22-DEC-27</p> <p>Page 2 of 11</p> <p>P403 - Store in a well-ventilated place.</p> <p>Precautionary Statements - Disposal <br />P501 - Dispose of contents/ container to an approved waste disposal plant.</p> <p>SECTION 3) COMPOSITION/INFORMATION ON INGREDIENTS <br />CAS</p> <p>Chemical Name</p> <p>% By Weight</p> <p>0053880-05-0</p> <p>POLYURETHANE PREPOLYMER</p> <p>27% - 50%</p> <p>0000098-56-6</p> <p>BENZENE-1-CHLORO-4(TRIFLUOROMETHYL)-</p> <p>13% - 24%</p> <p>0013463-67-7</p> <p>TITANIUM DIOXIDE</p> <p>13% - 25%</p> <p>0014808-60-7</p> <p>SILICA, CRYSTALLINE</p> <p>8% - 15%</p> <p>0001330-20-7</p> <p>XYLENE</p> <p>2% - 5%</p> <p>0064742-95-6</p> <p>AROMATIC HYDROCARBON MIXTURE >C9</p> <p>1.6% - 3%</p> <p>0000123-86-4</p> <p>N-BUTYL ACETATE</p> <p>1.3% - 2%</p> <p>0001309-64-4</p> <p>ANTIMONY TRIOXIDE</p> <p>0.9% - 1.6%</p> <p>0054914-37-3</p> <p>ALDIMINE</p> <p>0.8% - 1.4%</p> <p>0000100-41-4</p> <p>ETHYLBENZENE</p> <p>0.7% - 1.2%</p> <p>0004098-71-9</p> <p>ISOPHORONE DIISOCYANATE</p> <p>0.2% - 0.3%</p> <p>0000108-88-3</p> <p>TOLUENE</p> <p>Trace</p> <p>Specific chemical identity and/or exact percentage (concentration) of the composition has been withheld to protect confidentiality.</p> <p>SECTION 4) FIRST-AID MEASURES <br />Inhalation <br />Remove source of exposure or move person to fresh air and keep comfortable for breathing. If experiencing respiratory symptoms: Call a <br />POISON CENTER/doctor. If breathing is difficult, trained personnel should administer emergency oxygen if advised to do so by the <br />POISON CENTER/doctor. <br />If exposed/feel unwell/concerned: Call a POISON CENTER/doctor. <br />Eliminate all ignition sources if safe to do so.</p> <p>Skin Contact <br />Take off contaminated clothing, shoes and leather goods (e.g. watchbands, belts). Gently blot or brush away excess product. Wash with <br />plenty of lukewarm, gently flowing water for a duration of 15-20 minutes. If skin irritation or rash occurs: Get medical advice/attention. <br />Wash contaminated clothing before re-use or discard. <br />IF exposed or concerned: Get medical advice/attention.</p> <p>Eye Contact <br />Avoid direct contact. Wear chemical protective gloves, if necessary. <br />Rinse eyes cautiously with lukewarm, gently flowing water for several minutes, while holding the eyelids open. Remove contact lenses, if <br />present and easy to do. Continue rinsing for 15-20 minutes. Take care not to rinse contaminated water into the unaffected eye or onto the <br />face. If eye irritation persists: Get medical advice/attention.</p> <p>Ingestion <br />Rinse mouth. Do NOT induce vomiting. Immediately call a POISON CENTER/doctor. If vomiting occurs naturally, lie on your side, in the <br />recovery position. <br />IF exposed or concerned: Get medical advice/attention.</p> <p>SECTION 5) FIRE-FIGHTING MEASURES <br />Suitable Extinguishing Media <br />Dry chemical, foam, carbon dioxide is recommended. Water spray is recommended to cool or protect exposed materials or structures. <br />Carbon dioxide can displace oxygen. Use caution when applying carbon dioxide in confined spaces. Simultaneous use of foam and water</p> <p>SDS RE-ROOF White Urethane Top Coat FR <br />SDS DATE: 22-DEC-27</p> <p>Page 3 of 11</p> <p>on the same surface is to be avoided as water destroys the foam. Sand or earth may be used for small fires only.</p> <p>Unsuitable Extinguishing Media <br />If water is used, use very large quantities of cold water. The reaction between water and hot isocyanate may be vigorous.</p> <p>Specific Hazards in Case of Fire <br />Vapors may accumulate and travel to ignition sources distant from the handling site; flash fire can occur. <br />Excessive pressure or temperature may cause explosive rupture of containers. <br />Water contamination will produce carbon dioxide. Do not reseal contaminated containers as pressure buildup may rupture them.</p> <p>Fire-fighting Procedures <br />Isolate immediate hazard area and keep unauthorized personnel out. Stop spill/release if it can be done safely. Move undamaged <br />containers from immediate hazard area if it can be done safely. Water spray may be useful in minimizing or dispersing vapors and to <br />protect personnel. Water may be ineffective but can be used to cool containers exposed to heat or flame. Caution should be exercised <br />when using water or foam as frothing may occur, especially if sprayed into containers of hot, burning liquid. <br />Dispose of fire debris and contaminated extinguishing water in accordance with official regulations.</p> <p>Special Protective Actions <br />Wear NIOSH approved self-contained breathing apparatus in positive pressure mode with full-face piece. Boots, gloves (neoprene), <br />goggles, and full protective clothing are also required. <br />Care should always be exercised in dust/mist areas.</p> <p>SECTION 6) ACCIDENTAL RELEASE MEASURES <br />Emergency Procedure <br />ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area). <br />Do not touch or walk through spilled material. <br />Isolate hazard area and keep unnecessary people away. Remove all possible sources of ignition in the surrounding area. Notify <br />authorities if any exposure to the general public or the environment occurs or is likely to occur. <br />If spilled material is cleaned up using a regulated solvent, the resulting waste mixture may be regulated.</p> <p>Recommended Equipment <br />Appropriate dust or face mask to eliminate breathing foam dust particulates.</p> <p>Personal Precautions <br />Avoid breathing vapors. Avoid contact with skin, eyes or clothing. Do not touch damaged containers or spilled materials unless wearing <br />appropriate protective clothing.</p> <p>Environmental Precautions <br />Stop spill/release if it can be done safely. Prevent spilled material from entering sewers, storm drains, other unauthorized drainage <br />systems and natural waterways by using sand, earth, or other appropriate barriers.</p> <p>Methods and Materials for Containment and Cleaning up <br />Cover container, but do not seal, and remove from work area. Prepare a decontamination solution of 2.0% liquid detergent and 3-8% <br />concentrated ammonium hydroxide in water (5-10% sodium carbonate may be substituted for the ammonium hydroxide). Follow the <br />precautions on the supplier's safety data sheets. <br />Treat the spill area with the decontamination solution, using about 10 parts of the solution for each part of the spill, and allow it to react for <br />at least 15 minutes. Carbon dioxide will be evolved, leaving insoluble polyureas. Residues from spill cleanup, even when treated as <br />described may continue to be regulated under provisions of RCRA and require storage and disposal as hazardous waste. <br />Slowly stir the isocyanate waste into the decontamination solution described above. Let stand for 48 hours, allowing the evolved carbon <br />dioxide to vent away, residues may still be subject to RCRA storage and disposal requirements. Dispose off in compliance with all <br />relevant local, state, and federal laws and regulations regarding treatment.</p> <p>SECTION 7) HANDLING AND STORAGE <br />General <br />Wash hands after use. <br />Do not get in eyes, on skin or on clothing. <br />Do not breathe vapors or mists. <br />Use good personal hygiene practices.</p> <p>SDS RE-ROOF White Urethane Top Coat FR <br />SDS DATE: 22-DEC-27</p> <p>Page 4 of 11</p> <p>Eating, drinking and smoking in work areas is prohibited. <br />Remove contaminated clothing and protective equipment before entering eating areas.</p> <p>Ventilation Requirements <br />Use only with adequate ventilation to control air contaminants to their exposure limits. The use of local ventilation is recommended to <br />control emissions near the source.</p> <p>Storage Room Requirements <br />Keep container(s) tightly closed and properly labeled. Store in cool, dry, well-ventilated areas away from heat, direct sunlight, strong <br />oxidizers and any incompatibilities. Store in approved containers and protect against physical damage. Keep containers securely sealed <br />when not in use. Indoor storage should meet OSHA standards and appropriate fire codes. Containers that have been opened must be <br />carefully resealed to prevent leakage. Empty container retain residue and may be dangerous. <br />Use non-sparking ventilation systems, approved explosion-proof equipment and intrinsically safe electrical systems in areas where this <br />product is used and stored. <br />Ground and bond containers and receiving equipment. Avoid static electricity by grounding. <br />Do not cut, drill, grind, weld, or perform similar operations on or near containers. Do not pressurize containers to empty them. Ground all <br />structures, transfer containers and equipment to conform to the national electrical code. Use procedures that prevent static electrical <br />sparks. Static electricity may accumulate and create a fire hazard.</p> <p>SECTION 8) EXPOSURE CONTROLS/PERSONAL PROTECTION <br />Eye Protection <br />Wear eye protection with side shields or goggles. Wear indirect-vent, impact and splash resistant goggles when working with liquids. If <br />additional protection is needed for entire face, use in combination with a face shield.</p> <p>Skin Protection <br />Use of gloves approved to relevant standards made from the following materials may provide suitable chemical protection: PVC, <br />neoprene or nitrile rubber gloves. Suitability and durability of a glove is dependent on usage, e.g. frequency and duration of contact, <br />chemical resistance of glove material, glove thickness, dexterity. Always seek advice from glove suppliers. Contaminated gloves should <br />be replaced. Use of an apron and over- boots of chemically impervious materials such as neoprene or nitrile rubber is recommended to <br />avoid skin sensitization. The type of protective equipment must be selected according to the concentration and amount of the dangerous <br />substance at the specific workplace. Launder soiled clothes or properly disposed of contaminated material, which cannot be <br />decontaminated. <br />Depending on conditions of use, additional protection may be required such as apron, arm covers, or full body suit. <br />Wash contaminated clothing before re-wearing.</p> <p>Respiratory Protection <br />If airborne concentrations exceed or are expected to exceed the TLV, use MSHA/NIOSH approved positive pressure supplied pressure <br />supplied air respiratory with a full face piece or an air supplied hood. For emergencies, use a positive pressure self-contained breathing <br />apparatus. Air purifying (cartridge type) respirators are not approved for protection against isocyanates.</p> <p>Appropriate Engineering Controls <br />Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors below their respective threshold <br />limit value. <br />Chemical Name</p> <p>OSHA <br />TWA <br />(ppm)</p> <p>ANTIMONY <br />TRIOXIDE <br />AROMATIC <br />HYDROCARBON <br />MIXTURE >C9</p> <p>500</p> <p>BENZENE-1CHLORO-4 <br />(TRIFLUOROMET <br />HYL)ETHYLBENZENE</p> <p>100</p> <p>OSHA <br />TWA <br />(mg/m3)</p> <p>OSHA <br />STEL <br />(ppm)</p> <p>OSHA <br />STEL <br />(mg/m3)</p> <p>OSHA <br />Tables <br />(Z1, Z2, <br />Z3)</p> <p>0.5</p> <p>1</p> <p>2000</p> <p>1</p> <p>2.5</p> <p>1</p> <p>435</p> <p>1</p> <p>ISOPHORONE <br />DIISOCYANATE <br />N-BUTYL <br />ACETATE <br />SILICA, <br />CRYSTALLINE</p> <p>150</p> <p>710</p> <p>1</p> <p>a</p> <p>[10 <br />mg/m3</p> <p>[1,3]; [3];</p> <p>SDS RE-ROOF White Urethane Top Coat FR <br />SDS DATE: 22-DEC-27</p> <p>OSHA <br />NIOSH <br />OSHA <br />Skin <br />TWA <br />Carcinog designati (ppm) <br />en <br />on</p> <p>NIOSH <br />NIOSH <br />TWA <br />STEL <br />(mg/m3) <br />(ppm)</p> <p>NIOSH <br />STEL <br />NIOSH <br />(mg/m3) Carcinog <br />en</p> <p>100</p> <p>435</p> <p>125</p> <p>545</p> <p>0.005</p> <p>0.045</p> <p>0.02</p> <p>0.180</p> <p>150</p> <p>710</p> <p>200</p> <p>950</p> <p>0.05e</p> <p>1</p> <p>Page 5 of 11</p> <p>percent <br />SiO2+2 / <br />250 <br />percent <br />SiO2+5 <br />mppcf]; <br />[30 <br />mg/m3 <br />percent <br />SiO2+2]; <br />TITANIUM <br />DIOXIDE</p> <p>15</p> <p>TOLUENE</p> <p>XYLENE</p> <p>Chemical Name</p> <p>200 (a)/ <br />300 <br />ceiling</p> <p>0.2</p> <p>100</p> <p>435</p> <p>ACGIH <br />TWA <br />(ppm)</p> <p>ANTIMONY <br />TRIOXIDE</p> <p>ACGIH ACGIH <br />TWA <br />STEL <br />(mg/m3) <br />(ppm)</p> <p>(L)</p> <p>AROMATIC <br />HYDROCARBON <br />MIXTURE >C9</p> <p>b</p> <p>1</p> <p>1,2</p> <p>100</p> <p>375</p> <p>150</p> <p>560</p> <p>1</p> <p>100</p> <p>435</p> <p>150</p> <p>655</p> <p>ACGIH <br />STEL <br />(mg/m3)</p> <p>(L)</p> <p>(L)[N159] <br />[(L) <br />(L)[N800] [N159](L) <br />[N800]]; <br />[5 (I) <br />[N159]5 <br />(I) <br />[N800]];</p> <p>BENZENE-1CHLORO-4 <br />(TRIFLUOROMET <br />HYL)-</p> <p>2.5</p> <p>ETHYLBENZENE</p> <p>20</p> <p>ISOPHORONE <br />DIISOCYANATE</p> <p>0.005</p> <p>N-BUTYL <br />ACETATE</p> <p>500ppm <br />/10 <br />minutes <br />(a)</p> <p>1</p> <p>50</p> <p>SILICA, <br />CRYSTALLINE</p> <p>150 <br />0.025 (R)</p> <p>TITANIUM <br />DIOXIDE</p> <p>10</p> <p>TOLUENE</p> <p>20</p> <p>XYLENE</p> <p>100</p> <p>150</p> <p>(L) - Exposure by all routes should be carefully controlled to levels as low as possible, (R) - Respirable fraction</p> <p>SECTION 9) PHYSICAL AND CHEMICAL PROPERTIES <br />Physical and Chemical Properties <br />Density</p> <p>11.12 lb/gal</p> <p>Specific Gravity</p> <p>1.33</p> <p>VOC Regulatory</p> <p>0.42 lb/gal</p> <p>VOC Part A & B Combined</p> <p>N.A.</p> <p>SDS RE-ROOF White Urethane Top Coat FR <br />SDS DATE: 22-DEC-27</p> <p>Page 6 of 11</p> <p>Appearance</p> <p>Pigmented Liquid</p> <p>Odor Threshold</p> <p>N.A.</p> <p>Odor Description</p> <p>Mild Chemical</p> <p>pH</p> <p>N.A.</p> <p>Water Solubility</p> <p>Reacts with Water</p> <p>Flammability</p> <p>N/A</p> <p>Flash Point Symbol</p> <p>N.A.</p> <p>Flash Point</p> <p>68 °C</p> <p>Viscosity</p> <p>N.A.</p> <p>Lower Explosion Level</p> <p>N.A.</p> <p>Upper Explosion Level</p> <p>N.A.</p> <p>Vapor Pressure</p> <p>N.A.</p> <p>Vapor Density</p> <p>Heavier than air</p> <p>Freezing Point</p> <p>N.A.</p> <p>Melting Point</p> <p>N.A.</p> <p>Low Boiling Point</p> <p>110 °C</p> <p>High Boiling Point</p> <p>N.A.</p> <p>Auto Ignition Temp</p> <p>N.A.</p> <p>Decomposition Pt</p> <p>N.A.</p> <p>Evaporation Rate</p> <p>Slower than ether</p> <p>Coefficient Water/Oil</p> <p>N.A.</p> <p>SECTION 10) STABILITY AND REACTIVITY <br />Stability <br />Material is stable at standard temperature and pressure.</p> <p>Conditions to Avoid <br />Heat, high temperature, open flame, sparks, and moisture. Contact with incompatible materials in a closed system will cause liberation of <br />carbon dioxide and buildup of pressure.</p> <p>Hazardous Reactions/Polymerization <br />Will not occur under normal conditions but under high temperatures in the presence of alkalis,tertiary amines, and metal compounds will <br />accelerate polymerization. Possible evolution of carbon dioxide gas may rupture closed containers.</p> <p>Incompatible Materials <br />This product will react with any material containing active hydrogens, such as water, alcohol, ammonia, amines, alkalis and acids, the <br />reaction with water is slow under 50°C, but is accelerated at higher temperature and in the presence of alkalis, tertiary amines, and metal <br />compounds. Some reactions can be violent. Material can react with strong oxidizing agents.</p> <p>Hazardous Decomposition Products <br />Carbon dioxide, carbon monoxide, nitrogen oxides, trace amounts of hydrogen cyanide and unidentified organic compounds may be <br />formed during combustion.</p> <p>SECTION 11) TOXICOLOGICAL INFORMATION <br />Skin Corrosion/Irritation <br />Isocyanates react with skin protein and moisture and can cause irritation. Prolonged contact can cause reddening, swelling, rash, scaling, <br />blistering, and, in some cases, skin sensitization. Individuals who have developed a skin sensitization can develop these symptoms as a <br />result of contact with very small amounts of liquid material or as a result of exposure to vapor. <br />Causes skin irritation</p> <p>Serious Eye Damage/Irritation</p> <p>SDS RE-ROOF White Urethane Top Coat FR <br />SDS DATE: 22-DEC-27</p> <p>Page 7 of 11</p> <p>Liquid, aerosols or vapors are severely irritating and can cause pain, tearing, reddening and swelling. Prolonged vapor contact may cause <br />conjunctivitis. Any level of contact should not be left untreated. <br />Causes serious eye irritation</p> <p>Respiratory/Skin Sensitization <br />May cause allergy or asthma symptoms or breathing difficulties if inhaled <br />May cause an allergic skin reaction</p> <p>Carcinogenicity <br />May cause cancer.</p> <p>Germ Cell Mutagenicity <br />May cause genetic defects.</p> <p>Reproductive Toxicity <br />Suspected of damaging fertility or the unborn child.</p> <p>Specific Target Organ Toxicity - Single Exposure <br />Causes damage to organs.</p> <p>Specific Target Organ Toxicity - Repeated Exposure <br />May cause damage to organs through prolonged or repeated exposure.</p> <p>Aspiration Hazard <br />No data available</p> <p>Acute Toxicity <br />No data available</p> <p>0004098-71-9</p> <p>ISOPHORONE DIISOCYANATE</p> <p>LC50 (rat): 123-160 mg/m3 (13.6-17.6 ppm) (4-hour exposure) (aerosol) (1,2) <br />LD50 (oral, male rat): greater than 2,500 mg/kg (1) <br />LD50 (oral, male mouse): greater than 2,500 mg/kg (1) <br />LD50 (dermal, male rat): approx. 1,000 mg/kg (4-hour exposure); approx. 500 mg/kg (4-day exposure) (1) <br />0001330-20-7</p> <p>XYLENE</p> <p>LC50 (rat): 6350 ppm (4-hour exposure) (unspecified isomers and ethylbenzene) (1)LC50 (rat): 6700 ppm (4-hour exposure) (65% m-xylene, 7.6% <br />o-xylene, 7.8% p-xylene, 19.3% ethylbenzene) (2) ethylbenzene) (1) <br />LC50 (rat): 6700 ppm (4-hour exposure) (65% m-xylene, 7.6% o-xylene, 7.8% p-xylene, 19.3% ethylbenzene)(2) <br />LD50 (oral, rat): 5400 mg/kg (52% m-, 19% o-, 24% p-) (1)LD50 (oral, female mouse): 5251 mg/kg (60.2% m-, 9.1% o-, 14.6% p-, 17.0% <br />ethylbenzene) (4) <br />LD50 (oral, male mouse): 5627 mg/kg (60.2% m-, 9.1% o-, 14.6% p-, 17.0% ethylbenzene) (4) <br />LD50 (dermal, rabbit): 12180 mg/kg (m-xylene); greater than 1700 mg/kg (mixed xylenes - undefined composition) (3) <br />LD50 (oral, female mouse): 5251 mg/kg (60.2% m-, 9.1% o-, 14.6% p-, 17.0% ethylbenzene) (4) <br />LD50 (oral, male mouse): 5627 mg/kg (60.2% m-, 9.1% o-, 14.6% p-, 17.0% ethylbenzene) (4) <br />LD50 (dermal, rabbit): 12180 mg/kg (m-xylene); greater than 1700 mg/kg (mixed xylenes - undefined composition) (3) <br />0000123-86-4</p> <p>N-BUTYL ACETATE</p> <p>LC50 (rat): 1802 mg/m3; 4-hour exposure (aerosol)(9) Note: A lower LC50 (aerosol) value of 760 mg/m3 (160 ppm); 4-hour exposure has been <br />reported.(11,27) Extensive research has failed to confirm this value. <br />LD50 (oral, rat): 10770 mg/kg (12, unconfirmed) <br />LD50 (oral, mouse): 7100 mg/kg (5) <br />LD50 (oral, rabbit): 7400 mg/kg (cited as 64 millimols/kg) (13) <br />LD50 (dermal, rabbit): Greater than 5000 mg/kg (3, unconfirmed) <br />0000108-88-3</p> <p>TOLUENE</p> <p>LC50 (rat): 8800 ppm (4-hour exposure) (2) <br />LC50 (rat): 6000 ppm (6-hour exposure) (3) <br />LD50 (oral, rat): 2600 to 7500 mg/kg (3,5,11,17) <br />LD50 (oral, neonatal rat): less than 870 mg/kg (3) <br />LD50 (dermal, rabbit): 12,225 mg/kg (reported as 14.1 ml/kg) (1) <br />0000100-41-4</p> <p>ETHYLBENZENE</p> <p>LC50 (inhalation, rat): 4000 ppm; 4-hour exposure (3) <br />LD50 (oral, rat): 3.5 g/kg (1,3,5,10) <br />LD50 (oral, rat): 4.72 g/kg (3,5,7,8) <br />LD50 (dermal, rabbit): 17.8 g/kg (11)</p> <p>SDS RE-ROOF White Urethane Top Coat FR <br />SDS DATE: 22-DEC-27</p> <p>Page 8 of 11</p> <p>0001309-64-4</p> <p>ANTIMONY TRIOXIDE</p> <p>LD50 (oral,rat): 3250 mg/kg <br />0054914-37-3</p> <p>ALDIMINE</p> <p>LD50 (rat,oral): 4150 mg/kg (based on raw material SDS) <br />LD50 (rat,dermal): >5000 mg/kg (based on raw material SDS)</p> <p>SECTION 12) ECOLOGICAL INFORMATION <br />Toxicity <br />No data available. <br />Toxic to aquatic life <br />Toxic to aquatic life with long lasting effects</p> <p>Other Adverse Effects <br />No data available.</p> <p>SECTION 13) DISPOSAL CONSIDERATIONS <br />Waste Disposal <br />Under RCRA, it is the responsibility of the user of the product, to determine a the time of disposal whether the product meets RCRA <br />criteria for hazardous waste. Waste management should be in full compliance with federal, state, and local laws. <br />Empty containers retain product residue which may exhibit hazards of material, therefore do not pressurize, cut, glaze, weld or use for any <br />other purposes. Return drums to reclamation centers for proper cleaning and reuse.</p> <p>SECTION 14) TRANSPORT INFORMATION <br />U.S. DOT Information <br />Not Regulated</p> <p>IMDG Information <br />UN/NA #: 3082 <br />UN Proper Shipping Name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (ALDIMINE) <br />Hazard Class: 9 <br />Packing Group: III <br />Placard: class 9 <br />Marine Pollutant: Yes</p> <p>IATA Information <br />UN/NA #: 3082 <br />UN Proper Shipping Name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (ALDIMINE) <br />Hazard Class: 9 <br />Packing Group: III <br />Placard: class 9</p> <p>SDS RE-ROOF White Urethane Top Coat FR <br />SDS DATE: 22-DEC-27</p> <p>Page 9 of 11</p> <p>SECTION 15) REGULATORY INFORMATION</p> <p>CAS</p> <p>Chemical Name</p> <p>% By Weight</p> <p>Regulation List</p> <p>0053880-05-0</p> <p>POLYURETHANE <br />PREPOLYMER</p> <p>27% - 50%</p> <p>DSL,SARA312,TSCA</p> <p>0000098-56-6</p> <p>BENZENE-1CHLORO-4 <br />(TRIFLUOROMETHYL <br />)-</p> <p>13% - 24%</p> <p>DSL,SARA312,TSCA</p> <p>0013463-67-7</p> <p>TITANIUM DIOXIDE</p> <p>13% - 25%</p> <p>DSL,SARA312,TSCA,CA_Prop65 - California Proposition 65</p> <p>0014808-60-7</p> <p>SILICA, <br />CRYSTALLINE</p> <p>8% - 15%</p> <p>DSL,SARA312,TSCA,CA_Prop65 - California Proposition 65</p> <p>0001330-20-7</p> <p>XYLENE</p> <p>2% - 5%</p> <p>SARA313, DSL,CERCLA,HAPS,SARA312,VHAPS,VOC,TSCA,RCRA</p> <p>0064742-95-6</p> <p>AROMATIC <br />HYDROCARBON <br />MIXTURE >C9</p> <p>1.6% - 3%</p> <p>DSL,SARA312,VOC,TSCA</p> <p>0000123-86-4</p> <p>N-BUTYL ACETATE</p> <p>1.3% - 2%</p> <p>DSL,CERCLA,SARA312,VOC,TSCA</p> <p>0001309-64-4</p> <p>ANTIMONY TRIOXIDE</p> <p>0.9% - 1.6%</p> <p>SARA313, DSL,CERCLA,HAPS,SARA312,TSCA,CA_Prop65 - California Proposition 65</p> <p>0054914-37-3</p> <p>ALDIMINE</p> <p>0.8% - 1.4%</p> <p>DSL,SARA312,TSCA</p> <p>0000100-41-4</p> <p>ETHYLBENZENE</p> <p>0.7% - 1.2%</p> <p>SARA313, DSL,CERCLA,HAPS,SARA312,VHAPS,VOC,TSCA,CA_Prop65 - California <br />Proposition 65</p> <p>0004098-71-9</p> <p>ISOPHORONE <br />DIISOCYANATE</p> <p>0.2% - 0.3%</p> <p>SARA313, DSL,SARA312,VOC,TSCA</p> <p>0000108-88-3</p> <p>TOLUENE</p> <p>Trace</p> <p>SARA313, DSL,CERCLA,HAPS,SARA312,VHAPS,VOC,TSCA,RCRA,CA_Prop65 California Proposition 65</p> <p>SECTION 16) OTHER INFORMATION <br />OTHER INFORMATION <br />* There are points of differences between OSHA GHS and UN GHS. In 90% of the categories, they can be used interchangeably, but for the <br />Skin Corrosion/Irritant Category and the Specific Target Organ Toxicity (Single and Repeated Exposure) Categories. In these cases, our <br />system will say UN GHS.</p> <p>GLOSSARY <br />ACGIH- American Conference of Governmental Industrial Hygienists; ANSI- American National Standards Institute; CA Prop65- California <br />Proposition 65; Canadian TDG- Canadian Transportation of Dangerous Goods; CAS- Chemical Abstract Service; Chemtrec- Chemical <br />Transportation Emergency Center (US); CHIP- Chemical Hazard Information and Packaging; DSL- Domestic Substances List; ECEquivalent Concentration; EH40 (UK)- HSE Guidance Note EH40 Occupational Exposure Limits; EPCRA- Emergency Planning and <br />Community Right-To-Know Act; ESL- Effects screening levels; HMIS- Hazardous Material Information Service; LC- Lethal Concentration; <br />LD- Lethal Dose; NFPA- National Fire Protection Association; OEL- Occupational Exposure Limits; OSHA- Occupational Safety and Health <br />Administration, US Department of Labor; PEL- Permissible Exposure Limit; SARA (Title III)- Superfund Amendments and Reauthorization <br />Act; SARA 313- Superfund Amendments and Reauthorization Act, Section 313; SCBA- Self-Contained Breathing Apparatus; STEL- Short <br />Term Exposure Limit; TCEQ- Texas Commission on Environmental Quality; TLV- Threshold Limit Value; TSCA- Toxic Substances Control <br />Act Public Law 94-469; TWA- Time Weighted Value; US DOT- US Department of Transportation; WHMIS- Workplace Hazardous Materials <br />Information System.</p> <p>SDS RE-ROOF White Urethane Top Coat FR <br />SDS DATE: 22-DEC-27</p> <p>Page 10 of 11</p> <p>DISCLAIMER <br />To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its subsidiaries assumes <br />any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole <br />responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we <br />cannot guarantee that these are the only hazards that exist. The above information pertains to this product as currently formulated, and is based on the <br />information available at this time. Addition of reducers or other additives to this product may substantially alter the composition and hazards of the product. <br />Since conditions of use are outside our control, we make no warranties, express or implied, and assume no liability in connection with any use of this <br />information.</p> <p>SDS RE-ROOF White Urethane Top Coat FR <br />SDS DATE: 22-DEC-27</p> <p>Page 11 of 11</p>
