IDENTITY: VAPORTIGHT
SAFETY DATA SHEET
®
COAT -SG4 “COMPONENT-A”
SDS No. 5.4.1.A1
Date prepared: JANUARY 2016 Date revised: FEBRUARY 2019
SDS No 5.4.1.A1
Section 1 – Identification IDENTITY:
VAPORTIGHT COAT®-SG4
Product Name: Chemical Characterization:
EPOXY RESIN (IRRITANT)
AQUAFIN, INC. 505 BLUE BALL RD., NO. 160 ELKTON, MD 21921
(SDS 1 of 2)
“COMPONENT-A”
24 hr Emergency Phone: Chem-Tel Information Phone No:
info@aquafin.net
Recommended use of the chemical and restriction on use:
www.aquafin.net
(800) 255-3924 (410) 392-2300
Refer to the product technical data sheet. For industrial and professional users.
Section 2 – Hazards Identification GHS Classification: Skin irritation, Category 2 Sensitization, Skin, Category 1 Eye irritation, Category 2A
H315: Causes skin irritation. H317: May cause an allergic skin reaction. H319: Causes serious eye irritation.
Hazard-determining components of labelling: Reaction product: bisphenol-A-(epichlorhydrin) epoxy resin (number average molecular weight ≤ 700) 1,6-bis(2,3-ethoxypropoxy)hexane 1,3-propanediol, 2-ethyl-2-(hydroxymethyl)-, polymer with 2-(chloromethyl)oxirane bisphenol-F-epoxy resin
GHS Label element: Hazard Pictograms GHS07 Signal Word:
Warning
Hazard Statements: H315: H317: H319:
Causes skin irritation. May cause an allergic skin reaction. Causes serious eye irritation.
Precautionary Statements: Prevention: P102: Keep out of reach of children. P264: Wash skin thoroughly after handling. P270: Do not eat, drink or smoke when using this product. P280: Wear eye protection/face protection. P280: Wear protective gloves. P281: Use protective equipment as required. Response: P301 + P315: P302 + P352: P304 + P340:
IF SWALLOWED: Get immediate medical advice/attention. IF ON SKIN: Wash with plenty of water. IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Page 1 of 6
P305 + P351 + P338:
P308 + P313 P332 + P313: P362:
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF exposed or concerned, get medical advice/attention. IF skin irritation occurs, get medical advice/attention. Take off contaminated clothing and wash before reuse.
Storage: P403 + P232:
Store in a well-ventilated place. Protect from moisture.
Disposal: P501:
Dispose of contents/container to an approved waste disposal site.
Section 3 – Composition / Information on Ingredients Description:
Solvent-free preparation based on Bisphenol-A-Epichlorhydrin resin molecular weight ≤700.
COMPONENTS bisphenol-A-(epichlorhydrin) epoxy resin (number average molecular weight ≤700) Skin Irrit. 2, H315; Eye Irrit. 2A, H319; Skin Sens. 1, H317 1,6-bis(2,3-ethoxypropoxy)hexane Skin Irrit. 2, H315; Eye Irrit. 2A, H319; Skin Sens. 1, H317 1,3-propanediol, 2-ethyl-2-(hydroxymethyl)-, polymer with 2-(chloromethyl) oxirane Skin Irrit. 2, H315; Eye Irrit. 2A, H319; Skin Sens. 1, H317 bisphenol-F-epoxy resin Skin Irrit. 2, H315; Eye Irrit. 2A, H319; Skin Sens. 1, H317
CAS NUMBER
OSHA PEL
ACGIH TLV WEIGHT %
25068-38-6
Not Estab.
50-100%
16096-31-4
10-25%
30499-70-8
9003-36-5
2.5-10%
Section 4 – First Aid Measures General:
Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours after the incident. Personal protection for the First Aider.
After Inhalation:
Remove subject to fresh air. Administer oxygen if difficulty with breathing. Consult a physician for safety reasons.
After Ingestion:
Immediately seek medical attention. Do not induce vomiting. Drink plenty of water to dilute stomach contents. Do not give household remedy’s (i.e. milk, alcohol, etc.).
After Skin Contact:
Instantly wash skin with plenty of soap and water for at least 15 minutes. Wash clothing before reuse. Do not use solvents to clean the skin.
After Eye Contact:
Rinse opened eye with plenty of running water for at least 15 minutes, lifting upper and lower eyelids occasionally. Remove contact lenses. Consult physician if symptoms persist.
Section 5 – Fire Fighting Measures Extinguishing Media:
Carbon dioxide (CO2), extinguishing powder, water spray. Fight larger fires with water spray.
Special Fire Fighting Procedures:
As in any fire, wear full protective gear and NIOSH-approved selfPage 2 of 6
SAFETY DATA SHEET SDS No. 5.4.1.A1
contained breathing apparatus with full face-piece operated in the pressure demand or other positive pressure mode. Unusual Fire and Explosion Hazards: Bursting and explosion of container possible due to increase of pressure when exposed to increasing heat. In case of fire, cool nearby containers with water spray. Formation of poisonous gases during heating or in fires.
Section 6 – Accidental Release Measures Person-related Safety Precautions:
Provide plenty of fresh air. Avoid eye and skin contact. Avoid inhalation of vapors. Wear personal protective equipment. Remove or eliminate all ignition sources.
Methods for Cleaning up:
Contain and collect spillage with non-combustible, absorbent materials. I.e. sand, earth, vermiculate, diatomaceous earth, universal binders, sawdust and place in container for disposal.
Waste Disposal Method:
Dispose in accordance with local, state and federal regulations.
Ecological Information:
Do not allow product to reach ground water, bodies of water, storm water or sewage systems.
Section 7 – Handling and Storage Handling:
Avoid eye and skin contact. Keep out of reach of children.
Storage:
Keep away from heat and direct sunlight. Store in a cool, dry enclosed area off the ground in tightly closed/sealed containers. No special measures required against explosion and fires. Store away from foodstuffs. Provide fresh air when handling in closed rooms (open windows and doors). Protect from frost.
Section 8 – Exposure Controls / Personal Protection Engineering Controls:
Use with adequate general and local exhaust ventilation. Washing of the skin in the working area must be possible. Eye-wash station or bottle must be available.
Respiratory Protection:
Respirator in well ventilated areas not necessary. Wear a properly fitted NIOSH approved respirator in poorly ventilated areas or spillage.
Skin Protection:
When installing, wear appropriate protective rubber or plastic gloves to prevent hand-skin exposure. Wear appropriate impervious clothing to prevent skin exposure (long sleeve shirt and long pants).
Eye Protection:
Wear tightly sealed safety glasses with side shields or goggles. Face shield as necessary.
Work/Hygienic Practices:
Wash hands before breaks and after work, and before eating, drinking or smoking.
Section 9 – Physical and Chemical Properties Physical State: Appearance/Color: Odor: Solubility in water:
Liquid Clear Weak, characteristic Not miscible or difficult to mix Page 3 of 6
Boiling Point: Melting Point: Flash Point: Flammability: Explosion: Bulk Density: Viscosity: (dynamic) VOC Concentration:
Not determined Not determined Not applicable Does not self-ignite Does not explode 3 o o 1.14 kg/dm (9.5 lbs/gal) at 20 C (68 F) o o 730 cps (mPas) at 20 C (68 F) 0 g/l
Section 10 – Stability and Reactivity Chemical Stability:
Stable under normal conditions.
Conditions to Avoid:
Keep away from heat, ignition sources and incompatible materials.
Hazardous Decomposition:
Dangerous emissions of various decomposition products can be formed when exposed to heat.
Incompatibilities:
Avoid contact with acids and oxidizers. Violent reactions can occur.
Section 11 – Toxicological Information Acute Toxicity: 25068-38-6 bisphenol-A-(epichlorhydrin) epoxy resin (number average molecular weight = 700) Oral LD50 >5000 mg/kg (rat) Dermal LD50 >2000 mg/kg (rat) 16096-31-4 Oral Inhalative
1,6-bis(2,3-ethoxypropoxy)hexane LD50 1400 mg/kg (rabbit) LD50 2900 mg/kg (rat) LC50/4 h >100 mg/l (mouse)
9003-36-5 Oral Dermal
bisphenol F-epoxy resin LD50 >10000 mg/kg (rat) LD50 >2000 mg/kg (rat)
Primary Irritation: - Skin: - Eyes: - Sensibility:
irritant to skin and mucous membranes. irritating effect. may cause an allergic skin reaction.
Section 12 – Ecological Information Aquatic toxicity: 25068-38-6 bisphenol-A-(epichlorhydrin) epoxy resin (number average molecular weight = 700) EC50 (48 h) 1.7 mg/l (Daphnia magna) LC50 (96 h) 2.0 mg/l (Rainbow trout) 9003-36-5 EC50 LC50 ERC50
bisphenol F-epoxy resin 2.55 mg/l (Daphnia magna) (96 h) 2.54 mg/l (Leuciscus idus) 1.8 mg/l (Algae toxicity)
Bioaccumulative potential:
No further relevant information available.
Mobility in soil:
Remark:
Toxic for fish. Do not allow product or large quantities to reach into waterways or drains. Page 4 of 6
General notes:
Water hazard class 2 (Self-assessment): hazardous for water. Do not allow product to reach ground water, bodies of water, or storm water or sewage systems.
Section 13 – Disposal Considerations Waste Disposal Method:
Dispose of in a manner consistent with federal, state and local regulations. This includes pails containing uncured material. Pails with cured/hardened remains of product can be sent for recycling.
Recommendation:
Product mixed with hardener and fully cured is ecologically save and can be disposed to local refuse deposit or recycling facility. Empty containers with solid product rests can be sent for recycling. Empty containers containing liquid product rests are hazardous waste.
Section 14 – Transport Information USDOT (Domestic Surface):
UN 3082 Not regulated.
IATA/ICAO (Air):
UN 3082 Environmentally hazardous substance, liquid, NOS (bisphenol A-(epichlorhydrin), epoxy resin (number average molecular weight<700), 1,6Hexandioldiglycidylether. 9, PG III.
IMDG (Ocean):
UN 3082 Environmentally hazardous substance, liquid, NOS (bisphenol A-(epichlorhydrin), epoxy resin (number average molecular weight<700), 1,6Hexandioldiglycidylether. Marine pollutant. 9, PG III.
Section 15 – Regulatory Information
. All raw materials are on the U.S., EPA, TSCA Inventory. SARA Notification:
Nothing in this product is subject to regulation under SARA 302, 313. It may be subject to SARA 312 reporting, depending upon the purchaser’s storage circumstances.
CERCLA:
No CERCLA chemicals exist in this product above reportable concentrations.
Clean Air Act: Ozone-Depletion Potential:
This product does not contain any hazardous air pollutants (HAP), as defined by the U.S. Clean Air Act Section (40 CFR 61).
Section 16 – Other Information (Hazard Rating: 0 = Minimal;
HMIS III rating: Health: 2* Flammability: 1
1 = Slight;
2 = Moderate;
Physical hazard: 1
3 = Serious;
Personal Protection: B
Abbreviations and acronyms: USDOT: IMDG: IATA: CAS:
United States Department of Transportation. International Maritime Code for Dangerous Goods. International Air Transport Association. Chemical Abstracts Service (Division of the American Chemical Society). Page 5 of 6
4 = Severe; * = Chronic)
LC50: LD50: EC50: RQ:
Lethal concentration, 50 percent. Lethal dose, 50 percent. Median effective concentration. Reportable quantity.
SDS prepared by:
Aquafin product safety department.
DISCLAIMER:
We believe the statements, technical information and recommendations contained herein are reliable, but they are given without warranty or guarantee of any kind, expressed or implied, and we assume no responsibility for any loss, damage, or expense, direct or consequential, arising out of their use. Aquafin shall not be responsible for the use of this product in a manner to infringe on any patent or any other intellectual property rights held by others. User is responsible for determining appropriate safety measures and for applying the legislation covering his own activities. We recommend that user makes tests to determine the suitability of a product for its particular purpose prior to use.
END OF SDS
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(February 28, 2019)