SDS_EPOXY Gel_Component B_081822.pdf
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<h1>SDS_EPOXY Gel_Component B_081822.pdf</h1> <p>Safety Data Sheet (SDS)</p> <p>Page 1/6</p> <p>OSHA HazCom Standard 29 CFR 1910.1200(g) and GHS Rev 03.</p> <p>Printing date 08/18/2022</p> <p>Reviewed on 08/18/2022</p> <p>SECTION 1: PRODUCT AND COMPANY IDENTIFICATION</p> <p>IDENTITY:</p> <p>Product Name: EPOXY-Gel COMPONENT B <br />Product Use Description: Epoxy Resin Adhesive, For Further Information, Refer to the Product Technical</p> <p>Data Sheet</p> <p>AQUAFIN, INC. <br />505 BLUE BALL RD. #160 <br />ELKTON, MD 21921</p> <p>24 hr Emergency Phone: Chem-Tel (800) 255-3924 <br />Information Phone No: (410) 392-2300</p> <p>info@aquafin.net</p> <p>www.aquafin.net</p> <p>SECTION 2: HAZARDS IDENTIFICATION <br />GHS Hazard:</p> <p>ROUTES OF ENTRY: <br />SIGNAL WORD:</p> <p>EYE:</p> <p>YES</p> <p>SKIN:</p> <p>YES</p> <p>INGESTION:</p> <p>YES</p> <p>INHALATION:</p> <p>YES</p> <p>DANGER!</p> <p>PHYSICAL HAZARDS: Not Classified <br />HEALTH HAZARDS: (ACUTE AND CHRONIC) <br />Serious eye damage Cat. 1 <br />EYES: <br />Skin Corrosion Cat. 1B <br />SKIN: <br />Skin Irritation Cat. 2 <br />Skin Sensitization Cat.1 <br />Reproductive Toxicity Cat.1B <br />Specific target organ toxicity- single exposure Cat.3 <br />Acute Inhalation Toxicity Cat. 4 <br />INHALATION: <br />Specific target organ toxicity- single exposure Cat.3 <br />CARCINOGEN: Carbon Black IARC 2B <br />ENVIRONMENTAL HAZARDS: <br />Acute aquatic toxicity Cat.2 <br />Chronic aquatic toxicity Cat.2 <br />INGESTION:</p> <p>HAZARD STATEMENTS:</p> <p>H302+H312+H332 – Harmful if swallowed, inhaled or in contact with skin. <br />H314 - Causes severe skin burns and eye damage. <br />H315 – Causes serious eye damage. <br />H317 - May cause an allergic skin reaction <br />H318 - Causes serious eye damage. <br />H330 – Fatal if inhaled. <br />H335 – May cause respiratory irritation. <br />H361 – Suspected of damaging fertility or the unborn child. <br />H412 – Harmful to aquatic life with long lasting effects.</p> <p>PRECAUTIONARY STATEMENTS: <br />P261 – Avoid breathing dust/fume/gas/mist/vapors/spray. <br />P262 - Do not get in eyes, on skin, or on clothing <br />P264 - Wash…thoroughly after handling with soap and water. <br />P270 – Use outdoors or in a well-ventilated area. <br />P272 – Contaminated work clothing should not be allowed out of the workplace. <br />P273 – Avoid release to the environment. <br />P280 - Wear Protective gloves/protective clothing/eye protection/face protection. <br />P301+P330+P331 – IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. <br />P302+P352 – IF ON SKIN: Wash with plenty of soap and water. <br />P303+P361+P353 – IF ON SKIN (or hair): Remove/take off immediately all contaminated clothing. <br />Rinse skin with water/shower. <br />P304+P340+P310 – IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable <br />For breathing. Immediately call a POISON CENTER or doctor/physician. <br />P305+P351+P338 - IF IN EYES Rinse cautiously with water for several minutes. Remove contact lenses, <br />If present and easy to do. Continue rinsing. <br />P310 – Immediately call a POISON CENTER or doctor/physician. <br />P333+P313 – If skin irritation or rash occurs: Get medical advice/attention.</p> <p>SDS EPOXY-Gel Comp B <br />SDS DATE: 22-AUG-18</p> <p>www.aquafin.net</p> <p>Page 1 of 6</p> <p>EPOXY-Gel, Component B</p> <p>Safety Data Sheet</p> <p>P362 – Tale off contaminated clothing and wash before reuse. <br />P403+P233 – Store in a well-ventilated place. Keep container tightly closed. <br />P405 - Store locked up. <br />P501 -Dispose of contents/container to an approved waste disposal plant.</p> <p>MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE: <br />Persons with preexisting skin or respiratory disorders may have their conditions aggravated by over exposure to this <br />material. <br />This product is not for use in an aerosol or spray.This product contains a component that is toxic by inhalation when aerosolized or sprayed. <br />Refer to Section 11 of the SDS for toxicity information. Review the toxicity information against your intended use. If product is not being <br />aerosolized or sprayed, inhalation toxicity is not applicable. <br />SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS</p> <p>CAS #:</p> <p>CAL-OSHA <br />PEL TWA <br />(8hours)</p> <p>ACGIH <br />TLV TWA <br />(8 hours)</p> <p>Other Limits <br />RECOMMENDED</p> <p>% BY <br />WEIGHT</p> <p>HAZARDOUS COMPONENTS <br />Poly[oxy(methyl-1,2ethanediyl)],.alpha.’,.alpha.”-1,2,3propanetriyltris[.omega.-(2aminomethylethoxy)-</p> <p>64852-22-8</p> <p>No Data</p> <p>No Data</p> <p>4</p> <p>Tofa, reaction products with TEPA</p> <p>68953-36-6</p> <p>No Data</p> <p>No Data</p> <p>>17</p> <p>Tetraethylenepentamine</p> <p>112-57-2</p> <p>No Data</p> <p>No Data</p> <p>4-tert-Butylphenol</p> <p>98-54-4</p> <p>No Data</p> <p>No Data</p> <p><6</p> <p>Diethylenetriamine</p> <p>111-40-0</p> <p>No Data</p> <p>No Data</p> <p><2</p> <p>Benzyl Alcohol</p> <p>100-51-6</p> <p>No Data</p> <p>No Data</p> <p>Tris-2,4,6-(dimethylaminomethyl)phenol</p> <p>90-72-2</p> <p>No Data</p> <p>No Data</p> <p><3</p> <p>Bis(dimethylaminomethyl)phenol</p> <p>71074-89-0</p> <p>No Data</p> <p>No Data</p> <p><0.5</p> <p>Treated fumed silica</p> <p>67762-90-7</p> <p>No Data</p> <p>No Data</p> <p><4</p> <p>Carbon Black</p> <p>1333-86-4</p> <p>No Data</p> <p>No Data</p> <p><0.5</p> <p>TWA WEEL 1ppm(5mg/m3)</p> <p>TWA WEEL 10ppm(44mg/m3)</p> <p><3</p> <p>1.3</p> <p>SECTION 4: FIRST AID MEASURES <br />EYES: <br />SKIN: <br />INGESTION: <br />INHALATION:</p> <p>Immediately flush eyes with water for a minimum of 15 minutes while holding eyes open. Remove contact lenses if <br />present and easy to do. If redness, burning, blurred vision, or swelling persists, consult a physician. <br />Remove contaminated clothing and product. Immediately wash affected area with soap and water. Do not apply <br />greases or ointments. If skin irritation persists, consult a physician. <br />Rinse mouth immediately. Give small amounts of water, only if person is conscious. Only induce vomiting at the <br />instruction of medical personnel. consult a physician <br />Remove patient to fresh air. Give oxygen or artificial respiration if needed. If patient continues to experience <br />difficulty breathing, consult a physician.</p> <p>SECTION 5: FIRE-FIGHTING MEASURES <br />SUITABLE EXTINGUISHING MEDIA: <br />SPECIAL FIRE FIGHTING PROCEDURES:</p> <p>HAZARDOUS DECOMPOSITION PRODUCTS:</p> <p>FLASH POINT: <br />METHOD USED:</p> <p>Extinguish with foam, carbon dioxide, dry powder, or water fog. <br />Use standard fire-fighting procedures and consider the hazards of other involved <br />materials. In case of a fire and / or explosion do not breathe fumes. Self-contained <br />breathing apparatus and full protective clothing must be worn. Move containers <br />from fire area if you can do so without risk. Cool containers with flooding quantities <br />of water until well after fire is out. Prevent runoff from fire control or dilution from <br />entering streams, sewers, or drinking water supply. <br />Hazardous decomposition products may occur when material polymerizes at <br />temperatures above 500 oF (260 oC). Irritating and toxic gases/fumes may be <br />released during a fire. Do not allow run-off from fire-fighting to enter drains or water <br />courses.</p> <p>210 oF / 99 oC <br />PMCC</p> <p>SECTION 6: ACCIDENTAL RELEASE MEASURES <br />PERSONAL PROTECTION:</p> <p>SDS EPOXY-Gel Comp B <br />SDS DATE: 22-AUG-18</p> <p>Keep unnecessary personnel away. Eliminate all ignition sources (no smoking, flares, <br />sparks, or flames in immediate area). Wear appropriate personal protective equipment. Do <br />not touch containers or spilled material unless wearing appropriate protective clothing. Avoid <br />inhalation of vapors or mists. Ensure adequate ventilation. Local authorities should be</p> <p>www.aquafin.net</p> <p>Page 2 of 6</p> <p>EPOXY-Gel, Component B</p> <p>Safety Data Sheet</p> <p>ACCIDENTAL RELEASE MEASURES: <br />WASTE DISPOSAL:</p> <p>advised if significant spillage cannot be contained. <br />In case of spill, clean up using absorbent material such as earth or sand. Small quantities <br />can be wiped up with cloth, place cloth in leak proof container and dispose of properly. <br />Observe Federal, State and local regulations covering chemical waste spills.</p> <p>SECTION 7: HANDLING AND STORAGE <br />Use personal protective equipment to ensure product does not contact eyes or skin when handling <br />materials. <br />Store in cool dry place out of direct sun rays. Keep from freezing. Recommend storage temperatures <br />range: between 40o and 95 oF (4o - 35 oC)</p> <p>PERSONAL PROTECTION: <br />HANDLING AND STORAGE:</p> <p>SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION <br />PROTECTIVE MEASURE: <br />EYE PROTECTION: <br />HAND PROTECTION: <br />SKIN AND BODY PROTECTION: <br />RESPIRATORY PROTECTION: <br />WORK HYGIENIC PRACTICES: <br />ENGINEERING CONTROLS:</p> <p>Wear appropriate personal protective equipment. <br />Wear appropriate safety glasses with side shields, goggles or full face shield. When working on an <br />overhead application a full face shield is recommended. <br />Wear chemical-resistant gloves such as: Nitrile, neoprene, butyl. <br />Wear long sleeve shirts/long pants and other clothing as required to minimize contact. <br />Do not breathe gas/fumes/vapor/ or spray. The use of a respirator is not required during general <br />use of this product provided adequate ventilation. If grinding or cutting cured product the use of an <br />approved respirator is recommended. <br />Always observe good personal hygiene measures, such as washing after handling the material and <br />before eating, drinking and/or smoking. Routinely wash work clothing and protective equipment to <br />remove contaminants. <br />When using indoors, good ventilation (typically 10 air changes per hour) should be used. <br />Ventilation rates should be matched to conditions. Ready access to running water is required. <br />Provide eyewash station.</p> <p>EXPOSURE LIMITS <br />Component <br />Poly[oxy(methyl-1,2-ethanediyl)],.alpha.’,.alpha.”1,2,3-propanetriyltris[.omega.-(2aminomethylethoxy)64852-22-8 <br />Tofa, reaction products with TEPA 68953-36-6</p> <p>OSHA (PEL)</p> <p>ACGIH (TLV)</p> <p>NIOSH (Pocket Guide)</p> <p>No Data</p> <p>No Data</p> <p>No Data</p> <p>No Data</p> <p>No Data</p> <p>No Data</p> <p>No Data</p> <p>No Data</p> <p>No Data</p> <p>4-tert-Butylphenol 98-54-4</p> <p>No Data</p> <p>No Data</p> <p>No Data</p> <p>Diethylenetriamine 111-40-0</p> <p>1 ppm(4mg/m3)</p> <p>1 ppm(4mg/m3)</p> <p>1 ppm (4mg/m3) skin</p> <p>Benzyl Alcohol 100-51-6</p> <p>No Data</p> <p>No Data</p> <p>No Data</p> <p>Tris-2,4,6-(dimethylaminomethyl)phenol 90-72-2 <br />Bis(dimethylaminomethyl)phenol <br />71074-89-0</p> <p>No Data</p> <p>No Data</p> <p>No Data</p> <p>No Data</p> <p>No Data</p> <p>No Data</p> <p>No Data</p> <p>No Data</p> <p>No Data</p> <p>3.5 mg/m3</p> <p>TWA 3 mg/m3</p> <p>TWA 3.5 mg/m3</p> <p>Tetraethylenepentamine</p> <p>Treated fumed silica</p> <p>112-57-2</p> <p>67762-90-7</p> <p>Carbon Black 1333-86-4 <br />SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES <br />APPEARANCE: <br />ODOR: <br />PHYSICAL STATE: <br />pH AS SUPPLIED: <br />BOILING POINT: <br />MELTING POINT: <br />FREEZING POINT: <br />VAPOR PRESSURE: <br />VAPOR DENSITY (AIR = 1): <br />SPECIFIC GRAVITY (H2O = 1): <br />EVAPORATION RATE: <br />SOLUBILITY IN WATER: <br />PERCENT SOLIDS BY WEIGHT: <br />PERCENT VOLATILE: <br />VOLATILE ORGANIC COMPOUNDS (VOC): <br />MOLECULAR WEIGHT:</p> <p>SDS EPOXY-Gel Comp B <br />SDS DATE: 22-AUG-18</p> <p>Black <br />Ammonia <br />Paste <br />basic <br />N/D <br />N/D <br />N/D <br /><1mm @ 20C <br />Heavier than air <br />0.95 <br />N/D <br />Slight <br />N/D <br />N/D <br />ND <br />ND</p> <p>www.aquafin.net</p> <p>Page 3 of 6</p> <p>EPOXY-Gel, Component B <br />Safety Data Sheet</p> <p>6400 p.</p> <p>VISCOSITY: <br />SECTION 10: STABILITY AND REACTIVITY <br />STABILITY: <br />CONDITIONS TO AVOID (STABILITY): <br />INCOMPATIBILITY (MATERIAL TO AVOID): <br />HAZARDOUS DECOMPOSITION OR BYPRODUCTS: <br />HAZARDOUS POLYMERIZATION:</p> <p>Stable <br />Exposure to excessive heat and open flame <br />Strong acids, peroxides and other oxidizing agents. <br />Normal combustion forms carbon dioxide, carbon monoxide, oxides o carbon and other <br />organic compounds, <br />Will not occur</p> <p>SECTION 11: TOXICOLOGICAL INFORMATION <br />Toxicity <br />Acute Oral Toxicity: <br />Oral-Components <br />Carbon Black <br />Poly[oxy(methyl-1,2ethanediyl)],.alpha.’,.alpha.”-1,2,3propanetriyltris[.omega.-(2aminomethylethoxy)-</p> <p>CAS#</p> <p>1333-86-4 <br />64852-22-8</p> <p>LD50 15,400 mg/kg Species: Rat <br />Acute toxicity estimate: 2,690 mg/kg</p> <p>Tris-2,4,6-(dimethylaminomethyl)phenol <br />Acute Dermal Toxicity: <br />Dermal-Components <br />Poly[oxy(methyl-1,2ethanediyl)],.alpha.’,.alpha.”-1,2,3propanetriyltris[.omega.-(2aminomethylethoxy)Acute Inhalation Toxicity <br />Inhalation-Components <br />Diethylenetriamine <br />Benzyl Alcohol <br />Skin Corrosion/ Irritation: <br />Corrosion/Irritation Components <br />Poly[oxy(methyl-1,2ethanediyl)],.alpha.’,.alpha.”-1,2,3propanetriyltris[.omega.-(2aminomethylethoxy)-</p> <p>90-72-2</p> <p>LD50 2,169 mg/kg Species: Rat M/F</p> <p>No data available on the product itself</p> <p>No data available on the product itself <br />64852-22-8</p> <p>LD50 12,500 mg/kg Species: Rabbit</p> <p>No data available on the product itself <br />111-40-0 <br />100-51-6</p> <p>LC50(4hr): >0.07-<0.3 Species: Rat <br />LC50(4hr): >4.178 mg/l Species: Rat <br />Skin corrosion</p> <p>64852-22-8</p> <p>Extremely corrosive and destructive to tissue.</p> <p>Tris-2,4,6-(dimethylaminomethyl)phenol <br />Eye Damage/Irritation: <br />Damage/Irritation Components <br />Poly[oxy(methyl-1,2ethanediyl)],.alpha.’,.alpha.”-1,2,3propanetriyltris[.omega.-(2aminomethylethoxy)-</p> <p>90-72-2</p> <p>Corrosive (4hr) Species: Rabbit.</p> <p>64852-22-8</p> <p>May cause irreversible eye damage.</p> <p>Tris-2,4,6-(dimethylaminomethyl)phenol <br />Respiratory Damage/Irritation: <br />Damage/irritation Components <br />Sensitization:</p> <p>90-72-2</p> <p>Corrosive Species: Rabbit.</p> <p>Tris-2,4,6-(dimethylaminomethyl)phenol <br />Germ Cell Mutagenicity</p> <p>90-72-2</p> <p>Severe eye damage</p> <p>No data available on the product itself</p> <p>The product or a component may be mutagenic, the data is <br />inconclusive. <br />No data available on the product itself</p> <p>Maternal Toxicity: <br />Carcinogenicity: <br />Classification <br />ACGIH: <br />IARC: <br />NTP <br />OSHA</p> <p>May cause sensitization by inhalation or skin contact <br />Skin sensitizer , sub. cat. 1B</p> <p>Not Classified <br />Carbon Black IARC Carcinogen 2B <br />Not Listed <br />Not Classified</p> <p>SECTION 12: ECOLOGICAL INFORMATION</p> <p>SDS EPOXY-Gel Comp B <br />SDS DATE: 22-AUG-18</p> <p>www.aquafin.net</p> <p>Page 4 of 6</p> <p>EPOXY-Gel, Component B</p> <p>Safety Data Sheet</p> <p>ECOTOXICITY: <br />Aquatic toxicity: <br />Toxicity to Fish-Components <br />Benzyl Alcohol <br />Poly[oxy(methyl-1,2ethanediyl)],.alpha.’,.alpha.”-1,2,3propanetriyltris[.omega.-(2aminomethylethoxy)-</p> <p>CAS#</p> <p>100-51-6 <br />64852-22-8</p> <p>LC50(96hr) 460 mg/l Species: Fathead minnow <br />LC50(96hr) 68 mg/l</p> <p>Tris-2,4,6-(dimethylaminomethyl)phenol <br />Toxicity to algae-Components <br />Benzyl Alcohol</p> <p>90-72-2</p> <p>LC50(96hr) 175 mg/l Species: Cyprinus carpio</p> <p>100-51-6 <br />90-72-2</p> <p>IC50(72hr): 700 mg/l Species: Algae <br />EC50(72hr): 84 mg/l Species: Desmodesmus subspicatus.</p> <p>1333-86-4</p> <p>EC50(48hr): 37.5 mg/l Species: Water flea</p> <p>No data available on the product itself</p> <p>Tris-2,4,6-(dimethylaminomethyl)phenol <br />Toxicity-AquaticInvertabrates <br />Carbon Black <br />Toxicity to other organisms: <br />PERSISTENCE & DEGRADABILITY: <br />BIODEGRADABILITY: <br />Biodegradability-Components <br />Poly[oxy(methyl-1,2ethanediyl)],.alpha.’,.alpha.”-1,2,3propanetriyltris[.omega.-(2aminomethylethoxy)Tris-2,4,6-(dimethylaminomethyl)phenol <br />BIOACCUMULATIVE POTENTIAL: <br />BioAccumulaive-Components: <br />MOBILITY IN SOIL: <br />OTHER ADVERSE EFFECTS: <br />AQUATIC RELEASE:</p> <p>No data available on product itself <br />64852-22-8</p> <p>Not readily biodegradable <5% 28d</p> <p>90-72-2</p> <p>Not readily biodegradable 4% 28d <br />No data available on product itself <br />NDA <br />NDA <br />Advise authorities if product has entered or may enter watercourses <br />or sewer drains.</p> <p>SECTION 13: DISPOSAL CONSIDERATIONS <br />WASTE DISPOSAL METHOD:</p> <p>Do not allow this material to drain into sewers / waterways, ditches, containment pools or water <br />supplies. Dispose of contents / containers in accordance with local/regional/international <br />regulations.</p> <p>SECTION 14: TRANSPORT INFORMATION <br />U.S. DEPARTMENT OF TRANSPORTATION <br />Amines, liquid, corrosive, n.o.s. (Polyamidoamine, Tetraethylenepentamine) <br />PROPER SHIPPING NAME: <br />8 <br />HAZARD CLASS: <br />UN2735 <br />ID NUMBER: <br />III <br />PACKING GROUP: <br />WATER TRANSPORTATION <br />PROPER SHIPPING NAME: <br />HAZARD CLASS: <br />ID NUMBER: <br />PACKING GROUP:</p> <p>Amines, liquid, corrosive, n.o.s. (Polyamidoamine, Tetraethylenepentamine), Marine Pollutant <br />8 <br />UN2735 <br />III</p> <p>AIR TRANSPORTATION <br />PROPER SHIPPING NAME: <br />HAZARD CLASS: <br />ID NUMBER: <br />PACKING GROUP:</p> <p>Amines, liquid, corrosive, n.o.s. (Polyamidoamine, Tetraethylenepentamine), Marine Pollutant <br />8 <br />UN2735 <br />III</p> <p>SDS EPOXY-Gel Comp B <br />SDS DATE: 22-AUG-18</p> <p>www.aquafin.net</p> <p>Page 5 of 6</p> <p>EPOXY-Gel, Component B <br />Safety Data Sheet</p> <p>SECTION 15: REGULATORY INFORMATION <br />U.S. FEDERAL REGULATIONS <br />TSCA (TOXIC SUBSTANCE CONTROL ACT): <br />CERCLA (COMPREHENSIVE RESPONSE <br />COMPENSATION, AND LIABILITY ACT): <br />OSHA: <br />WHMIS</p> <p>xxxxxxxxxx <br />29 CFR 1910.1200 (Hazard Communication required) <br />XXXXXXXXXX</p> <p>SARA TITLE III (SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT): <br />XXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXX <br />302/304 <br />Acute Health Hazard: <br />Yes <br />311/312 HAZARD CATEGORIES: <br />Chronic Health Hazard: <br />Yes <br />Fire Hazard: <br />No <br />Pressure Release Hazard: <br />No <br />Reactivity Hazard: <br />No <br />Xxxxxxxxxx <br />313 REPORTABLE INGREDIENTS: <br />STATE REGULATIONS: <br />CALIFORNIA PROPOSITION 65 (THE SAFE DRINKING WATER AND TOXICS ENFORCEMENT ACT of 1986)</p> <p>This product does not contain known levels of any chemicals known to cause cancer or reproductive harm. <br />SECTION 16: OTHER INFORMATION <br />HAZARDOUS MATERIALS IDENTIFICATION SYSTEM <br />HMIS HAZARD RATING <br />HEALTH <br />2 <br />FLAMMABILITY <br />1 <br />REACTIVITY <br />1 <br />PERSONAL PROTECTION <br />C <br />4 – Severe, 3 – Serious, 2 – Moderate, 1 - Slight <br />C – (Safety glasses, gloves, apron) <br />The information provided herein was believed by Aquafin Inc. to be accurate at the time of preparation or prepared from sources <br />believed to be reliable, but it is the responsibility of the user to investigate and understand other pertinent sources of information, to comply <br />with all laws and procedures applicable to the safe handling and use of product and to determine the suitability of the product for its intended <br />use.</p> <p>SDS EPOXY-Gel Comp B <br />SDS DATE: 22-AUG-18</p> <p>www.aquafin.net</p> <p>Page 6 of 6</p>
